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1. 发明授权

US4791179A Chip resistant coating compositions containing epoxy-polyester graft copolymers 失效
标题翻译：含有环氧 - 聚酯接枝共聚物的耐芯片涂料组合物
公开(公告)号：US4791179A
公开(公告)日：1988-12-13
申请号：US93171
申请日：1987-09-03
申请人： Andrew H. Dervan , Panagiotis I. Kordomenos
发明人： Andrew H. Dervan , Panagiotis I. Kordomenos
IPC分类号： C08G18/42 , C08G18/46 , C08G18/79 , C08G18/80 , C08G59/02 , C08G59/42 , C08G59/62 , C08G59/64 , C08G63/08 , C09D163/00 , C08G59/16 , C08G63/18 , C08G63/20
CPC分类号： C08G18/4286 , C08G18/4294 , C08G18/4615 , C08G18/791 , C08G18/8061 , C08G59/02 , C08G59/4284 , C08G59/62 , C08G59/64 , C08G63/08 , C09D163/00
摘要： A solvent-based thermosetting coating composition comprising a hydroxy functional epoxy-polyester graft copolymer and polyfunctional, hydroxy-reactive crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. The composition may also be formulated as a high solids composition sprayable with conventional spraying equipment. Hydroxy-functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. The precursor is the reaction product of modified diepoxide and hydroxy functional secondary amine in about a 1:1 equivalent ratio. The modified diepoxide is the reaction product of polymerization of lactone monomers in the presence of diepoxide which has been reacted substantially simultaneously with diphenol and dicarboxylic acid.
摘要翻译：一种溶剂型热固性涂料组合物，其包含羟基官能的环氧 - 聚酯接枝共聚物和多官能的羟基反应性交联剂。涂料组合物可以配制成适合用作耐磨损的机动车辆底漆的可热喷涂的高固含量涂料组合物，适用于通过石头，砾石和其它道路碎屑破碎的身体面板区域上。组合物也可以配制成可用常规喷雾设备喷雾的高固体组分。羟基官能的环氧 - 聚酯接枝共聚物是通过在羟基官能环氧酯树脂前体的存在下聚合内酯单体来制备的。前体是约1：1当量比的改性二环氧化物和羟基官能仲胺的反应产物。改性二环氧化物是在二酚与二酚和二羧酸基本同时反应的情况下内酯单体的聚合的反应产物。

2. 发明授权

US4734463A Hydroxy group-containing modified polyester with polymerized lactone monomers 失效
标题翻译：含羟基的改性聚酯与聚合内酯单体
公开(公告)号：US4734463A
公开(公告)日：1988-03-29
申请号：US813104
申请日：1985-12-24
申请人： Panagiotis I. Kordomenos , Andrew H. Dervan , Tab Semanision
发明人： Panagiotis I. Kordomenos , Andrew H. Dervan , Tab Semanision
IPC分类号： C08G63/46 , C08G18/10 , C08G18/12 , C08G18/83 , C09D167/08 , C08G63/08 , C08G63/18 , C08G63/20
CPC分类号： C08G18/831 , C08G18/10 , C08G18/12
摘要： A hydroxy functional urethane modified polyester resin and solvent-based thermosetting coating composition comprising said resin and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional urethane modified polyester resin is the product of polymerization of lactone monomers in the presence of hydroxy-containing urethane modified polyester precursor. The polymerization reaction mixture comprises between about 10 and about 80 weight percent the hydroxy-containing urethane modified polyester precursor and between about 90 and about 20 weight percent lactone monomers.
摘要翻译：包含所述树脂和封端多异氰酸酯交联剂的羟基官能聚氨酯改性聚酯树脂和溶剂型热固性涂料组合物。涂料组合物可以配制成适合用作耐磨损的机动车辆底漆的可热喷涂的高固含量涂料组合物，适合用于通过石头，砾石和其它道路碎屑破碎的车身面板区域上。或者，组合物可以配制成可用常规喷雾设备喷雾的高固体组分。羟基官能聚氨酯改性聚酯树脂是在含羟基的氨基甲酸酯改性聚酯前体存在下内酯单体聚合的产物。聚合反应混合物包含约10至约80重量％的含羟基的氨基甲酸酯改性聚酯前体和约90至约20重量％的内酯单体。

3. 发明授权

US4714744A Epoxy-polyester graft copolymers suitable for chip resistant coating composition I 失效
标题翻译：环氧聚酯接枝共聚物，适用于耐芯片涂料组合物I
公开(公告)号：US4714744A
公开(公告)日：1987-12-22
申请号：US877908
申请日：1986-06-23
申请人： Panagiotis I. Kordomenos , Andrew H. Dervan
发明人： Panagiotis I. Kordomenos , Andrew H. Dervan
IPC分类号： C08G18/42 , C08G18/46 , C08G18/79 , C08G18/80 , C08G59/02 , C08G59/42 , C08G59/62 , C08G59/64 , C08G63/08 , C09D163/00 , C08G59/16 , C08G63/18 , C08G63/20
CPC分类号： C09D163/00 , C08G18/4286 , C08G18/4294 , C08G18/4615 , C08G18/791 , C08G18/8061 , C08G59/02 , C08G59/4284 , C08G59/62 , C08G59/64 , C08G63/08
摘要： A hydroxy functional epoxy-polyester graft copolymer and novel, solvent-based thermosetting coating composition comprising said copolymer and polyfunctional, hydroxy-reactive crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. The composition may also be formulated as a high solids composition sprayable with conventional spraying equipment. Hydroxy-functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. The precursor is the reaction product of modified diepoxide and hydroxy functional secondary amine in about a 1:1 equivalent ratio. The modified diepoxide is the reaction product of polymerization of lactone monomers in the presence of diepoxide which has been reacted substantially simultaneously with diphenol and dicarboxylic acid.
摘要翻译：羟基官能环氧 - 聚酯接枝共聚物和新型溶剂型热固性涂料组合物，其包含所述共聚物和多官能的羟基反应性交联剂。涂料组合物可以配制成适合用作耐磨损的机动车辆底漆的可热喷涂的高固含量涂料组合物，适用于通过石头，砾石和其它道路碎屑破碎的身体面板区域上。组合物也可以配制成可用常规喷雾设备喷雾的高固体组分。羟基官能的环氧 - 聚酯接枝共聚物是通过在羟基官能环氧酯树脂前体的存在下聚合内酯单体来制备的。前体是约1：1当量比的改性二环氧化物和羟基官能仲胺的反应产物。改性二环氧化物是在二酚与二酚和二羧酸基本同时反应的情况下内酯单体的聚合的反应产物。

4. 发明授权

US4708995A Chip resistant primer composition I 失效
标题翻译：耐芯片底漆组合物I
公开(公告)号：US4708995A
公开(公告)日：1987-11-24
申请号：US798044
申请日：1985-11-14
申请人： Panagiotis I. Kordomenos , Andrew H. Dervan , Dennis J. Grebur
发明人： Panagiotis I. Kordomenos , Andrew H. Dervan , Dennis J. Grebur
IPC分类号： C08G18/42 , C08G18/64 , C08G18/79 , C08G18/80 , C08G59/06 , C08G59/62 , C08G63/08 , C09D163/00 , C08G63/06
CPC分类号： C08G18/6407 , C08G18/4269 , C08G18/791 , C08G18/8061 , C08G59/066 , C08G59/62 , C08G59/625 , C08G63/08 , C09D163/00
摘要： A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer suitable for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of lactone members in the presence of hydroxy functional epoxy ester resin precursor. The precursor resin is the reaction product of diepoxide chain extended with diphenol and chain terminated with acid component comprising primary hydroxy functional acid. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree. C. and the polymerization reaction mixture comprises between about 10 and about 80 weight percent the hydroxy functional epoxy ester resin precursor and between about 90 and about 20 weight percent lactone monomers.
摘要翻译：包含所述共聚物和封端多异氰酸酯交联剂的羟基官能环氧 - 聚酯接枝共聚物和溶剂型热固性涂料组合物。涂料组合物可以配制成适合用作耐磨损的机动车底漆的可热喷涂的高固含量涂料组合物，适用于通过石头，砾石和其它道路碎屑破碎的车身面板区域上。或者，组合物可以配制成可用常规喷雾设备喷雾的高固体组分。羟基官能环氧 - 聚酯接枝共聚物是在羟基官能环氧酯树脂前体存在下内酯成分聚合的产物。前体树脂是与二酚延伸的双环氧化物链和用包含伯羟基官能酸的酸组分链终止的反应产物。内酯单体的聚合在约50℃至约300℃的温度下进行，聚合反应混合物占羟基官能环氧酯树脂前体的约10至约80重量％，约90至约80重量％约20重量％的内酯单体。

5. 发明授权

US4701502A Chip resistant primer composition V' 失效
标题翻译：耐芯片底漆组合物V'
公开(公告)号：US4701502A
公开(公告)日：1987-10-20
申请号：US808763
申请日：1985-12-13
申请人： Panagiotis I. Kordomenos , Andrew H. Dervan , Dennis J. Grebur
发明人： Panagiotis I. Kordomenos , Andrew H. Dervan , Dennis J. Grebur
IPC分类号： C08G18/42 , C08G59/12 , C08G59/42 , C08G59/62 , C08G63/08 , C09D163/00 , C09D167/04 , C08G63/06 , C08G63/02 , C08G63/66
CPC分类号： C09D167/04 , C08G18/4202 , C08G18/4294 , C08G59/12 , C08G59/4284 , C08G59/625 , C08G63/08 , C09D163/00
摘要： Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy ester resin, linear polycaprolactone diol, and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy ester resin is formed by reaction of diepoxide chain extended with dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.
摘要翻译：溶剂型热固性涂料组合物，其包含羟基官能环氧酯树脂，线型聚己内酯二醇和封端多异氰酸酯交联剂。涂料组合物可以配制成适合用作耐磨损的机动车辆底漆的可热喷涂的高固含量涂料组合物，适合用于通过石头，砾石和其它道路碎屑破碎的身体面板区域上。或者，组合物可以配制成可用常规喷雾设备喷雾的高固体组分。羟基官能环氧酯树脂通过与二羧酸延伸的二环氧化物链和用包含伯羟基官能酸的酸组分链终止的反应形成。

6. 发明授权

US4699959A Chip resistant primer composition VIII 失效
标题翻译：耐芯片底漆组合物VIII
公开(公告)号：US4699959A
公开(公告)日：1987-10-13
申请号：US809643
申请日：1985-12-16
申请人： Panagiotis I. Kordomenos , Andrew H. Dervan , Dennis J. Grebur
发明人： Panagiotis I. Kordomenos , Andrew H. Dervan , Dennis J. Grebur
IPC分类号： C08G18/40 , C08G18/64 , C08G18/79 , C08G18/80 , C08G63/66 , C08L63/02
CPC分类号： C08G18/4081 , C08G18/6407 , C08G18/791 , C08G18/8009 , C08G18/8061
摘要： Solvent-based thermosetting coating composition comprising a hydroxy functional epoxy amine adduct linear polycaprolactone diol and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy amine adduct is the reaction product of diepoxide chain extended with aliphatic diol and chain terminated with hydroxy functional secondary amine.
摘要翻译：溶剂型热固性涂料组合物，其包含羟基官能的环氧胺加合物线性聚己内酯二醇和封端的多异氰酸酯交联剂。涂料组合物可以配制成适合用作耐磨损的机动车辆底漆的可热喷涂的高固含量涂料组合物，适合用于通过石头，砾石和其它道路碎屑破碎的身体面板区域上。或者，组合物可以配制成可用常规喷雾设备喷雾的高固体组分。羟基官能环氧胺加合物是与脂肪族二醇延伸的二环氧化物链和用羟基官能的仲胺终止的链的反应产物。

7. 发明授权

US4698402A Chip resistant primer composition IV 失效
标题翻译：耐芯片底漆组合物IV
公开(公告)号：US4698402A
公开(公告)日：1987-10-06
申请号：US809605
申请日：1985-12-16
申请人： Panagiotis I. Kordomenos , Andrew H. Dervan , Dennis J. Grebur
发明人： Panagiotis I. Kordomenos , Andrew H. Dervan , Dennis J. Grebur
IPC分类号： C08G18/42 , C08G18/79 , C08G18/80 , C08G59/04 , C08G59/64 , C08G63/08 , C09D163/00 , C08G59/14 , C08L63/02
CPC分类号： C09D163/00 , C08G18/4269 , C08G18/4294 , C08G18/791 , C08G18/8061 , C08G59/04 , C08G59/64 , C08G63/08
摘要： An hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy functional epoxy-polyester graft copolymer is the product of polymerization of certain lactone monomers in the presence of hydroxy functional epoxy amine adduct precursor. The precursor resin is the reaction product of diepoxide with aliphatic diol and, subsequently, with hydroxy functional secondary amine. The polymerization of the lactone monomers is carried out at a temperature between about 50.degree. C. and about 300.degree. C. and the polymerization reaction mixture comprises between about 10 and about 80 weight percent hydroxy functional epoxy amine adduct precursor and between about 90 and about 20 weight percent lactone monomers.
摘要翻译：包含所述共聚物和封端多异氰酸酯交联剂的羟基官能环氧 - 聚酯接枝共聚物和溶剂型热固性涂料组合物。涂料组合物可以配制成适合用作耐磨损的机动车辆底漆的可热喷涂的高固含量涂料组合物，适合用于通过石头，砾石和其它道路碎屑破碎的身体面板区域上。或者，组合物可以配制成可用常规喷雾设备喷雾的高固体组分。羟基官能环氧 - 聚酯接枝共聚物是在羟基官能环氧胺加合物前体存在下某些内酯单体的聚合的产物。前体树脂是二环氧化物与脂族二醇的反应产物，随后是羟基官能的仲胺。内酯单体的聚合在约50℃至约300℃的温度下进行，并且聚合反应混合物包含约10至约80重量％的羟基官能环氧胺加合物前体，约90至约80重量％ 20重量％的内酯单体。

8. 发明授权

US4698399A Chip resistant primer composition I' 失效
标题翻译：耐芯片底漆组合物I'
公开(公告)号：US4698399A
公开(公告)日：1987-10-06
申请号：US798079
申请日：1985-11-14
申请人： Panagiotis I. Kordomenos , Andrew H. Dervan , Dennis J. Grebur
发明人： Panagiotis I. Kordomenos , Andrew H. Dervan , Dennis J. Grebur
IPC分类号： C08G18/42 , C08G18/79 , C08G18/80 , C08G59/12 , C08G59/42 , C08G59/62 , C08G63/08 , C09D163/00 , C09D167/04 , C08G63/60 , C08L63/02 , C08L67/04
CPC分类号： C09D163/00 , C08G18/4269 , C08G18/4294 , C08G18/791 , C08G18/8061 , C08G59/12 , C08G59/4284 , C08G59/625 , C08G63/08 , C09D167/04
摘要： A hydroxy functional epoxy-polyester graft copolymer and solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. The coating composition may be formulated as a hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, the composition may be formulated as a high solids composition sprayable with conventional spraying equipment. The hydroxy-functional epoxy-polyester graft copolymer is prepared by polymerization of lactone monomers in the presence of hydroxy functional epoxy ester resin precursor. Such precursor resin is formed by reaction of diepoxide chain extended with dicarboxylic acid and chain terminated with acid component comprising primary hydroxy functional acid.
摘要翻译：包含所述共聚物和封端多异氰酸酯交联剂的羟基官能环氧 - 聚酯接枝共聚物和溶剂型热固性涂料组合物。涂料组合物可以配制成适合用作耐磨损的机动车辆底漆的可热喷涂的高固含量涂料组合物，适用于通过石头，砾石和其它道路碎屑破碎的身体面板区域上。或者，组合物可以配制成可用常规喷雾设备喷雾的高固体组分。羟基官能的环氧 - 聚酯接枝共聚物是通过在羟基官能的环氧酯树脂前体的存在下聚合内酯单体来制备的。这种前体树脂通过与二羧酸延伸的二环氧化物链和用包含伯羟基官能酸的酸组分链终止的反应形成。

9. 发明授权

US4533684A Thermosetting coating composition useful as chip resistant primer II 失效
公开(公告)号：US4533684A
公开(公告)日：1985-08-06
申请号：US564143
申请日：1983-12-22
申请人： Panagiotis I. Kordomenos , Andrew H. Dervan , Dennis J. Grebur
发明人： Panagiotis I. Kordomenos , Andrew H. Dervan , Dennis J. Grebur
IPC分类号： C08G18/42 , C08G18/46 , C08G18/80 , C08L63/02 , C08L67/04
CPC分类号： C08G18/8061 , C08G18/4269 , C08G18/4615
摘要： Novel epoxy-polyester graft copolymer and novel, solvent-based thermosetting coating composition comprising said copolymer and blocked polyisocyanate crosslinking agent. Coating composition may be formulated as hot sprayable, high solids coating composition suitable for use as a chip resistant automotive vehicle primer adapted for use on body panel areas subject to chipping by stones, gravel and other road debris. Alternatively, composition may be formulated as a high solids composition sprayable with conventional spraying equipment. Epoxy-polyester monomers in presence of hydroxy functional epoxy ester resin precursor. Precursor resin is formed by reaction of diepoxide, chain extended with diphenol and dicarboxylic acid, with hydroxy functional secondary amine in chain terminating reaction.

10. 发明授权

US4491663A Trifunctional blocked isocyanate containing an isocyanurate ring 失效
标题翻译：含有异氰脲酸酯环的三官能封端异氰酸酯
公开(公告)号：US4491663A
公开(公告)日：1985-01-01
申请号：US614719
申请日：1984-05-29
申请人： Panagiotis I. Kordomenos , Andrew H. Dervan
发明人： Panagiotis I. Kordomenos , Andrew H. Dervan
IPC分类号： C07D251/34 , C08G18/42 , C08G18/79 , C08G18/80
CPC分类号： C08G18/4294 , C07D251/34 , C08G18/791 , C08G18/8061
摘要： Novel trifunctinal blocked isocyanates containing an isocyanurate ring and method of preparing are disclosed. Use of blocked isocyanates of invention as crosslinker for aqueous and nonaqueous compositions is also taught.
摘要翻译：公开了含有异氰脲酸酯环的新型三点封闭异氰酸酯及其制备方法。还教导了使用本发明的封闭异氰酸酯作为水性和非水性组合物的交联剂。

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