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1. 发明授权

US5468569A Use of standard uniform electrode components in cells of either high or low surface area design 失效
标题翻译：在高或低表面积设计的电池中使用标准均匀电极组件
公开(公告)号：US5468569A
公开(公告)日：1995-11-21
申请号：US213629
申请日：1994-03-15
申请人： Michael F. Pyszczek , Esther S. Takeuchi , Mark J. Kane
发明人： Michael F. Pyszczek , Esther S. Takeuchi , Mark J. Kane
IPC分类号： H01M4/04 , H01M6/10 , H01M6/14 , H01M6/00
CPC分类号： H01M4/04 , H01M4/0404 , H01M4/043 , H01M6/10 , H01M2300/002 , H01M6/14 , Y10T29/49115
摘要： A method for manufacturing electrochemical cells having a low electrochemical surface, from standard electrodes used in cells having a high electrochemical surface, includes configuring the standard electrodes by folding one or more of the standard electrodes to reduce the overall length, and hence the electrochemical surface area to a fraction of that of the unfolded standard electrode. A cell stack is assembled by placing the folded electrode and a standard electrode, or alternatively a folded cathode and a folded anode, in a face-to-face relationship with a separator therebetween.
摘要翻译：一种用于制造具有低电化学表面的电化学电池的方法，从具有高电化学表面的电池中使用的标准电极，包括通过折叠一个或多个标准电极来构成标准电极以减小总长度，因此电化学表面积到展开的标准电极的一小部分。通过将折叠的电极和标准电极，或者折叠的阴极和折叠的阳极以与它们之间的隔膜相对的关系放置来组装电池堆。

2. 发明授权

US5474859A Electrochemical cell design for use under high shock and vibration conditions 失效
标题翻译：电化学电池设计，在高冲击和振动条件下使用
公开(公告)号：US5474859A
公开(公告)日：1995-12-12
申请号：US363382
申请日：1995-02-13
申请人： Esther S. Takeuchi , Michael F. Pyszczek
发明人： Esther S. Takeuchi , Michael F. Pyszczek
IPC分类号： H01M2/02 , H01M2/00 , H01M2/34 , H01M6/10 , H01M10/04 , H01M10/16 , H01M2/10
CPC分类号： H01M10/0413 , H01M10/0468 , H01M10/16 , H01M2/00 , H01M6/10 , Y10T29/4911
摘要： A structure for stabilizing of an electrochemical cell stack against high shock and vibration forces through the use of a plurality of electrode connections at both the top and bottom of the stack is described. Constructing the cell casing having a tubular shape rather than the typical deep drawn can shape, allows access to the lower portion of the stack. There, additional leads are welded to the cell case, which significantly adds to the stability of the stack within the case. The lower portion of the case is then within the case. The lower portion of the case is then hermetically sealed by fitting and welding a disc in place.
摘要翻译：描述了通过在堆叠的顶部和底部使用多个电极连接来稳定电化学电池堆以抵抗高冲击和振动力的结构。构造具有管状形状的电池壳体而不是典型的深拉制罐形状，允许进入堆叠的下部。在这里，额外的引线焊接到电池盒，这显着增加了箱体内的堆叠的稳定性。然后壳体的下部在壳体内。然后通过将盘安装在适当位置将壳体的下部密封。

3. 发明授权

US5415959A Woven synthetic halogenated polymer fibers as separator material for electrochemical cells 失效
标题翻译：合成卤化聚合物纤维作为电化学电池的隔离材料
公开(公告)号：US5415959A
公开(公告)日：1995-05-16
申请号：US145782
申请日：1993-10-29
申请人： Michael F. Pyszczek , Christine A. Frysz , Steven J. Ebel , Esther S. Takeuchi
发明人： Michael F. Pyszczek , Christine A. Frysz , Steven J. Ebel , Esther S. Takeuchi
IPC分类号： H01M2/16 , H01M6/14 , H01M6/16 , H01M2/14
CPC分类号： H01M2/162
摘要： A fabric separator woven from synthetic halogenated polymeric fibers for use in an electrochemical cell comprising a Group IA, IIA and IIIB metal anode and a depolarizer/catholyte or a solid cathode/electrolyte system, is described. The separator is resistant to the highly oxidizing components present in the cell, is tear resistant and has a reduced thickness to minimize the diminishing effect of the separator on the volumetric amount of active components in the cell. The separator can be used by itself or as a laminate with a microporous film, preferably made of a fluoropolymeric fiber.
摘要翻译：描述了用于包含IA，IIA和IIIB族金属阳极的电化学电池和消偏振器/阴极电解液或固体阴极/电解质系统的由合成卤化聚合物纤维编织的织物隔离物。分离器对电池中存在的高度氧化成分具有抗性，具有抗撕裂性并且具有减小的厚度以最小化隔膜对电池中活性组分的体积量的减小的影响。隔膜可以单独使用或作为具有微孔膜的层压体使用，优选由含氟聚合纤维制成。

4. 发明授权

US5543249A Aqueous blended electrode material for use in electrochemical cells and method of manufacture 失效
标题翻译：用于电化学电池的水性共混电极材料及其制造方法
公开(公告)号：US5543249A
公开(公告)日：1996-08-06
申请号：US396665
申请日：1995-03-01
申请人： Esther S. Takeuchi , Michael F. Pyszczek
发明人： Esther S. Takeuchi , Michael F. Pyszczek
IPC分类号： H01M4/02 , B22F1/00 , H01M4/04 , H01M4/26 , H01M4/62 , B22F3/00
CPC分类号： H01M4/0471 , B22F1/0059 , H01M4/04 , H01M4/0402 , H01M4/0435 , H01M4/62 , H01M2004/028 , Y10T29/49115
摘要： A method for preparing an electrode component comprises mixing an electrode active material in a water-based environment with the aid of surfactants. A preferred embodiment of this process comprises combining a high surface area carbonaceous cathode active material with a water/surfactant mixture, and then adding a fluoro-polymer as the binder material to the slurry. The resulting paste is processed and formed into the cathode material. This process replaces the use of isopropyl alcohol with the water/surfactant mixture as the solvent. Preferred surfactants include those of the polyglycol family.
摘要翻译：一种制备电极组件的方法包括借助于表面活性剂在水基环境中混合电极活性材料。该方法的优选实施方案包括将高表面积碳质正极活性材料与水/表面活性剂混合物组合，然后将作为粘合剂材料的氟聚合物加入到浆料中。将所得糊状物加工并形成阴极材料。该方法取代了异丙醇与水/表面活性剂混合物作为溶剂的用途。优选的表面活性剂包括聚二醇家族的表面活性剂。

5. 发明授权

US07939199B1 Method of controlling voltage delay and RDC growth in an electrochemical cell using low basis weight cathode material 失效
标题翻译：使用低基重阴极材料控制电化学电池中的电压延迟和RDC生长的方法
公开(公告)号：US07939199B1
公开(公告)日：2011-05-10
申请号：US11736039
申请日：2007-04-17
申请人： Hong Gan , Joseph M. Lehnes , Esther S. Takeuchi
发明人： Hong Gan , Joseph M. Lehnes , Esther S. Takeuchi
IPC分类号： H01M10/32
CPC分类号： H01M4/131 , H01M4/366 , H01M4/38 , H01M4/382 , H01M4/485 , H01M4/505 , H01M4/5815 , H01M4/583 , H01M4/623 , H01M6/16 , H01M10/052 , H01M2004/021 , H01M2300/0037
摘要： An electrochemical cell comprising a lithium anode, a silver vanadium oxide cathode having a relatively lower basis weight, and an electrolyte activating the anode and the cathode is described. By limiting the amount of cathode active material per unit area (i.e. basis weight) facing the anode in the Li/SVO cell, the magnitude of the passivating film growth at the solid-electrolyte interphase (SEI) and its relative impermeability to lithium ion diffusion is reduced. Therefore, by using a cathode of a relatively low basis weight active material, it is possible to eliminate or significantly reduce undesirable irreversible Rdc growth and voltage delay in the cell and to extend its useful life in an implantable medical device.
摘要翻译：描述了包含锂阳极，具有相对较低基重的银钒氧化物阴极和激活阳极和阴极的电解质的电化学电池。通过限制在Li / SVO电池中面向阳极的每单位面积（即单位面积重量）的阴极活性材料的量，固体 - 电解质间相（SEI）的钝化膜生长的大小及其对锂离子扩散的相对不渗透性降低了。因此，通过使用相对低的基重量的活性材料的阴极，可以消除或显着减少电池中不期望的不可逆的Rdc生长和电压延迟并延长其在可植入医疗装置中的使用寿命。

6. 发明申请

US20110091776A1 Sandwich Cathode Electrochemical Cell With Wound Electrode Assembly 有权
标题翻译：带有电极组件的三明治阴极电化学电池
公开(公告)号：US20110091776A1
公开(公告)日：2011-04-21
申请号：US12967617
申请日：2010-12-14
申请人： Robert S. Rubino , Hong Gan , Esther S. Takeuchi
发明人： Robert S. Rubino , Hong Gan , Esther S. Takeuchi
IPC分类号： H01M4/54 , H01M10/04 , H01M10/02 , H01M10/26
CPC分类号： H01M10/0431 , H01M4/136 , H01M4/366 , H01M4/54 , H01M4/5825 , H01M4/661 , H01M4/667 , H01M10/052 , H01M10/0568 , H01M10/0569 , H01M10/0583 , H01M10/0585 , Y10T29/49108
摘要： A new design for a cathode having a configuration of: SVO/first current collector/CFx/second current collector/SVO is described. The two cathode current collectors are vertically aligned one on top of the other in a middle region or zone of the cathode. This coincides to where a winding mandrel will be positioned to form a wound electrode assembly with an anode. The overlapping region of the two current collectors helps balance the expansion forces of the exemplary SVO and CFx active material layers. This, in turn, helps maintain a planar cathode that is more amenable to downstream processing. The use of two current collectors on opposite sides of an intermediate cathode active material also provides for enhanced reliability when cathodes are wound from the center as they lend structural integrity to outer portions of the wind.
摘要翻译：描述了具有以下配置的阴极的新设计：SVO /第一集电器/ CFx /第二集电器/ SVO。在阴极的中间区域或区域中，两个阴极集电体在另一个的顶部垂直对准。这一点与绕组心轴将被定位以形成具有阳极的卷绕电极组件的情况相一致。两个集电器的重叠区域有助于平衡示例性SVO和CF x活性材料层的膨胀力。这又有助于维持更适合于下游处理的平面阴极。在中间阴极活性材料的相对侧上使用两个集电器还提供了当从中心缠绕阴极时提高可靠性，因为它们将结构完整性提供给风的外部部分。

7. 发明授权

US07820328B1 Electrochemical cell electrode with improved particle-to-particle contact and method of manufacturing 有权
标题翻译：具有改进的粒子与粒子接触的电化学电池电极和制造方法
公开(公告)号：US07820328B1
公开(公告)日：2010-10-26
申请号：US11829229
申请日：2007-07-27
申请人： Esther S. Takeuchi , Amy C. Marschilok , Randolph Leising
发明人： Esther S. Takeuchi , Amy C. Marschilok , Randolph Leising
IPC分类号： H01M4/62 , H01M4/02 , C08J9/26
CPC分类号： H01M4/621 , C08J9/26 , H01M4/0471 , H01M4/08 , H01M4/381 , H01M4/405 , H01M4/485 , H01M4/622 , H01M4/623 , H01M6/16 , H01M10/052 , Y10T29/49108
摘要： An electrochemical cell comprising an electrode, whether it is the cathode of a primary cell or an anode or a cathode of a secondary cell, comprised of a mixture of a robust, high temperature binder along with a sacrificial decomposable polymer is described. The robust binder remains in the electrode throughout formation and processing, and maintains adhesion and cohesion of the cathode during utilization. The sacrificial decomposable polymer is present during the electrode formation stage. However, it is decomposed via a controlled treatment prior to electrode utilization. Upon subsequent high pressure pressing, the void spaces formerly occupied by the sacrificial polymer provides sites where the electrode active material collapses into a tightly compressed mass with enhanced particle-to-particle contact between the active material particles. For a cathode in a primary cell, for example a Li/SVO cell, the result is believed to be improved rate capability, capacity and stability throughout discharge.
摘要翻译：描述了包括电极的电化学电池，无论其是初级电池的阴极还是二次电池的阳极或阴极，由稳定的高温粘合剂与牺牲的可分解聚合物的混合物组成。在整个形成和加工过程中，坚固的粘合剂保留在电极中，并且在使用期间保持阴极的粘附和内聚力。牺牲可分解聚合物在电极形成阶段存在。然而，它在电极利用之前通过受控处理分解。在随后的高压压制之后，先前由牺牲聚合物占据的空隙空间提供了电极活性材料塌陷成紧密压缩的物质的位置，其中活性材料颗粒之间具有增强的粒子与粒子之间的接触。对于初级电池中的阴极，例如Li / SVO电池，结果被认为是在整个放电过程中提高速率能力，容量和稳定性。

8. 发明申请

US20100185264A1 Method For Coating A Cathode Active Material With A Metal Oxide For Incorporation Into A Lithium Electrochemical Cell 审中-公开
标题翻译：用于将金属氧化物涂覆在锂电化学电池中的阴极活性材料的方法
公开(公告)号：US20100185264A1
公开(公告)日：2010-07-22
申请号：US11611904
申请日：2006-12-18
申请人： Randolph Leising , Esther S. Takeuchi
发明人： Randolph Leising , Esther S. Takeuchi
IPC分类号： A61N1/36 , H01M4/88
CPC分类号： H01M4/08 , H01M4/366 , H01M4/382 , H01M4/54 , H01M4/624 , H01M6/16
摘要： An improved cathode material for nonaqueous electrolyte lithium electrochemical cell is described. The preferred active material is silver vanadium oxide (SVO) coated with a protective layer of an inert metal oxide (MxOy) or lithiated metal oxide (LixMyOz). A preferred coating method is by a sol-gel process. The SVO core provides high capacity and rate capability while the protective coating reduces reactivity of the active particles with electrolyte to improve the long-term stability of the cathode.
摘要翻译：描述了用于非水电解质锂电化学电池的改进的阴极材料。优选的活性材料是涂覆有惰性金属氧化物（M x O y）或锂化金属氧化物（LixMyOz）的保护层的银钒氧化物（SVO）。优选的涂布方法是通过溶胶 - 凝胶法。 SVO核提供高容量和速率能力，而保护涂层降低活性颗粒与电解质的反应性，从而提高阴极的长期稳定性。

9. 发明授权

US07118829B2 Preparation of copper silver vanadium oxide from γ-phase SVO starting material 有权
标题翻译：从γ相SVO起始材料制备铜银钒氧化物
公开(公告)号：US07118829B2
公开(公告)日：2006-10-10
申请号：US10944661
申请日：2004-09-17
申请人： Randolph Leising , Esther S. Takeuchi
发明人： Randolph Leising , Esther S. Takeuchi
IPC分类号： H01M4/54 , C01G5/00 , C01G31/00
CPC分类号： H01M4/54 , C01G31/00 , C01G31/006 , C01G45/006 , C01P2002/50 , C01P2002/54 , C01P2006/12 , C01P2006/40 , H01M4/131 , H01M4/405 , H01M4/485 , H01M4/5825 , H01M6/16
摘要： The current invention relates to the preparation of an improved cathode active material for non-aqueous lithium electrochemical cell. In particular, the cathode active material comprises ε-phase silver vanadium oxide prepared by using a γ-phase silver vanadium oxide starting material. The reaction of γ-phase SVO with a silver salt produces the novel ε-phase SVO possessing a lower surface area than ε-phase SVO produced from vanadium oxide (V2O5) and a similar silver salt as starting materials. Consequently, the low surface area ε-phase SVO material provides an advantage in greater long-term stability in pulse dischargeable cells.
摘要翻译：本发明涉及用于非水电解锂电化学电池的改进的阴极活性材料的制备。特别地，正极活性物质包括通过使用γ相银钒氧化物原料制备的ε相银钒氧化物。 γ相SVO与银盐的反应产生具有比由氧化钒（V 2 O 5 O 3）产生的ε相SVO更低的表面积的新型ε相SVO >）和类似的银盐作为起始材料。因此，低表面积ε相SVO材料在脉冲可放电电池的更长的长期稳定性方面提供了优点。

10. 发明授权

US07092830B2 Method for estimating long term end-of-life characteristics using short-term data for lithium/silver vanadium oxide cells 有权
标题翻译：使用锂/银钒氧化物电池的短期数据估算长期寿命终止特性的方法
公开(公告)号：US07092830B2
公开(公告)日：2006-08-15
申请号：US11087302
申请日：2005-03-23
申请人： Kenneth Syracuse , Noelle Waite , Hong Gan , Esther S. Takeuchi
发明人： Kenneth Syracuse , Noelle Waite , Hong Gan , Esther S. Takeuchi
IPC分类号： G01R31/36
CPC分类号： G01R31/3627 , G01R31/3679
摘要： The present invention is directed to a method for analyzing the tail-end behavior of a lithium cell having a solid cathode. The tail of a longer-term accelerated discharge data (ADD) test is estimated from the tail of two shorter-term ADD tests. This is accomplished by first comparing the discharge tails of shorter-term ADD tests and determining angles or rotation that correspond to Rdc growth, and then trending rotation angles versus time to reach a give DoD. For example, the 18-month and 36-month ADD test tails are used to estimate the ADD test tail of a similarly constructed cell subjected to a longer-term ADD test, for example a 48-month ADD test.
摘要翻译：本发明涉及一种用于分析具有固体阴极的锂电池的尾端行为的方法。从两个短期ADD测试的尾部估计长期加速放电数据（ADD）测试的尾部。这是通过首先比较短期ADD测试的放电尾数和确定与Rdc生长相对应的角度或旋转，然后将趋势旋转角度与时间进行比较以达到给予DoD。例如，18个月和36个月的ADD测试尾部用于估计经历长期ADD测试的类似构建的细胞的ADD测试尾，例如48个月的ADD测试。

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