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    • 1. 发明授权
    • Terminal-modified conjugated diene-vinyl aromatic copolymer and method for manufacturing the same
    • 末端改性共轭二烯 - 乙烯基芳族共聚物及其制造方法
    • US08871867B2
    • 2014-10-28
    • US13326532
    • 2011-12-15
    • Kuei-Lun ChengChen-Pao Huang
    • Kuei-Lun ChengChen-Pao Huang
    • C08L83/05C08C19/44
    • C08C19/44
    • The invention discloses a terminal-modified conjugated diene-vinyl aromatic copolymer and a method for manufacturing the same. The method comprises the following steps. An organic alkali metal initiator is added into a first mixture containing a conjugated diene monomer and a vinyl aromatic hydrocarbon monomer to perform reaction to obtain a conjugated diene-vinyl aromatic copolymer with active terminal. The conjugated diene-vinyl aromatic copolymer with active terminal reacts with polysiloxane to obtain a terminal-modified conjugated diene-vinyl aromatic copolymer. The aforementioned polysiloxane is expressed as chemical formula (I): R1, R2, R3 and R5 independently are alkyl group with 1˜20 carbon atoms. R4 is selected from one of alkyl group, alkoxy group or hydroxyl group with 1˜5 carbon atoms, m is an integer of 2˜50, and n is an integer of 0˜50.
    • 本发明公开了一种末端改性共轭二烯 - 乙烯基芳族共聚物及其制造方法。 该方法包括以下步骤。 将有机碱金属引发剂加入到含有共轭二烯单体和乙烯基芳族烃单体的第一混合物中进行反应,得到具有活性末端的共轭二烯 - 乙烯基芳族共聚物。 具有活性末端的共轭二烯 - 乙烯基芳族共聚物与聚硅氧烷反应得到末端改性的共轭二烯 - 乙烯基芳族共聚物。 上述聚硅氧烷表示为化学式(I):R 1,R 2,R 3和R 5独立地为具有1〜20个碳原子的烷基。 R4选自烷基,烷氧基或具有1〜5个碳原子的羟基之一,m为2〜50的整数,n为0〜50的整数。
    • 2. 发明授权
    • Modified conjugated diene-vinyl aromatic copolymer and method for manufacturing the same
    • 改性共轭二烯 - 乙烯基芳族共聚物及其制造方法
    • US08362152B2
    • 2013-01-29
    • US13339799
    • 2011-12-29
    • Chen-Pao HuangKuei-Lun Cheng
    • Chen-Pao HuangKuei-Lun Cheng
    • C08F8/00C08F136/00
    • C08C19/44
    • A modified conjugated diene-vinyl aromatic copolymer and a method for manufacturing the same are provided. The modified conjugated diene-vinyl aromatic copolymer is formed by modifying a conjugated diene-vinyl aromatic copolymer by reacting with a first modifier in a solvent and then reacting with a second modifier. The solvent contains an organic alkali metal initiator. The first modifier is expressed as chemical formula (I): The second modifier is expressed as chemical formula (II): R1 is selected from one of hydrogen, methyl group or ethyl group. R2 is selected from hydrogen. R3 is selected from one of hydrogen, methyl group or ethyl group. X is selected from one of epoxypropoxy group, isocyanate group or 2-(3,4-epoxycyclohexyl) group. R4 is selected from one of alkyl groups with 2˜3 carbon atoms.
    • 提供改性共轭二烯 - 乙烯基芳族共聚物及其制造方法。 改性共轭二烯 - 乙烯基芳族共聚物通过在溶剂中与第一改性剂反应,然后与第二改性剂反应来改性共轭二烯 - 乙烯基芳族共聚物而形成。 溶剂含有有机碱金属引发剂。 第一改性剂表示为化学式(I):第二改性剂表示为化学式(II):R1选自氢,甲基或乙基之一。 R2选自氢。 R 3选自氢,甲基或乙基之一。 X选自环氧丙氧基,异氰酸酯基或2-(3,4-环氧环己基)基团之一。 R4选自具有2〜3个碳原子的烷基中的一个。
    • 3. 发明申请
    • TERMINAL-MODIFIED CONJUGATED DIENE-VINYL AROMATIC COPOLYMER AND METHOD FOR MANUFACTURING THE SAME
    • 终端改性的联苯胺芳族共聚物及其制备方法
    • US20120172528A1
    • 2012-07-05
    • US13326532
    • 2011-12-15
    • Kuei-Lun ChengChen-Pao Huang
    • Kuei-Lun ChengChen-Pao Huang
    • C08F8/42C08F36/06C08F36/08C08F36/04
    • C08C19/44
    • The invention discloses a terminal-modified conjugated diene-vinyl aromatic copolymer and a method for manufacturing the same. The method comprises the following steps. An organic alkali metal initiator is added into a first mixture containing a conjugated diene monomer and a vinyl aromatic hydrocarbon monomer to perform reaction to obtain a conjugated diene-vinyl aromatic copolymer with active terminal. The conjugated diene-vinyl aromatic copolymer with active terminal reacts with polysiloxane to obtain a terminal-modified conjugated diene-vinyl aromatic copolymer. The aforementioned polysiloxane is expressed as chemical formula (I): R1, R2, R3 and R5 independently are alkyl group with 1˜20 carbon atoms. R4 is selected from one of alkyl group, alkoxy group or hydroxyl group with 1˜5 carbon atoms, m is an integer of 2˜50, and n is an integer of 0˜50.
    • 本发明公开了一种末端改性共轭二烯 - 乙烯基芳族共聚物及其制造方法。 该方法包括以下步骤。 将有机碱金属引发剂加入到含有共轭二烯单体和乙烯基芳族烃单体的第一混合物中进行反应,得到具有活性末端的共轭二烯 - 乙烯基芳族共聚物。 具有活性末端的共轭二烯 - 乙烯基芳族共聚物与聚硅氧烷反应得到末端改性的共轭二烯 - 乙烯基芳族共聚物。 上述聚硅氧烷表示为化学式(I):R 1,R 2,R 3和R 5独立地为具有1〜20个碳原子的烷基。 R4选自烷基,烷氧基或具有1〜5个碳原子的羟基之一,m为2〜50的整数,n为0〜50的整数。
    • 4. 发明申请
    • MODIFIED CONJUGATED DIENE-VINYL AROMATIC COPOLYMER AND METHOD FOR MANUFACTURING THE SAME
    • 改性的联苯胺芳族共聚物及其制备方法
    • US20120172527A1
    • 2012-07-05
    • US13339799
    • 2011-12-29
    • Chen-Pao HuangKuei-Lun Cheng
    • Chen-Pao HuangKuei-Lun Cheng
    • C08F8/42C08F8/30C08F236/10
    • C08C19/44
    • A modified conjugated diene-vinyl aromatic copolymer and a method for manufacturing the same are provided. The modified conjugated diene-vinyl aromatic copolymer is formed by modifying a conjugated diene-vinyl aromatic copolymer by reacting with a first modifier in a solvent and then reacting with a second modifier. The solvent contains an organic alkali metal initiator. The first modifier is expressed as chemical formula (I): The second modifier is expressed as chemical formula (II): R1 is selected from one of hydrogen, methyl group or ethyl group. R2 is selected from hydrogen. R3 is selected from one of hydrogen, methyl group or ethyl group. X is selected from one of epoxypropoxy group, isocyanate group or 2-(3,4-epoxycyclohexyl) group. R4 is selected from one of alkyl groups with 2˜3 carbon atoms.
    • 提供改性共轭二烯 - 乙烯基芳族共聚物及其制造方法。 改性共轭二烯 - 乙烯基芳族共聚物通过在溶剂中与第一改性剂反应,然后与第二改性剂反应来改性共轭二烯 - 乙烯基芳族共聚物而形成。 溶剂含有有机碱金属引发剂。 第一改性剂表示为化学式(I):第二改性剂表示为化学式(II):R1选自氢,甲基或乙基之一。 R2选自氢。 R 3选自氢,甲基或乙基之一。 X选自环氧丙氧基,异氰酸酯基或2-(3,4-环氧环己基)基团之一。 R4选自具有2〜3个碳原子的烷基中的一个。