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1. 发明授权

US4695440A Crystalline aluminosilicate ISI-6 失效
标题翻译：结晶硅铝酸盐ISI-6
公开(公告)号：US4695440A
公开(公告)日：1987-09-22
申请号：US790741
申请日：1986-01-09
申请人： Nobuyuki Morimoto , Kozo Takatsu , Michio Sugimoto
发明人： Nobuyuki Morimoto , Kozo Takatsu , Michio Sugimoto
IPC分类号： B01J29/70 , C01B39/44 , C07C1/04 , C07C1/20 , C01B33/28
CPC分类号： C07C1/044 , B01J29/70 , C01B39/445 , C07C1/043 , C07C1/0435 , C07C1/20 , C07C2529/65
摘要： A crystalline aluminosilicate, ISI-6, having a composition represented by the general formula (I) after being calcined in air at 550.degree. C., .sub.p M.sub.2/n O.Al.sub.2 O.sub.3.q SiO.sub.2 . . . (I) wherein M represents at least one element selected from hydrogen, alkali metals, and alkaline earth metals, n represents the valence of M, and p and q are within the ranges of 0.05.ltoreq.p.ltoreq.3.0 and 60.ltoreq.q.ltoreq.500.

2. 发明授权

US4578259A Process for preparing a crystalline aluminosilicate 失效
标题翻译：制备结晶硅铝酸盐的方法
公开(公告)号：US4578259A
公开(公告)日：1986-03-25
申请号：US582529
申请日：1984-02-22
申请人： Nobuyuki Morimoto , Kozo Takatsu , Michio Sugimoto
发明人： Nobuyuki Morimoto , Kozo Takatsu , Michio Sugimoto
IPC分类号： B01J29/70 , C01B39/44 , C07C1/04 , C07C1/20 , C01B33/28
CPC分类号： C07C1/044 , B01J29/70 , C01B39/445 , C07C1/043 , C07C1/0435 , C07C1/20 , C07C2529/65
摘要： Crystalline aluminosilicates, a process for the production thereof and uses therefor are disclosed. The crystalline aluminosilicates are of new crystalline structure, which, as determined after calcination in the air at 550.degree. C., have a composition represented by the general formula (I):pM.sub.2/n O.Al.sub.2 O.sub.3.qSiO.sub.2(the symbols are as defined in the appended claims) and give a principal X-ray diffraction pattern as shown in Table 1. They are used as catalysts for the conversion of synthesis gas or oxygen-containing organic compounds such as alcohol, ether into hydrocarbons.
摘要翻译：公开了结晶硅铝酸盐，其制备方法和用途。结晶硅铝酸盐具有新的结晶结构，其在550℃下在空气中煅烧后测定，具有由通式（I）表示的组成：pM2 / nO.Al2O3.qSiO2（符号如所附权利要求书），并给出如表1所示的主要X射线衍射图。它们用作将合成气或含氧有机化合物如醇，醚转化为烃的催化剂。

3. 发明授权

US4766263A Hydrocarbon synthesis process utilizing crystalline aluminosilicate catalyst 失效
标题翻译：使用结晶硅铝酸盐催化剂的烃合成方法
公开(公告)号：US4766263A
公开(公告)日：1988-08-23
申请号：US67965
申请日：1987-06-29
申请人： Nobuyuki Morimoto , Kozo Takatsu , Michio Sugimoto
发明人： Nobuyuki Morimoto , Kozo Takatsu , Michio Sugimoto
IPC分类号： B01J29/70 , C01B39/44 , C07C1/04 , C07C1/20
CPC分类号： C07C1/044 , B01J29/70 , C01B39/445 , C07C1/043 , C07C1/0435 , C07C1/20 , C07C2529/65
摘要： An improved process for producing hydrocarbons which comprises bringing oxygen-containing compounds into contact with a catalyst, said catalyst being a crystalline aluminosilicate, when determined after calcination in the air at 550.degree. C., having a composition represented by the following formula (I):pM.sub.2/n O.Al.sub.2 O.sub.3.qSiO.sub.2 (I)(wherein M represents at least one element selected from hydrogen, alkali metals, and alkaline earth metals, n represents the valence of M, and p and q each represent a molar ratio and are chosen within the ranges of 0.05.ltoreq.p.ltoreq.3.0, 5.ltoreq.q.ltoreq.500) and has a principal X-ray diffraction pattern as set forth in Table 1.

4. 发明申请

US20080081374A1 Coloration Agent for Carbonyl Sulfide, Detecting Means and Fuel Cell System 失效
标题翻译：羰基硫化物着色剂，检测手段和燃料电池系统
公开(公告)号：US20080081374A1
公开(公告)日：2008-04-03
申请号：US11659965
申请日：2005-08-05
申请人： Kozo Takatsu , Gakuji Takegoshi
发明人： Kozo Takatsu , Gakuji Takegoshi
IPC分类号： G01N31/00
CPC分类号： G01N31/22 , H01M8/04089 , H01M8/0618 , H01M8/0675 , Y10T436/18 , Y10T436/182 , Y10T436/196666 , Y10T436/200833
摘要： Provided are a coloration agent for carbonyl sulfide which contains a metal oxide, and at least one metal component selected from among a cerium component, a silver component, a copper component, a nickel component, and an iron component, the metal component being supported on the metal oxide, or which contains at least one metal oxide selected from among a cerium oxide, a silver oxide, a copper oxide, a nickel oxide, and an iron oxide; carbonyl sulfide detection means including the coloration agent for carbonyl sulfide; and a fuel cell system including the detection means. The coloration agent for carbonyl sulfide has the ability to develop a color in the presence of carbonyl sulfide even at ambient temperature, exhibits excellent performance in detecting carbonyl sulfide contained in a hydrocarbon fuel, and enables the service life of a desulfurizing agent to be determined through visual observation.
摘要翻译：提供了含有金属氧化物的硫化氢着色剂和选自铈成分，银成分，铜成分，镍成分和铁成分中的至少一种金属成分，金属成分被负载在金属氧化物，或者含有选自氧化铈，氧化银，氧化铜，氧化镍和氧化铁中的至少一种金属氧化物; 包括硫化碳着色剂的羰基硫化物检测手段; 以及包括检测装置的燃料电池系统。硫化钴着色剂即使在环境温度下也具有在硫化羰存在下显色的能力，在检测碳氢化合物燃料中所含的羰基硫化物方面表现出优异的性能，能够通过以下方式确定脱硫剂的使用寿命：目视观察。

5. 发明申请

US20050221977A1 Catalyst for reforming hydrocarbon and method for preparation thereof, and process for reforming hydrocarbon using said catalyst 有权
标题翻译：用于重整烃的催化剂及其制备方法，以及使用所述催化剂重整烃的方法
公开(公告)号：US20050221977A1
公开(公告)日：2005-10-06
申请号：US10472899
申请日：2002-03-26
申请人： Tetsuya Fukunaga , Tomoki Yanagino , Kozo Takatsu , Takashi Umeki
发明人： Tetsuya Fukunaga , Tomoki Yanagino , Kozo Takatsu , Takashi Umeki
IPC分类号： B01J21/04 , B01J23/34 , B01J23/40 , B01J23/46 , B01J23/58 , B01J23/63 , B01J23/656 , B01J23/755 , B01J23/78 , B01J23/889 , B01J23/89 , B01J37/02 , B01J37/08 , C01B3/40 , H01M8/06
CPC分类号： B01J37/0207 , B01J21/04 , B01J23/6562 , B01J23/8892 , B01J23/8913 , B01J23/892 , B01J23/894 , B01J23/8946 , B01J23/8986 , B01J37/0205 , B01J37/0236 , B01J37/08 , C01B3/40 , C01B2203/0233 , C01B2203/0238 , C01B2203/1052 , C01B2203/1064 , C01B2203/1082 , Y02P20/52
摘要： The present invention relates to a catalyst for reforming a hydrocarbon comprising a carrier containing manganese oxide and carried thereon (a) at least one component selected from a ruthenium component, a platinum component, a rhodium component, a palladium component, an iridium component and a nickel component and a process for producing the same and to a process for reforming a hydrocarbon (steam reforming, self thermal reforming, partial oxidation reforming and carbon dioxide reforming) using the above catalyst. Provided are a catalyst for reforming a hydrocarbon which comprises ruthenium, platinum, rhodium, palladium, iridium or nickel as an active component and in which a reforming activity is elevated, a process for producing the same, and a steam reforming process, a self thermal reforming process, a partial oxidation reforming process and a carbon dioxide reforming process for a hydrocarbon using the above catalyst.
摘要翻译：本发明涉及一种用于重整烃的催化剂，其包含含有氧化锰的载体，并在其上载持（a）至少一种选自钌组分，铂组分，铑组分，钯组分，铱组分和镍成分及其制造方法以及使用上述催化剂的碳氢化合物的重整方法（蒸汽重整，自热重整，部分氧化重整和二氧化碳重整）。提供一种用于重整烃的催化剂，其包含钌，铂，铑，钯，铱或镍作为活性组分，其中重整活性升高，其制备方法和蒸汽重整过程，自热重整过程，部分氧化重整过程和使用上述催化剂的烃的二氧化碳重整过程。

6. 发明授权

US06780386B1 Carbon monoxide oxidation catalyst, and method for production of hydrogen-containing gas 失效
标题翻译：一氧化碳氧化催化剂及含氢气体的制造方法
公开(公告)号：US06780386B1
公开(公告)日：2004-08-24
申请号：US09831908
申请日：2001-06-19
申请人： Tetsuya Fukunaga , Kozo Takatsu , Masatoshi Shibata , Satoshi Hachiya , Hiroyuki Endo
发明人： Tetsuya Fukunaga , Kozo Takatsu , Masatoshi Shibata , Satoshi Hachiya , Hiroyuki Endo
IPC分类号： C10K134
CPC分类号： C01B3/583 , B01J23/462 , B01J23/58 , C01B2203/044 , C01B2203/047 , C10K3/04 , H01M8/0662 , Y02P70/56
摘要： Provided is a catalyst for selective oxidation of CO gas in a gas of essentially hydrogen, and a method for producing the catalyst. The catalyst is highly active in a relatively high temperature range. The catalyst is for selectively oxidizing CO gas with hydrogen, and this carries ruthenium held on a carrier of titania and alumina, or carries ruthenium with an alkali metal and/or an alkaline earth metal held thereon. For producing the catalyst, a solution containing ruthenium and an alkali metal and/or an alkaline earth metal is applied to the carrier.
摘要翻译：本发明提供一种用于在基本上为氢的气体中选择性氧化CO气体的催化剂及其制备方法。该催化剂在较高的温度范围内具有高活性。该催化剂用于用氢气选择性地氧化CO气体，并且其携带保持在二氧化钛和氧化铝载体上的钌，或者携带其上保留有碱金属和/或碱土金属的钌。为了制备催化剂，将含有钌和碱金属和/或碱土金属的溶液施加到载体上。

7. 发明申请

US20080241039A1 METHOD FOR PRODUCTION OF CARBON MONOXIDE-REDUCED HYDROGEN-CONTAINING GAS 审中-公开
标题翻译：生产含一氧化碳还原氢气的方法
公开(公告)号：US20080241039A1
公开(公告)日：2008-10-02
申请号：US12032094
申请日：2008-02-15
申请人： Tetsuya FUKUNAGA , Kozo Takatsu , Masatoshi Shibata , Satoshi Hachiya , Hiroyuki Endo
发明人： Tetsuya FUKUNAGA , Kozo Takatsu , Masatoshi Shibata , Satoshi Hachiya , Hiroyuki Endo
IPC分类号： C10K3/04 , B01D53/62 , C01B3/16
CPC分类号： C01B3/583 , B01J23/462 , B01J23/58 , C01B2203/044 , C01B2203/047 , C10K3/04 , H01M8/0662 , Y02P70/56
摘要： A method for the oxidative removal of carbon monoxide from a hydrogen containing gas employing a catalyst for the selective oxidation of carbon monoxide is provided.
摘要翻译：提供了使用一氧化碳选择性氧化催化剂从含氢气体中氧化除去一氧化碳的方法。

8. 发明授权

US5436380A Process for producing aromatic hydrocarbons 失效
标题翻译：芳烃生产方法
公开(公告)号：US5436380A
公开(公告)日：1995-07-25
申请号：US177720
申请日：1994-01-05
申请人： Masahiko Sawa , Yasushi Wakushima , Kozo Takatsu
发明人： Masahiko Sawa , Yasushi Wakushima , Kozo Takatsu
IPC分类号： B01J29/04 , B01J29/87 , C07B61/00 , C07C5/41 , C07C15/02 , C10G35/095 , C07C2/82
CPC分类号： C10G35/095 , B01J29/87
摘要： A process for producing aromatic hydrocarbons comprises bringing hydrocarbons having 2 to 12 carbon atoms into contact with a modified crystalline galloaluminosilicate catalyst prepared by treating a crystalline galloaluminosilicate having a tool ratio of SiO.sub.2 /(Ga.sub.2 O.sub.3 +Al.sub.2 O.sub.3) in the range from 5 to 1000 with a sulfur-containing substance. The process of the invention is simple and suited for general application and the catalyst can be prepared at a low cost. Aromatic hydrocarbons can be produced efficiently from the material hydrocarbons by bringing them into contact with the modified galloaluminosilicate having the excellent catalytic activity. The process of the invention can be adopted widely and effectively in the petroleum refining, in the petroleum chemistry and in the chemical industry in general.
摘要翻译：一种制备芳族烃的方法包括使具有2-12个碳原子的烃与通过将具有SiO 2 /（Ga 2 O 3 + Al 2 O 3）的工具比率的结晶镓铝硅酸盐处理在5至1000范围内的改性结晶镓铝硅酸盐催化剂接触，含硫物质。本发明的方法简单，适用于一般应用，催化剂可以低成本制备。可以通过使其与具有优异催化活性的改性的铝硅酸铝接触而从材料烃中有效地生产芳族烃。本发明的方法可广泛有效地用于石油炼制，石油化工和化工行业。

9. 发明申请

US20060108262A1 Method for removing sulfur compound in hydrocarbon-containing gas 有权
标题翻译：在含烃气体中除去硫化合物的方法
公开(公告)号：US20060108262A1
公开(公告)日：2006-05-25
申请号：US10540881
申请日：2003-12-24
申请人： Kozo Takatsu , Gakuji Takegoshi
发明人： Kozo Takatsu , Gakuji Takegoshi
IPC分类号： C10G27/00
CPC分类号： C10L3/102 , B01D53/04 , B01D2253/10 , B01D2253/108 , B01D2253/112 , B01D2256/16 , B01D2257/30 , B01D2257/304 , B01D2259/4009 , B01J20/186 , B01J21/12 , B01J23/72 , B01J23/755 , B01J29/06 , B01J35/0006 , C01B3/38 , C01B2203/1258 , C01B2203/127 , C10L3/00 , C10L3/10 , H01M8/0662 , Y02P20/52
摘要： Provided are a method for removing sulfur compounds contained in a hydrocarbon-containing gas in which in feeding a hydrocarbon-containing gas to a desulfurizing bed to remove sulfur compounds contained in the above gas, used is the desulfurizing bed constituted from a desulfurizing agent A comprising zeolite and a desulfurizing agent B comprising at least one selected from a metal element, a metal oxide and a metal component-carried oxide, and a production process of hydrogen for a fuel cell in which a hydrocarbon-containing gas subjected to desulfurization treatment by the above method is brought into contact with a partial oxidation reforming catalyst, an autothermal reforming catalyst or a steam reforming catalyst. According to the method of the present invention, combined use of two kinds of the desulfurizing agents having different desulfurizing performances and use of a raw material gas having a low concentration of carbonyl sulfide make it possible to efficiently remove all of sulfur compounds contained in a hydrocarbon-containing gas to a low concentration even at a room temperature. Further, hydrogen for a fuel cell can economically advantageously be produced by subjecting the desulfurization-treated hydrocarbon-containing gas obtained by the method described above to reforming treatment.
摘要翻译：提供了一种除去含烃气体中含有的硫化合物的方法，其中在将含烃气体供给到脱硫床中以除去上述气体中所含的硫化合物时使用的脱硫剂是由脱硫剂A构成的脱硫剂，所述脱硫剂包含沸石和包含选自金属元素，金属氧化物和金属成分负载氧化物中的至少一种的脱硫剂B和用于燃料电池的氢气的制造方法，其中通过所述燃料电池进行脱硫处理的含烃气体使上述方法与部分氧化重整催化剂，自热重整催化剂或蒸汽重整催化剂接触。根据本发明的方法，组合使用具有不同脱硫性能的两种脱硫剂和使用具有低浓度硫化羰的原料气体，可以有效地除去烃中所含的全部硫化合物即使在室温下也含有低浓度的气体。此外，通过将通过上述方法获得的脱硫处理过的含烃气体进行重整处理，可以有利地生产用于燃料电池的氢。

10. 发明授权

US5336393A Process for catalytically converting organic compounds 失效
标题翻译：催化转化有机化合物的方法
公开(公告)号：US5336393A
公开(公告)日：1994-08-09
申请号：US890580
申请日：1992-05-28
申请人： Kozo Takatsu , Yasushi Wakushima , Hiroharu Masunaga , Masahiko Sawa
发明人： Kozo Takatsu , Yasushi Wakushima , Hiroharu Masunaga , Masahiko Sawa
IPC分类号： B01J29/40 , B01J29/87 , C01B39/06 , C01B39/38 , C01B39/40 , C07C4/06 , C07C5/41 , C10G35/06 , C07C2/00 , C10G11/05
CPC分类号： C01B39/38 , B01J29/40 , B01J29/87 , C01B39/065 , C01B39/40 , C07C4/06 , C07C5/41 , C10G35/065 , B01J2229/26 , B01J2229/36 , B01J2229/42 , C07C2529/70 , C07C2529/74 , C07C2529/76
摘要： Catalytic conversion of organic compounds wherein catalysts come into contact with steam is performed efficiently by using a catalyst which comprises an MFI type zeolite having a ratio of SiO.sub.2 /(Al.sub.2 O.sub.3 +Ga.sub.2 O.sub.3) of 20 to 200 in molar ratio, a ratio of Ga.sub.2 O.sub.3 /Al.sub.2 O.sub.3 of 0 to 50 in molar ratio and a ratio of peak intensity of SiOH, I.sub.SiOH, to peak intensity of acidic OH, I.sub.H.sup.+, determined from .sup.1 H-NMR, I.sub.SiOH /I.sub.H.sup.+, of 0 to 0.5 and loses little catalytic activity on exposure to steam.
摘要翻译：通过使用包含SiO 2 /（Al 2 O 3 + Ga 2 O 3）的摩尔比为20〜200的MFI型沸石，Ga 2 O 3 / Al 2 O 3的比例的催化剂有效地进行催化剂与蒸汽接触的有机化合物的催化转化 0〜50摩尔比，1 H-NMR，ISiOH / IH +测定的SiOH，ISiOH峰强度与酸性OH，1H +峰强度的比值为0〜0.5，在蒸汽暴露时几乎没有催化活性。

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