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1. 发明授权

US07560404B2 UV absorbing gray glass composition 失效
标题翻译：紫外线吸收灰色玻璃组成
公开(公告)号：US07560404B2
公开(公告)日：2009-07-14
申请号：US11222406
申请日：2005-09-08
申请人： Larry J. Shelestak , Mehran Arbab , Dennis G. Smith
发明人： Larry J. Shelestak , Mehran Arbab , Dennis G. Smith
IPC分类号： C03C3/087 , C03C3/095
CPC分类号： C03C3/087 , C03C3/095 , C03C4/085
摘要： A novel glass composition is disclosed. The glass composition includes a base glass composition made up of SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent, B2O3 0 to 5%, and MnO2 0 to 0.5%, and a colorant and property modifying material portion made up of total iron up to 0.65 weight percent, Se ranging from 2 PPM to 10 PPM, at least one UV absorber selected from CeO2, V2O5, TiO2 and MoO3, CoO up to 20 PPM, and Cr2O3 up to 75 PPM, wherein the glass composition has a redox ratio ranging from 0.2 to 0.6.
摘要翻译：公开了一种新型玻璃组合物。玻璃组合物包括由SiO 2计为65〜75重量％，Na 2 O为10〜20重量％，CaO为5〜15重量％，MgO为0〜5重量％，Al 2 O 3为0〜5重量％，0〜5重量％的K 2 O，0〜5％的B 2 O 3和0〜0.5重量％的MnO 2，以及由总计铁达0.65重量％以上的着色剂和性能改性材料部分，Se在2PPM〜10PPM的范围内，选自CeO 2，V 2 O 5，TiO 2和MoO 3的至少一种紫外线吸收剂，高达20PPM的CoO和高达75PPM的Cr 2 O 3，其中所述玻璃组合物的氧化还原比范围为0.2至0.6。

2. 发明授权

US07691763B2 High performance blue glass 有权
标题翻译：高性能蓝色玻璃
公开(公告)号：US07691763B2
公开(公告)日：2010-04-06
申请号：US11713197
申请日：2007-03-02
申请人： Mehran Arbab , Robert B. Heithoff , Larry J. Shelestak , Dennis G. Smith
发明人： Mehran Arbab , Robert B. Heithoff , Larry J. Shelestak , Dennis G. Smith
IPC分类号： C03C3/095 , C03C3/087
CPC分类号： C03C4/02 , C03C3/087 , C03C3/091 , C03C3/095
摘要： A glass composition for forming a blue colored glass is disclosed. The glass composition is made up of a base glass portion, iron oxide, and at least one first additive compound selected from Nd2O3 in an amount up to 1 weight percent and/or CuO in an amount up to 0.5 weight percent. The base glass portion has the following components: SiO2 from 66 to 75 weight percent; Na2O from 10 to 20 weight percent; CaO from 5 to 15 weight percent; MgO from 0 to 5 weight percent; Al2O3 from 0 to 5 weight percent; B2O3 from 0 to 5 weight percent; and K2O from 0 to 5 weight percent. The total iron in the glass composition ranges from 0.3 to 1.2 weight percent, and the glass composition has a redox ratio ranging from 0.15 to 0.65.
摘要翻译：公开了一种用于形成蓝色玻璃的玻璃组合物。玻璃组合物由基础玻璃部分，氧化铁和至少一种选自Nd2O3的至多1重量％的量的第一添加剂化合物和/或CuO组成，其量高达0.5重量％。基础玻璃部分具有以下成分：SiO 2为66〜75重量％ Na2O为10〜20重量％ CaO为5〜15重量％ 0〜5重量％的MgO; 0〜5重量％的Al2O3; B2O3为0〜5重量％; 和K 2 O为0〜5重量％。玻璃组合物中的总铁量为0.3〜1.2质量％，玻璃组合物的氧化还原比为0.15〜0.65。

3. 发明授权

US07071133B2 Colored glass compositions and-automotive vision panels with-reduced transmitted-color shift 有权
标题翻译：彩色玻璃组合物和具有减少的透射色移的汽车视觉面板
公开(公告)号：US07071133B2
公开(公告)日：2006-07-04
申请号：US10373080
申请日：2003-02-21
申请人： Mehran Arbab , Dennis G. Smith , Larry J. Shelestak , Mary T. Strzelecki
发明人： Mehran Arbab , Dennis G. Smith , Larry J. Shelestak , Mary T. Strzelecki
IPC分类号： C03C3/087
CPC分类号： C03C4/085 , C03C3/087 , C03C4/02 , C03C4/082
摘要： A neutral gray colored glass composition for automotive vision panels having reduced transmitted color shift characteristics is provided. The glass composition has a base portion including 65 to 75 weight percent SiO2, 10 to 20 weight percent Na2O, 5 to 15 weight percent CaO, 0 to 5 weight percent MgO, 0 to 5 weight percent Al2O3, and 0 to 5 weight percent K2O. The composition also includes major colorants including 0.30 to 0.75 weight percent Fe2O3, 0 to 15 ppm CoO, and 1 to 15 ppm Se. The glass has a luminous transmittance of at least 65 percent at a thickness of 3.9 mm, a redox ratio of 0.2 to 0.675, a TSET of less than or equal to 65 percent, and a standard color shift of less than 6.
摘要翻译：提供了具有降低的透射色移特性的用于汽车视觉面板的中性灰色玻璃组合物。该玻璃组合物具有基础部分，其包含65至75重量％的SiO 2，10至20重量百分比的Na 2 O，5至15重量％的CaO，0至5重量％百分比的MgO，0至5重量％的Al 2 O 3 3和0至5重量％的K 2 O。该组合物还包括主要着色剂，其包括0.30至0.75重量％的Fe 2 O 3 3，0至15ppm的CoO和1至15ppm的Se。该玻璃的厚度为3.9mm，氧化还原比为0.2〜0.675，TSET小于或等于65％，标准色偏小于6的透光率为65％以上。

4. 发明授权

US06953758B2 Limited visible transmission blue glasses 有权
标题翻译：有限可见透射蓝眼镜
公开(公告)号：US06953758B2
公开(公告)日：2005-10-11
申请号：US10047353
申请日：2002-01-14
申请人： Mehran Arbab , Larry J. Shelestak , Dennis G. Smith
发明人： Mehran Arbab , Larry J. Shelestak , Dennis G. Smith
IPC分类号： C03C3/078 , C03C3/087 , C03C3/095 , C03C4/02 , C03C4/08
CPC分类号： C03C4/02 , C03C3/087 , C03C4/082 , C03C4/085
摘要： A blue colored, infrared and ultraviolet absorbing glass composition having a luminous transmittance of up to 60 percent can form transparent glass panel sets for mounting in automobiles. A non-limiting glass composition includes a standard soda-lime-silica glass base composition and a solar radiation absorbing and colorant portion having 0.9 to 2.0 percent by weight total iron, 0.15 to 0.65 percent by weight FeO, 90 to 250 PPM CoO, and optionally up to 12 PPM Se and up to 0.9 wt % TiO2, and preferably 1 to 1.4 percent by weight total iron, 0.20 to 0.50 percent by weight FeO, 100 to 150 PPM CoO, up to 8 PPM Se, and up to 0.5 wt % TiO2, at a thickness of 0.160 inches (4.06 millimeters) the glass has a dominant wavelength in the range of 480 to 489 nanometers and an excitation purity of at least 8 percent.
摘要翻译：具有高达60％的透光率的蓝色，红外和紫外线吸收玻璃组合物可以形成用于安装在汽车中的透明玻璃面板组。非限制性玻璃组合物包括标准钠钙石英玻璃基础组合物和具有0.9至2.0重量％总铁，0.15至0.65重量％FeO，90至250PPM CoO的太阳辐射吸收和着色剂部分，以及可选地高达12PPM Se和至多0.9重量％的TiO 2，优选1至1.4重量％的总铁，0.20至0.50重量％的FeO，100至150PPM的CoO，至多8 PPM Se和至多0.5重量％TiO 2，厚度为0.160英寸（4.06毫米），玻璃的主波长在480至489纳米之间，激发纯度至少为 8％。

5. 发明授权

US08440583B2 Blue glass composition 有权
标题翻译：蓝色玻璃组成
公开(公告)号：US08440583B2
公开(公告)日：2013-05-14
申请号：US12788810
申请日：2010-05-27
申请人： Larry J. Shelestak , Mehran Arbab
发明人： Larry J. Shelestak , Mehran Arbab
IPC分类号： C03C3/095 , C03C3/087
CPC分类号： C03C3/095 , C03C4/02 , C03C4/082 , C03C4/085
摘要： A blue colored, infrared and ultraviolet absorbing glass composition uses a standard soda-lime-silica glass base composition and additionally iron, cobalt, and additional colorants selected from the group of Er2O3, Cr2O3, CuO, NiO, TiO2, Nd2O3 and combinations thereof. The glass of the present invention has a luminous transmittance of up to 60 percent, a dominant wavelength in the range of 480 to 489 nanometers and an excitation purity of at least 8 percent at a thickness of 0.160 inches (4.06 millimeters). The glass composition can form transparent glass panels that have varying limited LTA from one another as panel sets for mounting in automobiles.
摘要翻译：蓝色，红外和紫外线吸收玻璃组合物使用标准的钠钙石英玻璃基础组合物，另外还有铁，钴和选自Er2O3，Cr2O3，CuO，NiO，TiO2，Nd2O3及其组合的其他着色剂。本发明的玻璃的透光率高达60％，主波长在480至489纳米之间，激发纯度至少为8％，厚度为0.160英寸（4.06毫米）。玻璃组合物可以形成具有彼此变化的有限LTA的透明玻璃面板，用于安装在汽车中的面板组。

6. 发明申请

US20110291436A1 BLUE GLASS COMPOSITION 有权
标题翻译：蓝玻璃组合物
公开(公告)号：US20110291436A1
公开(公告)日：2011-12-01
申请号：US12788810
申请日：2010-05-27
申请人： Larry J. Shelestak , Mehran Arbab
发明人： Larry J. Shelestak , Mehran Arbab
IPC分类号： B60J1/00 , C03C4/08
CPC分类号： C03C3/095 , C03C4/02 , C03C4/082 , C03C4/085
摘要： A blue colored, infrared and ultraviolet absorbing glass composition uses a standard soda-lime-silica glass base composition and additionally iron, cobalt, and additional colorants selected from the group of Er2O3, Cr2O3, CuO, NiO, TiO2, Nd2O3 and combinations thereof. The glass of the present invention has a luminous transmittance of up to 60 percent, a dominant wavelength in the range of 480 to 489 nanometers and an excitation purity of at least 8 percent at a thickness of 0.160 inches (4.06 millimeters). The glass composition can form transparent glass panels that have varying limited LTA from one another as panel sets for mounting in automobiles.
摘要翻译：蓝色，红外和紫外线吸收玻璃组合物使用标准的钠钙石英玻璃基础组合物，另外还有铁，钴和选自Er2O3，Cr2O3，CuO，NiO，TiO2，Nd2O3及其组合的其他着色剂。本发明的玻璃的透光率高达60％，主波长在480至489纳米之间，激发纯度至少为8％，厚度为0.160英寸（4.06毫米）。玻璃组合物可以形成具有彼此变化的有限LTA的透明玻璃面板，用于安装在汽车中的面板组。

7. 发明授权

US07825051B2 Colored glass compositions 有权
标题翻译：彩色玻璃组合物
公开(公告)号：US07825051B2
公开(公告)日：2010-11-02
申请号：US11331287
申请日：2006-01-12
申请人： Dennis G. Smith , Larry J. Shelestak
发明人： Dennis G. Smith , Larry J. Shelestak
IPC分类号： C03C3/095 , C03C3/087
CPC分类号： C03C3/095 , C03C1/002 , C03C4/02 , C03C4/085
摘要： A glass composition is disclosed. The glass composition includes base glass composition including SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent, and BaO from 0 to 1 weight percent, and a colorant and property modifying portion including total iron from up to 0.02 weight percent, CeO2 from 0.05 weight percent to 1.5 weight percent, CoO up to 50 PPM, Se up to 15 PPM, Cr2O3 up to 500 PPM, CuO up to 0.5 weight percent, V2O5 up to 0.3 weight percent, TiO2 up to 1 weight percent, NiO up to 200 PPM, Er2O3 up to 3 weight percent, MnO2 up to 0.6 weight percent, and Nd2O3 up to 2 weight percent, wherein the glass composition has a redox ratio up to 0.55.
摘要翻译：公开了玻璃组合物。玻璃组合物包括基础玻璃组合物，其包含65至75重量％的SiO 2，10至20重量％的Na 2 O，5至15重量％的CaO，0至5重量％的MgO，0至5重量％的Al 2 O 3，K 2 O 0至5重量％，BaO为0至1重量％，以及着色剂和性能改性部分，其包括总铁含量高达0.02重量％，CeO 2为0.05重量％至1.5重量％，CoO至50PPM，Se 至15PPM，Cr2O3高达500PPM，CuO高达0.5重量％，V2O5至0.3重量％，TiO 2高达1重量％，NiO高达200PPM，Er 2 O 3高达3重量％，MnO 2高达0.6重量％，Nd 2 O 3至2重量％，其中玻璃组合物的氧化还原比高达0.55。

8. 发明授权

US06849566B2 Blue-green grass 有权
标题翻译：蓝绿草
公开(公告)号：US06849566B2
公开(公告)日：2005-02-01
申请号：US10199774
申请日：2002-07-19
申请人： Larry J. Shelestak , Dennis G. Smith
发明人： Larry J. Shelestak , Dennis G. Smith
IPC分类号： E06B9/24 , C03C3/078 , C03C3/087 , C03C4/02
CPC分类号： C03C3/087 , C03C4/02
摘要： A blue-green colored glass composition includes a base portion, such as a conventional soda-lime-silica base, and major colorants. In one embodiment, the major colorants include 0.7 to 0.9 weight percent total iron (Fe2O3), 0.2 to 0.3 weight percent FeO, and 0 to 5 ppm CoO. The glass is characterized by a dominant wavelength in the range of 490 nm to 495 nm and an excitation purity in the range of 3% to 11%. The glass of the invention can be essentially free of Se.
摘要翻译：蓝绿色玻璃组合物包括碱性部分，例如常规钠钙硅胶基体和主要着色剂。在一个实施方案中，主要着色剂包括0.7至0.9重量％的总铁（Fe 2 O 3），0.2至0.3重量％的FeO和0至5ppm的CoO。玻璃的特征在于波长在490nm至495nm的范围内，激发纯度在3％至11％的范围内。本发明的玻璃基本上不含Se。

9. 发明授权

US07666806B2 Gray glass composition 有权
标题翻译：灰色玻璃组成
公开(公告)号：US07666806B2
公开(公告)日：2010-02-23
申请号：US11264908
申请日：2005-11-02
申请人： Larry J. Shelestak , Dennis G. Smith , James M. Baldauff
发明人： Larry J. Shelestak , Dennis G. Smith , James M. Baldauff
IPC分类号： C03C3/095 , C03C3/087
CPC分类号： C03C3/095 , C03C4/02
摘要： A glass composition that includes a base glass composition including: SiO2 from 65 to 75 weight percent, Na2O from 10 to 20 weight percent, CaO from 5 to 15 weight percent, MgO from 0 to 5 weight percent, Al2O3 from 0 to 5 weight percent, K2O from 0 to 5 weight percent and BaO 0 to 1 weight percent, and a colorant and property modifying portion including total iron from 0.25 to 0.9 weight percent, Cr2O3 from 6 PPM to 400 PPM, Er2O3 from 0.3 to 3.0 weight percent, and TiO2 from 0.1 to 0.8 weight percent, wherein the glass composition has a redox ratio ranging from 0.15 to 0.62.
摘要翻译：一种玻璃组合物，其包括基础玻璃组合物，其包含：65至75重量％的SiO 2，10至20重量％的Na 2 O，5至15重量％的CaO，0至5重量％的MgO，0至5重量％的Al 2 O 3，，0〜5重量％的K 2 O，BaO 0〜1重量％，以及0.25〜0.9重量％的总铁，6重量％〜400重量％的Cr 2 O 3，0.3〜3.0重量％的Er 2 O 3， TiO 2为0.1〜0.8重量％，其中玻璃组合物的氧化还原比为0.15〜0.62。

10. 发明授权

US08304358B2 Method of reducing redox ratio of molten glass and the glass made thereby 有权
标题翻译：降低熔融玻璃和由此制成的玻璃的氧化还原比的方法
公开(公告)号：US08304358B2
公开(公告)日：2012-11-06
申请号：US12275264
申请日：2008-11-21
申请人： Larry J. Shelestak , Ronald L. Shewenninger
发明人： Larry J. Shelestak , Ronald L. Shewenninger
IPC分类号： C03C3/087
CPC分类号： C03B5/235 , C03B5/173 , C03B5/193 , C03C3/087 , C03C4/0092 , C03C4/10
摘要： A soda-lime-silica glass for solar collector cover plates and solar mirrors has less than 0.010 weight percent total iron as Fe2O3, a redox ratio of less than 0.350, less than 0.0025 weight percent CeO2, and spectral properties that include a visible transmission, and a total solar infrared transmittance, of greater than 90% at a thickness of 5.5 millimeters, and reduced solarization. In one non-limiting embodiment of invention, the glass is made by heating a pool of molten soda-lime-silica with a mixture of combustion air and fuel gas having an air firing ratio of greater than 11, or an oxygen firing ratio of greater than 2.31. In another non-limiting embodiment of the invention, streams of oxygen bubbles are moved through a pool of molten glass. In both embodiments, the oxygen oxidizes ferrous iron to ferric iron to reduce the redox ratio.
摘要翻译：用于太阳能收集器盖板和太阳能反射镜的钠钙石英玻璃具有小于0.010重量％的铁，如Fe 2 O 3，氧化还原比小于0.350，小于0.0025重量％的CeO 2，以及包括可见透射，和总太阳红外透射率，厚度为5.5毫米时大于90％，减少了日晒。在本发明的一个非限制性实施方案中，玻璃通过用燃烧空气和空气燃烧比大于11的燃料气体的混合物加热熔融的钠钙二氧化硅池，或者燃烧比大于11 超过2.31。在本发明的另一非限制性实施方案中，氧气泡流移动通过熔融玻璃池。在两个实施方案中，氧氧化亚铁铁至三价铁以降低氧化还原比。

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