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1. 发明授权

US4320172A Organopolysiloxane resin compositions for release papers 失效
标题翻译：用于剥离纸的有机聚硅氧烷树脂组合物
公开(公告)号：US4320172A
公开(公告)日：1982-03-16
申请号：US165148
申请日：1980-07-01
申请人： Minoru Takamizawa , Toshio Shinohara , Yasushi Yamamoto , Tasuku Tanino , Kiyoyuki Takano , Fumiaki Mori
发明人： Minoru Takamizawa , Toshio Shinohara , Yasushi Yamamoto , Tasuku Tanino , Kiyoyuki Takano , Fumiaki Mori
IPC分类号： C08L33/06 , D21H27/00 , C08L31/02 , C08L67/06 , C08L83/10
CPC分类号： D21H27/001 , C08L33/06 , Y10T428/31663
摘要： The invention provides a novel in-process release paper, i.e. a release paper used as a backing paper in the manufacturing of, e.g. a synthetic leather with a polyurethane resin. The releasing resin composition with which the release paper is coated is novel as comprising (a) a base resin selected from the group consisting of alkyd resins and acrylic resins modified with an organopolysiloxane, of which from 15 to 50% by moles of the organic groups directly bonded to the silicon atoms in a molecule are phenyl groups, having at least one hydroxy-substituted organic group directly bonded to the silicon atom in a molecule, (b) an alkanol-modified amino resin and (c) an acidic catalyst. The inventive in-process release paper is very superior to the conventional ones in the very much reduced peeling resistance, increased surface gloss and durability in repeated use.
摘要翻译：本发明提供了一种新颖的过程中的脱模纸，即在例如制造中用作背纸的剥离纸。具有聚氨酯树脂的合成革。包含剥离纸的释放树脂组合物是新颖的，包括（a）选自醇酸树脂和用有机聚硅氧烷改性的丙烯酸树脂的基础树脂，其中15至50摩尔％的有机基团与分子中的硅原子直接键合的苯基具有至少一个羟基取代的有机基团，其分子中直接与硅原子键合，（b）链烷醇改性的氨基树脂和（c）酸性催化剂。本发明的在制脱模纸非常优于常规剥离纸，在非常降低的抗剥离性，增加的表面光泽度和重复使用中的耐久性。

2. 发明授权

US4957607A Method for the preparation of a cycloalkyl silane compound 失效
标题翻译：环烷基硅烷化合物的制备方法
公开(公告)号：US4957607A
公开(公告)日：1990-09-18
申请号：US380350
申请日：1989-07-17
申请人： Mikio Endo , Minoru Takamizawa , Toshinobu Ishihara , Tohru Kubota , Toshio Shinohara
发明人： Mikio Endo , Minoru Takamizawa , Toshinobu Ishihara , Tohru Kubota , Toshio Shinohara
IPC分类号： C07F7/12 , C07B61/00 , C07F7/08 , C07F7/14 , C07F7/18
CPC分类号： C07F7/0801 , C07F7/14 , C07F7/1876
摘要： Cycloalkyl silane compounds such as cyclohexyl methyl dichlorosilane can be efficiently prepared by the photochemically induced hydrosilylation reaction. For example, an equimolar mixture of cyclohexene and methyl dichlorosilane with admixture of a catalytic amount of a platinum catalyst, which is an alcohol complex of chloroplatinic acid, is irradiated at a temperature of 70.degree. C. with ultraviolet light so that the hydrosilylation reaction takes place and proceeds almost to completeness without deactivation of the platinum catalyst to give the desired product in a yield of 90% or even higher. Unexpectedly, the efficiency of the reaction can be greatly increased when the platinum catalyst is prepared by heating a solution of chloroplatinic acid in 2-ethylhexyl alcohol at 50.degree. to 80.degree. C. for at least 4 hours.

3. 发明授权

US4883569A Method for the preparation of a cycloalkyl silane compound 失效
标题翻译：环烷基硅烷化合物的制备方法
公开(公告)号：US4883569A
公开(公告)日：1989-11-28
申请号：US154691
申请日：1988-02-11
申请人： Mikio Endo , Minoru Takamizawa , Toshinobu Ishihara , Tohru Kubota , Toshio Shinohara
发明人： Mikio Endo , Minoru Takamizawa , Toshinobu Ishihara , Tohru Kubota , Toshio Shinohara
IPC分类号： C07F7/12 , C07B61/00 , C07F7/08 , C07F7/14 , C07F7/18
CPC分类号： C07F7/0801 , C07F7/14 , C07F7/1876
摘要： Cycloalkyl silane compound such as cyclohexyl methyl dichlorosilane can be efficiently prepared by the photochemically induced hydrosilylation reaction. For example, an equimolar mixture of cyclohexene and methyl dichlorosilane with admixture of a catalytic amount of an alcoholic solution of, chloroplatinic acid, is irradiated at a temperature up to 70.degree. C. with ultraviolet light so that the hydrosilylation reaction takes place and proceeds almost to completeness without deactivation of the platinum catalyst to give the desired product in a yield of 90% or even higher.

4. 发明授权

US4042613A Benzophenone derivatives and their preparation and application 失效
标题翻译：二苯甲酮衍生物及其制备及应用
公开(公告)号：US4042613A
公开(公告)日：1977-08-16
申请号：US569756
申请日：1975-04-21
申请人： Minoru Takamizawa , Yasushi Yamamoto , Yoshio Inoue , Atsumi Noshiro , Hitoshi Fujii
发明人： Minoru Takamizawa , Yasushi Yamamoto , Yoshio Inoue , Atsumi Noshiro , Hitoshi Fujii
IPC分类号： C07F7/08 , C08K5/54 , G03F7/075
CPC分类号： G03F7/0755 , C07F7/0818 , C07F7/0852 , C08K5/54
摘要： Novel benzophenone derivatives represented by the general formula R.sub.m.sup.1 --C.sub.6 H.sub.5-m --CO--C.sub.6 H.sub.5-n --R.sub.n.sup.2 where R.sup.1 is a halogen atom, a monovalent C.sub.1-10 hydrocarbon, alkoxy, thioalkoxy, amino, or dialkylamino group, R.sup.2 is an unsubstituted or organosiloxy-substituted organosilyl group, and m and n are each integers from 1 to 5. The benzophenone derivatives are useful as photosensitizers for making photo-curable compositions by blending with photo polymerizable resins, especially photopolymerizable organosilicon resins. Such photo-curable organosilicon resin compositions are further useful for making dry-planographic printing plates comprising non-image areas formed from the polymerized and cured layers of the composition.
摘要翻译：由通式Rm1-C6H5-m-CO-C6H5-n-Rn2表示的新型二苯甲酮衍生物，其中R1是卤素原子，一价C1-10烃基，烷氧基，硫代烷氧基，氨基或二烷基氨基，R2是未取代的或未取代的有机甲硅烷氧基取代的有机甲硅烷基，m和n各自为1〜5的整数。二苯甲酮衍生物可用作通过与光聚合性树脂，特别是光聚合性有机硅树脂共混来制造光固化性组合物的光敏剂。这种可光固化的有机硅氧烷树脂组合物还可用于制备包含由组合物的聚合和固化层形成的非图像区域的干版印刷版。

5. 发明授权

US4019904A Planographic printing plates and a method of preparing them using photopolymerizable organopolysiloxanes with maleimido groups 失效
标题翻译：平版印刷版和使用具有马来酰亚胺基的光聚合有机聚硅氧烷制备它们的方法
公开(公告)号：US4019904A
公开(公告)日：1977-04-26
申请号：US671737
申请日：1976-03-30
申请人： Atsumi Noshiro , Minoru Takamizawa , Yasushi Yamamoto , Yoshio Inoue , Hitoshi Fujii
发明人： Atsumi Noshiro , Minoru Takamizawa , Yasushi Yamamoto , Yoshio Inoue , Hitoshi Fujii
IPC分类号： C08F30/00 , B41N1/00 , C08F30/08 , C08F290/00 , C08F299/00 , C08G77/388 , C08L83/08 , G03F7/075 , G03F7/02 , G03C1/68
CPC分类号： B41N1/003 , C08G77/388 , C08L83/08 , G03F7/0757
摘要： The planographic printing plate has ink-receptive and ink-repellent areas provided on its base, the ink-repellent areas being covered with a layer formed by polymerizing and curing a composition which comprise a photopolymerizable organopolysiloxane with maleimido groups. The photopolymerizable organopolysiloxane has easily synthesized. The ink-repellency of the cured organopolysiloxane is excellent. The planographic printing plates can be used without dampening water and have a superior press life.
摘要翻译：平版印刷版在其基底上设置有吸墨和拒墨区域，疏墨区被覆有由聚合和固化包含具有马来酰亚胺基的可光聚合的有机聚硅氧烷的组合物形成的层。可光聚合的有机聚硅氧烷容易合成。固化的有机聚硅氧烷的拒墨性优异。平版印刷版可以不使用润湿水而使用，具有优异的印刷寿命。

6. 发明授权

US4075167A Maleimido group-containing organosilicon compounds 失效
标题翻译：含有马来酸的组合有机硅化合物
公开(公告)号：US4075167A
公开(公告)日：1978-02-21
申请号：US644319
申请日：1975-12-24
申请人： Minoru Takamizawa , Yasushi Yamamoto , Yoshio Inoue , Atsumi Noshiro , Hitoshi Fujii
发明人： Minoru Takamizawa , Yasushi Yamamoto , Yoshio Inoue , Atsumi Noshiro , Hitoshi Fujii
IPC分类号： C08F2/00 , C07F7/08 , C07F7/10 , C07F7/18 , C07F7/21 , C08F2/48 , C08F30/00 , C08F30/08 , C08F290/00 , C08F299/00 , C08G77/00 , C08G77/28 , C08G77/388 , C09D183/04 , C09D183/07 , C08G77/04
CPC分类号： C08G77/388 , C07F7/0854 , C07F7/0856 , C07F7/0859 , C07F7/0889 , C07F7/1868 , C07F7/21
摘要： Novel organosilicon compounds having in a molecule at least one maleimido group bonded to a silicon atom through a Si-C linkage, synthesized by reaction of a derivative of maleic anhydride with an organosilicon compound having an amino-substituted hydrocarbon group bonded to the silicon atom. The reaction proceeds in two steps, the first step being addition of the amino group to the maleic anhydride derivative to form an amide structure and the second step being dehydration of the amide structure to form a maleimido ring. The organosilicon compounds having remarkable photosensitivity can be polymerized and cured on exposure to ultraviolet light, and the cured films are insoluble in organic solvents.

7. 发明授权

US5011639A Method for the preparation of a sintered body of silicon carbide 失效
标题翻译：制备碳化硅烧结体的方法
公开(公告)号：US5011639A
公开(公告)日：1991-04-30
申请号：US453038
申请日：1989-12-12
申请人： Nobuaki Urasato , Minoru Takamizawa , Akira Hayashida , Hiromi Ohsaki , Jiyunitirow Maruta
发明人： Nobuaki Urasato , Minoru Takamizawa , Akira Hayashida , Hiromi Ohsaki , Jiyunitirow Maruta
IPC分类号： C04B35/565 , C04B35/626 , H01L21/48
CPC分类号： H01L21/4807 , C04B35/565
摘要： A powdery mixture of a fine silicon carbide powder admixed with boron or a boron compound, e.g. boron carbide, titanium boride and boron oxide, as a sintering aid is compression-molded into a green body which is subjected to a sintering treatment into a sintered body. Different from conventional methods in which the sintering treatment is performed always in an atmosphere of an inert gas, e.g. argon, the sintering treatment in the inventive method is performed in an atmosphere of a rare gas containing 0.005-5% by volume of nitrogen. The sintered body of silicon carbide obtained by this method has an outstandingly high electric volume resistivity of 10.sup.10 to 10.sup.13 ohm.cm and a coefficient of thermal conductivity of 100-220 W/m.K.
摘要翻译：与硼或硼化合物混合的细碳化硅粉末的粉末混合物，例如作为烧结助剂的碳化硼，硼化钛和氧化硼被压缩成型坯，其经历烧结处理成烧结体。不同于常规方法，其中始终在惰性气体气氛中进行烧结处理，例如，氩气中，本发明方法中的烧结处理在含有0.005-5体积％氮气的稀有气体的气氛中进行。通过该方法获得的碳化硅烧结体具有极高的体积电阻率为1010至1013欧姆·厘米，导热系数为100-220W / m·K。

8. 发明授权

US4948763A Preparation of hollow ceramic fibers 失效
标题翻译：中空陶瓷纤维的制备
公开(公告)号：US4948763A
公开(公告)日：1990-08-14
申请号：US404584
申请日：1989-09-08
申请人： Akira Hayashida , Minoru Takamizawa , Yoshihumi Takeda
发明人： Akira Hayashida , Minoru Takamizawa , Yoshihumi Takeda
IPC分类号： C04B20/00 , C04B35/571 , C04B35/589 , C08G77/62 , C08L83/16
CPC分类号： C04B20/0056 , C04B35/571 , C04B35/589 , C08G77/62 , C08L83/16
摘要： Hollow ceramic fibers are prepared by melt spinning an organic silazane polymer, infusibilizing the fiber to form an infusible layer on the surface, and pyrolyzing the fiber to obtain a ceramic fiber having an empty interior. The infusibilizing step includes two steps of treating the fiber with a gas containing the vapor of an infusibilizing silicon, boron, phosphorus or metal compound and further treating with a water vapor-containing gas or ammonia-containing gas. The surface infusible fibers are efficiently sintered into hollow ceramic fibers without fusion bond.
摘要翻译：中空陶瓷纤维通过熔融纺丝有机硅氮烷聚合物制备，使纤维不熔化以在表面上形成不熔层，并热解纤维以获得具有空的内部的陶瓷纤维。渗透步骤包括两个步骤：用含有不熔硅，硼，磷或金属化合物的蒸汽的气体处理纤维，并进一步用含水气体气体或含氨气体进行处理。将表面不熔纤维有效地烧结成中空陶瓷纤维而没有熔接。

9. 发明授权

US4847345A Process for manufacturing organic silazane polymers and ceramics therefrom 失效
标题翻译：从其制造有机硅氮烷聚合物和陶瓷的方法
公开(公告)号：US4847345A
公开(公告)日：1989-07-11
申请号：US159315
申请日：1988-02-23
申请人： Minoru Takamizawa , Yoshihumi Takeda , Akira Hayashida , Tsutomu Takeno
发明人： Minoru Takamizawa , Yoshihumi Takeda , Akira Hayashida , Tsutomu Takeno
IPC分类号： C01B21/068 , C01B31/36 , C04B35/571 , C04B35/589 , C08G77/48 , C08G77/60 , C08G77/62 , D01F9/10
CPC分类号： C08G77/60 , C04B35/571 , C04B35/589 , C08G77/62
摘要： A process for manufacturing an organic silazane polymer which comprises reacting an organic silicon compound of the following formula (I): ##STR1## in which R represents hydrogen, chlorine, bromine, methyl radical, ethyl radical, phenyl radical or vinyl radical, R.sub.1 represents hydrogen or methyl radical and X represents chlorine or bromine, or a mixture of organic silicon compounds of the formula (I) above and an organic silicon compound of the following formula (II): ##STR2## in which R.sub.2 and R.sub.3 represent hydrogen, chlorine, bromine, methyl radical, ethyl radical, phenyl radical or vinyl radical and X represents chlorine or bromine with a disilazane of the following formula (III): ##STR3## in which R.sub.4, R.sub.5, R.sub.6 represents hydrogen, methyl radical, ethyl radical, phenyl radical or vinyl radical in an anhydrous state at a temperature of from 25.degree. to 350.degree. C. while distilling off by-produced organic ingredients out of the system to obtain an organic silazane polymer. The organic silazane polymer is useful for preceramic materials.
摘要翻译：一种制备有机硅氮烷聚合物的方法，其包括使下式（I）的有机硅化合物：其中R表示氢，氯，溴，甲基，乙基，苯基或乙烯基，R 1表示氢或甲基，X表示氯或溴，或上述式（I）的有机硅化合物与下式（II）的有机硅化合物的混合物：其中R 2 并且R 3代表氢，氯，溴，甲基，乙基，苯基或乙烯基，X代表氯或溴与下列通式（III）的二硅氮烷：其中R4，R5，R6 在25至350℃的温度下，以无水状态代表氢，甲基，乙基，苯基或乙烯基，同时将副产物的有机成分蒸馏出体系，得到有机硅氮烷聚合物。有机硅氮烷聚合物可用于陶瓷材料。

10. 发明授权

US4727172A Method for the preparation of an organosiloxane oligomer and a novel organosiloxane oligomer thereby 失效
标题翻译：由此制备有机硅氧烷低聚物和新型有机硅氧烷低聚物的方法
公开(公告)号：US4727172A
公开(公告)日：1988-02-23
申请号：US905576
申请日：1986-09-09
申请人： Akira Yamamoto , Minoru Takamizawa , Toshinobu Ishihara , Tadao Kurosaki
发明人： Akira Yamamoto , Minoru Takamizawa , Toshinobu Ishihara , Tadao Kurosaki
IPC分类号： C07F7/08
CPC分类号： C07F7/0852 , C07F7/0874
摘要： An efficient method is proposed for the preparation of an organosiloxane oligomer represented by the general formula YSi(R.sup.1).sub.n (--O--SiR.sub.3).sub.3-n, in which each of the groups denoted by R and R.sup.1 is a halogen-substituted or unsubstituted monovalent hydrocarbon group having 1 to 8 carbon atoms, Y is a hydrogen atom or a monovalent group selected from methyl, phenyl, vinyl, chloromethyl and 3-(meth)acryloxypropyl groups and n is zero, 1 or 2, by the reaction of an organosilicon halomagnesium salt of the formula R.sub.3 Si--O--MgX, in which X is a halogen atom, and an organosilane compound of the general formula YSi(R.sup.1).sub.n (Z).sub.3-n, in which Z is a halogen atom or a lower alkoxy group. In particular, tetrasiloxane compounds represented by the general formula Y.sup.1 Si[--O--Si(CH.sub.3).sub.2 (CH.sub.2 CH.sub.2 CF.sub.3)].sub.3, in which Y.sup.1 is a hydrogen atom, chloromethyl group or 3-methacryloxypropyl group, are each a novel compound not known in the prior art.
摘要翻译：提出了制备由通式YSi（R1）n（-O-SiR 3）3-n表示的有机硅氧烷低聚物的有效方法，其中由R和R 1表示的每个基团是卤素取代或未取代的具有1至8个碳原子的一价烃基，Y是氢原子或选自甲基，苯基，乙烯基，氯甲基和3-（甲基）丙烯酰氧基丙基的一价基团，并且n为0,1或2，通过其中X为卤素原子的式R3Si-O-MgX的有机硅卤镁盐和通式YSi（R1）n（Z）3-n的有机硅烷化合物，其中Z为卤素原子或低级烷氧基。特别地，由通式Y1Si [-O-Si（CH3）2（CH2CH2CF3）] 3表示的四硅氧烷化合物，其中Y 1为氢原子，氯甲基或3-甲基丙烯酰氧基丙基，均为未知的新化合物现有技术

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