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1. 发明授权

US5258144A Method of manufacturing a transparent polymer material article with a refractive index gradient 失效
$Method of manufacturing a transparent polymer material article with a refractive index gradient$
标题翻译：制造具有折射率梯度的透明聚合物材料制品的方法
公开(公告)号：US5258144A
公开(公告)日：1993-11-02
申请号：US833532
申请日：1992-02-10
申请人： Leanirith Yean , Georges Wajs , Gerard Martin , Patrick Guerrero
发明人： Leanirith Yean , Georges Wajs , Gerard Martin , Patrick Guerrero
IPC分类号： C08L101/00 , B29D11/00 , G02B1/04 , G02B3/00 , G02C7/02
CPC分类号： B29D11/00355 , G02B3/0087 , B29K2995/0031 , G02C2202/12
摘要： In a method of manufacturing a transparent polymer material article having a refractive index gradient the polymer base material is caused to absorb a swelling agent including at least a monomer adapted to yield a polymer having a refractive index different than that of the polymer base material. A first preform having a first geometry is formed from the polymer base material sufficiently polymerized for the first preform to be self-supporting. A confinement space is defined between the first preform and an abutment member having facing it a second geometry at least partly different than the first geometry and having a greater volume than the latter. The first preform is brought into contact in the confinement space with a sufficient quantity of swelling agent for the swelling to which it is then subject to cause it to be urged actively into contact with all points of the second geometry. The resulting polymer material is polymerized and the second preform thus obtained is machined, if necessary, to the required final geometry of the required article. The method finds an application in the manufacture of ophthalmic lenses.
摘要翻译：在制造具有折射率梯度的透明聚合物材料制品的方法中，使聚合物基材吸收至少包含适于产生具有与聚合物基材的折射率不同的聚合物的单体的溶胀剂。具有第一几何形状的第一预成型体由对第一预成型体充分聚合的聚合物基材形成为自支撑。限定空间被限定在第一预制件和抵靠构件之间，所述抵接构件面向与第一几何形状至少部分不同的第二几何形状并且具有比后者更大的体积。第一预成型件在约束空间中与足够量的用于溶胀的溶胀剂接触，然后使其膨胀，使其被主动地与第二几何形状的所有点接触。所得到的聚合物材料被聚合，并且如果需要，如此获得的第二预制件被加工成所需制品所需的最终几何形状。该方法在眼科镜片的制造中得到应用。

2. 发明授权

US5095079A Method and device for producing a graded index polymer 失效
标题翻译：用于生产分级指数聚合物的方法和装置
公开(公告)号：US5095079A
公开(公告)日：1992-03-10
申请号：US543373
申请日：1990-06-26
申请人： Leanirith Yean , Georges Wajs , Gerard Martin , Patrick Guerrero
发明人： Leanirith Yean , Georges Wajs , Gerard Martin , Patrick Guerrero
IPC分类号： G01N21/41 , B01J4/00 , C08F2/00 , C08F2/02 , C08F18/14 , C08F18/24 , C08F218/00 , C08F263/00 , G02B1/04 , G02C7/02
CPC分类号： C08F2/00 , C08F263/00
摘要： To produce a graded index polymer there is diffused into a base material formed of at least one partly polymerized monomer adapted to yield a homopolymer with refractive index N1 in the gel state an additive material formed of at least one monomer adapted to yield a homopolymer with refractive index N2 different from N1. The polymerization of the base material treated in this way is then completed. The additive material comprises a mixture of at least two monomers and the composition of this mixture is varied with time.
摘要翻译：为了产生渐变折射率聚合物，扩散到由至少一种部分聚合的单体形成的基材中，所述单体适于在凝胶状态下产生折射率为N1的均聚物，所述添加剂材料由至少一种适于产生具有折射率的均聚物的单体形成指数N2不同于N1。然后以这种方式处理的基材的聚合完成。添加剂材料包含至少两种单体的混合物，并且该混合物的组成随时间变化。

3. 发明申请

US20050107537A1 Composition capable of free radical polymerization resulting in shockproof organic glass materials 失效
标题翻译：能够进行自由基聚合的组合物，从而产生防震有机玻璃材料
公开(公告)号：US20050107537A1
公开(公告)日：2005-05-19
申请号：US10496743
申请日：2002-11-26
申请人： Gilles Richard , Odile Primel , Leanirith Yean
发明人： Gilles Richard , Odile Primel , Leanirith Yean
IPC分类号： G02C7/02 , C08F290/06 , G02B1/04 , C08L33/02
CPC分类号： C08F290/061 , C08F290/06 , C08F290/062
摘要： A radically polymerizable composition comprising: a first component A comprising at least an oligomer having at least two radically polymerizable functions and the homopolymer of which has a glass transition temperature (Tg) lower than 50° C., such a component being able to result through polymerization in a (co)polymer having a glass transition temperature (Tg) equal to or lower than 50° C., preferably equal to or lower than 0° C. and more preferably ranging from −50° C. to −10C, said oligomer accounting for more than 15%, preferably at least 20% of the total weight of the polymerizable monomers present in the composition; and a second component B comprising at least a (meth)acrylic monomer having at least one H link promoting group, such a (meth)acrylic monomer accounting for at least 15% of the total weight of the polymerizable monomers and oligomers present in the composition when such a monomer is a methacrylic monomer and at least 35% of the total weight of such polymerizable monomers and oligomers present in the composition when such a monomer is an acrylic monomer.
摘要翻译：一种可自由基聚合的组合物，其包含：第一组分A，其包含至少一种具有至少两个可自由基聚合的功能的低聚物，其均聚物的玻璃化转变温度（T g）低于50℃，这种组分能够通过在等于或低于50℃，优选等于或低于0℃的玻璃化转变温度（T℃）的（共）聚合物中聚合而得到。更优选为-50℃至-10℃，所述低聚物占组合物中存在的可聚合单体的总重量的15重量％，优选至少20重量％。和包含至少一种具有至少一个H链段促进基团的（甲基）丙烯酸单体的第二组分B，所述（甲基）丙烯酸单体占组合物中存在的可聚合单体和低聚物的总重量的至少15％当这样的单体是甲基丙烯酸单体时，当这种单体是丙烯酸单体时，组合物中存在的这些可聚合单体和低聚物的总重量的至少35％。

4. 发明授权

US06677420B2 Polymerisable compositions for making transparent polymer substrates, resulting transparent polymer substrates, and uses thereof in optics 失效
标题翻译：用于制造透明聚合物基材，所得透明聚合物基材及其在光学中的用途的可聚合组合物
公开(公告)号：US06677420B2
公开(公告)日：2004-01-13
申请号：US10061761
申请日：2002-02-01
申请人： Gilles Richard , Odile Primel , Leanirith Yean
发明人： Gilles Richard , Odile Primel , Leanirith Yean
IPC分类号： C08F12602
CPC分类号： G02B1/04 , C08F222/1006 , C08F2222/108 , G02B1/041 , Y10S526/937 , C08L33/14 , C08F2222/1086
摘要： The invention is a composition comprising: 40 to 95 parts by weight of one or several monomers (I) of formula (a) wherein: R1 and R2 represent H or CH; A represents a divalent radical of formula (b) or (c) wherein m1 and m2 represent each an integer ranging between 2 and 6; and 5 to 50 parts by weight of a monomer (II) comprising at least a urethane unit and at least two (meth)acrylate functions. The invention is useful for making optical and ophthalmic articles.
摘要翻译：本发明是一种组合物，其包含：40至95重量份的一种或几种式（a）的单体（I），其中：R 1和R 2表示H或CH; A表示式（b）或（c）的二价基团，其中m1和m2各自为2和6之间的整数; 和5至50重量份的至少包含氨基甲酸酯单元和至少两个（甲基）丙烯酸酯官能团的单体（II）。本发明可用于制造光学和眼用物品。

5. 发明申请

US20080246187A1 Thermoplastic polyurethane lenses with a specified weight percentage of urethane repeating units 有权
标题翻译：具有指定重量百分比的聚氨酯重复单元的热塑性聚氨酯透镜
公开(公告)号：US20080246187A1
公开(公告)日：2008-10-09
申请号：US11732945
申请日：2007-04-05
申请人： Hao-Wen Chiu , Roger A. Mayr , Leanirith Yean
发明人： Hao-Wen Chiu , Roger A. Mayr , Leanirith Yean
IPC分类号： C08F6/00 , B29B7/00
CPC分类号： C08G18/4854 , C08G18/6674 , G02B1/043 , C08L75/04
摘要： A method of forming thermoplastic polyurethane (TPU) into an optical lens. Suitable TPUs contain urethane (—NHCOO—) repeating units that are present in at least 23% by weight. This range of urethane weights is an indicator of a flexural modulus above 1,400 MPa. The TPUs have refractive indices above 1.54 and Abbe numbers above 27. They have glass transition temperatures above about 100 degrees C. The selected TPU can be injection molded to form ophthalmic lenses, that are well suited for use in rimless spectacles. The lenses are highly solvent resistant, while at the same time being readily tintable. The lenses made according the invention meet FDA 21 CFR 801.41 Impact Requirement, and ANSI Z87.1 high velocity impact (HVI) standard.
摘要翻译：将热塑性聚氨酯（TPU）成型为光学透镜的方法。合适的TPU含有以至少23重量％存在的氨基甲酸酯（-NHCOO-）重复单元。聚氨酯重量的这一范围是1400MPa以上的挠曲模量的指标。 TPU具有高于1.54的折射率和高于27的阿贝数。它们具有高于约100℃的玻璃化转变温度。所选择的TPU可以注射成型以形成眼镜片，非常适用于无眼镜。透镜具有高耐溶剂性，同时易于着色。根据本发明制造的镜片符合FDA 21 CFR 801.41冲击要求和ANSI Z87.1高速冲击（HVI）标准。

6. 发明授权

US06794474B2 Polymerisable compositions for making transparent polymer substrates, resulting transparent polymer substrates and uses thereof in optics 失效
标题翻译：用于制造透明聚合物基材的聚合组合物，得到透明聚合物基材及其在光学中的用途
公开(公告)号：US06794474B2
公开(公告)日：2004-09-21
申请号：US10730740
申请日：2003-12-08
申请人： Gilles Richard , Odile Primel , Leanirith Yean
发明人： Gilles Richard , Odile Primel , Leanirith Yean
IPC分类号： C08F22210
CPC分类号： G02B1/04 , C08F222/1006 , C08F2222/108 , G02B1/041 , Y10S526/937 , C08L33/14 , C08F2222/1086
摘要： The invention is a composition comprising: 40 to 95 parts by weight of one or several monomers (I) of formula (a) wherein: R1 and R2 represent H or CH; A represents a divalent radical of formula (b) or (c) wherein m1 and m2 represent each an integer ranging between 2 and 6; and 5 to 50 parts by weight of a monomer (II) comprising at least a urethane unit and at least two (meth)acrylate functions. The invention is useful for making optical and ophthalmic articles.
摘要翻译：本发明是一种组合物，其包含：40至95重量份的一种或几种式（a）的单体（I），其中：R 1和R 2表示H或CH; A表示式（b）或（c）的二价基团，其中m1和m2各自为2和6之间的整数; 和5至50重量份的至少包含氨基甲酸酯单元和至少两个（甲基）丙烯酸酯官能团的单体（II）。本发明可用于制造光学和眼用物品。

7. 发明授权

US06518393B2 Polymerizable compositions for manufacturing transparent polymeric substrates, resulting transparent polymeric substrates and their applications in the optical field 失效
标题翻译：用于制造透明聚合物基材的聚合组合物，得到透明聚合物基材及其在光学领域中的应用
公开(公告)号：US06518393B2
公开(公告)日：2003-02-11
申请号：US09876280
申请日：2001-06-06
申请人： Odile Primel , Maxime Pillie , Gilles Richard , Leanirith Yean
发明人： Odile Primel , Maxime Pillie , Gilles Richard , Leanirith Yean
IPC分类号： C08G7504
CPC分类号： C08F228/02 , G02B1/041 , C08L41/00
摘要： The compositions comprise: (a) at least 40 parts by weight, preferably at least 50 parts by weight, of at least one thio(meth)acrylate monomer, (b) at least one high Abbe number monomer, (c) at the most 20 parts by weight, preferably at the most 15 parts by weight and more preferably 10 parts by weight of an aromatic polyvinyl monomer, and (d) at least one polythiol, for 100 parts by weight of (a), (b), (c) and (d). Application for the manufacture of optical lenses.
摘要翻译：组合物包含：（a）至少40重量份，优选至少50重量份的至少一种硫代（甲基）丙烯酸酯单体，（b）至少一个高阿贝数单体，（c）最多对于100重量份的（a），（b），（b），（b）的100重量份，优选至多15重量份，更优选10重量份的芳族聚乙烯基单体，和（d）至少一种多硫醇， c）和（d）。制造光学透镜的应用。

8. 发明授权

US5310847A Polymer compositions based on polythiourethanes for the manufacture of organic glasses 失效
标题翻译：基于用于制造有机眼镜的聚氨基甲酸乙酯的聚合物组合物
公开(公告)号：US5310847A
公开(公告)日：1994-05-10
申请号：US896795
申请日：1992-06-09
申请人： Leanirith Yean , Christophe Bochu
发明人： Leanirith Yean , Christophe Bochu
IPC分类号： G02C7/00 , B29D11/00 , B29K75/00 , B29K105/32 , C08G18/30 , C08G18/38 , C08G18/76 , G02B1/04 , C08G18/00
CPC分类号： C08G18/7628 , C08G18/3876 , G02B1/04 , Y10T428/31551
摘要： The present patent application relates to a polyurethane composition for organic glasses characterized in that it comprises: a first constituent formed by a polyisocyanate at least di-functional, and a second constituent formed by an acyclic saturated monomer bearing at least three reactive functions with respect to isocyanates to form carbamate links, among which reactive functions at least 40% in number are --SH mercapto groups, the proportion of the reactive functions being at least 45% by weight with respect to the molecular weight of the monomer.
摘要翻译：本专利申请涉及一种用于有机玻璃的聚氨酯组合物，其特征在于它包括：由至少二官能的多异氰酸酯形成的第一组分和由至少三个反应性官能团的无环饱和单体形成的第二组分，相对于异氰酸酯以形成氨基甲酸酯连接，其中至少40％的反应性官能团为-SH巯基，反应性官能团的比例相对于单体的分子量为至少45重量％。

9. 发明授权

US08270089B2 Thermoplastic polyurethane lenses with a specified weight percentage of urethane repeating units 有权
标题翻译：具有指定重量百分比的聚氨酯重复单元的热塑性聚氨酯透镜
公开(公告)号：US08270089B2
公开(公告)日：2012-09-18
申请号：US11732945
申请日：2007-04-05
申请人： Hao-Wen Chiu , Roger A. Mayr , Leanirith Yean
发明人： Hao-Wen Chiu , Roger A. Mayr , Leanirith Yean
IPC分类号： G02B3/00 , B29D11/00 , C08G18/00
CPC分类号： C08G18/4854 , C08G18/6674 , G02B1/043 , C08L75/04
摘要： A method of forming thermoplastic polyurethane (TPU) into an optical lens. Suitable TPUs contain urethane (—NHCOO—) repeating units that are present in at least 23% by weight. This range of urethane weights is an indicator of a flexural modulus above 1,400 MPa. The TPUs have refractive indices above 1.54 and Abbe numbers above 27. They have glass transition temperatures above about 100 degrees C. The selected TPU can be injection molded to form ophthalmic lenses, that are well suited for use in rimless spectacles. The lenses are highly solvent resistant, while at the same time being readily tintable. The lenses made according the invention meet FDA 21 CFR 801.41 Impact Requirement, and ANSI Z87.1 high velocity impact (HVI) standard.
摘要翻译：将热塑性聚氨酯（TPU）成型为光学透镜的方法。合适的TPU含有以至少23重量％存在的氨基甲酸酯（-NHCOO-）重复单元。聚氨酯重量的这一范围是1400MPa以上的挠曲模量的指标。 TPU具有高于1.54的折射率和高于27的阿贝数。它们具有高于约100℃的玻璃化转变温度。所选择的TPU可以注射成型以形成眼镜片，非常适用于无眼镜。透镜具有高耐溶剂性，同时易于着色。根据本发明制造的镜片符合FDA 21 CFR 801.41冲击要求和ANSI Z87.1高速冲击（HVI）标准。

10. 发明授权

US07393880B2 Radically polymerizable composition resulting in shock resistant organic lenses 失效
标题翻译：可自由基聚合的组合物产生抗冲击有机透镜
公开(公告)号：US07393880B2
公开(公告)日：2008-07-01
申请号：US10496743
申请日：2002-11-26
申请人： Gilles Richard , Odile Primel , Leanirith Yean
发明人： Gilles Richard , Odile Primel , Leanirith Yean
IPC分类号： C08F2/46 , C08F2/50
CPC分类号： C08F290/061 , C08F290/06 , C08F290/062
摘要： A radically polymerizable composition comprising: a first component A comprising at least an oligomer having at least two radically polymerizable functions and the homopolymer of which has a glass transition temperature (Tg) lower than 50° C., such a component being able to result through polymerization in a (co)polymer having a glass transition temperature (Tg) equal to or lower than 50° C., preferably equal to or lower than 0° C. and more preferably ranging from −50° C. to −10 C., said oligomer accounting for more than 15%, preferably at least 20% of the total weight of the polymerizable monomers present in the composition; and a second component B comprising at least a (meth)acrylic monomer having at least one H link promoting group, such a (meth)acrylic monomer accounting for at least 15% of the total weight of the polymerizable monomers and oligomers present in the composition when such a monomer is a methacrylic monomer and at least 35% of the total weight of such polymerizable monomers and oligomers present in the composition when such a monomer is an acrylic monomer.
摘要翻译：一种可自由基聚合的组合物，其包含：第一组分A，其包含至少一种具有至少两个可自由基聚合的功能的低聚物，其均聚物的玻璃化转变温度（T g）低于50℃，这种组分能够通过在等于或低于50℃，优选等于或低于0℃的玻璃化转变温度（T℃）的（共）聚合物中聚合而得到。更优选为-50℃至-10℃，所述低聚物占组合物中存在的可聚合单体的总重量的15重量％，优选至少20重量％。和包含至少一种具有至少一个H链段促进基团的（甲基）丙烯酸单体的第二组分B，所述（甲基）丙烯酸单体占组合物中存在的可聚合单体和低聚物的总重量的至少15％当这样的单体是甲基丙烯酸单体时，当这种单体是丙烯酸单体时，组合物中存在的这些可聚合单体和低聚物的总重量的至少35％。

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