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    • 1. 发明授权
    • Ni-based alloy improved in oxidation-resistance, high temperature strength and hot workability
    • Ni基合金的耐氧化性,耐高温性和热加工性提高
    • US06852177B2
    • 2005-02-08
    • US10322669
    • 2002-12-19
    • Satoshi KubotaToshihiro UeharaMotoi YamaguchiAkihiro Toji
    • Satoshi KubotaToshihiro UeharaMotoi YamaguchiAkihiro Toji
    • C22C19/05C22F1/10
    • C22C19/058C22C19/053C22C19/055C22C19/056C22F1/10
    • A nickel-based alloy is provided for provide parts and members of improved oxidation-resistance and high temperature strength for use in an oxidation atmosphere at high temperatures, such as automobile parts including an electrode for an ignition plug, power plant facility parts including a gas turbine nozzle, inner parts of heat treat furnaces, and fuel cell parts. The alloy improved in oxidation-resistance, high temperature strength and hot workability consists essentially of, in mass percentage, C: 0.003 to 0.1%, Si: 1.0% or less, Mn: 2.0% or less, Cr: 12 to 32%, Fe: 20% or less, Mg: 0.001 to 0.04%, at least one element, of not more than 2.5% in total, selected from the group consisting of Nb, Ta and V, impurity elements of S: 0.01% or less, but the ratio of the Mg-content to the S-content (Mg/S) being 1 or more, and Ti: 0 inclusive to 0.02%, and the rest being Ni and incidental impurities.
    • 提供了一种镍基合金,用于提供在高温下用于氧化气氛中的改善的耐氧化性和高温强度的部件和部件,例如包括用于火花塞的电极的汽车部件,包括气体的发电厂设备部件 涡轮喷嘴,热处理炉的内部部件和燃料电池部件。 该合金的耐氧化性,耐高温性和热加工性提高了质量百分比,基本上以C:0.003〜0.1%,Si:1.0%以下,Mn:2.0%以下,Cr:12〜32% Fe:20%以下,Mg:0.001〜0.04%,选自Nb,Ta和V中的至少一种不超过2.5%的元素,S:0.01%以下的杂质元素, 但Mg含量与S含量的比例(Mg / S)为1以上,Ti:0〜0.02%,其余为Ni及杂质。
    • 4. 发明授权
    • Steel for separators of solid-oxide type fuel cells
    • 用于固体氧化物型燃料电池分离器的钢
    • US06776956B2
    • 2004-08-17
    • US10132571
    • 2002-04-26
    • Toshihiro UeharaAkihiro TojiTakehiro Ohno
    • Toshihiro UeharaAkihiro TojiTakehiro Ohno
    • C22C3818
    • H01M8/0204C22C38/004C22C38/005C22C38/06C22C38/50H01M8/021H01M8/0228H01M8/0232
    • Provided is a steel for separators of solid-oxide type fuel cells, which forms oxide films having good electrical conductivity at 700 to 950° C. or so, has good oxidation resistance and, in particular, resistance to exfoliation even in the case of long hours of use, is excellent in impact properties at room temperature, shows a small difference in thermal expansion from the electrolyte, and is inexpensive. This steel for separators of solid-oxide fuel cells includes, by mass %, not more than 0.2% C, not more than 1.0% Si, not more than 1.0% Mn, not more than 2% Ni, 15 to 30% Cr, not more than 1% Al, one or more elements selected from the group of not more than 0.5% Y, not more than 0.2% REM and not more than 1% Zr, and the balance of Fe and unavoidable impurities. In this steel, amounts of S, O, N and B in the unavoidable impurities are restricted to not more than 0.015%, not more than 0.010%, not more than 0.050% and not more than 0.0050%, respectively, the following equation is satisfied: (0+2S)/(0.27Y+0.035Zr+0.16REM)≦2.0, Furthermore, in this steel, the hardness is not more than 280 HV and the average ferrite grain size number is not less than ASTM No. 2, which provides fine grains.
    • 本发明提供一种固体氧化物型燃料电池用隔板的钢,其形成在700〜950℃左右的导电性良好的氧化膜,具有良好的抗氧化性,特别是长时间耐剥离性 使用时间小,室温下的冲击性优异,与电解质的热膨胀差异小,成本低廉。 用于固体氧化物型燃料电池用隔板的钢中,以质量%计不超过0.2%C,1.0%以下的Si,1.0%以下的Mn,2%以下的Ni,15〜30%的Cr, 不大于1%的Al,选自不超过0.5%Y,不超过0.2%REM和不超过1%Zr的一种或多种元素,余量为Fe和不可避免的杂质。 在这种钢中,不可避免的杂质中的S,O,N和B的量分别限制在不大于0.015%,不大于0.010%,不大于0.050%和不大于0.0050%,下面的等式是 满意:此外,在该钢中,硬度为280HV以下,平均铁素体晶粒尺寸数不小于提供细晶粒的ASTM No.2。
    • 5. 发明授权
    • Heat resistant alloy for use as material of engine valve
    • 用作发动机阀门材料的耐热合金
    • US07481970B2
    • 2009-01-27
    • US11134329
    • 2005-05-23
    • Akihiro TojiToshihiro UeharaKatsuhiko TominagaShoichi NakayaKatsuaki Sato
    • Akihiro TojiToshihiro UeharaKatsuhiko TominagaShoichi NakayaKatsuaki Sato
    • C22C19/051
    • C22C19/051
    • A low cost, economical and less resource-consuming heat resistant alloy for use as material of engine valve is disclosed, while the alloy has excellent mechanical properties at high temperature and excellent toughness after heated for a long time that conventional heat resistant alloys have not had. The alloy consists essentially of, in mass percent, C of 0.01 to 0.15%, Si of 0.01 to 0.8%, Mn of 0.01 to 0.8, Cr of 14 to 17%, Mo of more than 3.0% but equal to or less than 5.0%, Al of 1.6 to 2.5%, Ti of 1.5 to 3.0%, Nb or Nb+Ta of 0.5 to 2.0%, Ni of 50 to 60%, B of 0.001 to 0.015%, at least one of Mg of 0.001 to 0.015% and Ca of 0.001 to 0.015%, and the balance being Fe, wherein value A defined by 0.293[Ni]−0.513[Cr]−1.814[Mo] is 2.0 to 5.8, value B defined by [Al]/([Al]+[Ti]+[Nb]+[Ta]) is 0.45 to 0.65, and value C defined by [Al]+[Ti]+[Nb]+[Ta] is 6.2 to 7.6, wherein brackets mean atomic % of each element in the alloy.
    • 公开了低成本,经济且耗资较少的用作发动机气门材料的耐热合金,同时合金在高温下具有优异的机械性能,并且在常规耐热合金没有加热之后长时间加热后具有优异的韧性 。 该合金基本上以质量%计含有0.01至0.15%的C,0.01至0.8%的Si,0.01至0.8的Mn,14至17%的Cr,大于3.0%但等于或小于5.0的Mo %,Al:1.6〜2.5%,Ti:1.5〜3.0%,Nb:Nb + Ta:0.5〜2.0%,Ni:50〜60%,B:0.001〜0.015%,Mg:0.001〜 %和Ca为0.001〜0.015%,余量为Fe,其中由0.293 [Ni] -0.513 [Cr] -1.814 [Mo]定义的值A为2.0〜5.8,由[Al] /([Al ] [Ti] + [Nb] + [Ta])为0.45〜0.65,由[Al] + [Ti] + [Nb] + [Ta]定义的值C为6.2〜7.6, 合金中的每个元素。
    • 6. 发明申请
    • Heat resistant alloy for use as material of engine valve
    • 用作发动机阀门材料的耐热合金
    • US20050265887A1
    • 2005-12-01
    • US11134329
    • 2005-05-23
    • Akihiro TojiToshihiro UeharaKatsuhiko TominagaShoichi NakayaKatsuaki Sato
    • Akihiro TojiToshihiro UeharaKatsuhiko TominagaShoichi NakayaKatsuaki Sato
    • C22C19/05
    • C22C19/051
    • A low cost, economical and less resource-consuming heat resistant alloy for use as material of engine valve is disclosed, while the alloy has excellent mechanical properties at high temperature and excellent toughness after heated for a long time that conventional heat resistant alloys have not had. The alloy consists essentially of, in mass percent, C of 0.01 to 0.15%, Si of 0.01 to 0.8%, Mn of 0.01 to 0.8, Cr of 14 to 17%, Mo of more than 3.0% but equal to or less than 5.0%, Al of 1.6 to 2.5%, Ti of 1.5 to 3.0%, Nb or Nb+Ta of 0.5 to 2.0%, Ni of 50 to 60%, B of 0.001 to 0.015%, at least one of Mg of 0.001 to 0.015% and Ca of 0.001 to 0.015%, and the balance being Fe, wherein value A defined by 0.293[Ni]−0.513[Cr]−1.814[Mo] is 2.0 to 5.8, value B defined by [Al]/([Al]+[Ti]+[Nb]+[Ta]) is 0.45 to 0.65, and value C defined by [Al]+[Ti]+[Nb]+[Ta] is 6.2 to 7.6, wherein brackets mean atomic % of each element in the alloy.
    • 公开了低成本,经济且耗资较少的用作发动机气门材料的耐热合金,同时合金在高温下具有优异的机械性能,并且在常规耐热合金没有加热之后长时间加热后具有优异的韧性 。 该合金基本上以质量%计含有0.01至0.15%的C,0.01至0.8%的Si,0.01至0.8的Mn,14至17%的Cr,大于3.0%但等于或小于5.0的Mo %,Al:1.6〜2.5%,Ti:1.5〜3.0%,Nb:Nb + Ta:0.5〜2.0%,Ni:50〜60%,B:0.001〜0.015%,Mg:0.001〜 %和Ca为0.001〜0.015%,余量为Fe,其中由0.293 [Ni] -0.513 [Cr] -1.814 [Mo]定义的值A为2.0〜5.8,由[Al] /([Al ] [Ti] + [Nb] + [Ta])为0.45〜0.65,由[Al] + [Ti] + [Nb] + [Ta]定义的值C为6.2〜7.6, 合金中的每个元素。
    • 8. 发明授权
    • Electrode material for electrode of spark plug
    • 火花塞电极用电极材料
    • US08915226B2
    • 2014-12-23
    • US13404290
    • 2012-02-24
    • Taiji YokoyamaToshihiro Uehara
    • Taiji YokoyamaToshihiro Uehara
    • H01T13/20H01T13/39
    • H01T13/39
    • An electrode material to be used for producing an earth electrode of a spark plug has a chemical composition of 0.3 to 3.0 mass % of Si, 0.01 to 0.3 mass % of one or more elements selected from the group consisting of Y and rare earth elements, not more than 0.5 mass % of Ti, not more than 1.2 mass % of Fe, and one or both of not more than 0.20 mass % of Ca and not more than 0.08 mass % of Mg. The electrode material further contains C, Mn, Cr, Al, N, S, a remainder Ni, and incidental impurities. In a total content of C, Mn, Cr, Al, N and S, C is not more than 0.1 mass %, Mn is less than 0.5 mass %, Cr is less than 0.5 mass %, Al is not more than 0.3 mass %, N is not more than 0.05 mass %, and S is not more than 0.03 mass %.
    • 用于制造火花塞的接地电极的电极材料的化学成分为Si的0.3〜3.0质量%,0.01〜0.3质量%的选自Y和稀土元素的一种以上的元素, 不大于0.5质量%的Ti,不超过1.2质量%的Fe,以及不大于0.20质量%的Ca和不超过0.08质量%的Mg中的一种或两种。 电极材料还含有C,Mn,Cr,Al,N,S,剩余的Ni和杂质。 在C,Mn,Cr,Al,N和S的总含量中,C不大于0.1质量%,Mn小于0.5质量%,Cr小于0.5质量%,Al不大于0.3质量% N为0.05质量%以下,S为0.03质量%以下。