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1. 发明授权

US5485250A Electrophotographic apparatus with photosensitive member having surface layer of binder resin and fluoro and/or silicon compound particles 失效
标题翻译：具有感光构件的电子照相设备，其具有粘合剂树脂的表面层和氟化物和/或硅化合物颗粒
公开(公告)号：US5485250A
公开(公告)日：1996-01-16
申请号：US289269
申请日：1994-08-11
申请人： Noboru Kashimura , Harumi Sakoh , Kazushige Nakamura , Shoji Amamiya , Takashige Kasuya , Haruyuki Tsuji , Masaaki Yamagami , Tatsuya Ikezue
发明人： Noboru Kashimura , Harumi Sakoh , Kazushige Nakamura , Shoji Amamiya , Takashige Kasuya , Haruyuki Tsuji , Masaaki Yamagami , Tatsuya Ikezue
IPC分类号： G03G5/05 , G03G5/147 , G03G5/00
CPC分类号： G03G5/0592 , G03G5/0539 , G03G5/0578 , G03G5/14726 , G03G5/14773 , G03G5/14791
摘要： An electrophotographic apparatus is disclosed which has an electrophotographic photosensitive member and a transfer device. The photosensitive member has a conductive support and a photosensitive layer, and further has a surface layer formed of a binder resin, fluorine atom- or silicon atom-containing compound particles incompatible with the binder resin, and a fluorine atom- or silicon atom-containing compound compatible with the binder resin. In the surface layer, the proportion of fluorine atoms and silicon atoms to carbon atoms, (F+Si)/C, as measured by X-ray photoelectron spectroscopy is 0.01 to 1.0. Additionally, the transfer device is a multiple-transfer device.
摘要翻译：公开了一种具有电子照相感光构件和转印装置的电子照相装置。感光构件具有导电性支持体和感光层，并且还具有由粘合剂树脂，与粘合剂树脂不相容的含氟原子或含硅原子的化合物颗粒以及含氟原子或硅原子形成的表面层化合物与粘合剂树脂相容。在表面层中，通过X射线光电子能谱测定的氟原子和硅原子与碳原子的比例（F + Si）/ C为0.01〜1.0。此外，传送设备是多传送设备。

2. 发明授权

US5357320A Electrophotographic apparatus 失效
标题翻译：电子照相设备
公开(公告)号：US5357320A
公开(公告)日：1994-10-18
申请号：US114925
申请日：1993-09-02
申请人： Noboru Kashimura , Harumi Sakoh , Kazushige Nakamura , Shoji Amamiya , Takashige Kasuya , Haruyuki Tsuji , Masaaki Yamagami , Tatsuya Ikezue
发明人： Noboru Kashimura , Harumi Sakoh , Kazushige Nakamura , Shoji Amamiya , Takashige Kasuya , Haruyuki Tsuji , Masaaki Yamagami , Tatsuya Ikezue
IPC分类号： G03G5/05 , G03G5/147 , G03G5/00
CPC分类号： G03G5/0592 , G03G5/0539 , G03G5/0578 , G03G5/14726 , G03G5/14773 , G03G5/14791
摘要： An electrophotographic apparatus is disclosed which has an electrophotographic photosensitive member and a transfer member. The photosensitive member has a conductive support and a photosensitive layer, and further has a surface layer formed of a binder resin, fluorine atom- or silicon atom-containing compound particles incompatible with the binder resin, and a fluorine atom- or silicon atom-containing compound compatible with the binder resin. In the surface layer, the proportion of fluorine atoms and silicon atoms to carbon atoms, (F+Si)/C, as measured by X-ray photoelectron spectroscopy is 0.01 to 1.0. Additionally, the transfer member is a multiple-transfer member.
摘要翻译：公开了一种具有电子照相感光构件和转印构件的电子照相设备。感光构件具有导电性支持体和感光层，并且还具有由粘合剂树脂，与粘合剂树脂不相容的含氟原子或含硅原子的化合物颗粒以及含氟原子或硅原子形成的表面层化合物与粘合剂树脂相容。在表面层中，通过X射线光电子能谱测定的氟原子和硅原子与碳原子的比例（F + Si）/ C为0.01〜1.0。另外，转印构件是多重转印构件。

3. 发明授权

US5455135A Electrophotographic photosensitive member with overlayer and electrophotographic apparatus employing same 失效
标题翻译：带有覆盖层和使用其的电子照相设备的电子照相感光构件
公开(公告)号：US5455135A
公开(公告)日：1995-10-03
申请号：US167049
申请日：1993-12-16
申请人： Akio Maruyama , Kazushige Nakamura , Shoji Amamiya , Shin Nagahara , Haruyuki Tsuji , Masaaki Yamagami , Michiyo Sekiya
发明人： Akio Maruyama , Kazushige Nakamura , Shoji Amamiya , Shin Nagahara , Haruyuki Tsuji , Masaaki Yamagami , Michiyo Sekiya
IPC分类号： G03G5/147 , G03G15/22
CPC分类号： G03G5/14704 , G03G5/14786 , G03G5/14791
摘要： An electrophotographic photosensitive member includes an electroconductive substrate, a photosensitive layer disposed on the electroconductive substrate, and a protective layer disposed on the photosensitive layer, the protective layer containing a resin formed by polymerization of compounds each having two or more ion polymerizable functional groups, and electroconductive particles.
摘要翻译：电子照相感光构件包括导电衬底，设置在导电衬底上的感光层和设置在感光层上的保护层，保护层含有通过具有两个或更多个离子可聚合官能团的化合物聚合形成的树脂，以及导电颗粒。

4. 发明授权

US06215971B1 Electrophotographic image-forming method, electrophotographic image-forming apparatus, and process cartridge 有权
标题翻译：电子照相成像方法，电照相成像装置和处理盒
公开(公告)号：US06215971B1
公开(公告)日：2001-04-10
申请号：US09536848
申请日：2000-03-28
申请人： Harumi Sakoh , Haruyuki Tsuji , Shinji Takagi
发明人： Harumi Sakoh , Haruyuki Tsuji , Shinji Takagi
IPC分类号： G03G1500
CPC分类号： G03G15/751 , G03G5/04 , G03G5/147 , G03G5/14704 , G03G2215/021 , G03G2221/0005
摘要： An electrophotographic image-forming method has a contact charging step of charging the surface of an electrophotographic photosensitive member; an electrostatic latent image forming step of forming an electrostatic latent image on the surface of the electrophotographic photosensitive member charged; a developing step of developing the electrostatic latent image formed into a toner image; and a transfer step of transferring the toner image formed by the development from the electrophotographic photosensitive member to a transfer material, the developing step serving also as a cleaning step for collecting a toner remaining on the electrophotographic photosensitive member after transfer. The toner contains an external additive and the electrophotographic photosensitive member has surface properties of universal hardness of 200 N/mm2 or above (provided that a curve that represents the relationship between hardness and depth of indentation by an indenter has no point of inflection) and a coefficient of surface friction of from 0.01 to 1.2.
摘要翻译：电子照相图像形成方法具有对电子照相感光构件的表面进行充电的接触充电步骤; 静电潜像形成步骤，在被充电的电照相感光构件的表面上形成静电潜像; 将形成为调色剂图像的静电潜像显影的显影步骤; 以及将通过显影形成的调色剂图像从电子照相感光构件转印到转印材料的转印步骤，显影步骤还用作在转印后收集在电子照相感光构件上残留的调色剂的清洁步骤。调色剂含有外部添加剂，并且电子照相感光构件具有200N / mm 2以上的通用硬度的表面特性（条件是表示硬度与压头的压痕深度之间的关系没有拐点的曲线）和表面摩擦系数为0.01〜1.2。

5. 发明授权

US09256145B2 Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus 有权
标题翻译：电子照相感光构件，处理盒和电子照相设备
公开(公告)号：US09256145B2
公开(公告)日：2016-02-09
申请号：US13384852
申请日：2010-09-03
申请人： Atsushi Fujii , Haruyuki Tsuji , Hideaki Matsuoka , Kazuhisa Shida , Nobuhiro Nakamura
发明人： Atsushi Fujii , Haruyuki Tsuji , Hideaki Matsuoka , Kazuhisa Shida , Nobuhiro Nakamura
IPC分类号： G03G5/04 , G03G5/08 , G03G5/14
CPC分类号： G03G5/08 , G03G5/104 , G03G5/142 , G03G5/144
摘要： An electrophotographic photosensitive member that can not easily cause charging lines even where it is an electrophotographic photosensitive member employing as a conductive layer a layer containing metal oxide particles is disclosed. Also disclosed are a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member. The electrophotographic photosensitive member has a conductive layer which contains titanium oxide particles coated with tin oxide doped with phosphorus or tungsten.
摘要翻译：公开了即使在作为导电层使用含有金属氧化物颗粒的层的电子照相感光构件的情况下也不容易引起充电线的电子照相感光构件。还公开了具有这种电子照相感光构件的处理盒和电子照相设备。电子照相感光构件具有包含掺杂有磷或钨的氧化锡的氧化钛颗粒的导电层。

6. 发明授权

US09046797B2 Process for producing electrophotographic photosensitive member 有权
标题翻译：电子照相感光构件的制造方法
公开(公告)号：US09046797B2
公开(公告)日：2015-06-02
申请号：US13983994
申请日：2012-03-01
申请人： Atsushi Fujii , Hideaki Matsuoka , Haruyuki Tsuji , Nobuhiro Nakamura , Kazuhisa Shida
发明人： Atsushi Fujii , Hideaki Matsuoka , Haruyuki Tsuji , Nobuhiro Nakamura , Kazuhisa Shida
IPC分类号： G03G5/00 , G03G7/00 , G03G5/10 , G03G5/14 , G03G5/05
CPC分类号： G03G7/0053 , G03G5/0507 , G03G5/0525 , G03G5/10 , G03G5/104 , G03G5/142 , G03G5/144
摘要： To provide a process for producing an electrophotographic photosensitive member that can not easily cause any fog due to an increase in dark attenuation, a conductive layer is formed with use of a coating liquid for conductive layer prepared with use of a solvent, a binder material and metal oxide particles. The metal oxide particles (P) and binder material (B) in the coating liquid for conductive layer are in a mass ratio (P/B) of from 1.5/1.0 to 3.5/1.0. The metal oxide particle is a titanium oxide particle coated with tin oxide doped with phosphorus or tungsten. Where powder resistivity of the metal oxide particle is represented by x (Ω·cm) and powder resistivity of the titanium oxide particle as a core particle constituting the metal oxide particle is represented by y (Ω·cm), the y and the x satisfy the following relations (i) and (ii): 5.0×107≦y≦5.0×109 (i) 1.0×102≦y/x≦1.0×106 (ii).
摘要翻译：为了提供一种用于制造由于暗衰减增加而不容易引起灰雾的电子照相感光构件的制造方法，使用通过使用溶剂，粘合剂材料和粘合剂材料制备的导电层用涂布液形成导电层，金属氧化物颗粒。用于导电层的涂布液中的金属氧化物颗粒（P）和粘合剂材料（B）的质量比（P / B）为1.5 / 1.0至3.5 / 1.0。金属氧化物颗粒是涂覆有掺杂有磷或钨的氧化锡的氧化钛颗粒。当金属氧化物颗粒的粉末电阻率由x（＆OHgr·cm）表示，作为构成金属氧化物颗粒的核心颗粒的氧化钛颗粒的粉末电阻率由y（＆Omega; cm）表示时，y和 x满足以下关系式（i）和（ii）：5.0×107＆nlE; y＆nlE; 5.0×109（i）1.0×102＆nlE; y / x＆nlE; 1.0×106（ii）。

7. 发明授权

US08778580B2 Electrophotographic photosensitive member, process cartridge, and electrophotographic apparatus 有权
标题翻译：电子照相感光构件，处理盒和电子照相设备
公开(公告)号：US08778580B2
公开(公告)日：2014-07-15
申请号：US13384149
申请日：2010-09-03
申请人： Haruyuki Tsuji , Atsushi Fujii , Hideaki Matsuoka
发明人： Haruyuki Tsuji , Atsushi Fujii , Hideaki Matsuoka
IPC分类号： G03G5/04
CPC分类号： G03G5/144 , G03G5/102 , G03G5/142
摘要： An electrophotographic photosensitive member having a specific conductive layer and promising less variation in light-area potential and residual potential in reproducing images repeatedly, and a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member are provided. Where a test in which a voltage of −1.0 kV having only a DC voltage component is continuously applied to the conductive layer for 1 hour is conducted, the conductive layer has volume resistivity satisfying the following mathematical expressions (1) and (2), as values before and after the test: −2.00≦(log|ρ2|−log|ρ1|)≦2.00 (1), and 1.0×108≦ρ1≦2.0×1013 (2), where, in the expressions (1) and (2), ρ1 is volume resistivity (Ω·cm) of the conductive layer as measured before the test and ρ2 is volume resistivity (Ω·cm) of the conductive layer as measured after the test.
摘要翻译：提供具有特定导电层的电子照相感光构件，并且重复地再现图像中的光区电位和剩余电位的变化较小，以及具有这种电子照相感光构件的处理盒和电子照相设备。在进行1小时的连续施加直流电压成分的-1.0kV的电压的试验中，导电层的体积电阻率满足下述数学式（1）和（2），如测试前后的值：-2.00＆nlE;（log |＆rgr; 2 | -log |＆rgr; 1 |）＆nlE; 2.00（1）和1.0×108＆nlE;＆rgr; 1＆nlE; 2.0×1013（2）在表达式（1）和（2）中，＆rgr; 1是测试前测量的导电层的体积电阻率（＆OHgr;·cm），2是导电层的体积电阻率（＆OHgr·cm）在测试后测量。

8. 发明申请

US20130323632A1 ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE AND ELECTROPHOTOGRAPHIC APPARATUS, AND METHOD OF MANUFACTURING ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER 有权
标题翻译：电子照相感光构件，工艺盒和电子照相装置及其制造电子感光构件的方法
公开(公告)号：US20130323632A1
公开(公告)日：2013-12-05
申请号：US13984264
申请日：2012-03-01
申请人： Atsushi Fujii , Hideaki Matsuoka , Haruyuki Tsuji , Kazuhisa Shida , Nobuhiro Nakamura
发明人： Atsushi Fujii , Hideaki Matsuoka , Haruyuki Tsuji , Kazuhisa Shida , Nobuhiro Nakamura
IPC分类号： G03G15/00 , G03G21/18
CPC分类号： G03G5/087 , G03G5/0507 , G03G5/0525 , G03G5/104 , G03G5/142 , G03G5/144 , G03G21/1814
摘要： Provided are an electrophotographic photosensitive member in which leakage doesn't easily occur, a process cartridge and an electrophotographic apparatus each including the electrophotographic photosensitive member, and a method of manufacturing the electrophotographic photosensitive member. The electrophotographic photosensitive member includes a conductive layer including titanium oxide particle coated with tin oxide doped with a hetero element. When an absolute value of a maximum current amount flowing through the conductive layer in a case of performing a test of applying −1.0 kV including DC voltage to the conductive layer is defined as Ia, and an absolute value of a current amount flowing through the conductive layer in a case where a decrease ratio of a current amount per minute reaches 1% or less for the first time is defined as Ib, the relations of Ia≦6000 and 10≦Ib are satisfied. A volume resistivity of the conductive layer before the test is 1.0×108 Ω·cm to 5.0×1012 Ω·cm.
摘要翻译：提供了不容易发生泄漏的电子照相感光构件，各自包括电子照相感光构件的处理盒和电子照相设备以及制造电子照相感光构件的方法。电子照相感光构件包括导电层，该导电层包括用掺杂有异质元素的氧化锡涂覆的氧化钛颗粒。在对导电层进行包含直流电压-1.0kV的试验的情况下，流过导电层的最大电流量的绝对值定义为Ia，流过导电性的电流量的绝对值在每分钟的电流量的降低比率首次达到1％以下的情况下，层被定义为Ib，满足Ia @ 6000和10 @ Ib的关系。试验前的导电层的体积电阻率为1.0×108Ω·cm〜5.0×1012Ω·cm。

9. 发明授权

US08455170B2 Method for producing electrophotographic photosensitive member 有权
标题翻译：电子照相感光构件的制造方法
公开(公告)号：US08455170B2
公开(公告)日：2013-06-04
申请号：US13409439
申请日：2012-03-01
申请人： Nobuhiro Nakamura , Hideaki Matsuoka , Atsushi Fujii , Haruyuki Tsuji , Kazuhisa Shida
发明人： Nobuhiro Nakamura , Hideaki Matsuoka , Atsushi Fujii , Haruyuki Tsuji , Kazuhisa Shida
IPC分类号： G03G5/04
CPC分类号： G03G5/104 , G03G5/144
摘要： An electrophotographic photosensitive member is provided in which black spots on an output image are hardly caused by local charge injection from a support to a photosensitive layer. For this purpose, a conductive layer is formed using a coating liquid for a conductive layer prepared using a solvent, a binder material and a metal oxide particle that satisfies the following relation (i): 45≦A×ρ×D≦65 (i) wherein A denotes the surface area of the metal oxide particle per unit mass [m2/g], D denotes the number average particle diameter of the metal oxide particle [μm], and ρ denotes the density of the metal oxide particle [g/cm3]. The metal oxide particle is a titanium oxide particle coated with tin oxide doped with phosphorus.
摘要翻译：提供一种电子照相感光构件，其中输出图像上的黑点几乎不会由从支持体到感光层的局部电荷注入引起。为此，使用使用满足以下关系式（i）的溶剂，粘合剂材料和金属氧化物粒子制备的导电层用涂布液形成导电层：45 @ A×rho×D @ 65（i ）其中A表示每单位质量的金属氧化物颗粒的表面积[m2 / g]，D表示金属氧化物颗粒的数均粒径[mum]，rho表示金属氧化物颗粒的密度[g / cm3]。金属氧化物颗粒是涂覆有掺杂有磷的氧化锡的氧化钛颗粒。

10. 发明申请

US20120121291A1 ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, PROCESS CARTRIDGE, AND ELECTROPHOTOGRAPHIC APPARATUS 有权
标题翻译：电子照相感光元件，工艺盒和电子照相设备
公开(公告)号：US20120121291A1
公开(公告)日：2012-05-17
申请号：US13384149
申请日：2010-09-03
申请人： Haruyuki Tsuji , Atsushi Fujii , Hideaki Matsuoka
发明人： Haruyuki Tsuji , Atsushi Fujii , Hideaki Matsuoka
IPC分类号： G03G21/18 , G03G15/00
CPC分类号： G03G5/144 , G03G5/102 , G03G5/142
摘要： An electrophotographic photosensitive member having a specific conductive layer and promising less variation in light-area potential and residual potential in reproducing images repeatedly, and a process cartridge and an electrophotographic apparatus which have such an electrophotographic photosensitive member are provided. Where a test in which a voltage of −1.0 kV having only a DC voltage component is continuously applied to the conductive layer for 1 hour is conducted, the conductive layer has volume resistivity satisfying the following mathematical expressions (1) and (2), as values before and after the test: −2.00≦(log|ρ2|−log|ρ1|)≦2.00 (1), and 1.0×108≦ρ1≦2.0×1013 (2), where, in the expressions (1) and (2), ρ1 is volume resistivity (Ω·cm) of the conductive layer as measured before the test and ρ2 is volume resistivity (Ω·cm) of the conductive layer as measured after the test.
摘要翻译：提供具有特定导电层的电子照相感光构件，并且重复地再现图像中的光区电位和剩余电位的变化较小，以及具有这种电子照相感光构件的处理盒和电子照相设备。在进行1小时的连续施加直流电压成分的-1.0kV的电压的试验中，导电层的体积电阻率满足下述数学式（1）和（2），如测试前后的值：-2.00＆nlE;（log |＆rgr; 2 | -log |＆rgr; 1 |）＆nlE; 2.00（1）和1.0×108＆nlE;＆rgr; 1＆nlE; 2.0×1013（2）在表达式（1）和（2）中，＆rgr; 1是测试前测量的导电层的体积电阻率（＆OHgr;·cm），2是导电层的体积电阻率（＆OHgr·cm）在测试后测量。

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