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    • 1. 发明授权
    • Fuel cell components including immobilized heteropolyacids
    • 燃料电池组分包括固定化的杂多酸
    • US08129069B2
    • 2012-03-06
    • US11992826
    • 2006-09-29
    • Ramanathan S. LalgudiJay R. SayreBhima R. Vijayendran
    • Ramanathan S. LalgudiJay R. SayreBhima R. Vijayendran
    • H01M8/10
    • H01M8/1048H01B1/122H01M8/0221H01M8/1011H01M8/1027H01M8/1032H01M2300/0082Y02E60/523
    • A fuel cell component is made with a composite including a proton conducting polymer, a water insoluble proton conducting inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material. In another embodiment, the fuel cell component is made with a composite including a non-proton conducting polymer, a water insoluble inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material, the heteropolyacid causing the composite to show proton conductivity. In a further embodiment, the fuel cell component is made with a composite comprising a proton conducting polymer, a water insoluble proton conducting inorganic material, and a heteropolyacid immobilized by chemically bonding to the inorganic material, the composite having substantially identical structure of the unmodified heteropolyacid.
    • 燃料电池部件由包含质子传导性聚合物,水不溶性质子传导性无机材料和通过化学键合而固定的杂多酸的复合体制成。 在另一个实施方案中,燃料电池组件由包含非质子导电聚合物,水不溶性无机材料和通过化学键合到无机材料固定的杂多酸的复合材料制成,所述杂多酸导致复合材料显示出质子传导性。 在另一个实施方案中,燃料电池组件由包含质子传导聚合物,水不溶性质子传导无机材料和通过化学键合到无机材料固定的杂多酸的复合材料制成,所述复合材料具有基本相同的未改性杂多酸结构 。
    • 5. 发明授权
    • Polymers for use in fuel cell components
    • 聚合物用于燃料电池组件
    • US08222367B2
    • 2012-07-17
    • US11992827
    • 2006-09-29
    • Ramanathan S. LalgudiBhima R. VijayendranJeffrey CafmeyerJay R. Sayre
    • Ramanathan S. LalgudiBhima R. VijayendranJeffrey CafmeyerJay R. Sayre
    • C08G8/02
    • C08J5/2262C08J2371/12H01B1/122H01M4/8605H01M8/1025H01M8/1027H01M8/103H01M8/1032H01M8/1039H01M8/1048H01M2300/0068H01M2300/0082H01M2300/0091
    • A proton conducting hydrocarbon-based polymer has acid groups on side chains attached to the main chain, where the acid groups are between 7 and 12 atoms away from the main chain. Another polymer includes a semi-fluorinated aromatic hydrocarbon main chain and side chains that include at least one —CF2— group and an acid group. Another polymer includes an aromatic hydrocarbon main chain and side chains that include at least one —CH2-CF2— group and an acid group. Another aromatic polymer includes acid groups attached to both the main chain and the side chains where less than about 65 weight percent of the acid groups are attached to the side chains. Another aromatic polymer includes side chains attached to the main chain that include at least one aryl ring, and acid groups attached to both the main chain and to the aryl groups. Another polymer includes an aliphatic hydrocarbon main chain, side chains that include at least one deactivating aryl ring, and acid groups attached to the deactivating aryl rings. Another aliphatic polymer has side chains that include —CF2— groups and an acid group. A fuel cell component includes a proton conducting polymer, a water insoluble inorganic material, and a heteropolyacid immobilized on the inorganic material.
    • 质子传导性烃基聚合物在连接到主链的侧链上具有酸基,其中酸基离开主链7至12个原子。 另一种聚合物包括半氟化芳烃主链和包含至少一个-CF2-基团和酸基团的侧链。 另一种聚合物包括芳族烃主链和包含至少一个-CH 2 -CF 2 - 基团和酸基团的侧链。 另一种芳族聚合物包括连接到主链和侧链上的酸基团,其中小于约65重量%的酸基团连接到侧链上。 另一种芳族聚合物包括连接到主链上的包含至少一个芳环的侧链,以及连接到主链和芳基上的酸基。 另一种聚合物包括脂族烃主链,包含至少一个失活芳基环的侧链和连接到失活芳基环上的酸基团。 另一种脂族聚合物具有包括-CF2-基团和酸基团的侧链。 燃料电池组件包括质子传导聚合物,水不溶性无机材料和固定在无机材料上的杂多酸。
    • 6. 发明申请
    • Polymers for Use in Fuel Cell Components
    • 聚合物用于燃料电池组件
    • US20100234479A1
    • 2010-09-16
    • US11992827
    • 2006-09-29
    • Ramanathan S. LalgudiBhima R. VijayendranJeffrey CafmeyerJay R. Sayre
    • Ramanathan S. LalgudiBhima R. VijayendranJeffrey CafmeyerJay R. Sayre
    • C08J5/20
    • C08J5/2262C08J2371/12H01B1/122H01M4/8605H01M8/1025H01M8/1027H01M8/103H01M8/1032H01M8/1039H01M8/1048H01M2300/0068H01M2300/0082H01M2300/0091
    • A proton conducting hydrocarbon-based polymer has acid groups on side chains attached to the main chain, where the acid groups are between 7 and 12 atoms away from the main chain. Another polymer includes a semi-fluorinated aromatic hydrocarbon main chain and side chains that include at least one —CF2— group and an acid group. Another polymer includes an aromatic hydrocarbon main chain and side chains that include at least one —CH2-CF2— group and an acid group. Another aromatic polymer includes acid groups attached to both the main chain and the side chains where less than about 65 weight percent of the acid groups are attached to the side chains. Another aromatic polymer includes side chains attached to the main chain that include at least one aryl ring, and acid groups attached to both the main chain and to the aryl groups. Another polymer includes an aliphatic hydrocarbon main chain, side chains that include at least one deactivating aryl ring, and acid groups attached to the deactivating aryl rings. Another aliphatic polymer has side chains that include —CF2— groups and an acid group. A fuel cell component includes a proton conducting polymer, a water insoluble inorganic material, and a heteropolyacid immobilized on the inorganic material.
    • 质子传导性烃基聚合物在连接到主链的侧链上具有酸基,其中酸基离开主链7至12个原子。 另一种聚合物包括半氟化芳烃主链和包含至少一个-CF2-基团和酸基团的侧链。 另一种聚合物包括芳族烃主链和包含至少一个-CH 2 -CF 2 - 基团和酸基团的侧链。 另一种芳族聚合物包括连接到主链和侧链上的酸基团,其中小于约65重量%的酸基团连接到侧链上。 另一种芳族聚合物包括连接到主链上的包含至少一个芳环的侧链,以及连接到主链和芳基上的酸基。 另一种聚合物包括脂族烃主链,包含至少一个失活芳基环的侧链和连接到失活芳基环上的酸基团。 另一种脂族聚合物具有包括-CF2-基团和酸基团的侧链。 燃料电池组件包括质子传导聚合物,水不溶性无机材料和固定在无机材料上的杂多酸。
    • 9. 发明授权
    • High refractive index composition
    • 高折射率组成
    • US08883935B2
    • 2014-11-11
    • US13643584
    • 2011-04-28
    • Ramanathan S. LalgudiBarry L. McGrawRobert J. Cain
    • Ramanathan S. LalgudiBarry L. McGrawRobert J. Cain
    • C08F226/12C08G77/38C08F271/02C08L83/04C08F220/28C08F230/04C08G77/04C08K3/22
    • C08F220/28C08F230/04C08G77/04C08K3/22C08K2003/2237C08L83/04
    • A high refractive index composition comprising a reaction product of one or more first organic compounds capable of undergoing polymerization and one or more second compounds with high refractive index, and the method of making and using the composition.A composition comprising an organic compound obtained by coupling two reactive groups (a) and (b), wherein a. the reactive group (a) is Y—(CH2)n-M(O—R)3, wherein R is CH3, C2H5, C3H8, C4H10; and Y is —NH2, —COOH, —NCO, or epoxy; and wherein M is selected from the group consisting of Ti, Zr, V, Mg, Al, Mn, Sb, Ba, Ca, Ce, Si, and Sn; and b. the reactive group (b) is selected from the group consisting of carbazole, fluorene, imidazole with one or more functional groups selected from —OH, —NH2, —COOH, —NCO, -epoxy, -vinyl, -acrylic, -acyl, -alkyl, -halide, -amino, -ketone, -allyl, -allylic, -thiol, -isocyanate, and a mixture thereof; and the method of making and using the composition.
    • 包含能够进行聚合的一种或多种第一有机化合物与一种或多种具有高折射率的第二化合物的反应产物的高折射率组合物,以及制备和使用该组合物的方法。 包含通过偶联两个反应性基团(a)和(b)获得的有机化合物的组合物,其中a。 反应性基团(a)是Y-(CH2)n-M(O-R)3,其中R是CH3,C2H5,C3H8,C4H10; Y是-NH 2,-COOH,-NCO或环氧基; 其中M选自Ti,Zr,V,Mg,Al,Mn,Sb,Ba,Ca,Ce,Si和Sn; 和b。 反应性基团(b)选自咔唑,芴,咪唑与一个或多个选自-OH,-NH 2,-COOH,-NCO, - 环氧基, - 乙烯基, - 丙烯酰基, - 酰基, - 烷基, - 卤素, - 氨基, - 酮, - 烯丙基, - 烯丙基, - 硫醇, - 异氰酸酯及其混合物; 以及制作和使用该组合物的方法。