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    • 5. 发明授权
    • Pigment dispersions containing dispersants prepared by controlled radical polymerization
    • 含有通过控制自由基聚合制备的分散剂的颜料分散体
    • US06326420B1
    • 2001-12-04
    • US09464947
    • 1999-12-16
    • Kevin C. OlsonSimion CocaJames B. O'DwyerKarl F. Schimmel
    • Kevin C. OlsonSimion CocaJames B. O'DwyerKarl F. Schimmel
    • C08L300
    • C09B67/009C09D17/001
    • A pigment dispersion which includes a pigment, an aqueous carrier and a pigment dispersant. The pigment dispersant is prepared by controlled radical polymerization initiated in the presence of a monomeric initiator having at least two radically transferable groups. The pigment dispersant has at least one of the following polymer chain structures: &phgr;-[(G)p—(E)s—T]z and &phgr;-[(E)3—(G)p—T]z where G is a hydrophobic residue of at least one radically polymerizable ethylenically unsaturated monomer; E is a hydrophilic residue of at least one radically polymerizable ethylenically unsaturated monomer; &phgr; is a residue of or derived from the initiator, and is free of the radically transferable group; T is or is derived from the radically transferable group of the initiator; z is 2 to 10; p and s are at least one and are selected such that the pigment dispersant has a number average molecular weight of at least 500.
    • 颜料分散体,其包含颜料,水性载体和颜料分散剂。 在具有至少两个可自由基转移基团的单体引发剂的存在下引发的受控自由基聚合来制备颜料分散剂。 颜料分散剂具有以下聚合物链结构中的至少一种:其中G是至少一个可自由基聚合的烯属不饱和单体的疏水残基; E是至少一种可自由基聚合的烯属不饱和单体的亲水性残基; phi是引发剂的残基或衍生自起始物,不含可自由基转移基团; T衍生自引发剂的可自由转移基团; z为2〜10; p和s是至少一个,并且被选择为使得颜料分散剂的数均分子量为至少500。
    • 6. 发明授权
    • Block copolymers
    • 嵌段共聚物
    • US06288173B1
    • 2001-09-11
    • US09325227
    • 1999-06-03
    • Karl F. SchimmelKaren A. BarkacKurt A. HumbertJonathan D. GoetzJames B. O'Dwyer
    • Karl F. SchimmelKaren A. BarkacKurt A. HumbertJonathan D. GoetzJames B. O'Dwyer
    • C08F29700
    • C08L53/00C08F293/005C09D153/00
    • Block copolymers containing at least two blocks are provided and comprise: (a) a first block containing residues of at least one first ethylenically unsaturated radically polymerizable monomer that is free of hydroxy functionality, e.g., 2-ethylhexyl methacrylate, and a minor amount of at least one hydroxy functional ethylenically unsaturated radically polymerizable monomer, e.g., hydroxypropyl methacrylate; and (b) a second block containing residues of at least one second ethylenically unsaturated radically polymerizable monomer that is free of hydroxy functionality, e.g., iso-butyl methacrylate, and a minor amount of at least one hydroxy functional ethylenically unsaturated radically polymerizable monomer. The calculated Tg of the second monomer of the block copolymer is at least 20° C. greater than the calculated Tg of the first monomer.
    • 提供含有至少两个嵌段的嵌段共聚物,其包含:(a)含有至少一种不含羟基官能团的至少一种第一烯属不饱和自由基可聚合单体的残基的第一嵌段,例如甲基丙烯酸2-乙基己基酯和少量的 至少一种羟基官能的烯属不饱和自由基聚合单体,例如甲基丙烯酸羟丙酯; 和(b)含有至少一种不含羟基官能团的第二烯属不饱和自由基可聚合单体残基的第二嵌段,例如甲基丙烯酸异丁酯和少量至少一种羟基官能烯属不饱和自由基聚合单体。 嵌段共聚物的第二单体的计算的Tg比第一单体的计算的Tg大至少20℃。