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1. 发明授权

US06414206B2 Process for preparing bisindenylalkanes 失效
标题翻译：双茚基烷烃的制备方法
公开(公告)号：US06414206B2
公开(公告)日：2002-07-02
申请号：US09790823
申请日：2001-02-22
申请人： Richard Herman Woudenberg , Faysal Kalmoua
发明人： Richard Herman Woudenberg , Faysal Kalmoua
IPC分类号： C07C126
CPC分类号： C07C1/325 , C07C2602/08 , C07C13/465
摘要： The present invention relates to a process for preparing bisindenylalkanes of formula I: wherein R1, R2, R3, and R4 independently represent H or a C1-C6 hydrocarbon group or R1 and R2 or R1 and R3 or R3 and R4 together with the carbon atoms to which they are attached form a saturated or unsaturated 5- or 6-membered ring, said ring being optionally substituted with a C1-C4 hydrocarbon group, and R5 represents a C1-C6 hydrocarbon group, comprising reacting, at a temperature which does not exceed about 5° C., a metallated indene of formula II with a disubstituted hydrocarbon of formula III: wherein R1, R2, R3, R4, and R5 have the same meaning as defined above, M represents a metal ion, and X independently represents a suitable leaving group, in a suitable reaction medium wherein the molar ratio of II to III is 2.05 or higher. The process is particularly suitable for preparing bisindenylethane, i.e., R1-R4 represent H and R5 represents an ethylene group.
摘要翻译：本发明涉及制备式I的双茚基烷烃的方法：其中R1，R2，R3和R4独立地表示H或C1-C6烃基或R1和R2或R1和R3或R3和R4与碳原子一起它们连接在其上形成饱和或不饱和的5-或6-元环，所述环任选被C 1 -C 4烃基取代，并且R 5表示C 1 -C 6烃基，其包括在不是超过约5℃，式II的金属化茚与式III的二取代烃：其中R1，R2，R3，R4和R5具有与上述相同的含义，M表示金属离子，X独立地表示合适的离去基团，其中II至III的摩尔比为2.05或更高的合适的反应介质。该方法特别适用于制备双茚基乙烷，即R1-R4代表H，R5代表亚乙基。

2. 发明授权

US06376639B1 Polymers comprising a fluorinated carbonate moiety 失效
标题翻译：包含氟化碳酸酯部分的聚合物
公开(公告)号：US06376639B1
公开(公告)日：2002-04-23
申请号：US09379924
申请日：1999-08-24
申请人： Richard Herman Woudenberg , Tjerk Oedse Boonstra
发明人： Richard Herman Woudenberg , Tjerk Oedse Boonstra
IPC分类号： C08G6400
CPC分类号： C08G64/1633 , C08G64/0216 , C08G64/0233 , C08G64/1616 , G02B1/048 , G02B6/02033 , G02B2006/12069 , G02F1/0147 , C08L69/00
摘要： The invention pertains to a cross-linkable fluorinated polymer comprising the carbonate moiety having formula (I) wherein n=1-10 and m=0-9. Preferably, the polymer further comprises a cross-linkable moiety derived from a diol selected from (II) and (III) wherein A, A1, and A2 are independently a bond or C1-12 alkylene, or together with the carbon atoms to which they are bonded form a 5- or 6-membered ring; B is independently O or C1-4 alkyl; Q is —CO—C(=E)D, wherein D is H or C1-4 alkyl, and E is C1-6 alkylidene; and each of the alkyl, alkylene, and alkylidene groups may be halogenated. The polymers of the invention can be used in cladding layers or waveguides, in particular for thermo-optical devices.
摘要翻译：本发明涉及可交联的氟化聚合物，其包含具有式（I）的碳酸酯部分，其中n = 1-10且m = 0-9。优选地，聚合物还包含衍生自选自（II）和（III）的二醇的可交联部分，其中A，A1和A2独立地是键或C1-12亚烷基，或与它们的碳原子一起键合形成5-或6-元环; B独立地为O或C 1-4烷基; Q是-CO-C（= E）D，其中D是H或C 1-4烷基，E是C 1-6亚烷基; 并且烷基，亚烷基和亚烷基中的每一个可以被卤化。本发明的聚合物可用于包覆层或波导管，特别是用于热光器件。

3. 发明授权

US08558021B2 Process for the catalytic halogenation of a diol 有权
标题翻译：二醇催化卤化的方法
公开(公告)号：US08558021B2
公开(公告)日：2013-10-15
申请号：US13256353
申请日：2010-03-17
申请人： Antoon Jacob Berend Ten Kate , Richard Herman Woudenberg , Eilertdina Henderika Renkema , Luc Louis Theophile Vertommen , Carolina Anna Maria Christina Dirix , Tim Baks
发明人： Antoon Jacob Berend Ten Kate , Richard Herman Woudenberg , Eilertdina Henderika Renkema , Luc Louis Theophile Vertommen , Carolina Anna Maria Christina Dirix , Tim Baks
IPC分类号： C07D301/24 , C07C31/34
CPC分类号： C07C29/62 , C07C31/42 , C07C31/36
摘要： The present invention relates to a process for the catalytic halogenation of an organic compound comprising at least one vicinal diol moiety, said process comprising a step of bringing the organic compound comprising at least one vicinal diol moiety into contact with a hydrogen halide in the presence of a catalyst, characterized in that the catalyst is an organic compound comprising a β-diketone moiety or a β-keto aldehyde moiety.
摘要翻译：本发明涉及包含至少一个邻位二醇部分的有机化合物的催化卤化的方法，所述方法包括使包含至少一个邻位二醇部分的有机化合物与卤化氢接触的步骤催化剂，其特征在于催化剂是包含β-二酮部分或β-酮醛部分的有机化合物。

4. 发明授权

US5776375A Electro-optical device stable in the 600-1600 nanometer wavelength range 失效
标题翻译：电光装置在600-1600纳米波长范围内稳定
公开(公告)号：US5776375A
公开(公告)日：1998-07-07
申请号：US600665
申请日：1996-02-13
申请人： Johannes Willem Hofstraat , Marinus Cornelis Flipse , Richard Herman Woudenberg
发明人： Johannes Willem Hofstraat , Marinus Cornelis Flipse , Richard Herman Woudenberg
IPC分类号： G02F1/35 , C07D207/12 , G02F1/355 , G02F1/361 , F21V9/00 , G02B6/00
CPC分类号： G02F1/3617
摘要： The present invention provides an electro-optical device comprising NLO polymer in the active layer with improved stability for light in the wavelength range of 600-1600 nm is guided through the device. The present invention is directed to an electro-optical device comprising two cladding layers and an active layer sandwiched between these cladding layers, with the active layer comprising a non-linear optically active side chain polymer with NLO-chromophores having an N-donor-delocated .pi. system-acceptor structure, the N-donor not being bonded directly to alkyl groups. There are two ways to create NLO-chromophores with N-donors which do not have adjacent linear alkyl groups: The first way is to bond one or two aromatic groups. The N-atom is further bonded to the delocated .pi. system. If only one aromatic group is present, the N-atom is, besides the delocated system, further bonded to a hydrogen or deuterium atom. The second way of avoiding adjacent alkyl groups is to employ an N-donor moiety wherein no adjacent linear alkyl groups are present.
摘要翻译：本发明提供了一种电光装置，其包括有源层中的NLO聚合物，对于在600-1600nm的波长范围内的光具有改进的稳定性。本发明涉及一种电光装置，其包括两层包层和夹在这些包覆层之间的有源层，活性层包含非线性光学活性侧链聚合物，NLO-发色团具有N-供体脱离的 π系统受体结构，N-供体不直接与烷基键合。使用不具有相邻直链烷基的N-配体的NLO发色团有两种方法：第一种方法是键合一个或两个芳族基团。 N-原子进一步键合到脱离的π系统。如果仅存在一个芳族基团，则除了脱离系统之外，N-原子还进一步键合到氢或氘原子上。避免相邻烷基的第二种方法是使用不存在相邻直链烷基的N-供体部分。

5. 发明授权

US06548710B2 Process for preparing 1-indanones 失效
标题翻译：制备1-茚满酮的方法
公开(公告)号：US06548710B2
公开(公告)日：2003-04-15
申请号：US09999368
申请日：2001-10-31
申请人： Richard Herman Woudenberg
发明人： Richard Herman Woudenberg
IPC分类号： C07C4563
CPC分类号： C07C49/675 , C07C45/46 , C07C45/63 , C07C45/65 , C07C49/76 , C07C49/792 , C07C49/788 , C07C49/80 , C07C49/67
摘要： The present invention relates to a process for preparing 1-indanones of formula I: and isomers thereof, wherein R1, R2, R3, R4, R5, and R6 independently represent H or a C1-C20 hydrocarbon group or R1 and R2 or R2 and R3 or R3 and R4 and/or R5 and R6 together with the carbon atoms to which they are attached form a saturated or unsaturated 5- or 6-membered ring, said hydrocarbon group and/or said ring optionally containing one or more hetero atoms, said ring optionally being substituted with a C1-C4 hydrocarbon group, said process comprising reacting a compound of formula II: wherein R1, R2, R3, R4, R5, and R6 have the same meaning as defined above, with a chlorinating agent, followed by reaction with a Friedel-Crafts catalyst. The invention further relates to the preparation of the corresponding indenes.
摘要翻译：本发明涉及制备式Ⅰ的1-茚并酮的方法及其异构体，其中R1，R2，R3，R4，R5和R6独立地表示H或C1-C20烃基或R1和R2或R2和 R3或R3和R4和/或R5和R6与它们所连接的碳原子一起形成饱和或不饱和的5-或6-元环，所述烃基和/或所述环任选地含有一个或多个杂原子，所述方法包括使式II化合物：其中R 1，R 2，R 3，R 4，R 5和R 6具有与上述定义相同的含义，与氯化剂反应，随后通过与Friedel-Crafts催化剂反应。本发明还涉及相应茚的制备。

6. 发明授权

US5942636A Process of preparing 2-alkyl-2,3-dihydro-1H-benz �e!indene-1-one derivatives 失效
标题翻译： 2-烷基-2,3-二氢-1H-苯并[e]茚-1-酮衍生物的制备方法
公开(公告)号：US5942636A
公开(公告)日：1999-08-24
申请号：US12164
申请日：1998-01-22
申请人： Richard Herman Woudenberg , Heert Andringa
发明人： Richard Herman Woudenberg , Heert Andringa
IPC分类号： C07C13/547 , C07C49/675 , C07F17/00 , C07C45/00 , C07F7/00
CPC分类号： C07C13/547 , C07C49/675 , C07F17/00 , C07C2103/16
摘要： The invention relates to a process of preparing a 2-alkyl-2,3-dihydro-1H-benz�e!indene-1-one derivative, preferably 2,3-dihydro-2-methyl-benz�e!indene-1-one, characterized in that a naphthalene derivative is condensed with an active ester of 2-alkyl-2-propenoic acid, preferably with 2-methyl-2-propenoyl chloride. The product which is obtained in high yield and substantially free from its isomer is an intermediate in the preparation of rac-dimethyl bis(2-alkyl-1H-benz�e!indenyl)silandiyl zirconium dichloride complex.
摘要翻译：本发明涉及制备2-烷基-2,3-二氢-1H-苯并[e]茚-1-酮衍生物，优选2,3-二氢-2-甲基 - 苯并[e]茚-1-酮的方法 - 酮，其特征在于萘衍生物与2-烷基-2-丙烯酸的活性酯，优选与2-甲基-2-丙烯酰氯缩合。以高产率获得并基本上不含其异构体的产物是制备外消旋 - 二甲基双（2-烷基-1H-苯并[e]茚基）硅烷基二氯化锆络合物的中间体。

7. 发明申请

US20120004432A1 PROCESS FOR THE CATALYTIC HALOGENATION OF A DIOL 有权
标题翻译：一种DIOL催化反应的方法
公开(公告)号：US20120004432A1
公开(公告)日：2012-01-05
申请号：US13256353
申请日：2010-03-17
申请人： Antoon Jacob Berend Ten Kate , Richard Herman Woudenberg , Eilertdina Henderika Renkema , Luc Louis Theophile Vertommen , Carolina Anna Maria Christina Dirix , Tim Baks
发明人： Antoon Jacob Berend Ten Kate , Richard Herman Woudenberg , Eilertdina Henderika Renkema , Luc Louis Theophile Vertommen , Carolina Anna Maria Christina Dirix , Tim Baks
IPC分类号： C07C31/36 , C07D301/26
CPC分类号： C07C29/62 , C07C31/42 , C07C31/36
摘要： The present invention relates to a process for the catalytic halogenation of an organic compound comprising at least one vicinal diol moiety, said process comprising a step of bringing the organic compound comprising at least one vicinal diol moiety into contact with a hydrogen halide in the presence of a catalyst, characterized in that the catalyst is an organic compound comprising a β-diketone moiety or a β-keto aldehyde moiety.
摘要翻译：本发明涉及包含至少一个邻位二醇部分的有机化合物的催化卤化的方法，所述方法包括使包含至少一个邻位二醇部分的有机化合物与卤化氢接触的步骤一种催化剂，其特征在于该催化剂是一种包含一个二 - 二酮部分或一个β-酮部分的有机化合物。

8. 发明授权

US5872882A Non-linear optical polycarbonates 失效
标题翻译：非线性光学聚碳酸酯
公开(公告)号：US5872882A
公开(公告)日：1999-02-16
申请号：US913206
申请日：1997-10-30
申请人： Richard Herman Woudenberg , Tjerk Oedse Boonstra , Johannes Wilhelm Ladage , Ulfert Elle Wiersum
发明人： Richard Herman Woudenberg , Tjerk Oedse Boonstra , Johannes Wilhelm Ladage , Ulfert Elle Wiersum
IPC分类号： G02F1/35 , C08G64/14 , C08G64/16 , C09K9/02 , G02F1/355 , G02F1/361 , G02B6/00
CPC分类号： C08G64/1616 , C08G64/14 , G02F1/3617 , Y10T428/31507
摘要： The invention relates to non-linear optically active (NLO) polycarbonates and to NLO active waveguides containing these polycarbonates. Waveguides containing these NLO polycarbonates have a low loss of signal, a high glass transition temperature and good polability and a high stability of the Pockel's coefficient.
摘要翻译： PCT No.PCT / EP96 / 00847 Sec。 371 1997年10月30日第 102（e）日期1997年10月30日PCT提交1996年2月28日PCT公布。公开号WO96 / 28757 日期1996年9月19日本发明涉及非线性光学活性（NLO）聚碳酸酯和含有这些聚碳酸酯的NLO有源波导。含有这些NLO聚碳酸酯的波导具有低的信号损失，高的玻璃化转变温度和良好的定向性以及Pockel系数的高稳定性。

9. 发明授权

US06232430B1 Cross-linkers for cross-linkable optical polycarbonates 失效
标题翻译：可交联光学聚碳酸酯的交联剂
公开(公告)号：US06232430B1
公开(公告)日：2001-05-15
申请号：US09284886
申请日：1999-08-04
申请人： Tjerk Oedse Boonstra , Richard Herman Woudenberg , David van Olden
发明人： Tjerk Oedse Boonstra , Richard Herman Woudenberg , David van Olden
IPC分类号： C08G6400
CPC分类号： C07D207/452
摘要： The invention pertains to a cross-linker of the formula wherein n is 0 or 1; m is 0 or 1; R is and R1 is independently OH or —CO—O(hydroxyphenyl), or of the formula with the proviso that 3,4-dihydroxyphenylmaleimide is excluded. The invention further pertains to cross-linked optical polycarbonate and optical articles obtainable by cross-linking a polycarbonate with this cross-linker or with 3,4-dihydroxyphenylmaleimide.
摘要翻译：本发明涉及式的化合物的交联剂为0或1; m为0或1; R 1和R 1独立地为OH或-CO-O（羟基苯基），或者其中3,4-二羟基苯基马来酰亚胺为排除本发明还涉及通过与该交联剂或3,4-二羟基苯基马来酰亚胺交联聚碳酸酯而获得的交联光学聚碳酸酯和光学制品。

10. 发明授权

US5908916A Cross-linked or cross-linkable optical polycarbonates and optical components comprising said optical polycarbonates 失效
标题翻译：包含所述光学聚碳酸酯的交联或可交联的光学聚碳酸酯和光学组件
公开(公告)号：US5908916A
公开(公告)日：1999-06-01
申请号：US750284
申请日：1997-03-07
申请人： Richard Herman Woudenberg , Tjerk Oedse Boonstra , David van Olden
发明人： Richard Herman Woudenberg , Tjerk Oedse Boonstra , David van Olden
IPC分类号： C08G64/14 , C08G64/16 , G02B1/04 , G02F1/35 , G02F1/361 , C08G64/00
CPC分类号： C08G64/14 , C08G64/1616 , G02F1/3617
摘要： The present invention is in the field of optical polymers, more particularly, optical polycarbonates for use in optical components.The present invention provides a cross-linkable or cross-linked optical polycarbonate built up from a monomer mixture comprising:compounds according to formula 1: ##STR1## wherein: P stands for --Cl, O--R, an imidazole group or --O--Ph, Q stands for --Cl, O--R, an imidazole group or --O--Ph,R stands for an alkylene group having 1-6 carbon atoms,Ph stands for phenyl,A stands for --Ph--, halogenated --Ph--, (halo)alkyl substituted --Ph, --Ph--Ph--, halogenated --Ph--Ph, --Ph--C(CH.sub.3).sub.2 --Ph--, --Ph--SO.sub.2 --Ph--, --Ph--C(CF.sub.3)--Ph--, halogenated --Ph--C(CH.sub.3).sub.2 --Ph, halogenated --Ph--C(CF.sub.3).sub.2 --Ph, phenolphtalein, --Ph--C(Ph).sub.2 --Ph,m is an integer from 0 to 5, with the A-groups being the same or different,optionally, diols, optionally, a dihydroxy-functionalised NLO-compound, and 2,3 dihydroxy propyl methacrylate as a crosslinker.
摘要翻译： PCT No.PCT / EP96 / 01101 Sec。 371日期1997年3月7日 102（e）1997年3月7日PCT 1996年3月11日PCT公布。公开号WO96 / 28493 日期1996年9月19日本发明涉及光学聚合物领域，更具体地说，涉及用于光学部件的光学聚碳酸酯。本发明提供由单体混合物构成的可交联或交联的光学聚碳酸酯，其包含：根据式1的化合物：其中：P代表-Cl，OR，咪唑基或-O-Ph，Q代表 -Cl，OR，咪唑基或-O-Ph，R代表具有1-6个碳原子的亚烷基，Ph代表苯基，A代表-Ph-，卤代-Ph-，（卤代）烷基取代的 - Ph，-Ph-Ph-，卤代-Ph-Ph，-Ph-C（CH3）2-Ph-，-Ph-SO2-Ph-，-Ph-C（CF3）-Ph-，卤代-Ph-C （CH 3）2-Ph，卤代-Ph-C（CF 3）2-Ph，酚酞，-Ph-C（Ph）2-Ph，m为0至5的整数，其中A基团相同或不同的，任选地，二醇，任选地，二羟基官能化的NLO化合物和作为交联剂的甲基丙烯酸2,3-二羟基丙酯。

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