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1. 发明授权

US4716142A Catalysts for the hydrodenitrogenation of organic materials and process for the preparation of the catalysts 失效
标题翻译：用于加氢脱氮有机材料的催化剂和制备催化剂的方法
公开(公告)号：US4716142A
公开(公告)日：1987-12-29
申请号：US900447
申请日：1986-08-26
申请人： Richard M. Laine , Albert S. Hirschon , Robert B. Wilson, Jr.
发明人： Richard M. Laine , Albert S. Hirschon , Robert B. Wilson, Jr.
IPC分类号： B01J27/047 , B01J23/85 , B01J27/051 , B01J37/20 , C10G45/08 , B01J21/04 , B01J27/049
CPC分类号： B01J23/85 , B01J37/20 , C10G45/08
摘要： The present invention discloses a process for forming a catalyst for the hydrodenitrogenation of an organic feedstock, which includes (a) obtaining a precatalyst comprising cobalt and molybdenum or nickel and molybdenum; (b) adding in a non-oxidizing an atmosphere selected from hydrogen, helium, nitrogen, neon, argon, carbon monoxide or mixtures thereof to the precatalyst of step (a), a transition metORIGIN OF THE INVENTIONThis invention was made in the course of research partially sponsored by the Department of Energy through grants DE-FG22-83P C60781 and DE-FG-85-PC80906, and partially supported by grant CHE82-19541 of the National Science Foundation. The invention is subject to Public Law 96-517 (and amendments), and the United States Government has rights in the present invention.
摘要翻译：本发明公开了一种用于形成用于有机原料的加氢脱氮的催化剂的方法，其包括（a）获得包含钴和钼或镍和钼的预催化剂; （b）将非氢氧化的选自氢，氦，氮，氖，氩，一氧化碳或其混合物的气氛加入到步骤（a）的预催化剂中，将选自铱，铑，铁，钌，钨或其混合物，在有效化学组合所述组分的温度下; 和（c）任选地在真空中加热步骤（b）的化学组合催化剂以除去残留的挥发性有机材料。优选地，在氢气氛中将钴/钼或氧化铝的预催化剂加热至钌的有机金属部分，优选羰基钌。本发明还包括所获得的催化剂和包括原油石油残渣，石油馏分，油页岩馏分，焦油砂级分，煤衍生的粉末，来自煤的液体或其混合物的有机原料的加氢脱氮方法。减少获得加氢脱氮通常需要的氢气量，并且比饱和有机产物更有选择地产生芳香族产物。

2. 发明授权

US07033840B1 Reaction calorimeter and differential scanning calorimeter for the high-throughput synthesis, screening and characterization of combinatorial libraries 失效
标题翻译：用于高通量合成，筛选和表征组合文库的反应量热计和差示扫描量热计
公开(公告)号：US07033840B1
公开(公告)日：2006-04-25
申请号：US09708687
申请日：2000-11-09
申请人： Christopher D. Tagge , Robert B. Wilson, Jr. , Seajin Oh , Albert S. Hirschon
发明人： Christopher D. Tagge , Robert B. Wilson, Jr. , Seajin Oh , Albert S. Hirschon
IPC分类号： G01N25/20 , G01N31/10
CPC分类号： B01L3/50851 , B01J2219/00317 , B01J2219/00351 , B01J2219/00495 , B01J2219/00585 , B01J2219/00704 , B01J2219/00747 , B01L3/50853 , B01L2300/0654 , B01L2300/1827 , B01L2300/185 , B01L2400/065 , G01N25/4846 , H01J49/04
摘要： Workstation, apparatuses and methods for the high-throughput synthesis, screening and/or characterization of combinatorial libraries. The invention relates to an array, which permits various high-throughput methods for synthesis, screening and/or characterization in the same array, without requiring sample transfer from the array. In a preferred embodiment, the synthesis, screening, and/or characterization steps are carried out in a highly parallel fashion, where more than one compound is synthesized, screened, and/or characterized at the same time. The invention may be practiced at the microscale. The array may comprise thermal channels, for regulating the temperature of the wells in the array. The wells of the array may comprise a membrane, which is used in various screening and characterization methods. The invention also relates to a covered array, comprising the array and an array cover, as well as an apparatus comprising the array, which comprises the array, an array cover and a stage. The array, array cover, and the stage may be modified as required for a variety of synthesis and/or analysis techniques. The array is easily interchangeable between different analytical instruments, and in an embodiment, the invention relates to an automated workstation, where the array is transferred between different synthesis, screening, and characterization stations. The invention also relates to a variety of methods for synthesis, screening, and characterization, which are adapted for combinatorial chemistry. Any of the embodiments of the invention may be used either alone or taken in various combinations.
摘要翻译：用于组合库的高通量合成，筛选和/或表征的工作站，设备和方法。本发明涉及阵列，其允许在相同阵列中进行合成，筛选和/或表征的各种高通量方法，而不需要从阵列转移样品。在优选实施方案中，合成，筛选和/或表征步骤以高度平行的方式进行，其中多于一种化合物被同时合成，筛选和/或表征。本发明可以在微尺度下实施。阵列可以包括用于调节阵列中的阱的温度的热通道。阵列的孔可以包括膜，其用于各种筛选和表征方法。本发明还涉及包括阵列和阵列盖的覆盖阵列，以及包括阵列的装置，其包括阵列，阵列盖和台。可以根据各种合成和/或分析技术的要求来修改阵列，阵列覆盖物和载物台。该阵列在不同的分析仪器之间易于互换，并且在一个实施例中，本发明涉及自动化工作站，其中阵列在不同的合成，筛选和表征台之间传送。本发明还涉及适用于组合化学的各种合成，筛选和表征的方法。本发明的任何实施方案可以单独使用或以各种组合使用。

3. 发明授权

US06392066B1 Epoxidation of olefins using lanthanide-promoted silver catalysts 失效
标题翻译：使用镧系元素促进的银催化剂对烯烃进行环氧化
公开(公告)号：US06392066B1
公开(公告)日：2002-05-21
申请号：US09791904
申请日：2001-02-22
申请人： Guido Mul , Marianna F. Asaro , Albert S. Hirschon , Robert B. Wilson, Jr.
发明人： Guido Mul , Marianna F. Asaro , Albert S. Hirschon , Robert B. Wilson, Jr.
IPC分类号： C07D30110
CPC分类号： C07D301/10
摘要： A process is provided for use in the epoxidation of olefins, having particular utility in the epoxidation of propylene to form propylene oxide, using a lanthanide-promoted, supported, silver catalyst prepared via precipitation. A preferred embodiment uses silver nitrate and lanthanum nitrate to form the catalyst on a BaCO3 support.
摘要翻译：提供了一种用于烯烃环氧化的方法，其特别用于丙烯环氧化形成环氧丙烷，使用通过沉淀制备的镧系元素促进的负载型银催化剂。优选的实施方案使用硝酸银和硝酸镧在BaCO 3载体上形成催化剂。

4. 发明授权

US06635793B2 Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts 失效
公开(公告)号：US06635793B2
公开(公告)日：2003-10-21
申请号：US10346679
申请日：2003-01-15
申请人： Guido Mul , Marianna F. Asaro , Albert S. Hirschon , Robert B. Wilson, Jr.
发明人： Guido Mul , Marianna F. Asaro , Albert S. Hirschon , Robert B. Wilson, Jr.
IPC分类号： C07C5327
CPC分类号： C07D301/22 , B01J23/002 , B01J23/66 , B01J23/685
摘要： A process is provided for use in the conversion of alkanes into alkylene oxides, having particular utility in the conversion of propane to form propylene oxide, using a lanthanide-promoted, supported, silver catalyst prepared via precipitation. A preferred embodiment uses silver nitrate and lanthanum nitrate to form the catalyst on a BaCO3 support.

5. 发明授权

US06602714B1 Viscosity and mass sensor for the high-throughput synthesis, screening and characterization of combinatorial libraries 失效
标题翻译：用于高通量合成，筛选和表征组合文库的粘度和质量传感器
公开(公告)号：US06602714B1
公开(公告)日：2003-08-05
申请号：US09708688
申请日：2000-11-09
申请人： Christopher D. Tagge , Robert B. Wilson, Jr. , Seajin Oh , Albert S Hirschon , Dale W. Ploeger
发明人： Christopher D. Tagge , Robert B. Wilson, Jr. , Seajin Oh , Albert S Hirschon , Dale W. Ploeger
IPC分类号： G01N3100
CPC分类号： G01N25/4846 , B01J19/0046 , B01J2219/00313 , B01J2219/00317 , B01J2219/00351 , B01J2219/00423 , B01J2219/00484 , B01J2219/00495 , B01J2219/00547 , B01J2219/00585 , B01J2219/00659 , B01J2219/00689 , B01J2219/00691 , B01J2219/00702 , B01J2219/00704 , B01J2219/00707 , B01J2219/0072 , B01J2219/00722 , B01L3/50851 , B01L3/50853 , B01L2300/0627 , C40B40/04 , C40B40/14 , C40B50/08 , C40B60/12 , C40B70/00 , G01N5/04 , G01N11/00 , G01N15/088 , G01N29/036 , G01N31/10 , G01N2035/00237 , G01N2291/0256
摘要： Workstation, apparatuses and methods for the high-throughput synthesis, screening and/or characterization of combinatorial libraries. The invention relates to an array, which permits various high-throughput methods for synthesis, screening and/or characterization in the same array, without requiring sample transfer from the array. In a preferred embodiment, the synthesis, screening, and/or characterization steps are carried out in a highly parallel fashion, where more than one compound is synthesized, screened, and/or characterized at the same time. The invention may be practiced at the microscale. The array may comprise thermal channels, for regulating the temperature of the wells in the array. The wells of the array may comprise a membrane, which is used in various screening and characterization methods. The invention also relates to a covered array, comprising the array and an array cover, as well as an apparatus comprising the array, which comprises the array, an array cover and a stage. The array, array cover, and the stage may be modified as required for a variety of synthesis and/or analysis techniques. The array is easily interchangeable between different analytical instruments, and in an embodiment, the invention relates to an automated workstation, where the array is transferred between different synthesis, screening, and characterization stations. The invention also relates to a variety of methods for synthesis, screening, and characterization, which are adapted for combinatorial chemistry. Any of the embodiments of the invention may be used either alone or taken in various combinations.
摘要翻译：组合库的高通量合成，筛选和/或表征的工作站，设备和方法。本发明涉及阵列，其允许在相同阵列中进行合成，筛选和/或表征的各种高通量方法，而不需要从阵列转移样品。在优选实施方案中，合成，筛选和/或表征步骤以高度平行的方式进行，其中多于一种化合物被同时合成，筛选和/或表征。本发明可以在微尺度下实施。阵列可以包括用于调节阵列中的阱的温度的热通道。阵列的孔可以包括膜，其用于各种筛选和表征方法。本发明还涉及包括阵列和阵列盖的覆盖阵列，以及包括阵列的装置，其包括阵列，阵列盖和台。可以根据各种合成和/或分析技术的要求来修改阵列，阵列覆盖物和载物台。该阵列在不同的分析仪器之间易于互换，并且在一个实施例中，本发明涉及自动化工作站，其中阵列在不同的合成，筛选和表征台之间传送。本发明还涉及适用于组合化学的各种合成，筛选和表征的方法。本发明的任何实施方案可以单独使用或以各种组合使用。

6. 发明授权

US06509485B2 Preparation of epoxides from alkanes using lanthanide-promoted silver catalysts 失效
公开(公告)号：US06509485B2
公开(公告)日：2003-01-21
申请号：US09792390
申请日：2001-02-22
申请人： Guido Mul , Marianna F. Asaro , Albert S. Hirschon , Robert B. Wilson, Jr.
发明人： Guido Mul , Marianna F. Asaro , Albert S. Hirschon , Robert B. Wilson, Jr.
IPC分类号： C07D30102
CPC分类号： C07D301/22 , B01J23/002 , B01J23/66 , B01J23/685
摘要： A process is provided for use in the conversion of alkanes into alkylene oxides, having particular utility in the conversion of propane to form propylene oxide, using a lanthanide-promoted, supported, silver catalyst prepared via precipitation. A preferred embodiment uses silver nitrate and lanthanum nitrate to form the catalyst on a BaCO3 support.

7. 发明授权

US4562291A Oligomerization of alkyl groups on amines 失效
标题翻译：烷基在胺上的低聚
公开(公告)号：US4562291A
公开(公告)日：1985-12-31
申请号：US683531
申请日：1984-12-19
申请人： Robert B. Wilson, Jr. , Richard M. Laine
发明人： Robert B. Wilson, Jr. , Richard M. Laine
IPC分类号： C07C85/00
CPC分类号： C07C209/68
摘要： Long chain alkylamines are synthesized by the oligomerization of shorter chain alkylamines at a temperature between 50.degree.-250.degree. C. and a pressure between 1-300 atmospheres in the presence of a catalyst mixture comprising a fluoroborate salt and a ruthenium, an osmium, or an iridium compound.
摘要翻译：在包含氟硼酸盐和钌，锇或锇的催化剂混合物的存在下，在50〜250℃的温度和1-300个大气压之间的短链烷基胺的低聚合成长链烷基胺。铱化合物。

8. 发明授权

US07592408B2 Olefin copolymers containing hydrolytically cleavable linkages and use thereof in degradable products 失效
标题翻译：含有水解可切割键的烯烃共聚物及其在降解产物中的用途
公开(公告)号：US07592408B2
公开(公告)日：2009-09-22
申请号：US12128411
申请日：2008-05-28
申请人： Robert B. Wilson, Jr. , Sigridur Jonasdottir
发明人： Robert B. Wilson, Jr. , Sigridur Jonasdottir
IPC分类号： C08F130/02
CPC分类号： C08F210/02 , Y10S526/943
摘要： The invention is directed to olefin copolymers composed of nonhydrolyzable monomer units and hydrolyzable monomer units, the latter resulting from copolymerization of monomers containing a linkage that is hydrolytically cleavable in the presence of aqueous base or aqueous acid. Generally, the hydrolyzable monomer units represent a significant fraction of the copolymer, such that upon hydrolysis, a substantial portion of the copolymer is degraded into low molecular weight fragments. Also provided are degradable articles that are at least partially composed of a degradable copolymer in which hydrolyzable monomer units represent at least 20 mole % of the copolymer. These degradable articles include agricultural film products, adhesive tape substrates, bed linens, containers, disposable absorbent articles, packaging materials, bags, labels, pillow cases, protective clothing, surgical drapes, sponges, tampon applicators, disposable syringes, temporary enclosures and temporary siding, toys, wipes, foamed plastic products, and controlled release pellets, strips and tabs.
摘要翻译：本发明涉及由不可水解的单体单元和可水解单体单元组成的烯烃共聚物，后者是由在含水碱或含水酸存在下可水解切割的连接体的单体的共聚得到的。通常，可水解单体单元代表共聚物的显着部分，使得在水解时，共聚物的大部分降解成低分子量片段。还提供了至少部分由可水解单体单元占共聚物的至少20摩尔％的可降解共聚物组成的可降解制品。这些可降解制品包括农用薄膜产品，胶带基材，床上用品，容器，一次性吸收制品，包装材料，袋子，标签，枕头套，防护服，手术用纱，海绵，棉塞施用器，一次性注射器，临时外壳和临时壁板，玩具，擦拭物，发泡塑料制品和控制释放的颗粒，条和片。

9. 发明授权

US07037992B2 Olefin copolymers containing hydrolytically cleavable linkages and use thereof in degradable products 失效
公开(公告)号：US07037992B2
公开(公告)日：2006-05-02
申请号：US10392270
申请日：2003-03-18
申请人： Robert B. Wilson, Jr. , Sigridur Jonasdottir
发明人： Robert B. Wilson, Jr. , Sigridur Jonasdottir
IPC分类号： C08F130/02
CPC分类号： C08F10/00 , C08F4/65912 , C08F4/6592 , C08F4/65927 , C08F8/12 , C08F210/02 , C08F214/26 , C08F230/02 , C08F2810/20 , C08F2810/50 , C08L3/02 , C08L3/04 , C08L21/00 , C08L23/04 , C08L23/083 , C08L23/0846 , C08L23/0892 , C08L101/00 , C08L2201/06 , C08L2666/02 , C08L2666/26 , C08L2666/06 , C08F220/00 , C08F222/00 , C08F232/00 , C08F4/7006
摘要： The invention is directed to olefin copolymers composed of nonhydrolyzable monomer units and hydrolyzable monomer units, the latter resulting from copolymerization of monomers containing a linkage that is hydrolytically cleavable in the presence of aqueous base or aqueous acid. Generally, the hydrolyzable monomer units represent a significant fraction of the copolymer, such that upon hydrolysis, a substantial portion of the copolymer is degraded into low molecular weight fragments. Also provided are degradable articles that are at least partially composed of a degradable copolymer in which hydrolyzable monomer units represent at least 20 mole % of the copolymer. These degradable articles include agricultural film products, adhesive tape substrates, bed linens, containers, disposable absorbent articles, packaging materials, bags, labels, pillow cases, protective clothing, surgical drapes, sponges, tampon applicators, disposable syringes, temporary enclosures and temporary siding, toys, wipes, foamed plastic products, and controlled release pellets, strips and tabs.

10. 发明授权

US06841676B2 Complexes of mid-transition metals and unsaturated nitrogenous ligands as single-site catalysts 失效
标题翻译：中间过渡金属和不饱和含氮配体的复合物作为单中心催化剂
公开(公告)号：US06841676B2
公开(公告)日：2005-01-11
申请号：US10023920
申请日：2001-12-17
申请人： Christopher D. Tagge , Robert B. Wilson, Jr.
发明人： Christopher D. Tagge , Robert B. Wilson, Jr.
IPC分类号： C07C251/12 , C07D213/53 , C07D241/12 , C07F7/00 , C07F11/00 , C08F4/02 , C08F4/22 , C08F4/78 , C08F10/00 , C07F9/80
CPC分类号： C07D213/53 , C07C251/12 , C07D241/12 , C07F7/003 , C07F11/005 , C08F10/00 , C08F4/69034 , C08F4/69043 , C08F4/64013
摘要： Novel compounds are provided which are useful as catalysts, particularly in the polymerization of addition polymerizable monomers such as olefinic or vinyl monomers. The compounds are complexes of a mid-transition metal coordinated to at least two ligands, at least one of which is an unsaturated nitrogenous ligand. Depending on ligand substitution, stereospecific catalysts can be provided, including isospecific catalysts and syndiospecific catalysts. Catalyst systems containing the novel compounds in combination with a catalyst activator are provided as well, as are methods of using the novel compounds in the preparation of polyolefins. One embodiment of the present invention is a compound having the formula L1[MQ1Q2]L2 in which M is Nb, Ta, Mo, W, Mn or Re, Q1 and Q2 are each a univalent substituent, and L1 and L2 are ligands coordinated to M, wherein L1 contains a first coordinating nitrogen atom within a C═N group, and a second coordinating atom that is either a second nitrogen atom, optionally present in a second C═N group, or an oxygen, sulfur or phosphorus atom. The L2 group contains a coordinating atom that is either a second nitrogen atom, optionally within a C═N group, or a sulfur or phosphorus atom.
摘要翻译：提供了可用作催化剂的新型化合物，特别是在可加聚单体如烯属或乙烯基单体的聚合中。这些化合物是与至少两个配体配位的中间过渡金属的络合物，其中至少一个是不饱和含氮配体。取决于配体取代，可以提供立体特异性催化剂，包括异相催化剂和间同立构催化剂。还提供了含有新型化合物与催化剂活化剂组合的催化剂体系，以及在制备聚烯烃中使用新化合物的方法。本发明的一个实施方案是具有式L 1 [MQ 1 Q 2] L 2的化合物，其中M是Nb，Ta，Mo，W，Mn或Re，Q 1，和Q 2各自是一价取代基，L 1和L 2是与M配位的配位体，其中L 1在C = N基团中含有第一配位氮原子，第二配位原子即第二个氮原子，任选存在于第二个C = N基团中，或者是氧，硫或磷原子。 L 2基团包含任选在C = N基团中的第二氮原子或硫或磷原子的配位原子。

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