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    • 1. 发明授权
    • Fractal structured nanoagglomerates as filter media
    • 分形结构纳米粒子作为过滤介质
    • US07645327B2
    • 2010-01-12
    • US11416034
    • 2006-05-02
    • Robert PfefferRajesh DaveStanislav DukhinJose A. QuevedoQun Yu
    • Robert PfefferRajesh DaveStanislav DukhinJose A. QuevedoQun Yu
    • B01D29/02
    • B01D46/30B01D39/04B01D46/003B01D2239/0258B01D2279/51Y10S977/773Y10S977/775Y10S977/776Y10S977/777Y10S977/778
    • Systems and methods for achieving filtration are provided that utilize agglomerates or granules of nanoparticles. The agglomerates or granules of nanoparticles may be used as and/or incorporated into a HEPA filtration system to remove solid or liquid submicron-sized particles, e.g., MPPS, in an efficient and efficacious manner. The filtration systems and methods are provided that utilize agglomerates or granules in a size range of about 100-500 microns. The agglomerates or granules of nanoparticles exhibit a hierarchical fractal structure. In the case of agglomerates of nanoparticles, porosities of 0.9 or greater are generally employed, and for granules of nanoparticles, porosities that are smaller than 0.9 may be employed. Filter media formed from the agglomerates or granules may be formed from materials such as carbon black and fumed silica, and may be employed in baffled or non-baffled filtration apparatus.
    • 提供用于实现过滤的系统和方法,其利用纳米颗粒的附聚物或颗粒。 纳米颗粒的附聚物或颗粒可以用作和/或并入HEPA过滤系统中以有效和有效的方式除去固体或液体亚微米尺寸的颗粒,例如MPPS。 提供了使用约100-500微米尺寸范围内的附聚物或颗粒的过滤系统和方法。 纳米颗粒的团聚体或颗粒呈现分层结构。 在纳米颗粒附聚物的情况下,通常使用0.9或更大的孔隙率,并且对于纳米颗粒的颗粒,可以使用小于0.9的孔隙率。 由附聚物或颗粒形成的过滤介质可以由诸如炭黑和煅制二氧化硅的材料形成,并且可以用于挡板或非挡板过滤装置中。
    • 5. 发明申请
    • System and method for nanoparticle and nanoagglomerate fluidization
    • 纳米颗粒和纳米颗粒流化的系统和方法
    • US20060086834A1
    • 2006-04-27
    • US10900868
    • 2004-07-27
    • Robert PfefferCaroline NamRajesh DaveGuangliang LiuJose QuevedoQun YuChao Zhu
    • Robert PfefferCaroline NamRajesh DaveGuangliang LiuJose QuevedoQun YuChao Zhu
    • B02C19/06
    • B01F13/0809B01F11/0266B01F13/0255B01J8/1872B01J8/40B01J8/42B01J19/10B01J2208/00681B82Y15/00
    • With the coupling of an external field and aeration (or a flow of another gas), nanoparticles can be smoothly and vigorously fluidized. Multiple external fields and/or pre-treatment may be employed with the fluidizing gas: sieving, magnetic assistance, vibration, acoustic/sound or rotational/centrifugal forces. Any of these forces, either alone or in combination, when coupled with a fluidizing medium, provide excellent means for achieving homogenous nanofluidization. The additional force(s) help to break channels as well as provide enough energy to disrupt the strong interparticle forces, thereby establishing an advantageous agglomerate size distribution. Enhanced fluidization is reflected by at least one of the following performance-related attributes: reduced levels of bubbles within the fluidized system, reduced gas bypass relative to the fluidized bed, smooth fluidization behavior, reduced elutriation, a high level of bed expansion, reduced gas velocity levels to achieve desired fluidization performance, and/or enhanced control of agglomerate size/distribution. The fluidized nanoparticles may be coated, surface-treated and/or surface-modified in the fluidized state. In addition, the fluidized nanoparticles may participate in a reaction, either as a reactant or a catalyst, while in the fluidized state.
    • 通过外场和通气(或另一种气体的流动)的耦合,纳米颗粒可以顺利且剧烈流化。 多种外部场和/或预处理可以与流化气体一起使用:筛分,磁辅助,振动,声/声或旋转/离心力。 当与流化介质结合时,单独或组合的这些力中的任何一个提供了实现均匀纳米流化的极好手段。 额外的力有助于破坏通道,并提供足够的能量来破坏强大的颗粒间力,从而建立有利的团聚体尺寸分布。 增强的流化反应由以下性能相关属性中的至少一个反映:流化系统内的气泡水平降低,相对于流化床的气体旁路减少,流化性能平稳,淘汰率降低,床膨胀高度降低 速度水平以实现期望的流化性能,和/或增强聚集体尺寸/分布的控制。 流化的纳米颗粒可以在流化状态下被涂覆,表面处理和/或表面改性。 此外,流化的纳米颗粒可以在流化状态下作为反应物或催化剂参与反应。
    • 9. 发明授权
    • Radiation-curable organopolysiloxane release compositions
    • 可辐射固化的有机聚硅氧烷释放组合物
    • US5616629A
    • 1997-04-01
    • US394726
    • 1995-02-27
    • Thanh V. NguyenJohn AllenQun Yu
    • Thanh V. NguyenJohn AllenQun Yu
    • C08F2/50C08F290/06C09D183/06C09J7/04C08L83/06C08L83/07
    • C09J7/045C08F290/068C09D183/06C09J7/0228C09J2205/114C09J2205/31C09J2400/226C09J2400/263C09J2400/283C09J2433/005C09J2483/005
    • A radiation-curable release composition is disclosed which comprises:(A) an organopolysiloxane represented by the formulaRSi(CH.sub.3).sub.2 --O--(Si(CH.sub.3).sub.2 O).sub.n (Si(CH.sub.3)(R)O).sub.m Si(CH.sub.3).sub.2 R (I) wherein in Formula (I), each R is --R.sup.1 --O(O)C--C(R.sup.2).dbd.CH.sub.2, --R.sup.1 --O--C(R.sup.2).dbd.CH.sub.2 or is derived from an organic molecule containing both ethylenic unsaturation and epoxide functionality; R.sup.1 is a hydrocarbylene group; each R.sup.2 is independently hydrogen or a methyl or ethyl group; m is a number from about 1 to about 15; and n is a number from about 50 to about 300; and(B) an organosiloxane copolymer represented by the formula(R.sub.3 SiO).sub.x (SiO.sub.4/2).sub.y (II) wherein in Formula (II), each R is independently a hydrocarbon group or a group represented by the formula--O(O)C--C(R*).dbd.CH.sub.2 wherein R* is hydrogen or a methyl or ethyl group; x is a number from about 0.25 to about 75; y is a number from about 1 to about 56; and the ratio of x to y is from about 0.3:1 to about 1.5. In one embodiment, the inventive release composition further comprises(C) an acrylate represented by the formulaCH.sub.2 .dbd.C(R**)--C(O)O--R.sup.2 (III) wherein in Formula (III), R** is hydrogen or a methyl or ethyl group, and R.sup.2 is a hydrocarbon group of about 10 to about 24 carbon atoms. A method of producing release-coated substrates, the release-crated articles thus produced, and multi-layer articles or constructions incorporating a release layer also are disclosed. When the release compositions are cured such as by radiation, the cured compositions exhibit a desirable high and controlled release force at high speeds such as the speeds utilized in label processing.
    • 公开了一种可辐射固化的剥离组合物,其包括:(A)由式RSi(CH 3)2 -O-(Si(CH 3)2 O)n(Si(CH 3)(R)O)m Si(CH 3)2 R (I)其中在式(I)中,每个R是-R1-O(O)CC(R2)= CH2,-R1-OC(R2)= CH2或衍生自含有烯属不饱和键和环氧官能团的有机分子 ; R1是亚烃基; 每个R 2独立地是氢或甲基或乙基; m为约1至约15的数; n为约50至约300的数; 和(B)由式(R3SiO)x(SiO4 / 2)y(II)表示的有机硅氧烷共聚物,其中在式(II)中,各R独立地为烃基或由式-O(O) CC(R *)= CH 2,其中R *是氢或甲基或乙基; x为约0.25至约75的数; y是约1至约56的数; 并且x与y的比率为约0.3:1至约1.5。 在一个实施方案中,本发明的释放组合物还包含(C)由式CH 2 = C(R **)-C(O)O-R 2(III)表示的丙烯酸酯,其中在式(III)中,R **是氢或 甲基或乙基,R 2为约10至约24个碳原子的烃基。 公开了一种制备剥离涂层基材的方法,如此制备的剥离制品,以及结合有剥离层的多层制品或结构。 当释放组合物例如通过辐射固化时,固化的组合物在高速下表现出期望的高且受控的释放力,例如在标签处理中使用的速度。