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    • 1. 发明授权
    • Treatment fluids containing a relative permeability modifier and a companion polymer interacting synergistically therewith and methods for use thereof
    • 含有相对渗透性调节剂和与其协同作用的伴侣聚合物的处理液及其使用方法
    • US09546314B2
    • 2017-01-17
    • US13081607
    • 2011-04-07
    • Larry S. EoffJeff W. LoucksB. Raghava Reddy
    • Larry S. EoffJeff W. LoucksB. Raghava Reddy
    • C09K8/60C09K8/508C09K8/035C09K8/588
    • C09K8/508C09K8/035C09K8/588
    • Methods and compositions are described for treating water- and hydrocarbon-producing subterranean formations with a relative permeability modifier at concentrations below those conventionally used in the art, while not substantially impacting the treatment fluid's performance. Treatment fluids described herein comprise a base fluid, a relative permeability modifier comprising a hydrophobically modified hydrophilic polymer, and a companion polymer interacting synergistically with the relative permeability modifier such that the treatment fluid is operable to reduce the water permeability or to increase an aqueous fluid injection pressure of at least a portion of a subterranean formation by more than the relative permeability modifier or the companion polymer acting alone at like concentration. The water permeability reduction and/or the aqueous fluid injection pressure increase can be more than additive. Methods described herein comprise placing such treatment fluids in at least a portion of a subterranean formation.
    • 描述了用相对渗透率调节剂处理含水和烃产生地层的方法和组合物,其浓度低于本领域常规使用的浓度,而基本上不影响处理液的性能。 本文所述的处理流体包括基础流体,包含疏水改性的亲水性聚合物的相对渗透性改进剂和与相对渗透性改性剂协同作用的伴侣聚合物,使得处理流体可操作以降低透水性或增加水性流体注射 至少一部分地层的压力大于相对渗透率调节剂或伴随聚合物以相同浓度单独作用的压力。 透水性降低和/或含水流体注射压力增加可以超过添加剂。 本文描述的方法包括将这种处理流体放置在地层的至少一部分中。
    • 5. 发明申请
    • Hydrophobically and Cationically Modified Relative Permeability Modifiers and Associated Methods
    • 疏水和阳离子改性相对渗透性改性剂及相关方法
    • US20120264885A1
    • 2012-10-18
    • US13534166
    • 2012-06-27
    • Larry S. EoffB. Raghava ReddyEldon D. Dalrymple
    • Larry S. EoffB. Raghava ReddyEldon D. Dalrymple
    • C08F265/06
    • C09K8/508
    • Methods comprising providing a relative permeability modifier that comprises a hydrophilic polymer backbone with a hydrophobic modification and incorporating at least one cationic compound onto the hydrophilic polymer backbone. The hydrophilic polymer is one or more of: a polyacrylamide; a polyvinylamine; a poly(vinylamine/vinyl alcohol); an alkyl acrylate polymer; cellulose; chitosan; a polyamide; a polyetheramine; a polyhydroxyetheramine; a polylysine; a polysulfone; a gum; or a starch. The hydrophobic modification is achieved either by reacting the hydrophilic polymer with a hydrophobic compound or by a polymerization reaction product of a hydrophilic monomer and a hydrophobically modified hydrophilic monomer. The hydrophobic compound has an alkyl chain length from 4 to 22 carbons and is one or more of: an alkyl acrylate; an alkyl methacrylate; an alkyl acrylamide; an alkyl methacrylamide; or an alkyl dimethylammoniumethyl methacrylate halide.
    • 方法包括提供相对渗透性调节剂,其包含具有疏水性修饰的亲水性聚合物主链并将至少一种阳离子化合物并入亲水性聚合物主链上。 亲水性聚合物是以下中的一种或多种:聚丙烯酰胺; 聚乙烯胺 聚(乙烯胺/乙烯醇); 丙烯酸烷基酯聚合物; 纤维素; 壳聚糖; 聚酰胺; 聚醚胺 聚羟基胺; 聚赖氨酸 聚砜; 口香糖 或淀粉。 通过使亲水性聚合物与疏水化合物反应或通过亲水性单体和疏水改性的亲水性单体的聚合反应产物来实现疏水改性。 疏水性化合物的烷基链长度为4〜22个碳原子,为丙烯酸烷基酯中的一种或多种。 甲基丙烯酸烷基酯 烷基丙烯酰胺; 烷基甲基丙烯酰胺; 或烷基二甲基铵乙基甲基丙烯酸酯卤化物。