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    • 4. 发明授权
    • Hard coat film
    • 硬涂膜
    • US08597780B2
    • 2013-12-03
    • US12672556
    • 2008-08-08
    • Emi ShimanoToshio Yoshihara
    • Emi ShimanoToshio Yoshihara
    • B32B5/16
    • G02B1/14C09D5/006C09D7/62G02B1/105Y10T428/2438Y10T428/25Y10T428/256
    • A hard coat film excellent in abrasion resistance and saponification resistance. A hard coat layer includes a cured product of a curable resin composition containing a reactive inorganic fine particle having an average particle diameter of 5 nm to 30 nm, and has a skin layer, wherein the reactive inorganic fine particles are localized, in its surface region being an interface and its vicinity on a side opposite to a transparent substrate film side of the hard coat layer. Alternatively, the reactive inorganic fine particle has an average particle diameter of 30 nm to 100 nm, and has density distribution in a thickness direction of the hard coat layer lowest at an interface on a side opposite to a transparent substrate film side of the hard coat layer while the density is highest at an interface and its vicinity on the transparent substrate film side of the hard coat layer.
    • 耐磨损性和耐皂化性优异的硬涂膜。 硬涂层包括含有平均粒径为5nm〜30nm的反应性无机细颗粒的固化性树脂组合物的固化物,并且在其表面区域具有表面层,其中反应性无机微粒定位 作为与硬涂层的透明基板膜侧相反的一侧的界面及其附近。 或者,反应性无机微粒的平均粒径为30nm〜100nm,并且在硬涂层的与硬涂层的透明基底膜侧相反的一侧的界面处的硬涂层的厚度方向上的密度分布 层,同时在硬涂层的透明基板膜侧的界面及其附近的密度最高。
    • 5. 发明申请
    • HARD COAT FILM
    • 硬涂膜
    • US20110217541A1
    • 2011-09-08
    • US12672556
    • 2008-08-08
    • Emi ShimanoToshio Yoshihara
    • Emi ShimanoToshio Yoshihara
    • B32B5/16
    • G02B1/14C09D5/006C09D7/62G02B1/105Y10T428/2438Y10T428/25Y10T428/256
    • A hard coat film excellent in abrasion resistance and saponification resistance. A hard coat layer includes a cured product of a curable resin composition containing a reactive inorganic fine particle having an average particle diameter of 5 nm to 30 nm, and has a skin layer, wherein the reactive inorganic fine particles are localized, in its surface region being an interface and its vicinity on a side opposite to a transparent substrate film side of the hard coat layer. Alternatively, the reactive inorganic fine particle has an average particle diameter of 30 nm to 100 nm, and has density distribution in a thickness direction of the hard coat layer lowest at an interface on a side opposite to a transparent substrate film side of the hard coat layer while the density is highest at an interface and its vicinity on the transparent substrate film side of the hard coat layer.
    • 耐磨损性和耐皂化性优异的硬涂膜。 硬涂层包括含有平均粒径为5nm〜30nm的反应性无机细颗粒的固化性树脂组合物的固化物,并且在其表面区域具有表面层,其中反应性无机微粒定位 作为与硬涂层的透明基板膜侧相反的一侧的界面及其附近。 或者,反应性无机微粒的平均粒径为30nm〜100nm,并且在硬涂层的与硬涂层的透明基底膜侧相反的一侧的界面处的硬涂层的厚度方向上的密度分布 层,同时在硬涂层的透明基板膜侧的界面及其附近的密度最高。