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    • 2. 发明授权
    • Emulsion polymer composition
    • 乳液聚合物组成
    • US5869569A
    • 1999-02-09
    • US826089
    • 1997-03-24
    • Zenichi AraiTomohiro ShinodaKunihide Takarabe
    • Zenichi AraiTomohiro ShinodaKunihide Takarabe
    • C08L25/08C08F291/00C08L33/00C08L33/04C08L33/06C08L57/00C09D125/00C09D125/08C09D133/04C09D133/06C09D151/00C09D157/00C09D201/00C08L43/02
    • C09D151/003C08F291/00C09D133/06
    • An emulsion polymer composition having fast drying properties that provides floor polish coating materials having superior resistance to black heel marks, resistance to scuffing, resistance to abrasion, adhesion, and resistance to cleaning agents characteristics, is obtained from a film forming emulsion polymer composition comprising from greater than 60 wt % to 95 wt % of a first emulsion copolymer having a glass transition temperature within the range of from 10.degree.-100.degree. C., and from 5 wt % to less than 40 wt % of a second emulsion copolymer having a glass transition temperature that is lower than that of the first emulsion copolymer and is within the range of from 0.degree.-50.degree. C., wherein the second emulsion copolymer contains from 1 to 8% by weight of nonionic hydrophilic units selected from the group consisting of hydroxy alkyl ester of alpha, beta unsaturated acid, vinyl alcohol, alkyl-phosphato-alkyl acrylates and methacrylates, alkyl-phosphono-alkyl acrylates and methacrylates, and alkyl amides of alpha, beta unsaturated acid, and wherein the second emulsion copolymer contains less than 5% by weight of units originated from vinyl alcohol.
    • 具有快速干燥性能的乳液聚合物组合物由具有优异的耐黑色跟痕痕,抗磨损性,耐磨性,粘合性和耐清洁剂特性的地板抛光涂料得到,该成膜乳液聚合物组合物包含 大于60重量%至95重量%的玻璃化转变温度在10-100℃范围内的第一乳液共聚物和5重量%至小于40重量%的第二乳液共聚物,其具有 玻璃化转变温度低于第一乳液共聚物的玻璃化转变温度,并且在0〜-50℃的范围内,其中第二乳液共聚物含有1至8重量%的非离子亲水单元,其选自 的α,β不饱和酸,乙烯基醇,烷基 - 磷酸烷基酯,丙烯酸酯和甲基丙烯酸酯,烷基 - 膦酰基烷基丙烯酸酯和甲基丙烯酸 酯和α,β-不饱和酸的烷基酰胺,并且其中第二乳液共聚物含有小于5重量%的源自乙烯醇的单元。