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1. 发明授权

US09523008B2 Ink coating formulations and polymerizable systems for producing the same 有权
标题翻译：油墨涂料配方和用于生产它的可聚合体系
公开(公告)号：US09523008B2
公开(公告)日：2016-12-20
申请号：US14835189
申请日：2015-08-25
申请人： Sirrus, Inc.
发明人： Bernard M. Malofsky , Adam G. Malofsky , Matthew M. Ellison
IPC分类号： A61K6/00 , C08F2/44 , B22F1/00 , C08F2/46 , C08G61/04 , C09D11/02 , C09D11/101 , C09D11/322 , C09D11/037 , C09D4/00 , C09D11/106 , C08F222/14 , C08K3/04 , C08K3/22 , C08K5/23 , C08K5/3437 , C08K5/3467 , C09D11/107
CPC分类号： C09D4/00 , C08F222/14 , C08K3/04 , C08K3/22 , C08K5/23 , C08K5/3437 , C08K5/3467 , C08K2003/2241 , C09D11/02 , C09D11/037 , C09D11/101 , C09D11/106 , C09D11/107 , C09D11/322 , Y10T428/31935
摘要： Ink and coating compositions, printing and coating processes, and printed and coated substrates utilizing a polymerizable composition comprising one or more di-activated vinyl compounds, with the proviso that said a di-activated vinyl compound is not a cyanoacrylate. Exemplary compositions include methylene malonates, methylene β-ketoesters, methylene β-diketones, dialkyl disubstituted vinyls, and dihaloalkyl disubstituted vinyls. Exemplary compositions are polymerizable at ambient temperatures.
摘要翻译：使用包含一种或多种二活化乙烯基化合物的可聚合组合物的油墨和涂料组合物，印刷和涂布方法以及印刷和涂布的基材，条件是所述二活化乙烯基化合物不是氰基丙烯酸酯。示例性组合物包括丙二酸亚甲基酯，亚甲基β-酮酯，亚甲基β-二酮，二烷基二取代的乙烯基和二卤烷基二取代的乙烯基。示例性组合物在环境温度下是可聚合的。

2. 发明授权

US09969822B2 Multifunctional monomers, methods for making multifunctional monomers, polymerizable compositions and products formed therefrom 有权
公开(公告)号：US09969822B2
公开(公告)日：2018-05-15
申请号：US15289300
申请日：2016-10-10
申请人： SIRRUS INC.
发明人： Bernard M. Malofsky , Adam G. Malofsky , Tanmoy Dey , Larry Hines , Matthew M. Ellison
IPC分类号： C07C45/75 , C07C49/794 , C07C49/796 , C07C49/798 , C07C49/80 , C07C67/30 , C07C67/03 , C07C69/738 , C07D307/46 , C07D333/22 , C07D307/54 , C07D333/24 , C08F24/00 , C08F20/68 , C08F20/28 , C09J133/06 , C08F116/36 , C08F128/06 , C09D129/12 , C09D141/00 , C08F28/06 , C07C69/604 , C08F222/14 , C08F20/30 , C08F20/38 , C08F22/20 , C08K5/00 , C08L21/00 , C08L33/14 , C08L33/16 , C08L35/02 , C09D133/14 , C09D133/16 , C09D135/02 , C09J133/14 , C09J133/16 , C09J135/02 , C08F20/14 , C09D4/00 , C08F222/10
CPC分类号： C08F20/28 , C07C45/75 , C07C49/794 , C07C49/796 , C07C49/798 , C07C49/80 , C07C67/03 , C07C67/30 , C07C69/604 , C07C69/738 , C07D307/46 , C07D307/54 , C07D333/22 , C07D333/24 , C08F20/14 , C08F20/30 , C08F20/38 , C08F20/68 , C08F22/20 , C08F24/00 , C08F28/06 , C08F116/36 , C08F128/06 , C08F222/1006 , C08F222/14 , C08K3/013 , C08K5/0008 , C08L21/00 , C08L33/14 , C08L33/16 , C08L35/02 , C09D4/00 , C09D129/12 , C09D133/14 , C09D133/16 , C09D135/02 , C09D141/00 , C09J133/06 , C09J133/14 , C09J133/16 , C09J135/02 , Y02P20/127
摘要： The present invention provides multifunctional monomers, including, but not limited to include multifunctional methylene malonate and methylene beta-ketoester monomers; methods for producing the same; and compositions and products formed therefrom. The multifunctional monomers of the invention may be produced by transesterification or by direct synthesis from monofunctional methylene malonate monomers or methylene beta-ketoester monomers. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

3. 发明申请

US20170088715A1 INK COATING FORMULATIONS AND POLYMERIZABLE SYSTEMS FOR PRODUCING THE SAME 审中-公开
公开(公告)号：US20170088715A1
公开(公告)日：2017-03-30
申请号：US15377191
申请日：2016-12-13
申请人： Sirrus, Inc.
发明人： Bernard M. Malofsky , Adam G. Malofsky , Matthew M. Ellison
IPC分类号： C09D4/00 , C09D11/037 , C09D11/107
CPC分类号： C09D4/00 , C08F222/14 , C08K3/22 , C08K5/23 , C08K5/3437 , C08K5/3467 , C08K2003/2241 , C09D11/101 , C09D11/106 , C09D11/107 , C09D11/322 , Y10T428/31935
摘要： Ink and coating compositions, printing and coating processes, and printed and coated substrates utilizing a polymerizable composition comprising one or more di-activated vinyl compounds, with the proviso that said a di-activated vinyl compound is not a cyanoacrylate. Exemplary compositions include methylene malonates, methylene β-ketoesters, methylene β-diketones, dialkyl disubstituted vinyls, and dihaloalkyl disubstituted vinyls. Exemplary compositions are polymerizable at ambient temperatures.

4. 发明授权

US09181365B2 Methods for activating polymerizable compositions, polymerizable systems, and products formed thereby 有权
标题翻译：活化可聚合组合物，可聚合体系和由此形成的产品的方法
公开(公告)号：US09181365B2
公开(公告)日：2015-11-10
申请号：US14388624
申请日：2013-03-29
申请人： Sirrus, Inc.
发明人： Bernard M. Malofsky , Adam G. Malofsky , Matthew M. Ellison , Stanley C. Wojciak
IPC分类号： C08F2/00 , C08F4/00 , C08F4/12 , C08F22/10 , C08F22/14 , C08F2/38
CPC分类号： C08F22/14 , C08F2/38
摘要： The exemplary embodiments disclosed herein relate to activating methods for initiation polymerization of methylene malonates and other polymerizable compositions. The polymerization may be activated by anionic or free radical mechanisms. Because the polymerization may occur very quickly upon contact between the activating agent and the polymerizable composition, methods are provide herein for separating or otherwise rendering the activating agent ineffective to initiate polymerization, until such a reaction is desired. The separation may be physical (separate packaging, separate application steps, encapsulation) or it may be based on latent-activation methods (activation precursors, UV activation). Products formed from the methods disclosed herein may include inks, adhesives, coatings, sealants, reactive moldings, fibers, films, sheets, medical polymers, composites, laminates and the like. Exemplary polymerizable compositions and products formed therefrom are environmentally sustainable, environmentally benign and/or biologically benign.
摘要翻译：本文公开的示例性实施方案涉及丙烯酸亚甲酯和其它可聚合组合物的起始聚合的活化方法。聚合可以通过阴离子或自由基机制来活化。因为在活化剂和可聚合组合物接触之后聚合可能非常快地发生，因此本文提供了分离或以其它方式使活化剂无效引发聚合的方法，直到需要这种反应。分离可以是物理的（单独的包装，单独的施加步骤，包封），或者它可以基于潜活化方法（活化前体，UV活化）。由本文公开的方法形成的产品可以包括油墨，粘合剂，涂料，密封剂，反应性模塑品，纤维，薄膜，片材，医用聚合物，复合材料，层压材料等。示例性的可聚合组合物和由其形成的产品是环境可持续的，环境友好的和/或生物学良性的。

5. 发明申请

US20210179892A1 COMPOSITE AND LAMINATE ARTICLES AND POLYMERIZABLE SYSTEMS FOR PRODUCING THE SAME 有权
公开(公告)号：US20210179892A1
公开(公告)日：2021-06-17
申请号：US17169119
申请日：2021-02-05
申请人： Sirrus, Inc.
发明人： Bernard M. Malofsky , Adam G. Malofsky , Matthew M. Ellison
IPC分类号： C09J4/00 , B32B27/28 , B32B29/00 , B32B15/18 , B32B7/12 , B32B15/20 , B32B5/24 , B32B15/04 , B32B27/36 , B32B27/32 , B32B21/04 , C09J5/00 , C08F122/14 , C08F20/36 , C08J3/24 , C08F222/14 , C08F20/28 , C08J5/24 , C08K3/22 , C08K3/36 , C08K7/06 , C08K7/14 , C09J11/04 , C09J11/08
摘要： A composite material comprises a reinforcing material carried in a polymer matrix material which is the polymerization product of a polymerizable composition comprising a di-activated vinyl compound, with the proviso that the di-activated vinyl compound is not a cyanoacrylate. The reinforcing materials may be a wide variety of substrates including thermally sensitive materials. Exemplary composites can be molded and cured at ambient temperatures. Also disclosed are laminate materials having layered materials adhered by curing a di-activated vinyl polymerizable composition.

6. 发明申请

US20190315892A1 POLYMERS INCLUDING A METHYLENE BETA-KETOESTER AND PRODUCTS FORMED THEREFROM 审中-公开
公开(公告)号：US20190315892A1
公开(公告)日：2019-10-17
申请号：US16455040
申请日：2019-06-27
申请人： Sirrus, Inc.
发明人： Bernard M. Malofsky , Adam G. Malofsky , Tanmoy Dey , Jeffrey M. Sullivan
IPC分类号： C08F20/28 , C08F24/00 , C07C67/333 , C07D333/24 , C09D129/12 , C08F128/06 , C08F116/36 , C07D333/22 , C09D141/00 , C07D307/46 , C09J133/06 , C08F20/68 , C07C67/343 , C08F20/14 , C09D4/00 , C09J4/00 , C08K3/013 , C08K5/00 , C07C67/30 , C07C49/80 , C09J133/16 , C09J135/02 , C09D135/02 , C09D133/16 , C09D133/14 , C08F20/30 , C07C69/738 , C08F28/06 , C08F222/14 , C08L35/02 , C08L33/16 , C08L33/14 , C08L21/00 , C08F22/20 , C08F20/38 , C07D307/54 , C09J133/14 , C07C45/75 , C07C49/798 , C07C49/796 , C07C49/794 , C07C67/03 , C07C69/604
摘要： The present teachings are directed at 1,1-di substituted alkene monomers (e.g., methylene beta-ketoester monomers), methods for producing the same, polymerizable compositions including a methylene beta-ketoester monomer, and polymers, compositions and products formed therefrom. The monomer preferably is a high purity monomer. In the method for producing the methylene beta-ketoesters of the invention, a beta-ketoester may be reacted with a source of formaldehyde. The methylene beta-ketoester monomers may be used in monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

7. 发明申请

US20180346615A1 MULTIFUNCTIONAL MONOMERS, METHODS FOR MAKING MULTIFUNCTIONAL MONOMERS, POLYMERIZABLE COMPOSITIONS AND PRODUCTS FORMED THEREFORM 审中-公开
公开(公告)号：US20180346615A1
公开(公告)日：2018-12-06
申请号：US15978923
申请日：2018-05-14
申请人： Sirrus, Inc.
发明人： Bernard M. Malofsky , Adam G. Malofsky , Tanmoy Dey , Matthew M. Ellison , Larry Hines
IPC分类号： C08F20/28 , C09D4/00 , C07D307/54 , C08K3/013 , C08F20/14 , C09J133/14 , C08F20/30 , C08F20/38 , C08F22/20 , C08K5/00 , C08L21/00 , C08L33/14 , C08L33/16 , C08L35/02 , C09D133/14 , C09D135/02 , C09J135/02 , C09J133/16 , C09D133/16 , C07C49/80 , C07C67/03 , C07C69/604
CPC分类号： C08F20/28 , C07C45/75 , C07C49/794 , C07C49/796 , C07C49/798 , C07C49/80 , C07C67/03 , C07C67/30 , C07C69/604 , C07C69/738 , C07D307/46 , C07D307/54 , C07D333/22 , C07D333/24 , C08F20/14 , C08F20/30 , C08F20/38 , C08F20/68 , C08F22/20 , C08F24/00 , C08F28/06 , C08F116/36 , C08F128/06 , C08F222/1006 , C08F222/14 , C08K3/013 , C08K5/0008 , C08L21/00 , C08L33/14 , C08L33/16 , C08L35/02 , C09D4/00 , C09D129/12 , C09D133/14 , C09D133/16 , C09D135/02 , C09D141/00 , C09J133/06 , C09J133/14 , C09J133/16 , C09J135/02 , Y02P20/127
摘要： The present invention provides multifunctional monomers, including, but not limited to include multifunctional methylene malonate and methylene beta-ketoester monomers; methods for producing the same; and compositions and products formed therefrom. The multifunctional monomers of the invention may be produced by transesterification or by direct synthesis from monofunctional methylene malonate monomers or methylene beta-ketoester monomers. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

8. 发明申请

US20170355789A1 POLYMERS INCLUDING A METHYLENE BETA-KETOESTER AND PRODUCTS FORMED THEREFROM 审中-公开
公开(公告)号：US20170355789A1
公开(公告)日：2017-12-14
申请号：US15661893
申请日：2017-07-27
申请人： SIRRUS, INC.
发明人： Bernard M. Malofsky , Adam G. Malofsky , Tanmoy Dey , Jeffrey M. Sullivan
IPC分类号： C08F20/28 , C09D135/02 , C07C67/30 , C08L33/14 , C08F24/00 , C08F20/68 , C07C69/604 , C09J133/16 , C07C49/794 , C09D133/16 , C08F20/38 , C07C49/80 , C08F20/30 , C07D307/54 , C08K3/00 , C08K5/00 , C08F128/06 , C07C49/798 , C07D333/22 , C07C49/796 , C09J133/06 , C07C69/738 , C07C67/03 , C09J133/14 , C07C45/75 , C08F28/06 , C09D141/00 , C09D129/12 , C08F116/36 , C08L21/00 , C08F22/20 , C07D307/46 , C08L33/16 , C08L35/02 , C09J135/02 , C07D333/24 , C09D133/14 , C08F222/14 , C08F222/10
CPC分类号： C08F20/28 , C07C45/75 , C07C49/794 , C07C49/796 , C07C49/798 , C07C49/80 , C07C67/03 , C07C67/30 , C07C67/333 , C07C67/343 , C07C69/604 , C07C69/738 , C07C2601/02 , C07C2601/04 , C07C2601/08 , C07C2601/14 , C07D307/46 , C07D307/54 , C07D333/22 , C07D333/24 , C08F20/14 , C08F20/30 , C08F20/38 , C08F20/68 , C08F22/20 , C08F24/00 , C08F28/06 , C08F116/36 , C08F128/06 , C08F222/1006 , C08F222/14 , C08K3/013 , C08K5/0008 , C08K5/005 , C08K5/08 , C08K5/13 , C08L21/00 , C08L33/14 , C08L33/16 , C08L35/02 , C09D4/00 , C09D129/12 , C09D133/14 , C09D133/16 , C09D135/02 , C09D141/00 , C09J4/00 , C09J133/06 , C09J133/14 , C09J133/16 , C09J135/02 , Y02P20/127 , C07C69/716
摘要： The present teachings are directed at 1,1-disubstituted alkene monomers (e.g., methylene beta-ketoester monomers), methods for producing the same, polymerizable compositions including a methylene beta-ketoester monomer, and polymers, compositions and products formed therefrom. The monomer preferably is a high purity monomer. In the method for producing the methylene beta-ketoesters of the invention, a beta-ketoester may be reacted with a source of formaldehyde. The methylene beta-ketoester monomers may be used in monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

9. 发明授权

US09828324B2 Methylene beta-diketone monomers, methods for making methylene beta-diketone monomers, polymerizable compositions and products formed therefrom 有权
公开(公告)号：US09828324B2
公开(公告)日：2017-11-28
申请号：US14868795
申请日：2015-09-29
申请人： Sirrus, Inc.
发明人： Jeffrey M. Sullivan , Adam G. Malofsky , Bernard M. Malofsky , Tanmoy Dey
IPC分类号： C07C45/00 , C07C49/00 , C08L27/12 , B03D1/016 , C08F214/06 , C08L27/00 , C07C49/84 , C07C45/75 , C07C49/203 , C07C49/794 , C07C49/796 , C07D333/22 , C07C49/557 , C07C49/227 , C07D307/46 , C07C49/80
CPC分类号： C07C49/84 , C07C45/75 , C07C49/203 , C07C49/227 , C07C49/557 , C07C49/794 , C07C49/796 , C07C49/80 , C07C2601/14 , C07D307/46 , C07D333/22
摘要： The present teachings are directed at 1,1-disubstituted alkene monomers (e.g., methylene beta-diketone monomers), methods for producing the same, and compositions and products formed therefrom. In the method for producing the monomer, a beta-diketone is preferably reacted with a source of formaldehyde in a modified Knoevenagel reaction optionally in the presence of an acidic or basic catalyst, and optionally in the presence of an acidic or non-acidic solvent, to form reaction complex. The reaction complex may be an oligomeric complex. The reaction complex is subjected to vaporization in order to isolate the monomer. The monomer(s) may be employed in compositions and products, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).

10. 发明授权

US09512058B2 Multifunctional monomers, methods for making multifunctional monomers, polymerizable compostions and products formed thereform 有权
标题翻译：多功能单体，制备多官能单体的方法，可聚合组合物和形成的产品
公开(公告)号：US09512058B2
公开(公告)日：2016-12-06
申请号：US14352356
申请日：2012-10-18
申请人： Sirrus, Inc.
发明人： Bernard M. Malofsky , Adam G. Malofsky , Tanmoy Dey , Larry Hines , Matthew M. Ellison
IPC分类号： C07C67/03 , C09J133/06 , C07C45/75 , C07C49/794 , C07C49/798 , C07C49/80 , C07D307/46 , C07C69/604 , C07C49/796 , C07D333/22 , C08F116/36 , C08F128/06 , C09D129/12 , C09D141/00 , C07C67/30 , C07C69/738 , C07D307/54 , C07D333/24 , C08F20/28 , C08F20/68 , C08F24/00 , C08F28/06 , C08F222/14 , C08F222/10
CPC分类号： C08F20/28 , C07C45/75 , C07C49/794 , C07C49/796 , C07C49/798 , C07C49/80 , C07C67/03 , C07C67/30 , C07C69/604 , C07C69/738 , C07D307/46 , C07D307/54 , C07D333/22 , C07D333/24 , C08F20/14 , C08F20/30 , C08F20/38 , C08F20/68 , C08F22/20 , C08F24/00 , C08F28/06 , C08F116/36 , C08F128/06 , C08F222/1006 , C08F222/14 , C08K3/013 , C08K5/0008 , C08L21/00 , C08L33/14 , C08L33/16 , C08L35/02 , C09D4/00 , C09D129/12 , C09D133/14 , C09D133/16 , C09D135/02 , C09D141/00 , C09J133/06 , C09J133/14 , C09J133/16 , C09J135/02 , Y02P20/127
摘要： The present invention provides multifunctional monomers, including, but not limited to include multifunctional methylene malonate and methylene beta-ketoester monomers; methods for producing the same; and compositions and products formed therefrom. The multifunctional monomers of the invention may be produced by transesterification or by direct synthesis from monofunctional methylene malonate monomers or methylene beta-ketoester monomers. The present invention further compositions and products formed from methylene beta-ketoester monomers of the invention, including monomer-based products (e.g., inks, adhesives, coatings, sealants or reactive molding) and polymer-based products (e.g., fibers, films, sheets, medical polymers, composite polymers and surfactants).
摘要翻译：本发明提供多官能单体，包括但不限于多官能亚甲基丙二酸酯和亚甲基β-酮酯单体; 生产方法; 以及由其形成的组合物和产品。本发明的多官能单体可以通过酯交换反应或通过直接合成由单官能亚甲基丙二酸酯单体或亚甲基β-酮酯单体制备。本发明还包括由本发明的亚甲基β-酮酯单体形成的组合物和产品，包括基于单体的产品（例如油墨，粘合剂，涂料，密封剂或反应性模塑）和基于聚合物的产品（例如纤维，薄膜，片材，医用聚合物，复合聚合物和表面活性剂）。

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