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1. 发明申请

US20100022730A1 POLYMERIZABLE COMPOUND HAVING ADAMANTANE STRUCTURE, PROCESS FOR PRODUCTION OF THE SAME, AND RESIN COMPOSITION 审中-公开
标题翻译：具有ADAMANTANE结构的可聚合化合物，其生产方法和树脂组合物
公开(公告)号：US20100022730A1
公开(公告)日：2010-01-28
申请号：US12376122
申请日：2007-07-09
申请人： Naoyoshi Hatakeyama , Hidetoshi Ono , Katsuki Ito
发明人： Naoyoshi Hatakeyama , Hidetoshi Ono , Katsuki Ito
IPC分类号： C08F18/20 , C07C69/54 , C07C69/593
CPC分类号： C07C67/10 , C07C67/29 , C07C2601/14 , C07C2603/74 , C08F220/24 , G03F7/0046 , G03F7/027 , G03F7/0397 , G03F7/11 , G03F7/2041 , C07C69/653
摘要： A polymerizable compound having a fluorinated substituent (Z) represented by the general formula (1), an adamantane structure and a polymerizable group (A) having the structure represented by the general formula (1), a production method thereof, and a photoresist composition, a thermocurable resin composition and a photocurable resin composition containing a polymer obtained using the polymerizable compound are provided. Use of the polymerizable compound with the adamantane structure and a resin composition thereof in the present invention provides in the field of photolithography the effect of preventing a liquid immersion medium from penetration and improving dry etching resistance in a liquid immersion exposure method as well as reducing adhesion to a mold and improving dry etching resistance in a nanoimprint method.
摘要翻译：具有由通式（1）表示的氟化取代基（Z），金刚烷结构和具有通式（1）表示的结构的聚合性基团（A）的聚合性化合物，其制造方法和光致抗蚀剂组合物提供了一种耐热树脂组合物和含有使用该聚合性化合物得到的聚合物的光固化性树脂组合物。在本发明中使用具有金刚烷结构的可聚合化合物和其树脂组合物在光刻领域中提供了防止液浸介质渗透的效果，并且在液浸曝光方法中提高了耐干蚀刻性以及降低附着力并且在纳米压印方法中提高干蚀刻电阻。

2. 发明申请

US20090253881A1 POLYMERIZABLE COMPOUND FOR PHOTORESIST, POLYMER THEREOF, AND PHOTORESIST COMPOSITION CONTAINING SUCH POLYMER 审中-公开
标题翻译：用于光聚合物的聚合物，其聚合物和包含这种聚合物的光聚合物组合物
公开(公告)号：US20090253881A1
公开(公告)日：2009-10-08
申请号：US11910535
申请日：2006-05-15
申请人： Naoyoshi Hatakeyama , Katsuki Ito , Hidetoshi Ono , Nobuaki Matsumoto
发明人： Naoyoshi Hatakeyama , Katsuki Ito , Hidetoshi Ono , Nobuaki Matsumoto
IPC分类号： C08F220/06 , C08F24/00
CPC分类号： C08F38/00 , C07C69/732 , C07C2601/08 , C07C2601/14 , C07C2602/42 , C07C2603/74 , C08F220/28 , G03F7/0397
摘要： The present invention provides a polymerizable compound having an alicyclic structure and a polymerizable group and represented by the general formula (1) or (19). The polymerizable compound exhibits high adhesion to substrates, reduced swelling during development, a reduced amount of water absorption during exposure in water, and high dry-etching resistance. Also provided are a polymer of such a polymerizable compound, a process for producing the same and a photoresist composition containing the polymer.
摘要翻译：本发明提供通式（1）或（19）表示的具有脂环结构和聚合性基团的聚合性化合物。可聚合化合物对基材表现出高粘合性，显影期间溶胀减少，在水中暴露时吸水量减少，耐干蚀刻性能高。还提供了这种可聚合化合物的聚合物，其制备方法和含有该聚合物的光致抗蚀剂组合物。

3. 发明申请

US20150316847A1 HOMOADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME AND PHOTOSENSITIVE MATERIALS FOR PHOTORESIST 审中-公开
标题翻译：羟基衍生物衍生物，其制备方法和光致抗蚀剂的感光材料
公开(公告)号：US20150316847A1
公开(公告)日：2015-11-05
申请号：US14798990
申请日：2015-07-14
申请人： Shinji TANAKA , Yoshitaka Uenoyama , Hidetoshi Ono , Naoya Kawano , Katsuki Ito
发明人： Shinji TANAKA , Yoshitaka Uenoyama , Hidetoshi Ono , Naoya Kawano , Katsuki Ito
IPC分类号： G03F7/039 , C08F222/10 , G03F7/30 , G03F7/16 , G03F7/20
CPC分类号： G03F7/039 , C07D313/10 , C08F20/26 , C08F222/10 , C08F224/00 , G03F7/0397 , G03F7/165 , G03F7/20 , G03F7/30 , G03F7/322
摘要： A (meth)acrylic polymer obtained by polymerizing a (meth)acrylic ester of formula wherein R1 and R2 are each independently a hydrogen atom or a linear, branched or cyclic hydrocarbon group having 1 to 6 carbon atoms; R3 is a hydrogen atom, a methyl group, or a trifluoromethyl group; and n and m are each independently an integer of 0 to 3, provided that n and m are not simultaneously 0. Also, a positive photoresist composition including the (meth)acrylic polymer and a method of forming a photoresist pattern with the positive photoresist composition.
摘要翻译：通过使下式的（甲基）丙烯酸酯聚合而得到的（甲基）丙烯酸系聚合物，其中R 1和R 2各自独立地为氢原子或具有1〜6个碳原子的直链，支链或环状烃基; R3是氢原子，甲基或三氟甲基; n和m各自独立地为0〜3的整数，条件是n和m不同时为O.此外，包含（甲基）丙烯酸类聚合物的正性光致抗蚀剂组合物和形成具有正性光致抗蚀剂组合物的光刻胶图案的方法。

4. 发明申请

US20130143157A1 HOMOADAMANTANE DERIVATIVES, PROCESS FOR PREPARING SAME, AND PHOTORESIST COMPOSITIONS 有权
标题翻译：同型异构体衍生物，其制备方法和光电组合物
公开(公告)号：US20130143157A1
公开(公告)日：2013-06-06
申请号：US13816071
申请日：2011-07-26
申请人： Shinji Tanaka , Yoshitaka Uenoyama , Hidetoshi Ono , Naoya Kawano , Katsuki Ito
发明人： Shinji Tanaka , Yoshitaka Uenoyama , Hidetoshi Ono , Naoya Kawano , Katsuki Ito
IPC分类号： G03F7/004 , C07D313/06
CPC分类号： G03F7/004 , C07D313/06 , C07D313/10 , C08F220/28 , C08F220/30 , G03F7/0397
摘要： A compound represented by the following formula (I), wherein R1 is a hydrogen atom, a halogen atom, a methyl group or a trifluoromethyl group.
摘要翻译：由下式（I）表示的化合物，其中R 1是氢原子，卤素原子，甲基或三氟甲基。

5. 发明授权

US08022151B2 Adamantane derivative, method for producing the same, resin composition containing the adamantane derivative and use thereof 有权
标题翻译：金刚烷衍生物，其制造方法，含有金刚烷衍生物的树脂组合物及其用途
公开(公告)号：US08022151B2
公开(公告)日：2011-09-20
申请号：US12598041
申请日：2008-04-28
申请人： Yasunari Okada , Hidetoshi Ono , Katsuki Ito
发明人： Yasunari Okada , Hidetoshi Ono , Katsuki Ito
IPC分类号： C08G59/12 , C08L63/00
CPC分类号： C07D303/16 , C08G59/24 , C08G59/3218 , C08G59/42 , C08L63/00 , G03F7/038
摘要： Provided are: an adamantane derivative represented by the following general formula (I) giving a cured product excellent in optical characteristics such as transparency and light resistance, durabilities such as heat resistance, and electrical characteristics such as dielectric constant; a method of producing the adamantane derivative; a resin composition containing the adamantane derivative and an epoxy resin curing agent; and a sealing agent for an optical semiconductor using the resin composition: where: Y represents a group selected from a hydrocarbon group, a hydroxyl group, a carboxyl group, and an ═O group formed by two Y's being combined together; Z represents a cyclic ether group; n represents an integer of 0 or more; and p represents an integer of 2 to 4 and q represents an integer of 0 to 14, while satisfying 2≦p+q≦16.
摘要翻译：提供：由以下通式（I）表示的金刚烷衍生物，其得到透明性和耐光性，耐热性等耐久性，介电常数等光学特性优异的固化物。生产金刚烷衍生物的方法; 含有金刚烷衍生物和环氧树脂固化剂的树脂组合物; 以及使用该树脂组合物的光学半导体用密封剂，其中：Y表示选自由两个Y组合在一起形成的烃基，羟基，羧基和≡O基的基团; Z表示环状醚基; n表示0以上的整数， p表示2〜4的整数，q表示0〜14的整数，满足2＆nlE; p + q＆nlE; 16。

6. 发明授权

US09513545B2 Homoadamantane derivatives, process for preparing same, and photoresist compositions 有权
标题翻译：高金刚烷衍生物，其制备方法和光致抗蚀剂组合物
公开(公告)号：US09513545B2
公开(公告)日：2016-12-06
申请号：US13816071
申请日：2011-07-26
申请人： Shinji Tanaka , Yoshitaka Uenoyama , Hidetoshi Ono , Naoya Kawano , Katsuki Ito
发明人： Shinji Tanaka , Yoshitaka Uenoyama , Hidetoshi Ono , Naoya Kawano , Katsuki Ito
IPC分类号： C08F220/28 , C08F220/30 , C07D313/06 , C07D313/10 , G03F7/004 , G03F7/039
CPC分类号： G03F7/004 , C07D313/06 , C07D313/10 , C08F220/28 , C08F220/30 , G03F7/0397
摘要： A compound represented by the following formula (I), wherein R1 is a hydrogen atom, a halogen atom, a methyl group or a trifluoromethyl group.

7. 发明申请

US20130022914A1 HOMOADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME AND PHOTOSENSITIVE MATERIALS FOR PHOTORESIST 审中-公开
标题翻译：羟基衍生物衍生物，其制备方法和光致抗蚀剂的感光材料
公开(公告)号：US20130022914A1
公开(公告)日：2013-01-24
申请号：US13638979
申请日：2011-03-16
申请人： Shinji Tanaka , Yoshitaka Uenoyama , Hidetoshi Ono , Naoya Kawano , Katsuki Ito
发明人： Shinji Tanaka , Yoshitaka Uenoyama , Hidetoshi Ono , Naoya Kawano , Katsuki Ito
IPC分类号： C07D313/06 , G03F7/004 , G03F7/20 , C08F122/20
CPC分类号： G03F7/039 , C07D313/10 , C08F20/26 , C08F222/10 , C08F224/00 , G03F7/0397 , G03F7/165 , G03F7/20 , G03F7/30 , G03F7/322
摘要： A homoadamantane derivative represented by the following formula (I): wherein R1 and R2 are independently a hydrogen atom or a linear, branched or cyclic hydrocarbon group having 1 to 6 carbon atoms, x is a hydroxyl group or a halogen atom, and n and m are independently an integer of 0 to 3, provided that n and m are not simultaneously 0.
摘要翻译：由下式（I）表示的高金刚烷衍生物：其中R1和R2独立地为氢原子或具有1至6个碳原子的直链，支链或环状烃基，x为羟基或卤素原子，n和 m独立地为0〜3的整数，条件是n和m不同时为0。

8. 发明申请

US20100266954A1 ADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME, AND CURING COMPOSITION CONTAINING ADAMANTANE DERIVATIVE 审中-公开
标题翻译：衍生物，其制备方法和含有ADAMANTANE衍生物的固化组合物
公开(公告)号：US20100266954A1
公开(公告)日：2010-10-21
申请号：US12742379
申请日：2008-11-10
申请人： Katsuki Ito , Shinji Tanaka , Naoya Kawano , Hideki Yamane , Hidetoshi Ono
发明人： Katsuki Ito , Shinji Tanaka , Naoya Kawano , Hideki Yamane , Hidetoshi Ono
IPC分类号： G03F7/004 , G03F7/20 , C07C69/608 , C08F20/10
CPC分类号： C07C69/54 , C07C2603/74 , C08F220/18 , C08F220/28 , G03F7/027 , G03F7/0397
摘要： An adamantane derivative capable of affording a cured product which is excellent in optical characteristics such as transparency and light resistance, durability such as long-term heat resistance, and electrical characteristics such as dielectric constant, a process for producing such an adamantane derivative, and a curable composition containing such an adamantane derivative, the adamantane derivative being represented by the general formula (I) shown below and having a group selected from an acrylate group, a methacrylate group and a trifluoromethacrylate group, where R1 represents a group selected from a hydroxyl group, an acrylate group, a methacrylate group and a trifluoromethacrylate group, R2 represents a group selected from a hydrogen atom, a methyl group and a trifluoromethyl group, k is an integer of 0 to 4 and n is an integer of 1 to 6.
摘要翻译：能够提供透明性，耐光性等光学特性，长期耐热性等耐久性，介电常数等电气特性，制造金刚烷衍生物的方法等的固化物的金刚烷衍生物，以及含有这种金刚烷衍生物的固化性组合物，金刚烷衍生物由下述通式（I）表示，具有选自丙烯酸酯基，甲基丙烯酸酯基和三氟甲基丙烯酸酯基的基团，其中R 1表示选自羟基的基团丙烯酸酯基，甲基丙烯酸酯基和三氟甲基丙烯酸酯基，R 2表示选自氢原子，甲基和三氟甲基的基团，k为0〜4的整数，n为1〜6的整数。

9. 发明申请

US20100093947A1 ADAMANTANE DERIVATIVE, METHOD FOR PRODUCING THE SAME, RESIN COMPOSITION CONTAINING THE ADAMANTANE DERIVATIVE AND USE THEREOF 有权
标题翻译：亚胺衍生物，其制备方法，含有衍生物的树脂组合物及其用途
公开(公告)号：US20100093947A1
公开(公告)日：2010-04-15
申请号：US12598041
申请日：2008-04-28
申请人： Yasunari Okada , Hidetoshi Ono , Katsuki Ito
发明人： Yasunari Okada , Hidetoshi Ono , Katsuki Ito
IPC分类号： C08L63/00 , C08G63/06 , C08L67/00
CPC分类号： C07D303/16 , C08G59/24 , C08G59/3218 , C08G59/42 , C08L63/00 , G03F7/038
摘要： Provided are: an adamantane derivative represented by the following general formula (I) giving a cured product excellent in optical characteristics such as transparency and light resistance, durabilities such as heat resistance, and electrical characteristics such as dielectric constant; a method of producing the adamantane derivative; a resin composition containing the adamantane derivative and an epoxy resin curing agent; and a sealing agent for an optical semiconductor using the resin composition: where: Y represents a group selected from a hydrocarbon group, a hydroxyl group, a carboxyl group, and an ═O group formed by two Y's being combined together; Z represents a cyclic ether group; n represents an integer of 0 or more; and p represents an integer of 2 to 4 and q represents an integer of 0 to 14, while satisfying 2≦p+q≦16.
摘要翻译：提供：由以下通式（I）表示的金刚烷衍生物，其得到透明性和耐光性，耐热性等耐久性，介电常数等光学特性优异的固化物。生产金刚烷衍生物的方法; 含有金刚烷衍生物和环氧树脂固化剂的树脂组合物; 以及使用该树脂组合物的光学半导体用密封剂，其中：Y表示选自由两个Y组合在一起形成的烃基，羟基，羧基和≡O基的基团; Z表示环状醚基; n表示0以上的整数， p表示2〜4的整数，q表示0〜14的整数，满足2＆nlE; p + q＆nlE; 16。

10. 发明申请

US20100048757A1 ADAMANTANE DERIVATIVE, PROCESS FOR PRODUCTION THEREOF, RESIN COMPOSITION, AND CURED PRODUCT OF THE RESIN COMPOSITION 审中-公开
标题翻译：衍生物衍生物，其生产方法，树脂组合物和树脂组合物的固化产物
公开(公告)号：US20100048757A1
公开(公告)日：2010-02-25
申请号：US12447308
申请日：2007-10-24
申请人： Yasunari Okada , Hideki Yamane , Katsuki Ito , Nobuaki Matsumoto
发明人： Yasunari Okada , Hideki Yamane , Katsuki Ito , Nobuaki Matsumoto
IPC分类号： C08F2/46 , C07C69/54 , C08L31/02
CPC分类号： G03F7/027 , C07C67/08 , C07C69/54 , C07C2603/74 , C08F20/20 , C08F20/28
摘要： Disclosed herein is an adamantane derivative represented by the following general formula (I): (wherein R represents a hydrogen atom, a fluorine atom, a methyl group or a trifluoromethyl group; Y represents a hydrogen atom, a hydroxyl group, ═O formed by two Ys together, a carboxyl group, or a hydrocarbon group having 1 to 20 carbon atoms or a cyclic hydrocarbon group having 3 to 20 carbon atoms; m is 13 and n is 3, or m is 12 and n is 4; and p is an integer of one or more), a production method thereof, a resin composition containing the adamantane derivative, and a cured product thereof. The present invention provides a cured product advantageous as various coating agents, a microlens, a film condenser, a colored composition for a liquid crystal color filter, a pattern organizer formed in nanoimprinting, and the like, having transparency, heat resistance, good mechanical properties, low volume shrinkage, and low coefficient of linear expansion, as well as liquid adamantyl group-containing (meth)acrylates to produce the cured product, the production method thereof, and the resin composition.
摘要翻译：本文公开了由以下通式（I）表示的金刚烷衍生物：其中R表示氢原子，氟原子，甲基或三氟甲基; Y表示氢原子，羟基，由式两个Y一起，一个羧基或一个碳原子数1〜20的烃基或碳原子数3〜20的环状烃基，m为13，n为3，m为12，n为4，p为 1个以上的整数），其制造方法，含有金刚烷衍生物的树脂组合物及其固化物。本发明提供了作为各种涂布剂，微透镜，薄膜冷凝器，液晶滤色器着色组合物，纳米压印等形成的图案组织器等有利的固化产物，具有透明性，耐热性，良好的机械性能，低体积收缩率和低的线性膨胀系数，以及含有金刚烷基的（甲基）丙烯酸酯以制备固化产物，其制备方法和树脂组合物。

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