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    • 4. 发明授权
    • Light-sensitive silver halide color photographic material
    • 感光卤化银彩色照相材料
    • US5278038A
    • 1994-01-11
    • US679937
    • 1991-04-03
    • Masanobu MiyoshiMakoto KajiwaraKaoru Onodera
    • Masanobu MiyoshiMakoto KajiwaraKaoru Onodera
    • G03C1/035G03C7/38G03C1/34
    • G03C7/3825G03C1/035
    • Light-sensitive silver halide color photographic material, having at least one light-sensitive silver halide emulsion layer on a support, wherein at least one of said emulsion layer contains light-sensitive silver halide grains having outer surfaces principally comprised of {100} face, and a magenta dye image forming coupler represented by Formula (I) shown below: ##STR1## wherein Z represents a group of nonmetal atom necessary for formation of a nitrogen-containing hetero ring; said ring formed by Z may have a substituent; X represents a hydrogen atom or a substituent eliminable by the reaction with an oxidant in a color developing agent; and R represents a hydrogen atom or a substituent.which can porovide a light-sensitive silver halide color photographic material having high sensitivity, being low in fogs, and having improved color reproducibility.
    • 感光卤化银彩色照相材料,其在载体上具有至少一个感光卤化银乳剂层,其中所述乳剂层中的至少一个含有感光卤化银颗粒,其外表面主要包括(100)面, (I)表示的品红染料影像成色剂:(*化学结构*)式(I):其中Z表示形成含氮杂环所必需的非金属原子团; 由Z形成的所述环可具有取代基; X表示氢原子或通过与彩色显影剂中的氧化剂反应可消除的取代基; R表示氢原子或取代基。 其可以具有高灵敏度的感光卤化银彩色照相材料,雾度低,并且具有改进的颜色再现性。
    • 5. 发明授权
    • Light-sensitive silver halide color photographic material
    • 感光卤化银彩色照相材料
    • US5023170A
    • 1991-06-11
    • US569778
    • 1990-08-21
    • Masanobu MiyoshiMakoto KajiwaraKaoru Onodera
    • Masanobu MiyoshiMakoto KajiwaraKaoru Onodera
    • G03C7/26G03C1/005G03C1/035G03C1/38G03C7/38
    • G03C7/3825G03C1/035
    • A light-sensitive silver halide color photographic material, having at least one light-sensitive silver halide emulsion layer on a support, wherein at least one of said emulsion layer contains light-sensitive silver halide grains having outer surfaces principally comprised of {100} face, and a magenta dye image forming coupler represented by Formula (I) shown below: ##STR1## wherein Z represents a group of nonmetal atom necessary for formation of a nitrogen-containing hetero ring; said ring formed by Z may have a substituent; X represents a hydrogen atom or a substituent eliminable by the reaction with an oxidant in a color developing agent; and R represents a hydrogen atom or a substituent,which can provide a light-sensitive silver halide color photographic material having high sensitivity, being low in fogs, and having improved color reproducibility.
    • 一种感光卤化银彩色照相材料,其在载体上具有至少一个感光卤化银乳剂层,其中至少一个所述乳剂层含有感光卤化银颗粒,其外表面主要由{100}面 ,和由下式(I)表示的品红染料影像形成成色剂:其中Z表示形成含氮杂环所必需的非金属原子团; 由Z形成的所述环可具有取代基; X表示氢原子或通过与彩色显影剂中的氧化剂反应可消除的取代基; 并且R表示氢原子或取代基,其可以提供具有高灵敏度,雾度低并且具有改善的颜色再现性的感光卤化银彩色照相材料。
    • 7. 发明授权
    • Light-sensitive silver halide photographic material feasible for rapid
processing comprising high boiling solvent and gold compounds
    • 感光卤化银照相材料可用于快速加工,包括高沸点溶剂和金化合物
    • US4912026A
    • 1990-03-27
    • US328721
    • 1989-03-23
    • Masanobu MiyoshiMakoto KajiwaraKaoru OnoderaEiichi Sakamoto
    • Masanobu MiyoshiMakoto KajiwaraKaoru OnoderaEiichi Sakamoto
    • G03C1/34G03C1/76
    • G03C1/346G03C1/7614
    • A light-sensitive silver halide photographic material having a support with at least one silver halide emulsion layer containing a dye-forming coupler, where the light-sensitive silver halide photographic material is characterized in that at least one of the silver halide emulsion layers contains (i) the dye-forming coupler dispersed with the use of a high boiling organic solvent having a dielectric constant of 6.0 or less, (ii) silver halide grains containing a gold compound and having silver chloride content of 90 mole % or more, and (iii) a compound represented by General Formula (S) shown below. General Formula (S): ##STR1## where Q is a group of atoms necessary to complete a 5- or 6-membered heterocyclic ring or a 5- or 6-membered ring fused with a benzene ring and M is a hydrogen atom, an alkali metal or an ammonium group.The light-sensitive material can achieve excellent preservation of the dye image, is feasible for rapid processing, has superior BF contamination resistance and pH variation resistance.
    • 一种感光卤化银照相材料,其具有至少一个含有染料形成成色剂的卤化银乳剂层的载体,其中感光卤化银照相材料的特征在于至少一种卤化银乳剂层含有 i)成色剂通过使用介电常数为6.0以下的高沸点有机溶剂分散,(ii)含有金化合物的卤化银颗粒和氯化银含量为90摩尔%以上,( iii)由以下所示的通式(S)表示的化合物。 通式(S):其中Q是完成5或6元杂环或与苯环稠合的5或6元环所必需的一组原子,M是氢原子, 碱金属或铵基。 感光材料可以实现对染料影像的优异保存,对于快速加工是可行的,具有优异的BF耐污染性和耐pH变异性。
    • 8. 发明授权
    • Method of forming dye image having superior rapid processing performance
    • US4839263A
    • 1989-06-13
    • US79220
    • 1987-07-29
    • Masanobu MiyoshiMakoto KajiwaraKaoru OnoderaEiichi Sakamoto
    • Masanobu MiyoshiMakoto KajiwaraKaoru OnoderaEiichi Sakamoto
    • G03C1/035G03C1/30G03C7/30G03C7/392G03C7/407
    • G03C7/3924G03C1/305Y10S430/164
    • A silver halide photographic material containing a support and, provided thereon, at least one silver halide emulsion layer, this silver halide emulsion layer containing silver halide grains containing 90 mol % or more of silver chloride, a dye-forming coupler, and a compound represented by general formula [S]; ##STR1## wherein Q is a group of atoms necessary to complete a 5- or 6-membered heterocyclic ring or a 5- or 6-membered ring fused with a benzene ring and M is a hydrogen atom, an alkali metal or an ammonium group;the silver halide layer having been hardened by a hardener represented by formula [HDA] or [HDB]; ##STR2## wherein Rd.sub.1 is selected from the group consisting of a chlorine atom, a hydroxyl group, an alkyl group, an alkoxy group, an alkylthio group, an --OM group, wherein M is an mono-valent metal atom, a --NR'R" group, wherein R' and R" are independently selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group and a --NHCOR'" group, in which R'" is selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group; Rd.sub.2 is selected from the group consisting of a hydroxyl group, an alkyl group, an alkoxy group, an alkylthio group, an --OM group, wherein M is an mono-valent metal atom, a --NR'R" group, wherein R' and R" are independently selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group and a --NHCOR'" group, in which R'" is selected from the group consisting of a hydrogen atom, an alkyl group and an aryl group; ##STR3## wherein Rd.sub.3 and Rd.sub.4 are independently selected from the group consisting of a chlorine atom, a hydroxyl group, an alkyl group, an alkoxy group and an --OM group, in which is a mono-valent metal atom; Q and Q' is a divalent atom or group selected from --O--, --S-- and --NH--; L is an alkylene group or an arylene group; and p and q are independently integers of 0 or 1. The above-described silver halide photographic material is processed with a color developing solution containing a sulfite ion in a quantity of 2.times.10.sup.-4 to 1.times.10.sup.-2 moles per liter, this developing solution being substantially free of bromide ion. The above-described material and process for developing the same, being better suited for use in rapid developing processes.