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1. 发明授权

US06413893B1 Green privacy glass 有权
标题翻译：绿色隐私玻璃
公开(公告)号：US06413893B1
公开(公告)日：2002-07-02
申请号：US09389840
申请日：1999-09-03
申请人： Larry J. Shelestak , Robert B. Heithoff , Andrew Calabrese , John F. Krumwiede , Anthony V. Longobardo
发明人： Larry J. Shelestak , Robert B. Heithoff , Andrew Calabrese , John F. Krumwiede , Anthony V. Longobardo
IPC分类号： C03C3087
CPC分类号： C03C3/087 , C03C4/02 , C03C4/082 , C03C4/085 , Y10S501/904 , Y10S501/905
摘要： The present invention provides a green colored, infrared and ultraviolet absorbing glass article having a luminous transmittance of up to 60 percent. The composition of the glass article uses a standard soda-lime-silica glass base composition and additionally iron, cobalt, selenium, and chromium, and titanium, as infrared and ultraviolet radiation absorbing materials and colorants. The glasses of the present invention have a color characterized by a dominant wavelength in the range of about 480 to 565 nanometers, preferably about 495 to 560 nanometers, with an excitation purity of no higher than about 20 percent, preferably no higher than about 10 percent, and more preferably no higher than about 7 percent. The glass compositions may be provided with different levels of spectral performance depending on the particular application and desired luminous transmittance. In one embodiment of the invention, the green colored glass composition in addition to the soda-lime-silica glass base composition has the solar radiation absorbing and colorant portion of about 0.60 to 4 percent by weight total iron, about 0.13 to 0.9 percent by weight FeO, about 40 to 500 PPM CoO, about 5 to 70 PPM Se, about 15 to 800 PPM Cr2O3, and about 0.02 to 1 percent by weight TiO2. In another embodiment of the invention, the glass composition of the article includes a solar radiation absorbing and colorant portion of 1 to less than 1.4 percent by weight total iron, about 0.2 to 0.6 percent by weight FeO, greater than 200 to about 500 PPM CoO, about 5 to 70 PPM Se, greater than 200 to about 800 PPM Cr2O3, and 0 to about 1 percent by weight TiO2.
摘要翻译：本发明提供了具有高达60％的透光率的绿色，红外和紫外线吸收玻璃制品。玻璃制品的组成使用标准的钠钙石英玻璃基础组合物，另外还有铁，钴，硒和铬以及钛作为红外和紫外线辐射吸收材料和着色剂。本发明的玻璃具有主要波长在约480至565纳米，优选约495至560纳米范围内的颜色，其激发纯度不高于约20％，优选不高于约10％，更优选不高于约7％。玻璃组合物可以根据具体应用和期望的透光度而具有不同水平的光谱性能。在本发明的一个实施方案中，除了钠钙石英玻璃基础组合物之外的绿色玻璃组合物具有约0.60至4重量％的总铁，约0.13至0.9重量％的太阳辐射吸收和着色剂部分约40至500PPM CoO，约5至70PPM Se，约15至800PPM Cr 2 O 3和约0.02至1重量％的TiO 2。在本发明的另一个实施方案中，制品的玻璃组合物包括太阳辐射吸收和着色剂部分，其总量为1至小于1.4重量％，约0.2至0.6重量％的FeO，大于200至约500PPM的CoO 约5至70PPM Se，大于200至约800PPM Cr 2 O 3和0至约1重量％的TiO 2。

2. 发明授权

US6114264A Gray glass composition 失效
标题翻译：灰色玻璃组成
公开(公告)号：US6114264A
公开(公告)日：2000-09-05
申请号：US414165
申请日：1995-03-31
申请人： John F. Krumwiede , Anthony V. Longobardo , Larry J. Shelestak
发明人： John F. Krumwiede , Anthony V. Longobardo , Larry J. Shelestak
IPC分类号： C03C3/076 , C03C3/087 , C03C4/02 , C03C4/08 , C03C3/095
CPC分类号： C03C3/087 , C03C4/02 , Y10S501/905
摘要： The present invention provides a glass composition having a neutral gray color and a luminous (visible) transmittance within a range that allows the glass to be used in the forward vision areas of a vehicle. The base glass is a soda-lime-silica composition and iron, cobalt, selenium and/or nickel are added as colorants. In one particular embodiment of the invention which is essentially nickel-free, a neutral gray colored glass with a luminous transmittance (C.I.E. illuminant A) of 60% and higher at a thickness of 3.9 millimeters may be attained by using as colorants: 0.30 to 0.70 wt. % Fe.sub.2 O.sub.3, no greater than 0.21 wt. % FeO, 3-50 PPM CoO and 1-15 PPM Se, and preferably 0.32 to 0.65 wt. % Fe.sub.2 O.sub.3, 0.065 to 0.20 wt. % FeO, 5 to 40 PPM CoO and 1 to 9 PPM Se. In an alternate embodiment of the invention which includes nickel oxide as a colorant, a neutral gray colored glass with a luminous transmittance of 60% and higher at a thickness of 3.9 millimeters may be attained by using 0.15 to 0.65 wt. % Fe.sub.2 O.sub.3, no greater than 0.18 wt. % FeO, 15-55 PPM CoO, 0-5 PPM Se and 25-350 PPM NiO as colorants, and preferably 0.17 to 0.60 wt. % Fe.sub.2 O.sub.3, 0.04 to 0.16 wt. % FeO, 20 to 52 PPM CoO, 0 to 3 PPM Se and at least 50 PPM NiO.
摘要翻译：本发明提供一种玻璃组合物，其在允许玻璃用于车辆前视区域的范围内具有中性灰色和发光（可见）透射率。基础玻璃是钠钙二氧化硅组合物，并且加入铁，钴，硒和/或镍作为着色剂。在基本上不含镍的本发明的一个具体实施方案中，通过使用0.30至0.70的着色剂，可以获得厚度为3.9毫米的具有60％或更高透光率（CIE发光体A）的中性灰色玻璃，其厚度为3.9毫米重量％Fe 2 O 3，不大于0.21wt。％FeO，3-50PPM CoO和1-15PPM Se，优选为0.32〜0.65wt。％Fe 2 O 3，0.065〜0.20重量％％FeO，5〜40PPM CoO和1〜9PPM Se。在包括氧化镍作为着色剂的本发明的替代实施方案中，通过使用0.15-0.65wt。％的透明度可以获得厚度为3.9mm的透光率为60％以上的中性灰色玻璃。％Fe 2 O 3，不大于0.18wt。％FeO，15-55PPM CoO，0-5PPM Se和25-350PPM NiO作为着色剂，优选为0.17〜0.60wt。％Fe 2 O 3，0.04〜0.16重量％％FeO，20〜52PPM CoO，0〜3PPM Se和至少50PPM NiO。

3. 发明授权

US5565388A Bronze glass composition 失效
标题翻译：青铜玻璃组成
公开(公告)号：US5565388A
公开(公告)日：1996-10-15
申请号：US415792
申请日：1995-04-03
申请人： John F. Krumwiede , Larry J. Shelestak , Anthony V. Longobardo
发明人： John F. Krumwiede , Larry J. Shelestak , Anthony V. Longobardo
IPC分类号： C03C1/10 , B60J1/00 , C03C3/078 , C03C3/083 , C03C3/087 , C03C4/02 , C03C4/08
CPC分类号： C03C3/087 , C03C4/02 , C03C4/085
摘要： The present invention provides a glass composition having a bronze color and a luminous (visible) transmittance of 70% or greater. The base glass is a soda-lime-silica composition and iron and selenium are added as colorants. In one particular embodiment of the invention, a bronze colored glass with a luminous transmittance (C.I.E. illuminant A) of 70% and higher at a thickness of 4.1 millimeters may be attained by using as colorants: 0.4 to 0.6 wt. % Fe.sub.2 O.sub.3, 0.09 to 0.17 wt. % FeO and 3 to 11 PPM Se. In addition, it is preferred that the total solar energy transmittance be no greater than 60%.
摘要翻译：本发明提供一种青铜色，发光（可见）透射率为70％以上的玻璃组合物。基础玻璃是钠钙二氧化硅组合物，加入铁和硒作为着色剂。在本发明的一个具体实施方案中，通过使用0.4至0.6重量％的着色剂，可以获得具有厚度为4.1毫米的70％以上的透光率（C.I.E.发光体A）的青铜色玻璃。％Fe 2 O 3，0.09〜0.17重量％％FeO和3至11 PPM Se。此外，优选总太阳能透射率不大于60％。

4. 发明授权

US06274523B1 Gray glass composition 失效
公开(公告)号：US06274523B1
公开(公告)日：2001-08-14
申请号：US08529039
申请日：1995-09-15
申请人： John F. Krumwiede , Anthony V. Longobardo , Larry J. Shelestak , David R. Haskins
发明人： John F. Krumwiede , Anthony V. Longobardo , Larry J. Shelestak , David R. Haskins
IPC分类号： C03C3087
CPC分类号： C03C3/087 , C03C4/02
摘要： The present invention provides a glass composition having a neutral gray color and a luminous (visible) transmittance within a range that allows the glass to be used as privacy glazing in a vehicle. The glass of the present invention has a standard soda-lime-silica flat glass base composition and uses iron, cobalt and selenium, and optionally nickel, as the colorants. It has also been found that a nickel-free, neutral gray colored glass with a luminous transmittance (C.I.E. illuminant A) of up to 40% at a thickness of 3.9 millimeters may be attained by using as colorants: 0.59 to 0.99 wt. % of the total glass Fe2O3 (total iron), no greater than 0.30 wt. % FeO; 60 to 180 PPM CoO and 5 to 30 PPM Se. It has been found that a nickel-bearing, neutral gray colored glass with a luminous transmittance (C.I.E. illuminant A) of up to but less than 40% at a thickness of 3.9 millimeters may be attained by using as colorants: 0.35 to 1.1 wt. % of the total glass Fe2O3 (total iron), no greater than 0.30 wt. % FeO; 60 to 180 PPM CoO; 1 to 30 PPM Se; and 25 to 550 PPM NiO.

5. 发明授权

US5393593A Dark gray, infrared absorbing glass composition and coated glass for privacy glazing 失效
标题翻译：深灰色，红外线吸收玻璃组合物和用于隐私玻璃的涂层玻璃
公开(公告)号：US5393593A
公开(公告)日：1995-02-28
申请号：US133949
申请日：1993-10-12
申请人： Joseph A. Gulotta , John F. Krumwiede , Luke A. Kutilek , Anthony V. Longobardo , Robert B. Heithoff
发明人： Joseph A. Gulotta , John F. Krumwiede , Luke A. Kutilek , Anthony V. Longobardo , Robert B. Heithoff
IPC分类号： C03C1/10 , C03C3/087 , C03C4/02 , C03C4/08 , B32B17/06
CPC分类号： C03C4/02 , C03C1/10 , C03C3/087 , C03C4/082 , Y10S501/904 , Y10S501/905 , Y10T428/24942
摘要： A neutral, dark gray, soda-lime-silica glass having luminous transmittance less than 35 percent, infrared transmittance less than 20 percent, and total solar energy transmittance less than 22 percent (all at 3.9 millimeter thickness) is produced with colorants consisting essentially of 1.0 to 2.2 percent by weight total iron, at least 0.20 percent FeO, 0.01 to 0.03 percent CoO, and 0.0005 to 0.005 percent Se. The flat glass product having such a composition is particularly suitable for use as privacy glazing. The use of the glass as a substrate for a reflectively coated product is also disclosed. A low transmittance, reflective coated article is disclosed comprising a soda-lime-silica glass substrate having luminous transmittance less than 35 percent, infrared transmittance less than 20 percent, and total solar energy transmittance less than 22 percent (all at 3.9 millimeter thickness) and a metal oxide coating having a luminous reflectance not more than 25 percent from the coated surface, and not more than 8 percent from the uncoated surface. The low transmittance coated glass product is particularly suitable for use as privacy glazing.
摘要翻译：产生具有透光率小于35％，红外透射率小于20％，总太阳能透射率小于22％（全部为3.9毫米厚度）的中性，深灰色，钠钙石英玻璃，其色素基本上由 1.0-2.2重量％总铁，至少0.20％FeO，0.01-0.03％CoO和0.0005-0.005％Se。具有这种组成的平板玻璃产品特别适合用作隐私玻璃。还公开了将玻璃用作反射涂层产品的基材。公开了一种低透光率的反射涂层制品，其包括具有小于35％的透光率，红外透射率小于20％，总太阳能透射率小于22％（全部为3.9毫米厚度）的钠钙石英玻璃基板和金属氧化物涂层的光反射率不超过涂布表面的25％，不超过未涂覆表面的8％。低透光率玻璃制品特别适用于隐私玻璃。

6. 发明授权

US06983104B2 Apparatus and method for bending and/or tempering glass 有权
公开(公告)号：US06983104B2
公开(公告)日：2006-01-03
申请号：US10245719
申请日：2002-09-18
申请人： Anthony V. Longobardo , George Neuman , Daniel F. Prone , Andre Heyen
发明人： Anthony V. Longobardo , George Neuman , Daniel F. Prone , Andre Heyen
IPC分类号： C03B23/03 , C03B27/12
CPC分类号： C03B29/04 , B32B17/10889 , C03B23/0258 , C03B27/00 , C03B29/00 , C03B29/025 , Y02P40/57
摘要： An apparatus and method for bending and/or tempering glass substrate(s) are provided. The amount of near-IR radiation which reaches the glass to be bent and/or tempered is limited (e.g., via filtering or any other suitable technique). Thus, the IR radiation (used for heating the glass) which reaches the glass to be bent and/or tempered includes mostly mid-IR and/or far-IR radiation, and not much near-IR. In such a manner, coating(s) provided on the glass can be protected and kept at lower temperatures so as to be less likely to be damaged during the bending and/or tempering process. Heating efficiency can be improved. A ceramic (e.g., aluminosilicate) filter or baffle may be used in certain embodiments in order to reduce the amount of mid-IR and/or far-IR radiation reaching the glass to be tempered and/or bent.

7. 发明授权

US07772144B2 Glass composition for improved refining and method 有权
标题翻译：改进精炼和方法的玻璃组合物
公开(公告)号：US07772144B2
公开(公告)日：2010-08-10
申请号：US11196477
申请日：2005-08-04
申请人： Leonid M. Landa , Ksenia A. Landa , Richard Hulme , Scott V. Thomsen , Anthony V. Longobardo
发明人： Leonid M. Landa , Ksenia A. Landa , Richard Hulme , Scott V. Thomsen , Anthony V. Longobardo
IPC分类号： C03C3/078 , C03C3/087
CPC分类号： C03C3/087 , C03C3/078
摘要： A soda-lime-silica based glass composition for manufacturing on a float line that has a faster refining rate due to the introduction of alkali earth oxides such as BaO, ZnO and/or SrO in the amount of from about 1-4% in total. These oxides replace part or all of the MgO in the base glass composition thereby decreasing the overall MgO content in the glass composition to about 2% or less. The glass can realize a lower viscosity at high temperatures so that refining of the melt may occur faster.
摘要翻译：一种用于制造浮法线的钠钙二氧化硅基玻璃组合物，其由于引入碱土金属氧化物如BaO，ZnO和/或SrO而具有更高的精炼速率，其总量为约1-4％。这些氧化物代替基础玻璃组合物中的部分或全部MgO，从而将玻璃组合物中的MgO总量降低到约2％以下。玻璃可以在高温下实现较低的粘度，从而可以更快地发生熔体的精炼。

8. 发明授权

US07488538B2 Coated article including soda-lime-silica glass substrate with lithium and/or potassium to reduce sodium migration and/or improve surface stability and method of making same 失效
标题翻译：包括具有锂和/或钾的钠钙石英玻璃基板以减少钠迁移和/或改善表面稳定性的涂层制品及其制备方法
公开(公告)号：US07488538B2
公开(公告)日：2009-02-10
申请号：US11198404
申请日：2005-08-08
申请人： Leonid M. Landa , Ksenia A. Landa , Anthony V. Longobardo , Vijayen S. Veerasamy
发明人： Leonid M. Landa , Ksenia A. Landa , Anthony V. Longobardo , Vijayen S. Veerasamy
IPC分类号： B32B15/00
CPC分类号： C03C3/087 , C03C17/3435 , C03C17/36 , C03C17/3618 , C03C17/3639 , C03C17/3644 , C03C17/3652 , C03C17/366 , C03C2217/732
摘要： A coated article includes a glass substrate that supports a coating such as a low-E (low emissivity) coating. In certain example embodiments, the glass substrate is formed of a soda-lime-silica based glass composition manufactured using a float process. In certain example embodiments, lithium oxide (e.g., LiO2) and/or potassium oxide (K2O) is used in the soda-lime-silica based glass substrate in order to reduce sodium migration and/or improve surface stability. Such coated articles are useful, for example and without limitation, in architectural, vehicular and/or residential glass window applications.
摘要翻译：涂覆制品包括支撑诸如低E（低发射率）涂层的涂层的玻璃基底。在某些示例性实施例中，玻璃基板由使用浮法工艺制造的钠钙二氧化硅基玻璃组合物形成。在某些示例性实施方案中，为了降低钠迁移和/或提高表面稳定性，在钠钙二氧化硅基玻璃基板中使用氧化锂（例如LiO 2）和/或氧化钾（K 2 O）。这种涂覆制品在建筑，车辆和/或住宅玻璃窗应用中是有用的，例如但不限于此。

9. 发明授权

US06701749B2 Vacuum IG window unit with edge seal at least partially diffused at temper and completed via microwave curing, and corresponding method of making the same 有权
标题翻译：具有边缘密封的真空IG窗单元至少部分地在回火下扩散并通过微波固化完成，以及相应的制造方法
公开(公告)号：US06701749B2
公开(公告)日：2004-03-09
申请号：US09777858
申请日：2001-02-07
申请人： Yei-Ping H. Wang , Anthony V. Longobardo
发明人： Yei-Ping H. Wang , Anthony V. Longobardo
IPC分类号： C03C2706
CPC分类号： E06B3/6612 , C03B27/00 , C03C17/04 , C03C27/06 , C03C27/10 , E06B3/66333 , E06B3/6736 , Y02A30/25 , Y02B80/24
摘要： A vacuum insulating glass (IG) unit and method of manufacturing the same. A peripheral or edge seal (11) of a vacuum IG unit is formed utilizing microwave energy (17) in order to enable tempered glass sheets (2, 3) of the IG unit to retain a significant portion of their original temper strength. In certain exemplary embodiments, the edge seal may be formed of glass frit or solder glass. In certain embodiments, at least a portion (12, 12a, 301) of the edge seal material may be deposited on one or both substrates prior to a thermal tempering process so that during tempering the edge seal material is permitted to diffuse into (i.e., bond to) the glass substrate(s) (2, 3). Optionally, additional edge seal material (303) may be added after tempering. The final edge seal (11) is preferably formed via microwave heating (17) of the edge seal material.
摘要翻译：一种真空绝缘玻璃（IG）单元及其制造方法。使用微波能量（17）形成真空IG单元的周边或边缘密封（11），以使得IG单元的钢化玻璃板（2,3）能够保持其原始回火强度的显着部分。在某些示例性实施例中，边缘密封可以由玻璃料或焊料玻璃形成。在某些实施例中，边缘密封材料的至少一部分（12,12a，301）可以在热回火过程之前沉积在一个或两个基板上，使得在回火期间允许边缘密封材料扩散到（即，粘合到）玻璃基板（2,3）。任选地，在回火之后可以添加另外的边缘密封材料（303）。最终边缘密封件（11）优选通过边缘密封材料的微波加热（17）形成。

10. 发明授权

US06573207B2 Grey glass composition including erbium 有权
标题翻译：灰色玻璃组成包括铒
公开(公告)号：US06573207B2
公开(公告)日：2003-06-03
申请号：US09824561
申请日：2001-04-03
申请人： Ksenia A. Landa , Leonid Landa , Scott V. Thomsen , Anthony V. Longobardo
发明人： Ksenia A. Landa , Leonid Landa , Scott V. Thomsen , Anthony V. Longobardo
IPC分类号： C03C3095
CPC分类号： C03C4/02 , C03C3/095 , C03C4/082 , C03C4/085
摘要： A grey glass composition employing as its colorant portion at least iron (Fe2O3/FeO) and erbium oxide (e.g., Er2O3), and also preferably selenium and cobalt. An exemplary colorant portion for use in a glass composition (with a soda lime silica or other suitable base glass) includes, by weight percentage: Total iron (expressed as Fe2O3): 0.1 to 0.6% erbium oxide (e.g., Er2O3): 0.3 to 1.5% selenium (Se): 0.0002 to 0.0010% cobalt oxide (e.g., Co3O4): 0.0005 to 0.0018% titanium oxide (e.g., TiO2): 0.0 to 1.0% boron oxide (e.g., B2O3): 0.0 to 2.0% The resulting glass may exhibit high visible transmittance (Lta), while at the same time low UV and IR transmittance.
摘要翻译：至少使用铁（Fe2O3 / FeO）和氧化铒（例如Er2O3）作为其着色剂部分，并且还优选硒和钴的灰玻璃组合物。用于玻璃组合物（钠钙二氧化硅或其他合适的基础玻璃）的示例性着色剂部分包括按重量百分比计：所得到的玻璃可以表现出高的可见光透射率（Lta），同时低的UV和IR透射率。

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