会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 3. 发明授权
    • Preparation of silicon-containing vinyl ethers and vinyl thioethers
    • 含硅乙烯基醚和乙烯基硫醚的制备
    • US5587503A
    • 1996-12-24
    • US518718
    • 1995-08-24
    • Marc HeiderJochem HenkelmannMichael Karcher
    • Marc HeiderJochem HenkelmannMichael Karcher
    • C07F7/08C07F7/18
    • C07F7/1892C07F7/083
    • Process for preparing silicon-containing vinyl ethers and vinyl thioethers of the general formula I ##STR1## where the variables have the following meanings: X is oxygen or sulfur,R.sup.1 is C.sub.1 -C.sub.20 -alkylene, C.sub.3 -C.sub.12 -cycloalkylene or C.sub.6 -C.sub.10 -arylene,R.sup.2, R.sup.3 and R.sup.4 are hydrogen, C.sub.1 -C.sub.20 -alkyl, C.sub.3 -C.sub.12 -cycloalkyl, C.sub.1 -C.sub.12 -alkoxy, phenoxy, heteroaryl or together with R.sup.1 form a C.sub.3 -C.sub.12 -cycle,by reaction of silicon-containing alcohols or thiols of the general formula II ##STR2## where the variables have the meaning indicated above, with acetylene, by carrying out the reaction in phenyl methyl sulfoxide, dimethyl sulfoxide, sulfolane or hexamethylphosphoramide in the presence of an alkali metal hydroxide.
    • 制备通式I的含硅乙烯基醚和乙烯基硫醚的方法意义:X是氧或硫,R1是C1-C20亚烷基,C3-C12-亚环烷基或C6-C10-亚芳基,R2,R3和R4 C 1 -C 20烷基,C 3 -C 12 - 环烷基,C 1 -C 12 - 烷氧基,苯氧基,杂芳基或与R 1一起形成C 3 -C 12环,通过使通式II的含硅醇或硫醇反应 通过在碱金属氢氧化物的存在下在苯基甲基亚砜,二甲基亚砜,环丁砜或六甲基磷酰胺中进行反应,其中变量具有上述含义的乙炔。