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1. 发明授权

US5728439A Multilayer packaging material for oxygen sensitive food and beverage 失效
标题翻译：用于氧敏感食品和饮料的多层包装材料
公开(公告)号：US5728439A
公开(公告)日：1998-03-17
申请号：US759905
申请日：1996-12-04
申请人： Leland H. Carlblom , Jerome A. Seiner , Ken W. Niederst
发明人： Leland H. Carlblom , Jerome A. Seiner , Ken W. Niederst
IPC分类号： B32B27/38 , B32B27/00 , B65D23/08 , C08G59/50 , C08J7/00 , C08J7/04 , C09D163/00 , B29D22/00 , B32B1/02 , B32B27/08
CPC分类号： C08J7/047 , C08G59/50 , C08J2367/02 , C08J2463/00 , Y10T428/1393 , Y10T428/31511 , Y10T428/31515 , Y10T428/31786
摘要： Disclosed is a multilayer packaging material which is suitable for use as a container for malt beverages and which is tinted so as to block at least 90% of light with wavelengths of electromagnetic radiation ranging from 300 nm to 500 nm. The tinted multilayer packaging materials of the present invention includes: (a) at least one layer of a carbon dioxide (CO.sub.2)-permeable polymeric packaging material, and (b) at least one layer of a CO.sub.2 -treated gas barrier coating, which has an oxygen permeability constant not more than 0.05 cubic centimeter-mil/100 square inches/atmosphere/day. The CO.sub.2 -permeable packaging material can be any polymeric material through which CO.sub.2 can pass and which can be used as a packaging material for food or beverages. The gas barrier coating has an oxygen permeability constant, before CO.sub.2 treatment, of less than 0.3. This gas barrier coating includes the reaction product of a polyamine (A) and a polyepoxide (B). The polyamine (A) can be an initial polyamine or an ungelled polyamine adduct having active amine hydrogens. Polyepoxide (B) can be a polyepoxide having a plurality of glycidyl groups linked to an aromatic member.
摘要翻译：公开了一种多层包装材料，其适用于麦芽饮料的容器，其被着色以阻挡至少90％的具有300nm至500nm的电磁辐射波长的光。本发明的有色多层包装材料包括：（a）至少一层二氧化碳（CO 2） - 可渗透聚合物包装材料，和（b）至少一层经CO 2处理的气体阻隔涂层，其具有氧气渗透常数不大于0.05立方厘米/ 100平方英寸/大气/天。二氧化碳可透过的包装材料可以是CO 2可以通过的任何聚合物材料，其可用作食品或饮料的包装材料。阻气涂层在CO2处理之前的氧气渗透率常数小于0.3。该阻气涂层包括多胺（A）和聚环氧化物（B）的反应产物。多胺（A）可以是具有活性胺氢的初始多胺或未凝胶化的多胺加合物。聚环氧化物（B）可以是具有连接到芳族成员的多个缩水甘油基的聚环氧化物。

2. 发明授权

US5902643A Multilayer packaging material having aminoepoxy gas barrier coating 失效
标题翻译：具有氨氧环氧阻气涂层的多层包装材料
公开(公告)号：US5902643A
公开(公告)日：1999-05-11
申请号：US977086
申请日：1997-11-24
申请人： Leland H. Carlblom , Jerome A. Seiner , Ken W. Niederst
发明人： Leland H. Carlblom , Jerome A. Seiner , Ken W. Niederst
IPC分类号： B32B27/38 , B32B27/00 , B65D23/08 , C08G59/50 , C08J7/00 , C08J7/04 , C09D163/00 , B05D3/10 , B29D22/00 , B32B1/02
CPC分类号： C08J7/047 , C08G59/50 , C08J2367/02 , C08J2463/00 , Y10T428/1393 , Y10T428/31511 , Y10T428/31515 , Y10T428/31786
摘要： Disclosed is a multilayer packaging material which is suitable for use as a container for malt beverages and which is tinted so as to block at least 90% of light with wavelengths of electromagnetic radiation ranging from 300 nm to 500 nm. The tinted multilayer packaging materials of the present invention includes: (a) at least one layer of a carbon dioxide (CO.sub.2)-permeable polymeric packaging material, and (b) at least one layer of a CO.sub.2 -treated gas barrier coating, which has an oxygen permeability constant not more than 0.05 cubic centimeter-mil/100 square inches/atmosphere/day. The CO.sub.2 -permeable packaging material can be any polymeric material through which CO.sub.2 can pass and which can be used as a packaging material for food or beverages. The gas barrier coating has an oxygen permeability constant, before CO.sub.2 treatment, of less than 0.3. This gas barrier coating includes the reaction product of a polyamine (A) and a polyepoxide (B). The polyamine (A) can be an initial polyamine or an ungelled polyamine adduct having active amine hydrogens. Polyepoxide (B) can be a polyepoxide having a plurality of glycidyl groups linked to an aromatic member.
摘要翻译：公开了一种多层包装材料，其适用于麦芽饮料的容器，其被着色以阻挡至少90％的具有300nm至500nm的电磁辐射波长的光。本发明的有色多层包装材料包括：（a）至少一层二氧化碳（CO 2） - 可渗透聚合物包装材料，和（b）至少一层经CO 2处理的气体阻隔涂层，其具有氧气渗透常数不大于0.05立方厘米/ 100平方英寸/大气/天。二氧化碳可透过的包装材料可以是CO 2可以通过的任何聚合物材料，其可用作食品或饮料的包装材料。阻气涂层在CO2处理之前的氧气渗透率常数小于0.3。该阻气涂层包括多胺（A）和聚环氧化物（B）的反应产物。多胺（A）可以是具有活性胺氢的初始多胺或未凝胶化的多胺加合物。聚环氧化物（B）可以是具有连接到芳族成员的多个缩水甘油基的聚环氧化物。

3. 发明授权

US06309757B1 Gas barrier coating of polyamine, polyepoxide and hydroxyaromatic compound 有权
标题翻译：多胺，聚环氧化物和羟基芳族化合物的阻气涂层
公开(公告)号：US06309757B1
公开(公告)日：2001-10-30
申请号：US09505416
申请日：2000-02-16
申请人： Leland H. Carlblom , Cynthia Kutchko , Ken W. Niederst
发明人： Leland H. Carlblom , Cynthia Kutchko , Ken W. Niederst
IPC分类号： B32B0102
CPC分类号： C08J7/047 , C08G59/56 , C08G59/62 , C08J2463/00 , Y10T428/1334 , Y10T428/139 , Y10T428/31511 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31938
摘要： Gas barrier coating compositions are provided which include a polyamine component, a polyepoxide component and a hydroxy-substituted aromatic compound that is present in an amount sufficient to provide a gas barrier coating having an oxygen permeability less than or equal to 75 percent of the oxygen permeability of the same composition without a hydroxy-substituted aromatic compound. Also provided is a multi-layer packaging material having at least one gas permeable packaging material layer and at least one gas barrier material layer formed from the gas barrier coating composition. Sealable containers are also provided.
摘要翻译：提供了阻气涂层组合物，其包括多胺组分，聚环氧化物组分和羟基取代的芳族化合物，其以足以提供氧透过率小于或等于透氧率的75％的阻气涂层的量存在没有羟基取代的芳族化合物的相同组成。还提供了具有至少一个透气性包装材料层和由阻气涂层组合物形成的至少一个阻气材料层的多层包装材料。还提供可密封的容器。

4. 发明授权

US5830274A Electrostatic deposition of charged coating particles onto a dielectric substrate 失效
标题翻译：带电涂层颗粒静电沉积到电介质基片上
公开(公告)号：US5830274A
公开(公告)日：1998-11-03
申请号：US575188
申请日：1995-12-20
申请人： Donald B. Jones , Leland H. Carlblom , Ken W. Niederst , Paul S. Chirgott
发明人： Donald B. Jones , Leland H. Carlblom , Ken W. Niederst , Paul S. Chirgott
IPC分类号： B05B5/043 , B05B5/08 , B05B5/00
CPC分类号： B05B5/087 , B05B5/043 , B05B5/082 , Y10S118/03
摘要： The present invention provides an apparatus for controlling the spray of positively-charged coating particles towards a grounded or negatively-charged dielectric material having a dielectric constant less than 4.0 and in the form of a hollow container. This apparatus includes: (a) a device for inducing a positive charge onto a coating composition, (b) a device for creating a field of positively-charged coating particles, (c) a device for supporting a series of hollow containers in spaced relation to one another which includes a series of vertically-oriented spindles, (d) a device for transporting the spindles in series through the field of positively-charged coating particles, (e) a gripping chuck made from, or coated with, a dielectric material, or both, mounted to the upper end of a spindle, the chuck having a recess defined therein for receiving the opening of a hollow container, and (f) a grounding device positioned such that, when the dielectric container is in the path of the sprayed, positively-charged coating particles the grounding device is also in the path but shielded therefrom by the dielectric material. The grounding device is insulated from direct electrical contact with the supported container. The grounding device can be replaced by an internal charging device for inducing a negative charge onto a hollow container being supported by the gripping chuck. Moreover, the grounding device or the internal charging device can be used in conjunction with an external charging device for inducing a negative charge onto a hollow container being supported by the gripping chuck.
摘要翻译：本发明提供了一种用于控制带正电荷的涂层颗粒朝着介电常数小于4.0的接地或带负电荷的电介质材料喷射并且以中空容器的形式的装置。该装置包括：（a）用于在涂料组合物上引起正电荷的装置，（b）用于产生带正电的涂层颗粒的场的装置，（c）用于以间隔关系支撑一系列中空容器的装置（d）用于通过带正电荷的涂层颗粒领域串联输送主轴的装置，（e）由介电材料制成或涂覆的夹紧卡盘或两者安装到主轴的上端，卡盘具有限定在其中的凹部，用于容纳中空容器的开口，以及（f）接地装置，其定位成使得当电介质容器处于喷涂的带正电荷的涂层颗粒，接地装置也在路径中，但是被电介质材料遮挡。接地装置与受支撑的容器直接电接触绝缘。接地装置可以由内部充电装置代替，用于在由卡盘支撑的中空容器上引起负电荷。此外，接地装置或内部充电装置可以与外部充电装置一起使用，用于将负电荷引导到由夹紧卡盘支撑的中空容器上。

5. 发明授权

US5698269A Electrostatic deposition of charged coating particles onto a dielectric substrate 失效
标题翻译：带电涂层颗粒静电沉积到电介质基片上
公开(公告)号：US5698269A
公开(公告)日：1997-12-16
申请号：US574758
申请日：1995-12-20
申请人： Leland H. Carlblom , Donald B. Jones , Ken W. Niederst , Paul S. Chirgott
发明人： Leland H. Carlblom , Donald B. Jones , Ken W. Niederst , Paul S. Chirgott
IPC分类号： B05B5/08 , B05D1/06 , B05D3/14
CPC分类号： B05B5/087
摘要： This invention provides a process for electrostatically applying a coating composition onto dielectric materials which have a dielectric constant less than 4.0. In this process, a positive charge is induced onto a coating composition. The dielectric material is electrically isolated, negatively charge, or both. The positively-charged coating composition is sprayed onto the dielectric material. If the dielectric material is charged negatively, the process of the present invention further includes the step of maintaining at least a portion of the negative charge on the dielectric material while positively-charged coating particles are being sprayed thereon.
摘要翻译：本发明提供了一种将涂料组合物静电涂覆在介电常数小于4.0的介电材料上的方法。在该方法中，在涂料组合物上引起正电荷。介电材料是电隔离的，带负电荷的，或两者都是。将带正电的涂料组合物喷涂到电介质材料上。如果介电材料带负电，本发明的方法还包括在正电荷的涂层颗粒被喷在其上的同时，在电介质材料上保持负电荷的至少一部分的步骤。

6. 发明授权

US5491204A Gas barrier coating from reacting polyamine, alkanolamine and polyepoxide 失效
标题翻译：来自多胺，链烷醇胺和聚环氧化物的气体阻隔涂层
公开(公告)号：US5491204A
公开(公告)日：1996-02-13
申请号：US429442
申请日：1995-04-27
申请人： Richard M. Nugent, Jr. , Ken W. Niederst , Jerome A. Seiner
发明人： Richard M. Nugent, Jr. , Ken W. Niederst , Jerome A. Seiner
IPC分类号： C08G59/18 , C08G59/50 , C08J7/04 , C09D163/00
CPC分类号： C08J7/047 , C08G59/184 , C09D163/00 , C08J2463/00 , Y10T428/1324 , Y10T428/1341 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31855
摘要： Barrier materials for reducing the permeability of plastic packaging materials are provided, characterized as containing at least about seven percent by weight amine nitrogen, or a total of at least about 17 percent amine nitrogen plus hydroxyl groups. The barrier materials exhibit oxygen permeability of less than about 1.5 cc-mil/100 in.sup.2 -day-atmosphere and a carbon dioxide permeability of less than about 15 cc-mil/100 in.sup.2 -day-atmosphere at 23.degree. C. and zero percent relative humidity. The barrier material is formed from a polyepoxide, a polyamine and an alkanolamine. Optionally the polyamine may comprise prereacted polymeric resin formed from a polyepoxide and a polyamine. Multilayer packaging materials and multilayer containers including the polyamine-polyepoxide barrier material are part of the invention.
摘要翻译：提供了用于降低塑料包装材料的渗透性的阻隔材料，其特征在于含有至少约7重量％的胺氮，或总共至少约17个胺氮加羟基。阻隔材料在2天大气中表现出小于约1.5cc密尔/ 100的氧气渗透性，在23℃下在2天大气压下的二氧化碳渗透性小于约15cc-mil / 100，相对于0％湿度。阻挡材料由聚环氧化物，多胺和链烷醇胺形成。任选地，多胺可以包含由聚环氧化物和多胺形成的预反应的聚合物树脂。包括多胺 - 聚环氧化物阻隔材料的多层包装材料和多层容器是本发明的一部分。

7. 发明授权

US5300334A Pressurizable thermoplastic container having an exterior polyurethane layer and its method of making 失效
标题翻译：具有外部聚氨酯层的可加压热塑性容器及其制造方法
公开(公告)号：US5300334A
公开(公告)日：1994-04-05
申请号：US991484
申请日：1992-12-16
申请人： Ken W. Niederst , John R. Zern , Jerome A. Seiner
发明人： Ken W. Niederst , John R. Zern , Jerome A. Seiner
IPC分类号： B65D1/00 , B65D23/08 , B65D25/34 , C08J7/04
CPC分类号： C08J7/047 , B65D23/0814 , C08J2475/00 , Y10T428/1352 , Y10T428/1379 , Y10T428/1386 , Y10T428/31551 , Y10T428/31565
摘要： Pressurizable thermoplastic containers, such as those made from polyethylene terephthalate containing a polyurethane layer on the exterior surface thereof are disclosed. The polyurethane layer which is typically applied by a coating process provides the bottle with resistance to stress cracking. The containers are useful as refillable bottles for carbonated beverages which have a tendency to stress crack.
摘要翻译：公开了可加压热塑性容器，例如由其外表面上含有聚氨酯层的聚对苯二甲酸乙二醇酯制成的那些。通常通过涂覆方法施加的聚氨酯层为瓶子提供抗应力开裂性。这些容器可用作具有压力裂纹倾向的碳酸饮料的可再填充瓶。

8. 发明授权

US5008137A Barrier coatings 失效
标题翻译：阻隔涂层
公开(公告)号：US5008137A
公开(公告)日：1991-04-16
申请号：US367992
申请日：1989-06-19
申请人： Richard M. Nugent, Jr. , Ken W. Niederst , Jerome A. Seiner
发明人： Richard M. Nugent, Jr. , Ken W. Niederst , Jerome A. Seiner
IPC分类号： C08G59/18 , C08J7/04 , C09D163/00
CPC分类号： C08J7/047 , C08G59/184 , C09D163/00 , C08J2463/00 , Y10T428/1341 , Y10T428/1379 , Y10T428/31507 , Y10T428/31511 , Y10T428/31797 , Y10T428/31913 , Y10T428/31938
摘要： Multilayer packaging materials and multilayer containers including a barrier material having excellent resistance to gas permeability are provided. The multilayer packaging materials and containers include at least one permeable polymeric material and at least one layer of a barrier material which is a reaction product of: (i) an ungelled amine-functional polymeric resin, which is a reaction product of a polyamine and a polyfunctional material having at least two functional groups reactive with said polyamine, the ungelled polymeric resin further containing an average of greater than two polyamine moieties per molecule within said resin; and (ii) a material selected from the group consisting of a polyepoxide, a polyoxalate or mixtures thereof, the barrier material characterized as containing at least about four percent by weight amine nitrogen and having an oxygen permeability of less than about 3 cc-mil/100 in.sup.2 -day-atmosphere and a carbon dioxide permeability of less than about 15 cc-mil/100 in.sup.2 -day-atmosphere at 23.degree. C. and zero percent relative humidity. The barrier material can be formed from coating compositions including as co-curable resinous materials, e.g., a polyepoxide and an ungelled amine-functional polymeric resin formed from a polyepoxide and a polyamine having up to about two primary amino nitrogen groups per molecule, the polyamine and polyepoxide present in a reaction mixture at a molar ratio of from about 1.4:1 to about 0.83:1.
摘要翻译：提供了具有优异的耐气体渗透性的阻隔材料的多层包装材料和多层容器。多层包装材料和容器包括至少一种可渗透聚合物材料和至少一层阻隔材料层，其是以下物质的反应产物：（i）未凝胶化的胺官能聚合物树脂，其是多胺和具有至少两个与所述多胺反应的官能团的多官能材料，所述未凝胶化聚合物树脂在所述树脂内每分子平均含有大于两个多胺部分; 所述阻挡材料的特征在于含有至少约4重量％的胺氮并具有小于约3cc-mil / cm 3的氧渗透性， 100天2天气氛，二氧化碳渗透性在23℃和0％相对湿度的2天大气压下小于约15cc密耳/ 100。阻挡材料可以由包括作为共固化树脂材料的涂料组合物形成，例如聚环氧化物和由聚环氧化物形成的未凝胶化的胺官能聚合物树脂和每分子具有多达约两个伯氨基氮基团的多胺，多胺和聚环氧化物以约1.4:1至约0.83:1的摩尔比存在于反应混合物中。

9. 发明授权

US5639848A Ungelled polyamine-polyepoxide resins 失效
标题翻译：未凝胶多胺 - 聚环氧树脂
公开(公告)号：US5639848A
公开(公告)日：1997-06-17
申请号：US631494
申请日：1996-04-12
申请人： Richard M. Nugent, Jr. , Ken W. Niederst , Jerome A. Seiner
发明人： Richard M. Nugent, Jr. , Ken W. Niederst , Jerome A. Seiner
IPC分类号： B32B27/08 , C08G59/18 , C08G59/50 , C08J7/04 , C08L63/00
CPC分类号： C08G59/5006 , B32B27/08 , C08G59/18 , C08G59/184 , C08G59/50 , C08J7/047 , C08L63/00 , C08J2323/12 , C08J2463/00 , Y10T428/1341 , Y10T428/1379 , Y10T428/1383 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31913 , Y10T428/31938
摘要： An ungelled thermoplastic resin having gas barrier properties and containing at least 7 percent by weight of amine nitrogen is derived via the reaction of a polyamine devoid of oxyalkylene moieties and containing up to about two primary amino nitrogen groups per molecule and a polyepoxide in a molar ratio of polyamine to polyepoxide of from 1.4:1 to 0.83:1.
摘要翻译：具有阻气性并含有至少7重量％胺氮的未凝胶热塑性树脂通过缺乏氧化烯部分的多胺与每分子含有至多约两个伯氨基氮基团和多环氧化物的摩尔比的反应得到的多胺与聚环氧化物的比例为1.4：1至0.83：1。

10. 发明授权

US5573819A Barrier coatings 失效
标题翻译：阻隔涂层
公开(公告)号：US5573819A
公开(公告)日：1996-11-12
申请号：US549291
申请日：1995-10-27
申请人： Richard M. Nugent, Jr. , Ken W. Niederst , Jerome A. Seiner
发明人： Richard M. Nugent, Jr. , Ken W. Niederst , Jerome A. Seiner
IPC分类号： C08G59/18 , C08G59/50 , C08J7/04 , C09D163/00 , B32B27/08 , B32B33/00
CPC分类号： C08J7/047 , C08G59/184 , C09D163/00 , C08J2463/00 , Y10T428/1324 , Y10T428/1341 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31855
摘要： Barrier materials for reducing the permeability of plastic packaging materials are provided, characterized as containing at least about seven percent by weight amine nitrogen, or a total of at least about 17 percent amine nitrogen plus hydroxyl groups. The barrier materials exhibit oxygen permeability of less than about 1.5 cc-mil/100 in.sup.2 -day-atmosphere and a carbon dioxide permeability of less than about 15 cc-mil/100 in.sup.2 -day-atmosphere at 23.degree. C. and zero percent relative humidity. The barrier material can be formed from polyepoxide and polyamine. Optionally the polyamine may comprise prereacted polymeric resin formed from a polyepoxide and a polyamine. Multilayer packaging materials and multilayer containers including the polyamine-polyepoxide barrier material are part of the invention.
摘要翻译：提供了用于降低塑料包装材料的渗透性的阻隔材料，其特征在于含有至少约7重量％的胺氮，或总共至少约17个胺氮加羟基。阻隔材料在2天大气中表现出小于约1.5cc密尔/ 100的氧气渗透性，在23℃下在2天大气压下的二氧化碳渗透性小于约15cc-mil / 100，相对于0％湿度。阻挡材料可以由聚环氧化物和多胺形成。任选地，多胺可以包含由聚环氧化物和多胺形成的预反应的聚合物树脂。包括多胺 - 聚环氧化物阻隔材料的多层包装材料和多层容器是本发明的一部分。

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