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1. 发明授权

US06962962B2 Optically active polymer of chiral alkoxy-substituted phenylacetylene 失效
标题翻译：手性烷氧基取代苯基乙炔的光学活性聚合物
公开(公告)号：US06962962B2
公开(公告)日：2005-11-08
申请号：US10431366
申请日：2003-05-08
申请人： Masayoshi Tabata , Yasuteru Mawatari
发明人： Masayoshi Tabata , Yasuteru Mawatari
IPC分类号： C08F4/80 , C08F4/64 , C08F38/02 , C08F138/02 , C08F238/02
CPC分类号： C08F38/02
摘要： The invention provides an optically active polymer which is a product obtained by polymerizing a chiral alkoxy-substituted phenylacetylene such as p-(2-methylbutoxy)phenylacetylene, of which the 2-methylbutoxy group has chirality, in an organic solvent such as triethylamine in the presence of a rhodium complex compound as a polymerization catalyst. The optically active polymer exhibits a much larger optical rotation than the monomeric compound per se and is colored in different colors of, e.g., yellow and black, depending on the organic solvent used for polymerization. The yellow polymer turns to black by exposure to the vapor of a specific organic solvent such as chloroform and returns to yellow by re-precipitation from a chloroform solution with addition of methyl alcohol as a precipitant.
摘要翻译：本发明提供一种光学活性聚合物，其是通过使2-甲基丁氧基具有手性的手性烷氧基取代的苯乙炔如对 - （2-甲基丁氧基）苯基乙炔在有机溶剂如三乙胺中聚合而获得的产物存在铑络合物作为聚合催化剂。根据用于聚合的有机溶剂，光学活性聚合物显示出比单体化合物本身大得多的旋光度，并且以不同颜色例如黄色和黑色着色。通过暴露于特定有机溶剂如氯仿的蒸气，黄色聚合物变黑，通过加入甲醇作为沉淀剂从氯仿溶液中重新沉淀返回黄色。

2. 发明授权

US5461132A Organic magnetic member, organic ferromagnetic member, and process for producing the same, and time-responsible organic ferromagnetic member and process for controlling development of ferromagnetism 失效
标题翻译：有机磁性部件，有机铁磁部件及其制造方法，以及时间有序的有机铁磁部件和用于控制铁磁性发展的工艺
公开(公告)号：US5461132A
公开(公告)日：1995-10-24
申请号：US205340
申请日：1994-03-03
申请人： Masayoshi Tabata , Kazuaki Yokota , Yoko Yoshinaga , Fumio Kishi , Norio Kaneko , Nobuo Kushibiki
发明人： Masayoshi Tabata , Kazuaki Yokota , Yoko Yoshinaga , Fumio Kishi , Norio Kaneko , Nobuo Kushibiki
IPC分类号： C08F38/00 , H01F1/00 , H01F1/42
CPC分类号： H01F1/42 , C08F38/00
摘要： An organic magnetic member comprises repetition units represented by the following general formula [I]: ##STR1## having at least one of R.sub.1 and R.sub.2 which is a substituted or unsubstituted aromatic ring, or a substituted or unsubstituted heterocyclic ring, and being spontaneously magnetized.
摘要翻译：有机磁性构件包括由以下通式[I]表示的重复单元：具有R 1和R 2中的至少一个是取代或未取代的芳环或取代或未取代的杂环，并且为自发磁化。

3. 发明授权

US08450724B2 Electrical device containing helical substituted polyacetylene 失效
标题翻译：含有螺旋取代聚乙炔的电气装置
公开(公告)号：US08450724B2
公开(公告)日：2013-05-28
申请号：US12294612
申请日：2007-09-21
申请人： Takeyuki Sone , Akira Kuriyama , Koji Yano , Otto Albrecht , Masayoshi Tabata
发明人： Takeyuki Sone , Akira Kuriyama , Koji Yano , Otto Albrecht , Masayoshi Tabata
IPC分类号： H01L29/06 , H01L35/24 , H01L51/30
CPC分类号： H01L51/0041 , B82Y10/00 , H01L51/0545 , H01L51/0595
摘要： A device is provided by use of a helical substituted polyacetylene. The device comprises a structure comprised of a helical substituted polyacetylene having a helical main chain, and a pair of electrodes for applying a voltage or electric current to the structure, wherein the molecule of the helical substituted polyacetylene has a length larger than the distance between the pair of the electrodes.
摘要翻译：通过使用螺旋取代的聚乙炔提供装置。该装置包括由具有螺旋形主链的螺旋取代聚乙炔构成的结构和用于向结构施加电压或电流的一对电极，其中螺旋取代聚乙炔的分子的长度大于一对电极。

4. 发明授权

US08129493B2 Aromatic polyester 失效
标题翻译：芳香聚酯
公开(公告)号：US08129493B2
公开(公告)日：2012-03-06
申请号：US12871213
申请日：2010-08-30
申请人： Masayoshi Tabata , Takayoshi Yamazaki
发明人： Masayoshi Tabata , Takayoshi Yamazaki
IPC分类号： C08G64/00 , C08G63/02
CPC分类号： C08G63/193 , C08G63/195 , Y10T428/31504 , Y10T428/31507
摘要： There is provided an aromatic polyester suitable for optical applications, which has not only high heat resistance and transparency, but also enhanced fluidity at a relatively low molding temperature of less than 300° C. despite its high molecular weight to be substantially colorless after the molding process. The aromatic polyester of the present invention comprises polyhydric phenol residues and residues of aromatic polycarboxylic acid, acid halide or acid anhydride thereof; wherein the polyhydric phenol residues comprise polyhydric phenol residues represented by Formula (I): —O—Ar—W1x—Ar—O— and/or Formula (II): —O—Ar—O—, and bulky polyhydric phenol residues represented by Formula (III): —O—Ar—W2—Ar—O—; wherein the molar ratio of the polyhydric phenol residues represented by Formula (I) and/or Formula (II) to the polyhydric phenol residues represented by Formula (III) is in the range of 100:0 to 30:70 (exclusive of 100:0).
摘要翻译：提供了适用于光学应用的芳族聚酯，其不仅具有高耐热性和透明性，而且在低于300℃的相对较低的成型温度下也提高了流动性，尽管其成型后其高分子量基本上无色处理。本发明的芳族聚酯包括多元酚残基和芳族多元羧酸，酰卤或其酸酐的残基; 其中所述多元酚残基包括由式（I）表示的多元酚残基：-O-Ar-W1x-Ar-O-和/或式（II）：-O-Ar-O-，和大体积多元酚残基式（III）：-O-Ar-W2-Ar-O-; 其中由式（I）和/或式（II）表示的多元酚残基与由式（III）表示的多元酚残基的摩尔比在100:0至30:70（不包括100： 0）。

5. 发明申请

US20120172570A1 AROMATIC POLYESTER 审中-公开
标题翻译：芳香聚酯
公开(公告)号：US20120172570A1
公开(公告)日：2012-07-05
申请号：US13496215
申请日：2010-09-09
申请人： Masayoshi Tabata , Yasuteru Mawatari , Takayoshi Yamazaki
发明人： Masayoshi Tabata , Yasuteru Mawatari , Takayoshi Yamazaki
IPC分类号： C08G63/00 , C08G63/78
CPC分类号： C08G63/19
摘要： The present invention provides an aromatic polyester which is substantially free from the occurrence of coloration and retains significantly high transparency even after being thermally processed at high temperature and which has high flowability. The aromatic polyester contains a polyhydric phenol residue and a residue of any one of aromatic polycarboxylic acid, halide thereof, and anhydride thereof, and terminals of the aromatic polyester have a structure represented by the formula —C(O)—R. The aromatic polyester has an end-capping rate of 90% or higher and a weight average molecular weight (Mw) ranging from 3,000 to 1,000,000.
摘要翻译：本发明提供了一种芳香族聚酯，其基本上没有着色的发生，并且即使在高温热处理并且具有高流动性之后也保持显着高的透明度。芳香族聚酯含有多元酚残基和芳香族多元羧酸，其卤化物及其无机酸中的任一种的残基，芳香族聚酯的末端具有由式-C（O）-R表示的结构。芳香族聚酯的封端率为90％以上，重均分子量（Mw）为3,000〜1,000,000。

6. 发明申请

US20090179197A1 DEVICE 失效
标题翻译：设备
公开(公告)号：US20090179197A1
公开(公告)日：2009-07-16
申请号：US12294612
申请日：2007-09-21
申请人： Takeyuki Sone , Akira Kuriyama , Koji Yano , Otto Albrecht , Masayoshi Tabata
发明人： Takeyuki Sone , Akira Kuriyama , Koji Yano , Otto Albrecht , Masayoshi Tabata
IPC分类号： H01L51/30
CPC分类号： H01L51/0041 , B82Y10/00 , H01L51/0545 , H01L51/0595
摘要： A device is provided by use of a helical substituted polyacetylene. The device comprises a structure comprised of a helical substituted polyacetylene having a helical main chain, and a pair of electrodes for applying a voltage or electric current to the structure, wherein the molecule of the helical substituted polyacetylene has a length larger than the distance between the pair of the electrodes.
摘要翻译：通过使用螺旋取代的聚乙炔提供装置。该装置包括由具有螺旋形主链的螺旋取代聚乙炔构成的结构和用于向结构施加电压或电流的一对电极，其中螺旋取代聚乙炔的分子的长度大于一对电极。

7. 发明申请

US20050154164A1 Acetylene polymers showing reversible changes in absorption and emission spectra 审中-公开
标题翻译：显示吸收和发射光谱的可逆变化的乙炔聚合物
公开(公告)号：US20050154164A1
公开(公告)日：2005-07-14
申请号：US10505966
申请日：2003-02-28
申请人： Masayoshi Tabata
发明人： Masayoshi Tabata
IPC分类号： C08F38/00 , C08F38/02 , C08F12/28
CPC分类号： C08F38/00 , C08F38/02
摘要： Provided is a polymer represented by the structural formula, —(HC═CR)n—, (n in the formula is an integer of 30 or larger and R is —C6H4—OCxH2x+1, —C6H4—N═NCOCxH2x+1, —C6H4—NHCOCxH2x+1, o-trifluoromethylphenyl or o-(2-thienyl)phenyl, x being a positive integer and —C6H4— being o-, m- or p-phenylene group) which is a polymer having a regular spiral structure of the molecular chains and subject to reversible changes in the shapes and peak wavelengths of the absorption and emission spectra by means-of the reversible changes in the pitch of the spiral structure by impartment of a stimulation or by a solvent treatment or alteration thereof.
摘要翻译：提供一种由结构式表示的聚合物，<？in-line-formula description =“In-line Formulas”end =“lead”→>（HC-CR）n < in-line-formula description =“In-line Formulas”end =“tail”？>（公式中的n为30以上的整数，R为-C 6） 2×+ 1， - C 6 H-N-NCOC 3， H 2 H + H 2，C 6 H 4，-NHCOC 1 H 2， SO 2 x + 1，o-三氟甲基苯基或邻 - （2-噻吩基）苯基，x为正整数，-C为6 H 4 - 邻 - ，间 - 或对亚苯基），其是具有分子链的规则螺旋结构的聚合物，并且受到吸收和发射光谱的形状和峰值波长的可逆变化，借助于可逆变化通过刺激或通过溶剂处理或改变螺旋结构的间距。

8. 发明授权

US5082358A Polymer of vinyl-biphenyl derivative adapted for optical use 失效
标题翻译：用于光学应用的乙烯基苯乙烯衍生物衍生物的聚合物
公开(公告)号：US5082358A
公开(公告)日：1992-01-21
申请号：US371647
申请日：1989-06-22
申请人： Masayoshi Tabata , Nobuo Kushibiki , Yoko Yoshinaga
发明人： Masayoshi Tabata , Nobuo Kushibiki , Yoko Yoshinaga
IPC分类号： C08F12/32 , G02B1/04
CPC分类号： C08F12/32 , G02B1/04
摘要： A polymer of vinyl-biphenyl derivative comprising recurring units of the formula: ##STR1## wherein X is Cl or Br; a is an integer of 0-4; Y is --CH.sub.3, --OH, --OR, --SR, --SOR, --SO.sub.2 R, --SeR, --SeOR, --SeO.sub.2 R, --TeR, --TeOR, or --TeO.sub.2 R, wherein R is alkyl capable of having a substituent, aryl capable of having a substituent, or ##STR2## and Z is --CH.sub.2 --, --C(CH.sub.3).sub.2 --, --O--, --S--, --SO--, --SeO.sub.2 --, --Te--, --TeO--, or --TeO.sub.2 --; b and c are integers giving the sum of 1 to 5, and c is 1 or more. The polymer has a high refractive index and an excellent transparency. Further, the polymer can have a variable refractive index at a constant Abbe's number.
摘要翻译：包含下式的重复单元的乙烯基 - 联苯衍生物的聚合物：其中X是Cl或Br; a是0-4的整数; Y是-CH 3，-OH，-OR，-SR，-SOR，-SO 2 R，-SeR，-SeOR，-SeO 2 R，-TeR，-TeOR或-TeO 2 R，其中R是可以具有取代基的烷基，可以具有取代基，或者Z是-CH 2 - ， - C（CH 3）2 - ， - O - ， - S - ， - SO-，-SeO 2 - ，-Te-，-TeO-或 -TeO2-; b和c是给出总和为1至5，c为1或更大的整数。聚合物具有高折射率和优异的透明度。此外，聚合物可以具有恒定阿贝数的可变折射率。

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