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1. 发明授权

US3979385A 1-Aminoalkane-1,1-diphosphonic acids and their salts 失效
标题翻译： 1-氨基链烷-1,1-二膦酸及其盐
公开(公告)号：US3979385A
公开(公告)日：1976-09-07
申请号：US475207
申请日：1974-05-31
申请人： Klaus Wollmann , Walter Ploger , Karl-Heinz Worms
发明人： Klaus Wollmann , Walter Ploger , Karl-Heinz Worms
IPC分类号： C07F9/38 , C07D295/04
CPC分类号： C07F9/3873
摘要： A process for the production of 1-aminoalkane-1,1-diphosphonates of the formula ##SPC1##Wherein R.sub.1 is a member selected from the group consisting of hydrogen, lower alkyl and phenyl, R.sub.2 and R.sub. 3 are members selected from the group consisting of hydrogen, alkyl having 1 to 22 carbon atoms, cycloalkyl having 5 to 6 carbon atoms, phenyl, alkylphenyl having 7 to 18 carbon atoms, phenylalkyl having 7 to 18 carbon atoms and together with the nitrogen atom, piperidino, pyrrolidino and morpholino, and X is a member selected from the group consisting of hydrogen, alkali metal, ammonium, pyridinium, guanidinium and mono-, di-, and tri-lower-alkanol-ammonium with the proviso that at least one of R.sub.1, R.sub.2 and R.sub.3 is other than hydrogen, which consists essentially in reacting a phosphorus trihalide selected from the group consisting of phosphosus trichloride and phosphorus tribromide with a monocarboxylic acid amide of the formula ##SPC2##wherein the molecular weight of said carboxylic acid amide is over 46 and R.sub.1, R.sub.2 and R.sub. 3 have the above assigned meanings, at a temperature of from 0.degree. to 75.degree.C, subjecting the resultant reaction product to hydrolysis, and recovering said 1-aminoalkane-1,1-diphosphonates. The 1-aminoalkane-1,1-diphosphonates, some of which are novel, are capable of forming complexes with heavy metals.
摘要翻译：制备式WHEREIN R1的1-氨基烷烃-1,1-二膦酸盐的方法是选自氢，低级烷基和苯基的成员，R 2和R 3是选自氢，具有1至22个碳原子的烷基，具有5至6个碳原子的环烷基，苯基，具有7至18个碳原子的烷基苯基，具有7至18个碳原子的苯基烷基以及氮原子，哌啶子基，吡咯烷子基和吗啉代，X是选自氢，碱金属，铵，吡啶鎓，胍和单 - ，二 - 和三 - 低级 - 链烷醇 - 铵的成员，条件是R 1，R 2和R 3中的至少一个不是氢，其主要在于使选自三磷化磷和三溴化磷的三卤化磷与下式的一元羧酸酰胺反应，其中所述羧酸酰胺的分子量超过46且R1，R2 和R 3具有上述含义，在0℃至75℃的温度下，使所得反应产物水解，并回收所述1-氨基烷烃-1,1-二膦酸盐。其中一些是新型的1-氨基烷烃-1,1-二膦酸盐能够与重金属形成络合物。

2. 发明授权

US4740562A Method for the surface modification of objects made of polyvinylidene fluoride 失效
标题翻译：聚偏二氟乙烯制成的物体的表面改性方法
公开(公告)号：US4740562A
公开(公告)日：1988-04-26
申请号：US865781
申请日：1986-05-22
申请人： Klaus Menke , Klaus Wollmann , Gerhard Glink
发明人： Klaus Menke , Klaus Wollmann , Gerhard Glink
IPC分类号： B01D67/00 , C08J5/12 , C08J7/12 , C08F8/00
CPC分类号： B01D67/0088 , C08J5/121 , C08J7/12
摘要： A method for the surface modification of objects made from polyvinylidene fluoride by dehydrofluorinated of the surface of the objects. The dehydrofluorination is carried out with an etching solution which, in addition to a strong basic compound and a swelling agent and/or solvent for polyvinylidene fluoride, contains an auxiliary agent for the homogenization of the etching solution. The effect of etching is supported by an adhesion promoter. High resistance to shearing and good tough-elasticity in composite structure and laminates is achieved.
摘要翻译：一种通过对象表面的脱氟化氟化从聚偏二氟乙烯制成的物体的表面改性方法。脱氟化氢用蚀刻溶液进行，除了强碱性化合物和用于聚偏二氟乙烯的溶胀剂和/或溶剂之外，还含有用于蚀刻溶液均化的助剂。蚀刻效果由粘合促进剂支持。实现了复合结构和层压板的高抗剪切性和良好的韧性弹性。

3. 发明授权

US5374304A Special amyloses and their use for producing biodegradable plastics 失效
标题翻译：特殊的直链淀粉及其生产可生物降解塑料的用途
公开(公告)号：US5374304A
公开(公告)日：1994-12-20
申请号：US145718
申请日：1993-11-04
申请人： Rainer Frische , Klaus Wollmann , Renate Gross-Lannert , Judith Schneider , Bernd Best
发明人： Rainer Frische , Klaus Wollmann , Renate Gross-Lannert , Judith Schneider , Bernd Best
IPC分类号： C08B30/20 , C08L3/12 , C08L3/18 , C08L3/06 , C09D103/06
CPC分类号： C08L3/12 , C08B30/20 , C08L3/18
摘要： The invention relates to special amyloses for producing biodegradable, clear, transparent and flexible plastic, in particular sheets and films, whicha) are swellable, but not soluble, in cold water;b) yield homogenous, flowable quasi-solutions without formation of gels if they are heated, with stirring, to temperatures above 80.degree. C., at atmospheric pressure; during cooling to a temperature of 50.degree. C., this state is maintained for at least five minutes, without gel formation or retrogradation, and the solution in a concentration between 5 and 25% is applicable to knife coating onto a plane surface with a gap width between 100 and 700 .mu.m.
摘要翻译：本发明涉及用于生产可生物降解，透明，透明和柔性的塑料，特别是薄片和薄膜的特殊的直链淀粉，其a）在冷水中可溶胀但不溶; b）如果在搅拌下在大气压下加热至80℃以上，则可产生均匀的可流动的准溶液而不形成凝胶; 在冷却至50℃的温度下，该状态保持至少5分钟，没有凝胶形成或退化，浓度为5至25％的溶液可用于刀片涂覆到具有间隙的平面上宽度在100到700亩之间。

4. 发明授权

US5302670A Plastics on fatty acid basis 失效
标题翻译：新型塑料在脂肪酸的基础上
公开(公告)号：US5302670A
公开(公告)日：1994-04-12
申请号：US659317
申请日：1991-02-28
申请人： Rainer Frische , Jurgen Volkheimer , Klaus Wollmann , Herrmann Schomann , Judith Schneider , Alexander Ach , Renate Gross-Lannert , Bernd Best
发明人： Rainer Frische , Jurgen Volkheimer , Klaus Wollmann , Herrmann Schomann , Judith Schneider , Alexander Ach , Renate Gross-Lannert , Bernd Best
IPC分类号： C08G75/00 , C07C235/10 , C07C235/28 , C08G18/30 , C08G18/32 , C08G18/36 , C08G18/38 , C08G59/20 , C08G63/16 , C08G63/48 , C08G64/02 , C08L67/08
CPC分类号： C08G64/02 , C07C235/10 , C07C235/28 , C08G18/36 , C08G18/3825 , C08G63/48
摘要： The present invention relates to plastics that can be obtained by reacting unsaturated and/or hydroxyl-group-containing fatty acids or their esters or mixtures of various such fatty acids and esters with bifunctional ester-forming and/or amide-forming compounds and, if necessary, subsequently converting ethylenic double bonds, to give difatty acid diamides, difatty acid diesters, difatty acid amide esters, monofatty acid amide amines or monofatty acid amide alcohols as monomer components which contain at least two reactive groups suited for linkage to give polymers, in particular ethylenic double bonds, hydroxyl groups, epoxy groups or amino groups, and by linking the said compounds in the known way via a second group of bifunctional compounds that are capable of reacting with these free reactive groups to give the desired plastics.
摘要翻译： PCT No.PCT / EP90 / 00995 Sec。 371日期1991年2月28日 102（e）日期1991年2月28日PCT Filed 1990年6月22日PCT公布。出版物WO91 / 00305 日本1991年1月10日。本发明涉及可以通过使不饱和和/或含羟基的脂肪酸或它们的酯或各种这样的脂肪酸和酯的混合物与双官能酯形成和/或酰胺形成化合物，并且如果需要随后转化烯属双键，得到二酸二酰胺，二缩二酸二酯，二缩酰胺酯，单脂肪酸酰胺胺或单脂肪酰胺醇，作为单体组分，其含有至少两个适合的反应性基团用于连接以产生聚合物，特别是乙烯基双键，羟基，环氧基或氨基，并且通过能够与这些游离反应性基团反应的第二组双官能化合物以已知方式连接所述化合物，得到所需的塑料。

5. 发明授权

US4195549A Pintle wire for high load hinge connections 失效
标题翻译：用于高负载铰链连接的枢轴
公开(公告)号：US4195549A
公开(公告)日：1980-04-01
申请号：US493980
申请日：1974-08-01
申请人： Wilhelm Schuster , Klaus Wollmann , Jurgen Stahl
发明人： Wilhelm Schuster , Klaus Wollmann , Jurgen Stahl
IPC分类号： D04C1/12 , F16G3/02 , D04C1/06
CPC分类号： D07B1/142 , D04C1/12 , F16G3/02 , D07B2201/1096
摘要： A pintle wire for high load hinge connections, especially for textile webs and transmission belts, and method of making same, according to which continuous synthetic fibers are braided individually or in strands and are embedded in high wear resistant and hydrolysis resistant duroplastic material and interconnected thereby.
摘要翻译：用于高负载铰链连接的枢轴线，特别是用于纺织网和传动带，以及制造方法，其中连续合成纤维单独地或以线束编织，并且嵌入在高耐磨和耐水解的塑料材料中并由此相互连接。

6. 发明授权

US5019199A Method of joining wood material to plastic material 失效
标题翻译：将木材与塑料材料接合的方法
公开(公告)号：US5019199A
公开(公告)日：1991-05-28
申请号：US336326
申请日：1989-04-11
申请人： Klaus Menke , Peter Wiesert , Klaus Wollmann , Bernd Best
发明人： Klaus Menke , Peter Wiesert , Klaus Wollmann , Bernd Best
IPC分类号： B29C37/00 , B29C45/14 , B29C63/00 , B29C63/48 , B29C65/00 , B29C65/52 , B29K105/20 , C08J5/12
CPC分类号： C08J5/124 , B29C37/0082 , B29C45/14778 , B29C63/00 , B29C63/48 , B29C66/02 , B29C66/7392 , B29C66/7487 , B29C2045/0079 , B29C66/71 , B29C66/7212 , B29C66/7294 , B29K2711/12 , B29K2711/14
摘要： A method of joining wood material and plasstic material. An anchoring layer is applied to the area of the wood material that is to be joined to the plastic material and adhesively joined to the respective area which has a high specific surface area and with which the plastic material is joined by injection molding. The resultant composite material can be used in particular in the furniture sector and in housing construction, where low-cost and stable veneered plastic parts can be produced by the method, which can be made fire-proof by using appropriate plastic materials. Additional fields of application are the automobile industry, the construction of campers and boats, and aircraft construction. The wood material that is mainly used is veneer wood, because of the high quality of the visible surface of the composite.
摘要翻译：连接木材和纤维素材料的方法。将锚定层施加到待连接到塑料材料的木材材料的区域，并且粘合地接合到具有高比表面积的相应区域，并且通过注射成型将塑料材料与其接合。所得到的复合材料可以特别用于家具部门和住房结构中，其中通过该方法可以生产低成本且稳定的贴面塑料部件，其可以通过使用适当的塑料材料制成防火。其他应用领域包括汽车工业，营员和船只的建造以及飞机的建造。主要使用的木材是单板木，因为复合材料的可见表面质量高。

7. 发明授权

US4007303A Method of making pintle wire for high load hinge connections 失效
标题翻译：用于高负载铰链连接的制造线的方法
公开(公告)号：US4007303A
公开(公告)日：1977-02-08
申请号：US496910
申请日：1974-08-12
申请人： Wilhelm Schuster , Klaus Wollmann , Jurgen Stahl
发明人： Wilhelm Schuster , Klaus Wollmann , Jurgen Stahl
IPC分类号： F16G3/02 , B05D1/18 , B05D3/00
CPC分类号： F16G3/02 , Y10T16/557
摘要： A pintle wire for high load hinge connections, especially for textile webs and transmission belts, and method of making same, according to which endless synthetic fibers are braided individually or in strands and are embedded in high wear resistant and hydrolysis resistant heat hardenable material and interconnected thereby.
摘要翻译：用于高负载铰链连接的枢轴线，特别是用于纺织网和传动带的方法及其制造方法，根据该方法，环形合成纤维单独或绞合编织并嵌入高耐磨和耐水解的热可硬化材料中并且互连从而。

8. 发明授权

US4447477A Method for the production of corrosion-inhibiting coatings on metallic surfaces 失效
标题翻译：在金属表面上生产腐蚀抑制涂层的方法
公开(公告)号：US4447477A
公开(公告)日：1984-05-08
申请号：US459693
申请日：1982-12-29
申请人： Heinrich Deibig , Klaus Wollmann
发明人： Heinrich Deibig , Klaus Wollmann
IPC分类号： B05D20060101 , B05D7/14 , C09D5/08 , C09D161/20 , B05D3/02
CPC分类号： C09D5/08
摘要： In a method for the production of corrosion-inhibiting coatings on metallic surfaces, a mixture consisting of a phenol, low molecular condensation products of formaldehyde and ammonia or amines and a wetting agent, which is chemically reactive with the starting materials, is applied onto the surface to be coated and is cured under heat. The mixture is applied in the form of a solution, dispersion or powder.
摘要翻译： PCT No.PCT / EP82 / 00131 Sec。 1982年12月29日第 102（e）1982年12月29日PCT PCT。1982年6月24日PCT公布。公开号WO83 / 00105 日本1983年1月20日。在金属表面上生产腐蚀抑制涂层的方法中，由苯酚，甲醛和氨或胺的低分子缩合产物和润湿剂组成的混合物，其与起始材料施加到待涂覆的表面上并在加热下固化。混合物以溶液，分散体或粉末的形式施用。

9. 发明授权

US4075093A Process of separating citric acid and/or isocitric acid or their salts from aqueous solutions 失效
标题翻译：从水溶液中分离柠檬酸和/或异柠檬酸或其盐的方法
公开(公告)号：US4075093A
公开(公告)日：1978-02-21
申请号：US625140
申请日：1975-10-23
申请人： Axel Walch , Albrecht Klimmek , Klaus Wollmann
发明人： Axel Walch , Albrecht Klimmek , Klaus Wollmann
IPC分类号： C12P7/48 , B01D61/02 , B01D65/00 , B01D67/00 , B01D71/40 , B01D71/42 , B01D71/64 , C07C51/00 , C07C51/42 , C07C59/265 , C07C67/00 , B01D13/00
CPC分类号： B01D67/0093 , B01D71/40 , B01D71/42 , B01D71/64 , B01D71/68 , C07C51/42 , B01D2323/30 , B01D2325/14 , B01D2325/16
摘要： The process of separating citric acid and/or isocitric acid and their salts from aqueous solutions containing said acids or their salts, and especially from fermentation solutions, consists in contacting said solutions under pressure with a permselective membrane. The material composing said membrane has introduced thereinto acid or basic groups so as to yield membranes of predetermined swelling power. Preferred membranes are those consisting of polyimide or polyamide polycondensation products which are modified by acid or basic groups, of polysulfones modified by acid groups, or of vinyl polymers modified by acid or basic groups. Adjustment of the starting solutions to a pH lower than 3.0 is advantageously effected by means of polyvinylsulfonic acid.
摘要翻译：从含有所述酸或其盐的水溶液，特别是发酵溶液的水溶液中分离柠檬酸和/或异柠檬酸及其盐的过程包括使压力下的所述溶液与选择性渗透膜接触。构成所述膜的材料已经引入酸或碱性基团，以产生预定溶胀力的膜。优选的膜是由通过酸或碱性基团改性的聚酰亚胺或聚酰胺缩聚产物，由酸基改性的聚砜或由酸或碱性基团改性的乙烯基聚合物组成的膜。将初始溶液调节至低于3.0的pH有利地通过聚乙烯基磺酸进行。

10. 发明授权

US5576425A Process for the direct production of alkyl glycosides 失效
标题翻译：直接生产烷基糖苷的方法
公开(公告)号：US5576425A
公开(公告)日：1996-11-19
申请号：US279673
申请日：1994-07-25
申请人： Karlheinz Hill , Manfred Biermann , Henry Rossmaier , Rainer Eskuchen , Willi Wuest , Josef Wollmann , Andreas Bruns , Guenter Hellmann , Karl-Heinz Ott , Walter Winkle , Klaus Wollmann
发明人： Karlheinz Hill , Manfred Biermann , Henry Rossmaier , Rainer Eskuchen , Willi Wuest , Josef Wollmann , Andreas Bruns , Guenter Hellmann , Karl-Heinz Ott , Walter Winkle , Klaus Wollmann
IPC分类号： C07H15/04 , C07G3/00 , C07H1/00
CPC分类号： C07H15/04
摘要： The aliphatic primary alcohols are reacted with a glycose, more especially glucose, in the presence of an acidic catalyst in certain process steps so that particularly light-colored and alkali-stable alkyl glucosides are obtained after a subsequent, compulsory bleaching step, which represents an improvement over known direct synthesis processes. The process may be carried out both on a laboratory scale and also on an industrial production scale.
摘要翻译：脂肪族伯醇在一定的工艺步骤中，在酸性催化剂的存在下，与糖，更特别是葡萄糖反应，从而在随后的强制漂白步骤之后获得特别是浅色和碱稳定的烷基葡糖苷，改进已知的直接合成方法。该过程可以在实验室规模上进行，也可以在工业生产规模上进行。

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