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1. 发明授权

US07479240B2 Boron oxide and related compounds for hydrogen storage 失效
标题翻译：用于储氢的氧化硼和相关化合物
公开(公告)号：US07479240B2
公开(公告)日：2009-01-20
申请号：US11271446
申请日：2005-11-09
申请人： Seung-Hoon Jhi , Young-Kyun Kwon , Keith Bradley , Jean-Christophe P. Gabriel
发明人： Seung-Hoon Jhi , Young-Kyun Kwon , Keith Bradley , Jean-Christophe P. Gabriel
IPC分类号： C09K3/00
CPC分类号： B01D53/02 , B01D2253/104 , B01D2253/106 , B01D2253/112 , B01D2253/306 , B01D2253/308 , B01D2256/16 , B01D2259/4525 , C01B3/001 , Y02E60/324
摘要： A hydrogen storage medium is provided, where the medium is comprised of boron oxide and closely related compounds such as orthoboric acid, metaboric acid, hydrated boric acid, and disodium borohydrate. The medium is substantially an amorphous glassy network, albeit with local regions of order, pores, and networks that provide surface area. Hydrogen is adsorbed by the medium with a heat of adsorption of about 9 kJ/mol to about 13 kJ/mol, a value which is higher than that of the heat of adsorption of hydrogen on carbon. The value for the heat of adsorption of hydrogen on the inventive storage medium is provided by computation, and corroborated by experimental observation. The higher heat of adsorption of the medium provides for operation at temperatures higher temperatures higher than those provided by carbon. Further provided are methods by which the storage medium can be prepared in such a form so as to permit high capacity hydrogen storage, as well as an apparatus, with the inventive medium disposed therein, for storing hydrogen.
摘要翻译：提供了一种储氢介质，其中介质由氧化硼和紧密相关的化合物如原硼酸，偏硼酸，水合硼酸和硼酸二钠组成。该介质基本上是非晶玻璃质网络，尽管有局部的顺序区域，孔隙和提供表面积的网络。氢气吸附在约9kJ / mol至约13kJ / mol的吸附热下，该值高于碳对碳的吸附热。通过计算提供了本发明储存介质上氢的吸附热值，并通过实验观察证实。介质吸收较高的热量在比碳提供的温度更高的温度下运行。还提供了存储介质可以以允许高容量氢存储的形式制备的方法，以及其中设置有本发明介质的装置，用于储存氢。

2. 发明授权

US06991773B2 Boron-oxide and related compounds for hydrogen storage 失效
标题翻译：用于氢存储的硼氧化物和相关化合物
公开(公告)号：US06991773B2
公开(公告)日：2006-01-31
申请号：US10267792
申请日：2002-10-08
申请人： Seung-Hoon Jhi , Young-Kyun Kwon , Keith Bradley , Jean-Christophe P. Gabriel
发明人： Seung-Hoon Jhi , Young-Kyun Kwon , Keith Bradley , Jean-Christophe P. Gabriel
IPC分类号： C01B3/04 , C09K3/00
CPC分类号： B01D53/02 , B01D2253/104 , B01D2253/106 , B01D2253/112 , B01D2253/306 , B01D2253/308 , B01D2256/16 , B01D2259/4525 , C01B3/001 , Y02E60/324
摘要： A hydrogen storage medium is provided, where the medium is comprised of boron oxide and closely related compounds such as orthoboric acid, metaboric acid, hydrated boric acid, and disodium borohydrate. The medium is substantially an amorphous glassy network, albeit with local regions of order, pores, and networks that provide surface area. Hydrogen is adsorbed by the medium with a heat of adsorption of about 9 kJ/mol to about 13 kJ/mol, a value which is higher than that of the heat of adsorption of hydrogen on carbon. The value for the heat of adsorption of hydrogen on the inventive storage medium is provided by computation, and corroborated by experimental observation. The higher heat of adsorption of the medium provides for operation at temperatures higher temperatures higher than those provided by carbon. Further provided are methods by which the storage medium can be prepared in such a form so as to permit high capacity hydrogen storage, as well as an apparatus, with the inventive medium disposed therein, for storing hydrogen.
摘要翻译：提供了一种储氢介质，其中介质由氧化硼和紧密相关的化合物如原硼酸，偏硼酸，水合硼酸和硼酸二钠组成。该介质基本上是非晶玻璃质网络，尽管有局部的顺序区域，孔隙和提供表面积的网络。氢气吸附在约9kJ / mol至约13kJ / mol的吸附热下，该值高于碳对碳的吸附热。通过计算提供了本发明储存介质上氢的吸附热值，并通过实验观察证实。介质吸收较高的热量在比碳提供的温度更高的温度下运行。还提供了存储介质可以以允许高容量氢存储的形式制备的方法，以及其中设置有本发明介质的装置，用于储存氢。

3. 发明授权

US06672077B1 Hydrogen storage in nanostructure with physisorption 有权
标题翻译：具有物理吸附的纳米结构中的氢储存
公开(公告)号：US06672077B1
公开(公告)日：2004-01-06
申请号：US10020392
申请日：2001-12-11
申请人： Keith Bradley , Philip G. Collins , Jean-Christophe P. Gabriel , Young-Kyun Kwon , Seung-Hoon Jhi , George Grüner
发明人： Keith Bradley , Philip G. Collins , Jean-Christophe P. Gabriel , Young-Kyun Kwon , Seung-Hoon Jhi , George Grüner
IPC分类号： F17C1100
CPC分类号： C01B3/001 , F17C11/005 , Y02E60/321 , Y02E60/324 , Y10S977/948
摘要： A hydrogen containing nanostructure is provided, where the hydrogen is adsorbed to the nanostructure by physisorption. The nanostructure includes light elements, selected from the second and third rows of the periodic table. The nanostructure is formed as a layered network of light elements coupled with covalent sp2 bonds. The chemical composition of the nanostructure can be such that the desorption temperature of hydrogen is greater than the liquefaction temperature of nitrogen, 77 K. Further, a hydrogen storage system is provided, including a container and a nanostructured storage material within the container, wherein the nanostructured storage material includes light elements, and the nanostructured storage material is capable of adsorbing hydrogen by physisorption. The hydrogen storage system can include a liquid nitrogen based cooling system, capable of cooling the nanostructured storage material below the desorption temperature of hydrogen. Some embodiments contain a heater to control the temperature of the nanostructured storage material.
摘要翻译：提供含氢的纳米结构，其中通过物理吸附将氢吸附到纳米结构。纳米结构包括选自周期表的第二行和第三行的光元件。纳米结构形成为与共价sp 2结合的光元件的分层网络。纳米结构的化学组成可以使得氢的解吸温度大于氮的液化温度（77K）。此外，提供了一种储氢系统，其包括容器内的容器和纳米结构的储存材料，其中纳米结构储存材料包括轻元素，纳米结构储存材料能够通过物理吸附吸附氢。氢存储系统可以包括液氮冷却系统，其能够将纳米结构的储存材料冷却至低于氢的解吸温度。一些实施例包含用于控制纳米结构存储材料的温度的加热器。

4. 发明授权

US07956525B2 Flexible nanostructure electronic devices 有权
标题翻译：柔性纳米结构电子器件
公开(公告)号：US07956525B2
公开(公告)日：2011-06-07
申请号：US10846072
申请日：2004-05-14
申请人： N. Peter Armitage , Keith Bradley , Jean-Christophe P. Gabriel , George Grüner
发明人： N. Peter Armitage , Keith Bradley , Jean-Christophe P. Gabriel , George Grüner
IPC分类号： H01J1/02
CPC分类号： H01B1/24 , B82Y10/00 , B82Y15/00 , H01L51/0048 , H01L51/0097 , H01L51/0595
摘要： A flexible electronic device is made up of nanostructures. Specifically, the device includes a flexible substrate, a film of nanostructures in contact with the flexible substrate, a first conducting element in contact with the film of nanostructures, and a second conducting element in contact with the film of nanostructures. The nanostructures may comprise nanotubes, such as carbon nanotubes disposed along the flexible substrate, such as an organic or polymer substrate. The first and second conductive elements may serve as electrical terminals, or as a source and drain. In addition, the electronic device may include a gate electrode that is in proximity to the nanotubes and not in electrical contact with the nanotubes. In this configuration, the device can operate as a transistor or a FET. The device may also be operated in a resistive mode as a chemical sensor (e.g., for sensing NH3).
摘要翻译：灵活的电子设备由纳米结构组成。具体地，该装置包括柔性基板，与柔性基板接触的纳米结构薄膜，与纳米结构薄膜接触的第一导电元件和与纳米结构薄膜接触的第二导电元件。纳米结构可以包括纳米管，例如沿着柔性基底设置的碳纳米管，例如有机或聚合物基底。第一和第二导电元件可以用作电端子，或用作源极和漏极。此外，电子器件可以包括位于纳米管附近并且不与纳米管电接触的栅电极。在这种配置中，器件可以作为晶体管或FET工作。该装置还可以作为化学传感器（例如，用于感测NH 3）以电阻模式操作。

5. 发明授权

US07575933B2 Modification of selectivity for sensing for nanostructure device arrays 失效
标题翻译：纳米结构器件阵列感测选择性的改进
公开(公告)号：US07575933B2
公开(公告)日：2009-08-18
申请号：US11139184
申请日：2005-05-27
申请人： Jean-Christophe P. Gabriel , Philip G. Collins , Keith Bradley , George Gruner
发明人： Jean-Christophe P. Gabriel , Philip G. Collins , Keith Bradley , George Gruner
IPC分类号： G01N21/00
CPC分类号： G01N27/127 , B01J2219/00653 , B01L3/5027 , B82Y15/00 , G01N27/126 , Y10S977/84 , Y10S977/855 , Y10S977/882 , Y10S977/92 , Y10S977/957 , Y10S977/958 , Y10T436/11
摘要： An electronic system for selectively detecting and identifying a plurality of chemical species, which comprises an array of nanostructure sensing devices, is disclosed. Within the array, there are at least two different selectivities for sensing among the nanostructure sensing devices. Methods for fabricating the electronic system are also disclosed. The methods involve modifying nanostructures within the devices to have different selectivity for sensing chemical species. Modification can involve chemical, electrochemical, and self-limiting point defect reactions. Reactants for these reactions can be supplied using a bath method or a chemical jet method. Methods for using the arrays of nanostructure sensing devices to detect and identify a plurality of chemical species are also provided. The methods involve comparing signals from nanostructure sensing devices that have not been exposed to the chemical species of interest with signals from nanostructure sensing devices that have been exposed to the chemical species of interest. Nanostructure sensing device array structures that can measure and subtract out environmental factors are also disclosed.
摘要翻译：公开了一种用于选择性地检测和识别包括纳米结构感测装置阵列的多种化学物质的电子系统。在阵列内，在纳米结构感测装置中有至少两种用于感测的不同选择性。还公开了用于制造电子系统的方法。这些方法包括修改装置内的纳米结构以具有感测化学物质的不同选择性。修饰可能涉及化学，电化学和自限制点缺陷反应。这些反应的反应物可以使用浴法或化学喷射法提供。还提供了使用纳米结构感测装置的阵列来检测和识别多种化学物种的方法。该方法涉及将未暴露于感兴趣的化学物质的纳米结构感测装置的信号与已经暴露于感兴趣的化学物质的纳米结构感测装置的信号进行比较。还公开了可以测量和减去环境因素的纳米结构感测装置阵列结构。

6. 发明授权

US06894359B2 Sensitivity control for nanotube sensors 有权
标题翻译：纳米管传感器的灵敏度控制
公开(公告)号：US06894359B2
公开(公告)日：2005-05-17
申请号：US10280265
申请日：2002-10-26
申请人： Keith Bradley , Philip G. Collins , Jean-Christophe P. Gabriel , George Gruner , Alexander Star
发明人： Keith Bradley , Philip G. Collins , Jean-Christophe P. Gabriel , George Gruner , Alexander Star
IPC分类号： G01N27/12 , G01N27/414 , H01L27/14 , H01L29/82 , H01L29/84
CPC分类号： B82Y15/00 , G01N27/129 , Y10S977/734
摘要： Nanostructure sensing devices for detecting an analyte are described. The devices include nanostructures connected to conductive elements, all on a substrate. Contact regions adjacent to points of contact between the nanostructures and the conductive elements are given special treatment. The proportion of nanostructure surface area within contact regions can be maximized to effect sensing at very low analyte concentrations. The contact regions can be passivated in an effort to prevent interaction between the environment and the contact regions for sensing at higher analyte concentrations and for reducing cross-sensing. Both contact regions and at least some portion of the nanostructures can be covered with a material that is at least partially permeable to the analyte of interest and impermeable to some other species to tune selectivity and sensitivity of the nanostructure sensing device.
摘要翻译：描述了用于检测分析物的纳米结构感测装置。这些器件包括连接到导电元件的纳米结构，全部在衬底上。给予与纳米结构和导电元件之间的接触点相邻的接触区域的特殊处理。可以使接触区域内的纳米结构表面积的比例最大化，以在非常低的分析物浓度下进行感测。可以钝化接触区域，以防止环境和接触区域之间的相互作用，以便在较高分析物浓度下进行感测并减少交叉感测。两个接触区域和纳米结构的至少一部分可以被对感兴趣的分析物至少部分可渗透的材料覆盖，并且对于一些其它物质是不可渗透的，以调节纳米结构感测装置的选择性和灵敏度。

7. 发明申请

US20130075794A1 NANO-ELECTRONIC SENSORS FOR CHEMICAL AND BIOLOGICAL ANALYTES, INCLUDING CAPACITANCE AND BIO-MEMBRANE DEVICES 审中-公开
标题翻译：用于化学和生物分析的纳电子传感器，包括电容和生物膜装置
公开(公告)号：US20130075794A1
公开(公告)日：2013-03-28
申请号：US13442856
申请日：2012-04-10
申请人： Keith Bradley , Ying-Lan Chang , Jean-Christophe P. Gabriel , John Loren Passmore , Sergei Skarupo , Eugene Tu , Christian Valcke
发明人： Keith Bradley , Ying-Lan Chang , Jean-Christophe P. Gabriel , John Loren Passmore , Sergei Skarupo , Eugene Tu , Christian Valcke
IPC分类号： G01N27/414
CPC分类号： G01N27/4146 , B82Y10/00 , B82Y15/00 , G01N27/4145 , H01L29/0665 , H01L29/0673 , Y10S977/742
摘要： Embodiments of nanoelectronic sensors are described, including sensors for detecting analytes inorganic gases, organic vapors, biomolecules, viruses and the like. A number of embodiments of capacitive sensors having alternative architectures are described. Particular examples include integrated cell membranes and membrane-like structures in nanoelectronic sensors.
摘要翻译：描述了纳米电子传感器的实施例，包括用于检测分析物无机气体，有机蒸气，生物分子，病毒等的传感器。描述了具有替代架构的电容传感器的许多实施例。具体实例包括纳米电子传感器中的集成细胞膜和膜状结构。

8. 发明申请

US20100047901A1 SYSTEM AND METHOD FOR ELECTRONIC SENSING OF BIOMOLECULES 审中-公开
标题翻译：电子感应生物分子的系统和方法
公开(公告)号：US20100047901A1
公开(公告)日：2010-02-25
申请号：US12607912
申请日：2009-10-28
申请人： Keith Bradley , Jean-Christophe P. Gabriel , George Grüner , Alexander Star , Eugene Tu , Christian Valcke
发明人： Keith Bradley , Jean-Christophe P. Gabriel , George Grüner , Alexander Star , Eugene Tu , Christian Valcke
IPC分类号： G01N33/53
CPC分类号： B82Y30/00 , B01L3/50857 , B01L2300/0636 , B01L2300/0663 , B01L2300/0819 , B01L2300/0851 , B01L2300/0893 , B01L2300/0896 , B01L2300/16 , B82Y10/00 , G01N33/5438 , G01N33/551 , G01N33/566 , G01N33/582
摘要： A nanoelectronic device is combined with a cellular membrane component to provide a sensor for biomolecules or to provide information about the structure of the membrane. The nanoelectronic device may comprise a network of randomly-oriented nanotubes, or other nanostructure, arranged on a substrate with adjacent electrodes so as to operate as a field-effect transistor sensor or as a capacitive sensor. A cellular membrane is disposed over the nanostructure element.
摘要翻译：纳米电子器件与细胞膜组件组合以提供用于生物分子的传感器或提供关于膜结构的信息。纳米电子器件可以包括布置在具有相邻电极的衬底上的随机取向的纳米管或其他纳米结构的网络，以便作为场效应晶体管传感器或电容式传感器工作。细胞膜设置在纳米结构元件上。

9. 发明申请

US20090101996A1 NANOSTRUCTURES WITH ELECTRODEPOSITED NANOPARTICLES 审中-公开
标题翻译：具有电沉积纳米颗粒的纳米结构
公开(公告)号：US20090101996A1
公开(公告)日：2009-04-23
申请号：US12268327
申请日：2008-11-10
申请人： Keith BRADLEY , Alona J. Davis , Jean-Christophe P. Gabriel , Tzong-Ru Han , Vikram Joshi , Alexander Star
发明人： Keith BRADLEY , Alona J. Davis , Jean-Christophe P. Gabriel , Tzong-Ru Han , Vikram Joshi , Alexander Star
IPC分类号： G01N27/403 , H01L21/288
CPC分类号： B82Y30/00 , C25D3/12 , C25D3/46 , C25D3/48 , C25D3/50 , C25D5/02 , C25D5/10 , C25D5/54 , C25D17/005 , C25D21/12 , G01N27/4146 , G01N33/005 , Y10S977/72
摘要： A nanoelectronic device includes a nanostructure, such as a nanotube or network of nanotube, disposed on a substrate. Nanoparticles are disposed on or adjacent to the nanostructure so as to operatively effect the electrical properties of the nanostructure. The nanoparticles may be composed of metals, metal oxides or salts and nanoparticles composed of different materials may be present. The amount of nanoparticles may be controlled to preserve semiconductive properties of the nanostructure, and the substrate immediately adjacent to the nanostructure may remain substantially free of nanoparticles. A method for fabricating the device includes electrodeposition of the nanoparticles using one of more solutions of dissolved ions while providing an electric current to the nanostructures but not to the surrounding substrate.
摘要翻译：纳米电子器件包括纳米结构，例如纳米管或纳米管网络，其设置在衬底上。将纳米颗粒设置在纳米结构上或与纳米结构相邻，以便有效地影响纳米结构的电性能。纳米颗粒可以由金属，金属氧化物或盐组成，并且可以存在由不同材料组成的纳米颗粒。可以控制纳米颗粒的量以保持纳米结构的半导体性质，并且紧邻纳米结构的衬底可以基本上不含纳米颗粒。制造该器件的方法包括使用溶解离子的更多溶液中的一种电解沉积纳米颗粒，同时向纳米结构提供电流，但不向周围衬底提供电流。

10. 发明授权

US09103775B2 Nano-electronic sensors for chemical and biological analytes, including capacitance and bio-membrane devices 有权
标题翻译：用于化学和生物分析物的纳米电子传感器，包括电容和生物膜装置
公开(公告)号：US09103775B2
公开(公告)日：2015-08-11
申请号：US13442856
申请日：2012-04-10
申请人： Keith Bradley , Ying-Lan Chang , Jean-Christophe P. Gabriel , John Loren Passmore , Sergei Skarupo , Eugene Tu , Christian Valcke
发明人： Keith Bradley , Ying-Lan Chang , Jean-Christophe P. Gabriel , John Loren Passmore , Sergei Skarupo , Eugene Tu , Christian Valcke
IPC分类号： H01L29/06 , G01N27/414 , B82Y10/00 , B82Y15/00
CPC分类号： G01N27/4146 , B82Y10/00 , B82Y15/00 , G01N27/4145 , H01L29/0665 , H01L29/0673 , Y10S977/742
摘要： Embodiments of nanoelectronic sensors are described, including sensors for detecting analytes inorganic gases, organic vapors, biomolecules, viruses and the like. A number of embodiments of capacitive sensors having alternative architectures are described. Particular examples include integrated cell membranes and membrane-like structures in nanoelectronic sensors.
摘要翻译：描述了纳米电子传感器的实施例，包括用于检测分析物的无机气体，有机蒸气，生物分子，病毒等的传感器。描述了具有替代架构的电容传感器的许多实施例。具体实例包括纳米电子传感器中的集成细胞膜和膜状结构。

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