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    • 3. 发明授权
    • Processes for producing a fluorosulfonyl group-containing compound and a compound LED from the fluorosulfonyl group-containing compound
    • 从含氟磺酰基的化合物制备含氟磺酰基的化合物和化合物LED的方法
    • US07709665B2
    • 2010-05-04
    • US11829579
    • 2007-07-27
    • Takashi OkazoeAtsushi WatakabeMasahiro ItoKunio WatanabeTakeshi EriguchiKimiaki KashiwagiShu-zhong Wang
    • Takashi OkazoeAtsushi WatakabeMasahiro ItoKunio WatanabeTakeshi EriguchiKimiaki KashiwagiShu-zhong Wang
    • C07D317/00
    • C08F24/00C07D317/18C07D317/24C07D317/42
    • A fluorosulfonyl group-containing compound having a high polymerization reactivity, a process for its production, a sulfonyl group-containing polymerizable monomer led from the sulfonyl group-containing compound, and a polymer obtainable by polymerizing the sulfonyl group-containing polymerizable monomer, are provided.A compound (3) is fluorinated to form a compound (4), and then, the compound (4) is subjected to a decomposition reaction to produce a compound (5). A preferred compound (5-1) of the compound (5) is thermally decomposed to produce a compound (7-1) having a high polymerization reactivity. wherein RA is a bivalent organic group such as a fluoroalkylene group, RAF is a group having RA fluorinated, or the same group as RA, each of RB to RD which are independent of one another, is a hydrogen atom, etc., each of RBF to RDF is a fluorine atom, etc., RE is a monovalent organic group, REF is a group having RE fluorinated, or the same group as RE, E is a bivalent connecting group, EF is the same group as E, or a group having E fluorinated, EF1 is a group formed by scission of EF, each of X1 to X3 is a hydrogen atom, etc., and each of X1F to X3F is a fluorine atom, etc.
    • 提供具有高聚合反应性的含氟磺酰基的化合物,其制备方法,由含磺酰基的化合物引发的含磺酰基的可聚合单体和通过聚合含磺酰基的可聚合单体获得的聚合物 。 化合物(3)被氟化以形成化合物(4),然后使化合物(4)进行分解反应以制备化合物(5)。 将化合物(5)的优选化合物(5-1)热分解,得到聚合反应性高的化合物(7-1)。 其中RA是二价有机基团,例如氟代亚烷基,RAF是具有RA氟化的基团,或与RA相同的基团,每个RB与RD彼此独立,为氢原子等 RBF与RDF是氟原子等,RE是一价有机基团,REF是具有RE氟化的基团,或与RE相同的基团,E是二价连接基团,EF与E相同,或者 具有E氟原子的基团,EF1是通过EF的断裂形成的基团,X1〜X3各自为氢原子等,X1F〜X3F各自为氟原子等。
    • 5. 发明申请
    • PROCESSES FOR PRODUCING A FLUOROSULFONYL GROUP-CONTAINING COMPOUND AND A COMPOUND LED FROM THE FLUOROSULFONYL GROUP-CONTAINING COMPOUND
    • 用于生产含氟聚合物基团的化合物的方法和来自含氟化合物基团的化合物的化合物
    • US20080287694A1
    • 2008-11-20
    • US11829579
    • 2007-07-27
    • Takashi OKAZOEAtsushi WatakabeMasahiro ItoKunio WatanabeTakeshi EriguchiKimiaki KashiwagiShu-zhong Wang
    • Takashi OKAZOEAtsushi WatakabeMasahiro ItoKunio WatanabeTakeshi EriguchiKimiaki KashiwagiShu-zhong Wang
    • C07D317/30C07D317/18
    • C08F24/00C07D317/18C07D317/24C07D317/42
    • A fluorosulfonyl group-containing compound having a high polymerization reactivity, a process for its production, a sulfonyl group-containing polymerizable monomer led from the sulfonyl group-containing compound, and a polymer obtainable by polymerizing the sulfonyl group-containing polymerizable monomer, are provided.A compound (3) is fluorinated to form a compound (4), and then, the compound (4) is subjected to a decomposition reaction to produce a compound (5). A preferred compound (5-1) of the compound (5) is thermally decomposed to produce a compound (7-1) having a high polymerization reactivity. wherein RA is a bivalent organic group such as a fluoroalkylene group, RAF is a group having RA fluorinated, or the same group as RA, each of RB to RD which are independent of one another, is a hydrogen atom, etc., each of RBF to RDF is a fluorine atom, etc., RE is a monovalent organic group, REF is a group having RE fluorinated, or the same group as RE, E is a bivalent connecting group, EF is the same group as E, or a group having E fluorinated, EF1 is a group formed by scission of EF, each of X1 to X3 is a hydrogen atom, etc., and each of X1F to X3F is a fluorine atom, etc.
    • 提供具有高聚合反应性的含氟磺酰基的化合物,其制备方法,由含磺酰基的化合物引发的含磺酰基的可聚合单体和通过聚合含磺酰基的可聚合单体获得的聚合物 。 化合物(3)被氟化以形成化合物(4),然后使化合物(4)进行分解反应以制备化合物(5)。 将化合物(5)的优选化合物(5-1)热分解,得到聚合反应性高的化合物(7-1)。 其中R A是二价有机基团,例如氟代亚烷基,R AF是​​具有氟代的基团,或与氟代亚烷基相同的基团 各自独立的R B,R D,D各自为氢原子等,R a, 另一方面,BF> BF 是氟原子等,R E是一价有机基团,R EF是 氟化的基团或与R E相同的基团,E是二价连接基团,E是与 E或具有E氟化基团的基团,是通过将X 1和X 2各自分开形成的基团。 > 3是氢原子等,X 1〜X 3各自为氟原子等。
    • 9. 发明授权
    • Fuel cell system
    • 燃料电池系统
    • US08182951B2
    • 2012-05-22
    • US12828710
    • 2010-07-01
    • Satoru HommuraSusumu SaitoTetsuji ShimohiraAtsushi WatakabeJunichi Tayanagi
    • Satoru HommuraSusumu SaitoTetsuji ShimohiraAtsushi WatakabeJunichi Tayanagi
    • H01M8/04H01M8/10
    • H01M8/1067C08J5/2237C08J2327/12H01M8/04358H01M8/04768H01M8/04835H01M8/1025H01M8/1039
    • To provide a fuel cell system provided with a polymer electrolyte fuel cell which is excellent in the power generation characteristics under high temperature and low or no humidity conditions.A fuel cell system 20 comprising a polymer electrolyte fuel cell 22 having a membrane/electrode assembly 10 having a catalyst layer containing a polymer (H) which has repeating units based on a perfluoromonomer having an alicyclic structure and has ion exchange groups, a temperature controlling means for controlling temperature of the polymer electrolyte fuel cell 22, a temperature sensor 38 for detecting temperature of the polymer electrolyte fuel cell 22, and a controlling device 40 for controlling the temperature controlling means based on temperature information from the temperature sensor 38 so that the maximum temperature of the polymer electrolyte fuel cell 22 becomes within the range of from 90 to 140° C.
    • 提供一种设置有在高温低湿条件下发电特性优异的聚合物电解质型燃料电池的燃料电池系统。 一种燃料电池系统20,包括具有膜/电极组件10的聚合物电解质燃料电池22,所述膜/电极组件10具有含有聚合物(H)的催化剂层,所述聚合物(H)具有基于具有脂环结构的全氟单体的重复单元并具有离子交换基团,温度控制 用于控制聚合物电解质燃料电池22的温度的装置,用于检测聚合物电解质燃料电池22的温度的温度传感器38,以及用于基于来自温度传感器38的温度信息来控制温度控制装置的控制装置40, 聚合物电解质燃料电池22的最高温度在90〜140℃的范围内。