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1. 发明申请

US20100136353A1 AQUEOUS OLIGOMER / POLYMER EMULSION WITH CATIONIC FUNCTIONALITY 审中-公开
标题翻译：具有阳离子功能的水性低聚物/聚合物乳液
公开(公告)号：US20100136353A1
公开(公告)日：2010-06-03
申请号：US12594704
申请日：2008-04-03
申请人： Michael Arnoldus Jacobus Schellekens , John Geurts , Tijs Nabuurs , Gerardus Cornelis Overbeek
发明人： Michael Arnoldus Jacobus Schellekens , John Geurts , Tijs Nabuurs , Gerardus Cornelis Overbeek
IPC分类号： C09D153/00 , C08L39/00 , C08L53/00 , C09D5/14 , B32B27/00
CPC分类号： C09D151/003 , C08F293/005 , C08F2438/03 , C08L53/00 , C09D5/14 , C09D153/00 , C09D153/005 , Y10T428/31855 , Y10T428/31938 , C08L2666/02
摘要： An aqueous emulsion comprising at least a covalently bound vinyl oligomer and vinyl polymer, wherein said vinyl oligomer comprises 5 to 85 mol % of vinyl monomers bearing quaternary ammonium ion functional groups or quaternisable amine functional groups and is obtained by a controlled radical polymerisation of at least one vinyl monomer via a reversible addition-fragmentation chain transfer mechanism in solution in the presence of a control agent and a source of free radicals; wherein said vinyl polymer is obtained by emulsion polymerisation of vinyl monomers in the presence of the vinyl oligomer; wherein the weight % ratio of vinyl oligomer to vinyl polymer is in the range of from 0.5:99.5 to 65:35.
摘要翻译：包含至少共价结合的乙烯基低聚物和乙烯基聚合物的水性乳液，其中所述乙烯基低聚物包含5-85摩尔％的带有季铵离子官能团或可季铵化胺官能团的乙烯基单体，并且通过至少一种受控自由基聚合获得一种乙烯基单体通过在控制剂和自由基来源的溶液中的可逆加成 - 断裂链转移机理; 其中所述乙烯基聚合物通过乙烯基单体在乙烯基低聚物存在下的乳液聚合获得; 其中乙烯基低聚物与乙烯基聚合物的重量％比在0.5:99.5至65:35的范围内。

2. 发明申请

US20110159306A1 ADHESION TO METAL SURFACES WITH BLOCK COPOLYMERS OBTAINED USING RAFT 审中-公开
公开(公告)号：US20110159306A1
公开(公告)日：2011-06-30
申请号：US13001940
申请日：2009-06-30
申请人： Michael Arnoldus Jacobus Schellekens , Tijs Nabuurs , John Geurts , Gerardus Cornelis Overbeek
发明人： Michael Arnoldus Jacobus Schellekens , Tijs Nabuurs , John Geurts , Gerardus Cornelis Overbeek
IPC分类号： B32B15/08 , B05D3/00 , C09D153/00
CPC分类号： B32B15/082 , C08F2/22 , C08F2/38 , C08F293/005 , C08L53/00 , C08L53/005 , C08L2666/02 , C09D153/00 , C09J153/00 , C23F11/00 , Y10T428/31692
摘要： An aqueous, metal, coating composition (and process for obtaining it) comprising a block copolymer and a polymer P; wherein the block copolymer comprises at least blocks [A]x[B]y, where at least block [A] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism in solution in the presence of a control agent and a source of free radicals; and where (a) block [A] comprises (i) 0 to 80 mol % of metal adhering ethylenically unsaturated monomers; (ii) 0 to 100 mol % of water dispersible ethylenically unsaturated monomers; (iii) 0 to 70 mol % of C1 to C30 hydrocarbo (meth)acrylate and/or styrenic monomers; (iv) 0 to 35 mol % of ethylenically unsaturated monomer different from i), ii)+iii); where the amount of at least one of i), ii), iii)+iv) is >0 mol %; block [A] has a Hansch parameter x); and (c) polymer P is obtained by an emulsion polymerisation process in the presence of the block copolymer [A][B] and comprises: i) 0 to 5 wt % of metal adhering ethylenically unsaturated monomers; ii) 0 to 15 wt % of water dispersible ethylenically unsaturated monomers; iii) 50 to 100 wt % C1 to C30 hydrocarbo (meth)acrylate and/or styrenic monomers; and iv) 0 to 35% by weight of ethylenically unsaturated monomers units different from those from i), ii)+iii).

3. 发明申请

US20120282212A1 AQUEOUS OLIGOMER/POLYMER EMULSION WITH CATIONIC FUNCTIONALITY 审中-公开
标题翻译：具有阳离子功能的水性低聚物/聚合物乳液
公开(公告)号：US20120282212A1
公开(公告)日：2012-11-08
申请号：US13536883
申请日：2012-06-28
申请人： Michael Arnoldus Jacobus SCHELLEKENS , John Geurts , Tijs Nabuurs , Gerardus Cornelis Overbeek
发明人： Michael Arnoldus Jacobus SCHELLEKENS , John Geurts , Tijs Nabuurs , Gerardus Cornelis Overbeek
IPC分类号： C08L53/00 , B32B27/30 , C08K3/20 , C09D153/00 , A01N37/00 , H01B1/12
CPC分类号： C09D151/003 , C08F293/005 , C08F2438/03 , C08L53/00 , C09D5/14 , C09D153/00 , C09D153/005 , Y10T428/31855 , Y10T428/31938 , C08L2666/02
摘要： An aqueous emulsion comprising at least a covalently bound vinyl oligomer and vinyl polymer, wherein said vinyl oligomer comprises 5 to 85 mol % of vinyl monomers bearing quaternary ammonium ion functional groups or quaternisable amine functional groups and is obtained by a controlled radical polymerisation of at least one vinyl monomer via a reversible addition-fragmentation chain transfer mechanism in solution in the presence of a control agent and a source of free radicals; wherein said vinyl polymer is obtained by emulsion polymerisation of vinyl monomers in the presence of the vinyl oligomer; wherein the weight % ratio of vinyl oligomer to vinyl polymer is in the range of from 0.5:99.5 to 65:35.
摘要翻译：包含至少共价结合的乙烯基低聚物和乙烯基聚合物的水性乳液，其中所述乙烯基低聚物包含5-85摩尔％的带有季铵离子官能团或可季铵化胺官能团的乙烯基单体，并且通过至少一种受控自由基聚合获得一种乙烯基单体通过在控制剂和自由基来源的溶液中的可逆加成 - 断裂链转移机理; 其中所述乙烯基聚合物通过乙烯基单体在乙烯基低聚物存在下的乳液聚合获得; 其中乙烯基低聚物与乙烯基聚合物的重量％比在0.5:99.5至65:35的范围内。

4. 发明申请

US20110111244A1 ADHESION TO PLASTIC WITH BLOCK COPOLYMERS OBTAINED USING RAFT 审中-公开
标题翻译：使用RAFT获得的具有嵌段共聚物的塑料粘合剂
公开(公告)号：US20110111244A1
公开(公告)日：2011-05-12
申请号：US12935991
申请日：2009-04-01
申请人： Michael Arnoldus Jacobus Schellekens , Gerardus Cornelis Overbeek , Tijs Nabuurs , John Geurts
发明人： Michael Arnoldus Jacobus Schellekens , Gerardus Cornelis Overbeek , Tijs Nabuurs , John Geurts
IPC分类号： B32B27/08 , C09D153/00 , B05D3/10
CPC分类号： C09D153/00 , C08F2/24 , C08F287/00 , C08F293/005 , C08L53/00 , C08L53/005 , Y10T428/31935 , Y10T428/31938 , C08L2666/02
摘要： An aqueous coating composition (which optionally can coat plastic substrates) the composition comprising a block copolymer and a polymer P; where the block copolymer comprises at least blocks [A]x[B]y; where at least block [A] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism (optionally in solution in the presence of a control agent and a source of free radicals); and wherein block [A] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing water-dispersing functional groups; wherein block [B] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing plastic adhesion promoting functional groups; and wherein polymer P is prepared in the presence of blocks [A]x[B]y. The compositions may be used to coat plastic substrates, foam; surfaces having low surface energy, hydrophobic substrates and/or polyolefins.
摘要翻译：包含嵌段共聚物和聚合物P的组合物的水性涂料组合物（其可任选地可以涂覆塑料基材）; 其中嵌段共聚物至少包含嵌段[A] x [B] y; 其中至少通过可逆加成 - 断裂链转移（RAFT）机理（任选在溶液中存在控制剂和自由基来源）通过至少一种烯属不饱和单体的受控自由基聚合获得嵌段[A] ）; 并且其中嵌段[A]包含20至100摩尔％的带有水分散官能团的烯属不饱和单体单元; 其中嵌段[B]包含20至100摩尔％的具有塑性粘合促进官能团的烯属不饱和单体单元; 并且其中聚合物P在嵌段[A] x [B] y的存在下制备。组合物可用于涂覆塑料基材，泡沫; 具有低表面能的表面，疏水性基材和/或聚烯烃。

5. 发明申请

US20110021689A1 WATER BORNE CROSSLINKABLE BLOCK COPOLYMERS OBTAINED USING RAFT 审中-公开
标题翻译：使用RAFT获得的水性可交换嵌段共聚物
公开(公告)号：US20110021689A1
公开(公告)日：2011-01-27
申请号：US12812659
申请日：2009-01-16
申请人： Michael Arnoldus Jacobus Schellekens , Tijs Nabuurs , John Geurts , Gerardus Cornelis Overbeek
发明人： Michael Arnoldus Jacobus Schellekens , Tijs Nabuurs , John Geurts , Gerardus Cornelis Overbeek
IPC分类号： C08L53/00
CPC分类号： C09D133/08 , C08F293/005 , C08F2438/03 , C08L53/00 , C08L53/005 , C09D153/00 , C08L2666/02
摘要： There is disclosed a process for obtaining a water-borne crosslinkable composition comprising a block copolymer comprising at least blocks [A]x[B]y (where x is an integer from 3 to 80 (inc.), where y is an integer ≧10 and where y>x) and a polymer P, the block copolymer-polymer having an acid value ≦150 mg KOH per g of block copolymer-polymer, where at least block [A] and [B] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism in solution in the presence of a control agent and a source of free radicals; and where polymer P is obtained in the presence of blocks [A]x[B]y by an emulsion polymerisation process.
摘要翻译：公开了一种获得水性交联组合物的方法，该组合物包含至少包含嵌段[A] x [B] y（其中x为3-80（inc。）的整数）的嵌段共聚物，其中y为整数≧ 10，并且其中y> x）和聚合物P，具有酸值＆nlE的嵌段共聚物 - 聚合物;每克嵌段共聚物 - 聚合物为150mg KOH，其中至少块[A]和[B]通过受控在控制剂和自由基源的存在下，通过可逆加成 - 断裂链转移（RAFT）机理在溶液中自由基聚合至少一种烯属不饱和单体; 并且其中通过乳液聚合方法在嵌段[A] x [B] y存在下获得聚合物P。

6. 发明申请

US20120196143A1 ADHESION TO PLASTIC WITH BLOCK COPOLYMERS OBTAINED USING RAFT 审中-公开
标题翻译：使用RAFT获得的具有嵌段共聚物的塑料粘合剂
公开(公告)号：US20120196143A1
公开(公告)日：2012-08-02
申请号：US13439278
申请日：2012-04-04
申请人： Michael Arnoldus Jacobus SCHELLEKENS , Gerardus Cornelis Overbeek , Tijs Nabuurs , John Geurts
发明人： Michael Arnoldus Jacobus SCHELLEKENS , Gerardus Cornelis Overbeek , Tijs Nabuurs , John Geurts
IPC分类号： C09D153/00 , B05D7/02 , B32B27/30 , B05D5/00 , C08F2/22 , B05D3/00 , B05D7/24
CPC分类号： C09D153/00 , C08F2/24 , C08F287/00 , C08F293/005 , C08L53/00 , C08L53/005 , Y10T428/31935 , Y10T428/31938 , C08L2666/02
摘要： An aqueous coating composition (which optionally can coat plastic substrates) the composition comprising a block copolymer and a polymer P; where the block copolymer comprises at least blocks [A]x[B]y; where at least block [A] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism (optionally in solution in the presence of a control agent and a source of free radicals); and wherein block [A] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing water-dispersing functional groups; wherein block [B] comprises 20 to 100 mol % of ethylenically unsaturated monomer units bearing plastic adhesion promoting functional groups; and wherein polymer P is prepared in the presence of blocks [A]x[B]y. The compositions may be used to coat plastic substrates, foam; surfaces having low surface energy, hydrophobic substrates and/or polyolefins.
摘要翻译：包含嵌段共聚物和聚合物P的组合物的水性涂料组合物（其可任选地可以涂覆塑料基材）; 其中嵌段共聚物至少包含嵌段[A] x [B] y; 其中至少通过可逆加成 - 断裂链转移（RAFT）机理（任选在溶液中存在控制剂和自由基来源）通过至少一种烯属不饱和单体的受控自由基聚合获得嵌段[A] ）; 并且其中嵌段[A]包含20至100摩尔％的带有水分散官能团的烯属不饱和单体单元; 其中嵌段[B]包含20至100摩尔％的具有塑性粘合促进官能团的烯属不饱和单体单元; 并且其中聚合物P在嵌段[A] x [B] y的存在下制备。组合物可用于涂覆塑料基材，泡沫; 具有低表面能的表面，疏水性基材和/或聚烯烃。

7. 发明申请

US20100256299A1 PROCESS FOR OBTAINING LOW FREE MONOMER LEVELS IN A BLOCK COPOLYMER EMULSION PREPARED WITH (REVERSE) IODINE TRANSFER POLYMERISATION 审中-公开
标题翻译：制备（反向）碘转移聚合的嵌段共聚物乳液中低自由基单体含量的方法
公开(公告)号：US20100256299A1
公开(公告)日：2010-10-07
申请号：US12664922
申请日：2008-06-17
申请人： Tijs Nabuurs , Gerardus Cornelis Overbeek , Michael Arnoldus Jacobus Schellekens , Danny Visser , Frank Vaes
发明人： Tijs Nabuurs , Gerardus Cornelis Overbeek , Michael Arnoldus Jacobus Schellekens , Danny Visser , Frank Vaes
IPC分类号： C08L53/00
CPC分类号： C08L53/00 , C08F293/00 , C08F293/005 , C08F2438/00 , C08L2666/02 , C09D153/00 , C09J153/00
摘要： A process for obtaining an aqueous emulsion comprising a block copolymer by the solution polymerisation of vinyl monomers to obtain block [B] in the presence of a) a radical precursor; and b) an iodine atom containing block [A]; where block [A] and [B] together comprise 0 to 2 wt % of methacrylic acid; where block [A] and block [B] together comprise ≧2.5 wt % of vinyl monomers bearing ionic or potentially ionic water-dispersing groups not including methacrylic acid; and performing a post polymerisation reaction on the block copolymer emulsion obtained in step II; and wherein said aqueous emulsion has a free vinyl monomer level
摘要翻译：一种通过乙烯基单体的溶液聚合获得嵌段共聚物以在a）自由基前体存在下获得嵌段[B]的方法; 和b）含有碘原子的嵌段[A]; 其中嵌段[A]和[B]一起包含0至2重量％的甲基丙烯酸; 其中嵌段[A]和嵌段[B]一起包含≥2.5wt％的具有不包括甲基丙烯酸的离子或潜在离子水分散基团的乙烯基单体; 并对在步骤II中获得的嵌段共聚物乳液进行后聚合反应; 并且其中当固体含量为≥20wt％时，所述水性乳液的游离乙烯基单体含量<1000ppm。

8. 发明申请

US20110207871A1 AQUEOUS DISPERSIONS CONTAINING CRYSTALLISABLE BLOCK COPOLYMERS 审中-公开
标题翻译：含有可溶性嵌段共聚物的水性分散体
公开(公告)号：US20110207871A1
公开(公告)日：2011-08-25
申请号：US12671887
申请日：2008-07-31
申请人： John Geurts , Michael Arnoldus Jacobus Schellekens , Tijs Nabuurs , Gerardus Comelis Overbeek
发明人： John Geurts , Michael Arnoldus Jacobus Schellekens , Tijs Nabuurs , Gerardus Comelis Overbeek
IPC分类号： C08F2/22 , C08L53/00
CPC分类号： C08F2/18 , C08F2/38 , C08F293/005 , C08F2438/03 , C08L53/00 , C09D153/00 , C08L2666/02
摘要： An aqueous dispersion comprising a crystallisable vinyl block copolymer-polymer which comprises: i) a vinyl block copolymer comprising at least blocks [A]x [B]y , wherein at least a crystallisable block [A] is obtained by a controlled radical polymerisation of at least one vinyl monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism in solution, in the presence of a control agent and a source of free radicals; and wherein the vinyl block copolymer comprises 2 to 50 wt % of vinyl monomers bearing at least a crystallisable side chain by weight of the vinyl block copolymer-polymer; wherein crystallisable block [A] has an average degree of polymerisation x, wherein x is an integer in the range of from 3 to 80; wherein block [B] has an average degree of polymerisation y, wherein y is an integer ≦3; and ii) a vinyl polymer [P] obtained by the free radical emulsion polymerisation of one or more vinyl monomers in the presence of the vinyl block copolymer; and wherein the block copolymer:polymer weight ratio is in the range of from 10:90 to 70:30.
摘要翻译：包含可结晶乙烯基嵌段共聚物 - 聚合物的水分散体，其包含：i）至少包含嵌段[A] x [B] y的乙烯基嵌段共聚物，其中至少可结晶嵌段[A]通过受控自由基聚合至少一种乙烯基单体通过溶解中的可逆加成 - 断裂链转移（RAFT）机理，在控制剂和自由基源的存在下进行; 并且其中所述乙烯基嵌段共聚物包含2-50重量％的至少具有乙烯基嵌段共聚物 - 聚合物重量的可结晶侧链的乙烯基单体; 其中可结晶嵌段[A]具有平均聚合度x，其中x是3至80的整数; 其中嵌段[B]具有平均聚合度y，其中y是整数nlE; 3; 和ii）在乙烯基嵌段共聚物存在下通过一种或多种乙烯基单体的自由基乳液聚合获得的乙烯基聚合物[P]; 并且其中所述嵌段共聚物：聚合物重量比在10:90至70:30的范围内。

9. 发明授权

US09567476B2 Water-borne crosslinkable block copolymers obtained using raft 有权
标题翻译：使用木筏获得的水性交联嵌段共聚物
公开(公告)号：US09567476B2
公开(公告)日：2017-02-14
申请号：US13758803
申请日：2013-02-04
申请人： Michael Arnoldus Jacobus Schellekens , Tijs Nabuurs , John Geurts , Gerardus Cornslis Overbeek
发明人： Michael Arnoldus Jacobus Schellekens , Tijs Nabuurs , John Geurts , Gerardus Cornslis Overbeek
IPC分类号： C08L53/00 , C09D133/08 , C08F293/00 , C09D153/00
CPC分类号： C09D133/08 , C08F293/005 , C08F2438/03 , C08L53/00 , C08L53/005 , C09D153/00 , C08L2666/02
摘要： There is disclosed a process for obtaining a water-borne crosslinkable composition comprising a block copolymer comprising at least blocks [A]x[B]y (where x is an integer from 3 to 80 (inc.), where y is an integer ≧10 and where y>x) and a polymer P, the block copolymer-polymer having an acid value ≦150 mg KOH per g of block copolymer-polymer, where at least block [A] and [B] is obtained by a controlled radical polymerisation of at least one ethylenically unsaturated monomer via a reversible addition-fragmentation chain transfer (RAFT) mechanism in solution in the presence of a control agent and a source of free radicals; and where polymer P is obtained in the presence of blocks [A]x[B]y by an emulsion polymerisation process.
摘要翻译：公开了一种获得水性交联组合物的方法，该组合物包含至少包含嵌段[A] x [B] y（其中x为3-80（inc。）的整数）的嵌段共聚物，其中y为整数≧ 10，其中y> x）和聚合物P，每克嵌段共聚物 - 聚合物具有酸值≤150mgKOH的嵌段共聚物 - 聚合物，其中至少嵌段[A]和[B]由受控的基团在控制剂和自由基源的存在下，通过可逆的加成 - 断裂链转移（RAFT）机理在溶液中聚合至少一种烯属不饱和单体; 并且其中通过乳液聚合方法在嵌段[A] x [B] y存在下获得聚合物P。

10. 发明授权

US06395827B1 Aqueous crosslinkable coating compositions 失效
标题翻译：水性交联涂料组合物
公开(公告)号：US06395827B1
公开(公告)日：2002-05-28
申请号：US09402586
申请日：1999-11-22
申请人： David Alan Pears , Erik Hendrik Colstee , Gerardus Cornelis Overbeek , John Christopher Padget , Tijs Nabuurs
发明人： David Alan Pears , Erik Hendrik Colstee , Gerardus Cornelis Overbeek , John Christopher Padget , Tijs Nabuurs
IPC分类号： C08F800
CPC分类号： C08G18/6254
摘要： An aqueous crosslinkable coating composition suitable for the provision of thick coatings without incurring carbon dioxide bubble formation comprising: (A) an aqueous dispersion of at least one hydroxyl- and acid-functional vinyl polymer having a hydroxyl value of 8 to 250 mg KOH/g of polymer and an acid value of 2 to 55 mg KOH/g of polymer, where the contribution of at least 30% of the acid value results from a monocarboxylic acid(s) of formula: CH2—CR1—Q—CO2H (1) where R1 is H or lower alkyl of 1 to 5 carbon atoms and Q is a spacer group of formula: [—C(═O)—X—(CH2)m—]k (2) where X is —O— or —NH—, m is at least 1, preferably 2 or 3, and k is at least 1, preferably 2, 3, 4 or 5; and (B) at least one organic polyisocyanate. The acid of formula (1) preferably comprises &bgr;-carboxyethyl acrylate.
摘要翻译：适用于提供厚涂层而不引起二氧化碳气泡形成的水性可交联涂料组合物，其包含：（A）羟基值为8至250mg KOH / g的至少一种羟基和酸官能的乙烯基聚合物的水分散体的聚合物，酸值为2至55mg KOH / g聚合物，其中至少30％酸值的贡献来自下式的单羧酸：其中R 1为H或低级烷基为1至 5个碳原子，Q是下式的间隔基：其中X是-O-或-NH-，m是至少1，优选2或3，k是至少1，优选2,3,4或5; 和（B）至少一种有机多异氰酸酯。式（1）的酸优选包含丙烯酸β-羧乙酯。

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