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    • 2. 发明申请
    • METHOD FOR PRODUCING DIFLUOROPHOSPHATE
    • 二磷酸盐生产方法
    • US20160090306A1
    • 2016-03-31
    • US14419071
    • 2014-06-06
    • STELLA CHEMIFA CORPORATION
    • Sojiro KonTetsuo Nishida
    • C01B25/455
    • C01B25/455
    • Provided is a method for producing a difluorophosphate, which can simply and easily produce a high-purity difluorophosphate in an industrially advantageous manner. The method includes steps of: reacting an aqueous hydrofluoric acid solution with an oxyhalide of phosphorous (except phosphoric trifluoride) to produce a crude difluorophosphoric acid; reacting the crude difluorophosphoric acid with a halide of an alkali metal, an alkaline earth metal, aluminum or an onium to produce a difluorophosphate in the crude difluorophosphoric acid; and heating and drying the crude difluorophosphoric acid containing the difluorophosphate to distill away the crude difluorophosphoric acid, or precipitating the difluorophosphate in the crude difluorophosphoric acid by crystallization, subsequently separating the difluorophosphate by solid-liquid separation, and further distilling away the crude difluorophosphoric acid contained in the difluorophosphate after solid-liquid separation.
    • 本发明提供可以简单且容易地以工业上有利的方式制备高纯度二氟磷酸盐的二氟磷酸盐的制造方法。 该方法包括以下步骤:使氢氟酸水溶液与磷的卤氧化物(除了三氟化磷)反应以产生粗二氟磷酸; 使粗二氟磷酸与碱金属,碱土金属,铝或鎓的卤化物反应,在粗二氟磷酸中产生二氟磷酸盐; 并加热干燥含有二氟磷酸的粗二氟磷酸,蒸出粗二氟磷酸,或通过结晶沉淀粗二氟磷酸中的二氟磷酸盐,随后通过固液分离分离出二氟磷酸盐,进一步蒸馏除去含二氟磷酸的粗二氟磷酸 在固液分离后的二氟磷酸盐中。
    • 6. 发明授权
    • Method for producing difluorophosphate
    • 二氟磷酸盐生产方法
    • US09567217B2
    • 2017-02-14
    • US14419071
    • 2014-06-06
    • STELLA CHEMIFA CORPORATION
    • Sojiro KonTetsuo Nishida
    • C01B25/455
    • C01B25/455
    • Provided is a method for producing a difluorophosphate, which can simply and easily produce a high-purity difluorophosphate in an industrially advantageous manner. The method includes steps of: reacting an aqueous hydrofluoric acid solution with an oxyhalide of phosphorous (except phosphoric trifluoride) to produce a crude difluorophosphoric acid; reacting the crude difluorophosphoric acid with a halide of an alkali metal, an alkaline earth metal, aluminum or an onium to produce a difluorophosphate in the crude difluorophosphoric acid; and heating and drying the crude difluorophosphoric acid containing the difluorophosphate to distill away the crude difluorophosphoric acid, or precipitating the difluorophosphate in the crude difluorophosphoric acid by crystallization, subsequently separating the difluorophosphate by solid-liquid separation, and further distilling away the crude difluorophosphoric acid contained in the difluorophosphate after solid-liquid separation.
    • 本发明提供可以简单且容易地以工业上有利的方式制备高纯度二氟磷酸盐的二氟磷酸盐的制造方法。 该方法包括以下步骤:使氢氟酸水溶液与磷的卤氧化物(除了三氟化磷)反应以产生粗二氟磷酸; 使粗二氟磷酸与碱金属,碱土金属,铝或鎓的卤化物反应,在粗二氟磷酸中产生二氟磷酸盐; 并加热干燥含有二氟磷酸的粗二氟磷酸,蒸出粗二氟磷酸,或通过结晶沉淀粗二氟磷酸中的二氟磷酸盐,随后通过固 - 液分离分离二氟磷酸盐,进一步蒸馏除去含二氟磷酸的粗二氟磷酸 在固液分离后的二氟磷酸盐中。