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1. 发明授权

US6136119A Method for adhering two surfaces by use of a polyisobutylene adhesive crayon 失效
标题翻译：通过使用聚异丁烯粘结剂蜡笔粘合两个表面的方法
公开(公告)号：US6136119A
公开(公告)日：2000-10-24
申请号：US225889
申请日：1994-04-11
申请人： Peter Spiros Columbus , Yogeshbhai Babubhai Patel
发明人： Peter Spiros Columbus , Yogeshbhai Babubhai Patel
IPC分类号： C08L23/22 , C09J5/00 , C09J123/18 , C09J123/22 , C09J191/06 , C09J193/00 , C09J193/04 , B29C65/06
CPC分类号： C09J123/22 , C09J9/005 , C08L23/22 , C09J2423/00 , Y02P20/582
摘要： This invention relates to thermoplastic, pressure-sensitive solid adhesives capable of transferring an adhesive film to a substrate by friction rubbing of the adhesive on the substrate. The adhesives of this invention consist essentially of polyisobutylene, wax and optionally an adhesive promoter resin. Said ingredients are within certain proportions, molecular weights, melting points, or hardness values.
摘要翻译：本发明涉及通过摩擦摩擦衬底上的粘合剂，能够将粘合剂膜转移到基底上的热塑性压敏固体粘合剂。本发明的粘合剂基本上由聚异丁烯，蜡和任选的粘合促进剂树脂组成。所述成分在一定比例范围内，分子量，熔点或硬度值。

2. 发明授权

US6127518A Monomer-free polyvinyl acetate dispersions and method of making same 失效
标题翻译：无单体聚乙酸乙烯酯分散体及其制备方法
公开(公告)号：US6127518A
公开(公告)日：2000-10-03
申请号：US83038
申请日：1998-05-22
申请人： Peter Spiros Columbus , Yogeshbhai Babubhai Patel
发明人： Peter Spiros Columbus , Yogeshbhai Babubhai Patel
IPC分类号： C09J131/04 , C08J3/05 , C08J3/12 , C08L29/00
CPC分类号： C09J131/04
摘要： Method of producing dry polyvinyl acetate particles that are readily dispersible in water, are vinyl acetate monomer free and are useful for making polyvinyl acetate dispersion compositions that are low in odor, form clear dried films and may be used in adhesives, sealants, caulks and coatings. The method includes manufacturing an aqueous, e.g. water, dispersion of polyvinyl acetate containing polyvinyl alcohol; drying to remove volatiles by converting the dispersion to dry form under controlled temperature conditions and redispersing the dried polyvinyl acetate particles in an aqueous medium to form a polyvinyl acetate dispersion that is substantially free of vinyl acetate monomer.
摘要翻译：制备易于分散在水中的干燥聚乙酸乙烯酯颗粒的方法是不含乙酸乙烯酯单体，并且可用于制备低气味的聚乙酸乙烯酯分散体组合物，形成透明的干燥膜，并可用于粘合剂，密封剂，填缝剂和涂料。该方法包括制备例如水溶液。水，聚乙酸乙烯酯含聚乙烯醇的分散体; 干燥以通过在受控温度条件下将分散体转变成干燥形式并将干燥的聚乙酸乙烯酯颗粒再分散在水性介质中以形成基本上不含乙酸乙烯酯单体的聚乙酸乙烯酯分散体，从而除去挥发物。

3. 发明授权

US6066689A Adhesive applicator crayon 失效
标题翻译：胶粘剂蜡笔
公开(公告)号：US6066689A
公开(公告)日：2000-05-23
申请号：US973215
申请日：1997-12-04
申请人： Peter Spiros Columbus , John Anderson
发明人： Peter Spiros Columbus , John Anderson
IPC分类号： C08K5/098 , C08L39/06 , C09J5/00 , C09J139/06
CPC分类号： C08K5/098 , C09J139/06 , C09J9/005 , C08L2205/02 , C08L39/06
摘要： Adhesive compositions exhibiting fast cure time in solid form, e.g. in the form of an applicator crayon or glue stick. The adhesive exhibiting polymer of the composition is based on a mixture of critical amounts of high molecular weight polyvinylpyrrolidone polymer, with a lower molecular weight polyvinylpyrrolidone polymer, with water, an organic solvent, and a salt of a long-claim fatty acid, e.g. sodium stearate. Color indicators and other optional ingredients, e.g. mildewcide, can be included.
摘要翻译： PCT No.PCT / US97 / 06713 Sec。 371 1997年12月4日第 102（e）日期1997年12月4日PCT 1997年4月23日提交PCT公布。第WO98 / 47953号公报日期1998年10月29日固体形式的固化时间，例如以施用器蜡笔或胶棒的形式。显示该组合物的聚合物的粘合剂基于临界量的高分子量聚乙烯吡咯烷酮聚合物与较低分子量的聚乙烯吡咯烷酮聚合物与水，有机溶剂和长脂肪酸的盐的混合物，硬脂酸钠。颜色指示剂和其他任选成分，例如可以包括防霉剂。

4. 发明授权

US4077932A Acrylate adhesive aqueous dispersions 失效
标题翻译：丙烯酸酯粘合剂水性分散体
公开(公告)号：US4077932A
公开(公告)日：1978-03-07
申请号：US653437
申请日：1976-01-29
申请人： Peter Spiros Columbus
发明人： Peter Spiros Columbus
IPC分类号： C08K5/5435 , C09J133/06 , C08L33/08
CPC分类号： C08K5/5435 , C09J133/064
摘要： An aqueous adhesive composition having pH of about 8 to 10 containing from about 25 to 75% by weight of water, the water having dispersed therein:A. from about 25 to 75% by weight of the composition, of a water-insoluble linear polymer of interpolymerized monoethylenically unsaturated monomers in amounts by weight based on the linear polymer:(1) from about 50 to 99% of an acrylic ester monomer of the formula ##STR1## or a mixture thereof, where R is H or methyl and R.sup.2 is lower alkyl of 1 to 4 carbon atoms,(2) from about 0.1 to 10% of acrylic acid or methacrylic acid,(3) from about 0.1 to about 10% of a nitrogen containing monomer selected from the group consisting essentially of vinyl amines and salts thereof, vinyl ureido monomers, vinyl compounds having heterocyclic nitrogen containing groups, and mixtures thereof, andB. 0.001 to 2% of a silane containing both alkoxy and epoxy functionalities.
摘要翻译：一种pH约为8至10的水性粘合剂组合物，其含有约25至75重量％的水，其中分散有水：

5. 发明授权

US4057527A Aqueous acrylate contact adhesive dispersions 失效
标题翻译：丙烯酸酯水溶液接触粘合剂分散体
公开(公告)号：US4057527A
公开(公告)日：1977-11-08
申请号：US686469
申请日：1976-05-14
申请人： Peter Spiros Columbus
发明人： Peter Spiros Columbus
IPC分类号： C08L33/02 , C09J133/06
CPC分类号： C09J133/064 , C08L33/02
摘要： An adhesive composition which comprises for each 100 parts, by weight, of an aqueous dispersion having a pH of from about 3 to 10 of the following ingredients dispersed in 25 to 75 parts of water.A. from 25 to 70 parts by weight of a water insoluble polymer containing the following interpolymerized monoethylenically unsaturated monomers.A. at least 50% by weight, based on the polymer, of acrylate monomers;B. from about 0.1 to 10% by weight based on the polymer, of N-methylolacrylamide, andC. from about 0.1 to 25% by weight, based upon the polymer, of a monoethylenically unsaturated monomer containing carboxylic acid groupsD. from about 2 to 40% based upon the polymer of an acrylonitrileE. from 0 to 40% by weight based on the polymers of an addition polymerizable vinyl monomer other than those defined aboveF. from 0 to 1% by weight based on the polymer of a cross-linking agentB. a small but effective amount to thicken the acrylate composition up to 3 parts by weight of the composition of an alkali metal or ammonium salt of a polyacrylic acidC. from a small but effective amount to impart freeze-thaw stability up to 3 parts of a surface active agentD. from a small but effective amount to depress the freezing point of the dispersion up to 3 parts of a freezing point depressorE. from a small but effective amount to render the dried adhesive tacky up to 10 parts of a tackifying agent. Compositions within the scope of the present invention are useful as contact adhesives. These adhesives have the same utility as known contact cements that effect strong instant bonds on contact with a variety of substrates including plywood, hardboard, particleboard, wood, leather, floor coverings, Styrofoam, metal sheeting and plastic laminates such as Formica. The cured adhesive films formed are resistant to oil, gasoline, water, heat and discoloration or aging.
摘要翻译：一种粘合剂组合物，其包含每100重量份的分散在25至75份水中的以下成分的约3至10的pH的水分散体。

6. 发明授权

US4032487A Aqueous acrylate-epoxy silane crosslinker adhesive dispersion composition 失效
标题翻译：水性丙烯酸 - 环氧硅烷交联胶粘合剂分散体组合物
公开(公告)号：US4032487A
公开(公告)日：1977-06-28
申请号：US676046
申请日：1976-04-12
申请人： Peter Spiros Columbus
发明人： Peter Spiros Columbus
IPC分类号： C08K5/5435 , C09J133/06 , C08L1/28
CPC分类号： C08K5/5435 , C08K5/54 , C09J133/064 , Y10T428/31649 , Y10T428/31833
摘要： An adhesive composition which comprises, for each 100 parts by weight thereof, an aqueous dispersion having pH of about 8 to 12 of the following components dispersed in 25 to 75 parts of water:A. from 25 to 75 parts by weight of water insoluble linear polymer containing the following interpolymerized unsaturated monomers in parts by weight based on the weight of the polymer:1. at least 50 parts and up to 99 parts of an acrylate monomer containing from about 4 to 27 carbon atoms selected from alkyl acrylates, alkyl methacrylates, and mixtures thereof:2. from about 0.1 to 10 parts of a nitrogen monomer selected from vinyl amines and salts thereof; vinyl ureido monomers; vinyl compounds having heterocyclic nitrogen containing groups and halogen, hydroxyalkyl or aminoalkyl substituted derivatives thereof; amino and loweralkyl amino loweralkyl acrylates and methacrylates; and mixtures thereof;3. from about 0.1 to 25 parts of an acid selected from acrylic acid, methacrylic acid and mixtures thereof;B. from a small but effective amount to effect cross-linking of the polymer to 5 parts of a silane containing both alkoxy and epoxy functionalities.

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