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1. 发明授权

US5883179A Rubber composition comprising carbon black surface treated with silica 失效
标题翻译：包含用二氧化硅处理的炭黑表面的橡胶组合物
公开(公告)号：US5883179A
公开(公告)日：1999-03-16
申请号：US860477
申请日：1997-06-24
申请人： Masayuki Kawazoe , Tetsuji Kawazura , Kouichi Ikai , Yoshiaki Hashimura , Fumito Yatsuyanagi , Kazunori Ishikawa
发明人： Masayuki Kawazoe , Tetsuji Kawazura , Kouichi Ikai , Yoshiaki Hashimura , Fumito Yatsuyanagi , Kazunori Ishikawa
IPC分类号： C08K9/02 , C09C1/56 , C08K3/00
CPC分类号： C09C1/56 , C08K9/02 , C01P2006/12 , C01P2006/19
摘要： A rubber composition containing at least one rubber component containing a diene rubber and a rubber reinforcing carbon black having silica deposited on the surface thereof.
摘要翻译： PCT No.PCT / JP96 / 03003 Sec。 371日期：1997年6月24日 102（e）日期1997年6月24日PCT提交1996年10月16日PCT公布。公开号WO97 / 15620 PCT 日期1997年5月1日含有至少一种含有二烯橡胶的橡胶组分和在其表面沉积有二氧化硅的橡胶增强炭黑的橡胶组合物。

2. 发明授权

US06191247B1 Polysiloxane composition having superior storage stability and rubber composition containing same 失效
标题翻译：具有优异的储存稳定性的聚硅氧烷组合物和含有它们的橡胶组合物
公开(公告)号：US06191247B1
公开(公告)日：2001-02-20
申请号：US08831850
申请日：1997-04-04
申请人： Kazunori Ishikawa , Fumito Yatsuyanagi , Tetsuji Kawazura
发明人： Kazunori Ishikawa , Fumito Yatsuyanagi , Tetsuji Kawazura
IPC分类号： C08K536
CPC分类号： C08K5/05 , C08G77/045 , C08G77/12 , C08G77/14 , C08G77/18 , C08G77/46 , C08G77/50 , C08G77/70 , C08K5/54 , C08K5/544 , C08K5/56 , C08L7/00 , C08L9/00 , C08L9/06 , C08L21/00 , C08L83/04 , C08L91/06 , C08L2205/02 , C08L2205/03 , Y10T428/2995 , C08L2666/14 , C08L83/00
摘要： A polysiloxane composition comprising (A) a polysiloxane having a group represented by the formula (I): ≡Si—OR (I) wherein, R is a C1 to C18 substituted or unsubstituted monovalent hydrocarbon group or ether bond containing an organic group; and (B) at least 1 ppm of (a) a compound having an N, P, S, Sn, or As component or (b) an acetylene alcohol and a rubber composition containing the same. Specific polysiloxanes (A) contain both formula (I): ≡Si—OR as well as Si—H.
摘要翻译：一种聚硅氧烷组合物，其包含（A）具有由式（I）表示的基团的聚硅氧烷：其中，R是含有有机基团的C1至C18取代或未取代的单价烃基或醚键; 和（B）至少1ppm的（a）具有N，P，S，Sn或As组分的化合物或（b）乙炔醇和含有它们的橡胶组合物。特定聚硅氧烷（A）含有式（I）：= Si-OR以及Si-H。

3. 发明授权

US06525110B1 Polysiloxane-containing rubber composition 失效
标题翻译：含聚硅氧烷的橡胶组合物
公开(公告)号：US06525110B1
公开(公告)日：2003-02-25
申请号：US09713298
申请日：2000-11-16
申请人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
发明人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
IPC分类号： C08K906
CPC分类号： C08K9/06 , C08K9/08 , C08L7/00 , C08L9/06 , C08L21/00 , Y10T428/2982 , Y10T428/2998 , C08L2666/14 , C08L83/06 , C08L9/00
摘要： A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000: ≡Si—OR1 (I) ≡Si—OCOR2 (II) wherein, R1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms.
摘要翻译：具有改性性能的橡胶组合物，其含有起始橡胶（例如二烯橡胶）和具有以下烷氧基甲硅烷基（I）和/或酰氧基甲硅烷基（II）的聚硅氧烷，其平均聚合度为3〜10,000。是具有1至18个碳原子的取代或未取代的一价烃基或含有醚键的有机基团，R 2是氢或具有1至21个碳原子的烃基。

4. 发明授权

US6033597A Polysiloxane-containing rubber composition 失效
标题翻译：含聚硅氧烷的橡胶组合物
公开(公告)号：US6033597A
公开(公告)日：2000-03-07
申请号：US188694
申请日：1998-11-10
申请人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
发明人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
IPC分类号： C08K9/06 , C08K9/08 , C08L21/00 , C09K3/00
CPC分类号： C08K9/06 , C08K9/08 , C08L21/00 , C08L7/00 , C08L9/06 , Y10T428/2982 , Y10T428/2998
摘要： A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a compounding agent comprising a mixture of a polysiloxane having the following alkoxysilyl group (I) and having an average degree of polymerization of 3 to 10,000:.tbd.Si--OR.sup.1 (I).tbd.Si--OCOR.sup.2 (II)wherein, R.sup.1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R.sup.2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms, and a sulfur containing silane.
摘要翻译：具有改性性能的橡胶组合物，其含有起始橡胶（例如二烯橡胶）和包含具有以下烷氧基甲硅烷基（I）的聚硅氧烷和平均聚合度为3至10,000:3THSi-OR1的混合物的配混剂（I）3 SiSiOOR 2（II）其中，R 1为取代或未取代的碳原子数为1〜18的一价烃基或含有醚键的有机基团，R 2为氢或碳原子数1〜21的烃基，和含硫硅烷。

5. 发明授权

US06337361B1 Polysiloxane-containing rubber composition 失效
标题翻译：含聚硅氧烷的橡胶组合物
公开(公告)号：US06337361B1
公开(公告)日：2002-01-08
申请号：US09526733
申请日：2000-03-16
申请人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
发明人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
IPC分类号： C08K906
CPC分类号： C08K9/06 , C08K9/08 , C08L7/00 , C08L9/06 , C08L21/00 , Y10T428/2982 , Y10T428/2998 , C08L2666/14 , C08L83/06 , C08L9/00
摘要： A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000: ≡Si—OR1 (I) ≡Si—OCOR2 (II) wherein, R1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms. The polysiloxane is impregnated in an inert powder.
摘要翻译：具有改性性能的橡胶组合物，其含有起始橡胶（例如二烯橡胶）和具有以下烷氧基甲硅烷基（I）和/或酰氧基甲硅烷基（II）的聚硅氧烷，其平均聚合度为3〜10,000。是具有1至18个碳原子的取代或未取代的一价烃基或含有醚键的有机基团，R 2是氢或具有1至21个碳原子的烃基。聚硅氧烷浸渍在惰性粉末中。

6. 发明授权

US6121347A Polysiloxane-containing rubber composition 失效
标题翻译：含聚硅氧烷的橡胶组合物
公开(公告)号：US6121347A
公开(公告)日：2000-09-19
申请号：US188695
申请日：1998-11-10
申请人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
发明人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
IPC分类号： C08K9/06 , C08K9/08 , C08L21/00
CPC分类号： C08K9/06 , C08K9/08 , C08L21/00 , C08L7/00 , C08L9/06 , Y10T428/2982 , Y10T428/2998
摘要： A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a compounding agent consisting of a silane coupling agent and a carbon black, calcium carbonate or stearic acid powder impregnated with a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000:.tbd.Si--OR.sup.1 (I).tbd.Si--OCOR.sup.2 (II)wherein, R.sup.1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R.sup.2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms.
摘要翻译：具有改性性能的橡胶组合物，其含有起始橡胶（例如二烯橡胶）和由硅烷偶联剂和炭黑，碳酸钙或硬脂酸粉末组成的配混剂，所述炭黑，碳酸钙或硬脂酸粉末浸渍有具有以下烷氧基甲硅烷基（I）的聚硅氧烷和（II），平均聚合度为3〜10,000：3 Si-OR 1（I）3 SiSiO OCOR 2（II）其中，R 1为取代或未取代的碳原子数为1〜18的一价烃基或含有醚键的有机基团，R 2为氢或碳原子数1〜21的烃基。

7. 发明授权

US06177505B1 Polysiloxane-containing rubber composition 失效
标题翻译：含聚硅氧烷的橡胶组合物
公开(公告)号：US06177505B1
公开(公告)日：2001-01-23
申请号：US08708060
申请日：1996-08-30
申请人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
发明人： Fumito Yatsuyanagi , Kazunori Ishikawa , Yoshiaki Hashimura , Tetsuji Kawazura , Hiroyuki Kaido
IPC分类号： C08K300
CPC分类号： C08K9/06 , C08K9/08 , C08L7/00 , C08L9/06 , C08L21/00 , Y10T428/2982 , Y10T428/2998 , C08L2666/14 , C08L83/06 , C08L9/00
摘要： A rubber composition having improved properties containing a starting rubber (e.g., diene rubber) and a polysiloxane having the following alkoxysilyl group (I) and/or acyloxysilyl group (II) and having an average degree of polymerization of 3 to 10,000: ≡Si—OR1 (I) ≡Si—OCOR2 (II) wherein, R1 is a substituted or unsubstituted monovalent hydrocarbon group having 1 to 18 carbon atoms or an organic group containing an ether bond and R2 is hydrogen or a hydrocarbon group having 1 to 21 carbon atoms.
摘要翻译：具有改性性能的橡胶组合物，其含有起始橡胶（例如二烯橡胶）和具有以下烷氧基甲硅烷基（I）和/或酰氧基甲硅烷基（II）的聚硅氧烷，其平均聚合度为3〜10,000。是具有1至18个碳原子的取代或未取代的一价烃基或含有醚键的有机基团，R 2是氢或具有1至21个碳原子的烃基。

8. 发明授权

US6077899A Process for production of rubber composition 失效
标题翻译：橡胶组合物生产工艺
公开(公告)号：US6077899A
公开(公告)日：2000-06-20
申请号：US952486
申请日：1997-11-19
申请人： Fumito Yatsuyanagi , Hiroyuki Kaido , Tetsuji Kawazura
发明人： Fumito Yatsuyanagi , Hiroyuki Kaido , Tetsuji Kawazura
IPC分类号： C08L15/00 , C08L9/06 , C08L9/00
CPC分类号： C08L15/00 , C08K3/04 , C08L9/00
摘要： (i) A starting rubber (A) comprising a terminal-modified and/or coupled diene rubber and having an average glass transition temperature TgA (.degree. C.) is mixed with a specific amount of the reinforcing agent are mixed at a temperature of at least 135.degree. C., followed by adding a starting rubber (B) comprising a terminal unmodified diene rubber and having a specific average glass transition temperature TgB (.degree. C.), and the remaining reinforcing agent and a softening agent; (ii) a starting diene rubber (A') having a specific weight average molecular weight Mw(A') and average glass transition temperature TgA' (.degree. C.) is contacted with a reinforcing agent, followed by adding a starting diene rubber (B') having a specific weight average molecular weight Mw(B) and average glass transition temperature TgB' (.degree. C.), and a softening agent to produce a rubber composition; or (iii) 100 parts by weight of a starting rubber comprising a starting rubber (A") comprising 20 to 100% by weight of a terminal-modified and/or coupled diene rubber and a starting rubber (B") comprising a terminal-unmodified and/or uncoupled rubber are mixed with a specific carbon black (X) in specific amounts at a temperature of at least 135.degree. C., followed by adding the starting rubber (B") and the remaining carbon black and a softening agent.
摘要翻译： PCT No.PCT / JP96 / 03635 Sec。 371日期：1997年11月19日 102（e）日期1997年11月19日PCT Filted 1996年12月12日PCT公布。第WO97 / 48766号公报日期1997年12月24日（i）将具有平均玻璃化转变温度TgA（℃）的末端改性和/或偶合二烯橡胶的起始橡胶（A）与特定量的增强剂混合在至少135℃的温度下混合，然后加入包含末端未改性二烯橡胶并具有比平均玻璃化转变温度TgB（℃）的起始橡胶（B），剩余的增强剂和软化代理人（ii）具有比重重均分子量Mw（A'）和平均玻璃化转变温度TgA'（℃）的起始二烯橡胶（A'）与增强剂接触，然后加入起始二烯橡胶（具有比重重均分子量Mw（B）和平均玻璃化转变温度TgB'（℃）的软化剂B'）和软化剂以产生橡胶组合物; 或（iii）100重量份的起始橡胶，其包含起始橡胶（A“），其包含20至100重量％的末端改性和/或偶合的二烯橡胶和起始橡胶（B”），其包含末端未改性和/或未偶联的橡胶与特定碳黑（X）在至少135℃的温度下以特定量混合，随后加入起始橡胶（B“）和剩余的炭黑和软化剂。

9. 发明授权

US08034868B2 Rubber composition containing modified conjugated diene-based polymer bonded to fullerene 失效
标题翻译：含有与富勒烯键合的改性共轭二烯类聚合物的橡胶组合物
公开(公告)号：US08034868B2
公开(公告)日：2011-10-11
申请号：US12406188
申请日：2009-03-18
申请人： Makoto Ashiura , Tetsuji Kawazura , Fumito Yatsuyanagi
发明人： Makoto Ashiura , Tetsuji Kawazura , Fumito Yatsuyanagi
IPC分类号： C08K3/04 , B60C1/00 , C08L23/18 , C08L23/26
CPC分类号： B82Y30/00 , B60C1/00 , C08L19/006
摘要： A rubber composition obtained by compounding thereinto a rubber component containing 0.5 to 100% by weight of a modified conjugated diene-based polymer having a fullerene bonded thereto in the molecule and having a weight average molecular weight of 50,000 or more excellent processability, superior balance of modulus and heat buildup, excellent cold flowability and superior tan δ balance.
摘要翻译：通过在分子中配合含有0.5〜100重量％的具有与其结合的富勒烯的改性共轭二烯系聚合物，重均分子量为50,000以上，优异的加工性的橡胶组合物，优异的平衡性模量和热积累，优异的冷流动性和优异的tanδ平衡。

10. 发明申请

US20060270784A1 Rubber composition containing modified conjugated diene-based polymer bonded to fullerene 审中-公开
标题翻译：含有与富勒烯键合的改性共轭二烯类聚合物的橡胶组合物
公开(公告)号：US20060270784A1
公开(公告)日：2006-11-30
申请号：US10553963
申请日：2004-04-28
申请人： Makoto Ashiura , Tetsuji Kawazura , Fumito Yatsuyanagi
发明人： Makoto Ashiura , Tetsuji Kawazura , Fumito Yatsuyanagi
IPC分类号： C08L9/00
CPC分类号： B82Y30/00 , B60C1/00 , C08L19/006
摘要： A rubber composition obtained by compounding thereinto a rubber component containing 0.5 to 100% by weight of a modified conjugated diene-based polymer having a fullerene bonded thereto in the molecule and having a weight average molecular weight of 50,000 or more excellent processability, superior balance of modulus and heat buildup, excellent cold flowability and superior tan δ balance.
摘要翻译：通过在分子中配合含有0.5〜100重量％的具有与其结合的富勒烯的改性共轭二烯系聚合物，重均分子量为50,000以上，优异的加工性的橡胶组合物，优异的平衡性模量和热积累，优异的冷流动性和优异的tanδ平衡。

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