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    • 1. 发明授权
    • Method for recovering methanol solvent
    • 甲醇溶剂回收方法
    • US5395994A
    • 1995-03-07
    • US245949
    • 1994-05-19
    • Robert E. WilliamsWilliam J. Cranston, III
    • Robert E. WilliamsWilliam J. Cranston, III
    • C07C29/80C07C37/62C07C39/367C07C27/26C07C29/74C07C37/68
    • C07C29/80C07C37/62
    • This invention provides an environmentally acceptable method for recovery of phenolic and brominated phenolic compounds, alcohol solvent, and bromide values from the a reaction medium liquid mixture formed in the production of a tetrabromobisphenol-A predominant product. The process comprises (a) separating the tetrabromobisphenol-A predominant product and alkyl bromide from the reaction medium thereby forming a liquid mixture containing alcohol, phenolic and brominated phenolic compounds, HBr, and water; (b) treating the liquid mixture with a sufficient amount of alkaline or alkaline earth metal hydroxide so as to form a treated aqueous mixture having a pH in the range of from about 9.5 to about 14.0, and containing MBr.sub.n, water, alcohol, and soluble salts of the phenolic and brominated phenolic compounds, wherein M is an alkaline or alkaline earth metal ion, and n is the valence of M; (c) distilling alcohol from the treated aqueous mixture of (b); (d) acidifying the treated aqueous mixture from (c) subsequent to distillation with a sufficient amount of acid to precipitate the phenolic and brominated phenolic compounds therefrom; and (e) separating the precipitated phenolic and brominated phenolic compounds from the acidified aqueous mixture of (d).
    • 本发明提供了一种用于从生产四溴双酚A主要产物中形成的反应介质液体混合物回收酚类和溴化酚类化合物,醇溶剂和溴化物值的环境可接受的方法。 该方法包括(a)从反应介质中分离出四溴双酚A主要产物和烷基溴,从而形成含有醇,酚和溴化酚化合物HBr和水的液体混合物; (b)用足量的碱金属或碱土金属氢氧化物处理液体混合物,以形成pH在约9.5至约14.0范围内的处理过的水性混合物,并含有MBrn,水,醇和可溶的 酚类和溴化酚类化合物的盐,其中M是碱金属或碱土金属离子,n是M的化合价; (c)从经处理的(b)水混合物中蒸馏出醇; (d)用(c)在蒸馏后用足够量的酸酸化经处理的含水混合物以从其中沉淀酚类和溴化酚类化合物; 和(e)从(d)的酸化含水混合物中分离出沉淀的酚类和溴化酚类化合物。
    • 3. 发明授权
    • Enhanced monitoring device for surgical gloves and other barriers
    • 增强的手术手套监护装置及其他障碍
    • US5389097A
    • 1995-02-14
    • US277984
    • 1994-06-22
    • John K. BennettMark MaxhamWilliam H. MarshallRobert E. Williams
    • John K. BennettMark MaxhamWilliam H. MarshallRobert E. Williams
    • A61B19/04G01M3/18G01M3/40A61B17/36
    • G01M3/40A61B42/30G01M3/187
    • A monitoring device for detecting adulteration of an article used in critical use applications such as a surgical glove where the gloves are worn by the surgeon and are exposed to the body fluids of a patient. The device includes the detection of a particular value of electrical condition, preferably resistance or impedance, as well as the first and second derivatives of electrical condition. These values are monitored in a substantially continuous manner and are smoothed and filtered to determine when a hole or thin spot in the glove occurs. In addition, the device includes an autoranging function which maintains the measured voltage in a prescribed range, thus allowing the device to operate at a higher level of accuracy for a greater period of time than a device without the feature. Also, the device warns the health care professional when the electrical properties of the gloves have degraded to a point where the device may no longer reliably detect holes in the gloves.
    • 一种监测装置,用于检测用于临界使用应用中的制品的掺假,所述关键用途应用例如手术手套,其中手套由外科医生佩戴并暴露于患者的体液。 该装置包括检测电气条件的特定值,优选电阻或阻抗,以及电气条件的第一和第二导数。 以基本连续的方式监测这些值,并对其进行平滑和过滤,以确定手套中的孔或薄点何时发生。 此外,该装置还包括一个自动量程功能,它将测量的电压维持在规定的范围内,从而允许器件在比没有特征的器件更长的时间内以更高的精度工作。 此外,当手套的电气性能降低到设备不再可靠地检测手套中的孔的时候,该装置警告保健专业人员。
    • 6. 发明授权
    • Apparatus and method for removing and recovering oil and/or other
oil-based drilling mud additives from drill cuttings
    • 从钻屑中去除和回收油和/或其他油基钻井泥浆添加剂的装置和方法
    • US4836302A
    • 1989-06-06
    • US104838
    • 1987-10-05
    • Joe K. HeilheckerRobert E. WilliamsWilliam H. Marshall
    • Joe K. HeilheckerRobert E. WilliamsWilliam H. Marshall
    • B01D11/04B01D11/02C09K8/02E21B21/06E21B41/00
    • E21B41/005B01D11/028B09B3/0091E21B21/066
    • Method and apparatus for removing oil-based drilling mud from drill cuttings in order to prepare the drill cuttings for an environmentally safe disposal in the sea. A solvent in the range of solvents which may be condensed by ambient seawater and vaporized by heated internal combustion engine coolant is utilized in the process. The method of this invention includes the steps of transporting oil-based mud-laden cuttings to a solid feed tank wherein the oil-based cuttings are subjected to turbulent mixing to leave the surface of the cuttings substantially free of oil. The cuttings are then transported to a countercurrent flow column and subjected to countercurrent, laminar flow of solvent in order to separate oily solvent and fines smaller than a chosen diameter from the heavier solids. The heavier solids are cleaned of any remaining oil-based muds, separated from cleaning solvent and ultimately returned to the sea environment. The method includes the further step of treating the oil-based mud laden solvent for separation of remaining solvent for return of the solvent to the continuous process and for recycling of the recovered oil-based drilling mud into the drilling mud system.
    • 用于从钻屑中去除油基钻井泥浆的方法和装置,以便准备用于在海中环境安全处置的钻屑。 在该过程中可以使用可由环境海水冷凝并通过加热的内燃机冷却剂蒸发的溶剂范围内的溶剂。 本发明的方法包括以下步骤:将基于油的含泥的切屑输送到固体进料罐,其中油基切屑经受湍流混合以使切屑的表面基本上不含油。 然后将切屑输送到逆流流动塔并进行逆流层流的溶剂,以便从较重的固体中分离出油性溶剂和小于所选直径的细粒。 将较重的固体清洁任何剩余的油基泥浆,与清洁溶剂分离,最终返回到海洋环境。 该方法还包括处理载有油基泥浆的溶剂以分离剩余溶剂以使溶剂返回到连续方法以及回收的油基钻井泥浆进入钻井泥浆系统的步骤。
    • 9. 发明授权
    • Separation process
    • 分离过程
    • US06964728B2
    • 2005-11-15
    • US10147621
    • 2002-05-16
    • Bonnie G. McKinnieRobert E. WilliamsGary L. SharpAlireza M. Dadgar
    • Bonnie G. McKinnieRobert E. WilliamsGary L. SharpAlireza M. Dadgar
    • B01D3/34C07C27/28C07C29/80
    • B01D3/34Y10S203/11Y10S203/14
    • Bisphenol-A-bis(neopentylglycolphosphate) products of enhanced properties and processes for preparing them are described. One of the processes includes (a) mixing and reacting neopentyl glycol and bisphenol-A-bis(dichlorophosphate) in an inert polar organic solvent which (1) if mixed by itself with an equal volume of water at 25° C., will form a separate phase, (2) the solvent by itself will dissolve at least about 10 wt % of bisphenol-A-bis(neopentylglycolphosphate) at a temperature in the range of 25 to 50° C., and optionally but preferably (3) the solvent by itself can be completely vaporized at a temperature below about 180° C.; (b) washing bisphenol-A-bis(neopentylglycolphosphate) product formed in a) while dissolved in inert organic solvent having such characteristics at least once with an aqueous alkaline washing solution; and (c) optionally but preferably, recovering bisphenol-A-bis(neopentylglycolphosphate) product from organic solvent having such characteristics. The reaction of (a) can be conducted in an inert non-polar solvent if that solvent is replaced by an inert polar organic solvent satisfying (1) and (2), and preferably (3). A solvent satisfying (1), (2), and (3) is used when (c) is conducted by distilling or vaporizing off the solvent to recover the bisphenol-A-bis(neopentylglycolphosphate) product as such. The product has a low acid number or a high thermal stability, and usually both.
    • 描述了增强性能的双酚A双(新戊二醇磷酸酯)产物及其制备方法。 其中一个方法包括(a)在惰性极性有机溶剂中将新戊二醇和双酚-A-双(二氯磷酸盐)混合和反应,(1)如果在25℃下与等体积的水自身混合,将形成 单独的相,(2)溶剂本身将在25至50℃的温度范围内溶解至少约10重量%的双酚A-双(新戊基乙二醇酯磷酸酯),并且任选但优选(3) 溶剂本身可以在低于约180℃的温度下完全蒸发; (b)洗涤a)中形成的双酚-A-双(新戊基乙二醇磷酸酯)产物,同时用碱性洗涤液溶解至少一次具有这种特性的惰性有机溶剂; 和(c)任选地但优选地,从具有这种特性的有机溶剂中回收双酚A-双(新戊基乙二醇磷酸酯)产物。 (a)的反应可以在惰性非极性溶剂中进行,如果该溶剂被满足(1)和(2),优选(3)的惰性极性有机溶剂代替。 (c)通过蒸馏除去溶剂进行蒸发以回收双酚A-双(新戊基乙二醇酯磷酸酯)产物时,使用满足(1),(2)和(3)的溶剂。 该产品具有低酸值或高热稳定性,通常两者都是。
    • 10. 发明授权
    • Retrofitable fan shroud
    • 可改装风扇罩
    • US6045330A
    • 2000-04-04
    • US845604
    • 1997-04-25
    • Robert E. Williams
    • Robert E. Williams
    • F04D29/70F04B39/10
    • F04D29/703
    • A fan shroud retrofittable about a vehicle's fan and mountable to the fan housing, to prevent access thereto by animals. A first embodiment includes a pair of semi-circular screened housing members which include a pair of aligned, planar flange members. When the respective pairs are joined to the companion pairs of a second housing member, the assembly defines a circular shroud for mounting to the fan housing. A second embodiment for the shroud of this invention consists of a unitary, circular housing having a radially extending opening to override the shaft of the fan.
    • 风扇罩可以围绕车辆的风扇改装并可安装到风扇壳体上,以防止动物进入。 第一实施例包括一对半圆形屏蔽壳体构件,其包括一对对准的平面凸缘构件。 当相应的对连接到第二壳体构件的配对对时,组件限定了用于安装到风扇壳体的圆形罩。 本发明的护罩的第二实施例由一个整体的圆形壳体组成,其具有径向延伸的开口以覆盖风扇的轴。