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1. 发明授权

US08067115B2 Non-aqueous electrolyte secondary battery 失效
标题翻译：非水电解质二次电池
公开(公告)号：US08067115B2
公开(公告)日：2011-11-29
申请号：US12030528
申请日：2008-02-13
申请人： Takayuki Shirane , Kaoru Inoue , Masaya Ugaji , Masato Fujikawa , Toshitada Sato
发明人： Takayuki Shirane , Kaoru Inoue , Masaya Ugaji , Masato Fujikawa , Toshitada Sato
IPC分类号： H01M4/13 , H01M4/58
CPC分类号： H01M10/0525 , H01M4/13 , H01M4/131 , H01M4/485 , H01M2004/027 , H01M2300/004
摘要： A non-aqueous electrolyte secondary battery comprising at least a negative electrode having a current collector provided thereon with convex portions and columnar bodies formed on the convex portions, each of the columnar bodies comprising n stages (where n≧2) of overlaid columnar body portions alternately tilted to different orientations along a longitudinal direction of the current collector, a positive electrode having a positive electrode current collector provided on both surfaces thereof with a positive electrode mixture layer containing a positive electrode active material capable of inserting and extracting lithium ions reversibly, and a separator interposed between the positive electrode and the negative electrode in a confronting manner, wherein tip portions of the columnar body portions at the uppermost stage of the columnar bodies on the negative electrode are tilted toward a trailing end of winding direction.
摘要翻译：本发明提供一种非水电解质二次电池，其至少包括具有集电体的至少具有凸部的集电体和形成在所述凸部上的柱状体的负极，每个所述柱状体包括重叠的柱状体部的n个阶段（n≥2）交替地沿着集电体的纵向方向倾斜到不同的取向，具有正极集电体的正电极在其两个表面上设置有包含能够可逆地插入和提取锂离子的正极活性材料的正电极混合物层，以及以相对的方式插入在正极和负极之间的隔板，其中在负极上的柱状体的最上段的柱状体部的末端部朝向卷绕方向的后端倾斜。

2. 发明申请

US20080193840A1 NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 失效
标题翻译：非水电解质二次电池
公开(公告)号：US20080193840A1
公开(公告)日：2008-08-14
申请号：US12030528
申请日：2008-02-13
申请人： Takayuki Shirane , Kaoru Inoue , Masaya Ugaji , Masato Fujikawa , Toshitada Sato
发明人： Takayuki Shirane , Kaoru Inoue , Masaya Ugaji , Masato Fujikawa , Toshitada Sato
IPC分类号： H01M4/02
CPC分类号： H01M10/0525 , H01M4/13 , H01M4/131 , H01M4/485 , H01M2004/027 , H01M2300/004
摘要： A non-aqueous electrolyte secondary battery comprising at least a negative electrode having a current collector provided thereon with convex portions and columnar bodies formed on the convex portions, each of the columnar bodies comprising n stages (where n≧2) of overlaid columnar body portions alternately tilted to different orientations along a longitudinal direction of the current collector, a positive electrode having a positive electrode current collector provided on both surfaces thereof with a positive electrode mixture layer containing a positive electrode active material capable of inserting and extracting lithium ions reversibly, and a separator interposed between the positive electrode and the negative electrode in a confronting manner, wherein tip portions of the columnar body portions at the uppermost stage of the columnar bodies on the negative electrode are tilted toward a trailing end of winding direction.
摘要翻译：本发明提供一种非水电解质二次电池，其至少包括具有设置在所述凸部上的集电体的集电体的负极和在所述凸部上形成的柱状体，所述柱状体包括重叠柱状体的n个阶段（n> = 2）沿着集电体的长度方向交替地倾斜到不同取向的部分，具有正极集电体的正极具有正极集电体，该正极集电体在其两面设置有含有能够可逆地插入和提取锂离子的正极活性物质的正极合剂层，以及相对于正极和负极之间插入的隔膜，其中负极上柱状体的最上段的柱状体部的末端部向卷绕方向的后端倾斜。

3. 发明申请

US20080193848A1 NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 失效
标题翻译：非水电解质二次电池
公开(公告)号：US20080193848A1
公开(公告)日：2008-08-14
申请号：US12030411
申请日：2008-02-13
申请人： Masato Fujikawa , Masaya Ugaji , Takayuki Shirane , Kaoru Inoue
发明人： Masato Fujikawa , Masaya Ugaji , Takayuki Shirane , Kaoru Inoue
IPC分类号： H01M4/58
CPC分类号： H01M10/0525 , H01M4/70 , H01M4/75 , H01M4/78
摘要： A non-aqueous electrolyte secondary battery comprising a negative electrode having a current collector provided with convex portions and concave portions on both surfaces, a first columnar body formed in a tilting orientation on the convex portion on one of the surfaces of the current collector, and a second columnar body formed in a tilting orientation on the convex portion on the other surface, a positive electrode having a positive electrode current collector provided with a positive electrode mixture layer containing a positive electrode active material capable of reversibly inserting and extracting lithium ions on both surfaces, and a separator interposed between the positive electrode and the negative electrode in a confronting manner, wherein the first columnar body and the second columnar body on the negative electrode are tilted to an orthogonal direction of a winding direction of the current collector.
摘要翻译：一种非水电解质二次电池，包括具有集电体的负极，所述集电器在两个表面上设置有凸部和凹部，在所述集电体的一个表面上的所述凸部上以倾斜取向形成的第一柱状体，以及在另一个表面的凸部上以倾斜取向形成的第二柱状体，具有正极集电体的正极，该正极集电体设置有包含能够在两者上可逆地插入和提取锂离子的正极活性物质的正极合剂层表面和以相对方式夹在正极和负极之间的隔膜，其中负极上的第一柱状体和第二柱状体沿着集电体的卷绕方向的正交方向倾斜。

4. 发明申请

US20070190408A1 Separator and method of manufacturing non-aqueous electrolyte secondary battery using the same 审中-公开
标题翻译：使用该非水电解质二次电池的分离器及其制造方法
公开(公告)号：US20070190408A1
公开(公告)日：2007-08-16
申请号：US11705417
申请日：2007-02-13
申请人： Kaoru Inoue , Masato Fujikawa , Takayuki Shirane
发明人： Kaoru Inoue , Masato Fujikawa , Takayuki Shirane
IPC分类号： H01M2/16 , H01M4/58
CPC分类号： H01M2/1646 , H01M2/1673 , H01M2/1686 , H01M4/131 , H01M4/1391 , H01M10/0525 , Y10T29/49108
摘要： A separator includes a porous sheet, a heat-resistant porous layer, and a metal lithium layer. The heat-resistant porous layer is provided on one of surfaces of the porous sheet. The metal lithium layer is provided on the surface of the heat-resistant porous layer. The separator is disposed between a negative electrode that includes an active material capable of reversibly storing and emitting lithium ions and having a theoretical capacity density of 400 mAh/g or higher, and a positive electrode capable of reversibly storing and emitting lithium ions, so that the metal lithium layer faces the negative electrode.
摘要翻译：隔膜包括多孔片，耐热多孔层和金属锂层。耐热多孔层设置在多孔片的一个表面上。金属锂层设置在耐热多孔层的表面上。分离器设置在包含能够可逆地存储和发射锂离子并具有400mAh / g以上的理论容量密度的活性物质的负极和能够可逆地存储和释放锂离子的正极之间，使得金属锂层面向负极。

5. 发明申请

US20070111102A1 Negative electrode for non-aqueous electrolyte secondary batteries, non-aqueous electrolyte secondary battery having the electrode, and method for producing negative electrode for non-aqueous electrolyte secondary batteries 审中-公开
标题翻译：非水电解质二次电池用负极，具有该电极的非水电解质二次电池及非水电解质二次电池用负极的制造方法
公开(公告)号：US20070111102A1
公开(公告)日：2007-05-17
申请号：US11529299
申请日：2006-09-29
申请人： Kaoru Inoue , Masato Fujikawa , Takayuki Shirane , Hiroaki Matsuda , Sumihito Ishida
发明人： Kaoru Inoue , Masato Fujikawa , Takayuki Shirane , Hiroaki Matsuda , Sumihito Ishida
IPC分类号： H01M4/62 , H01M4/58 , B05D5/12
CPC分类号： H01M4/483 , H01M4/362 , H01M4/587 , H01M4/62 , H01M10/052 , H01M2004/021 , H01M2004/027
摘要： A negative electrode for non-aqueous electrolyte secondary batteries has a mixture layer including a composite negative electrode active material which is composed of active material cores capable of charging and discharging at least lithium ions; carbon nanofibers; and catalyst elements. The carbon nanofibers are attached to the surfaces of the active material cores. The catalyst elements are at least one selected from the group consisting of copper, iron, cobalt, nickel, molybdenum, and manganese, and promote the growth of the carbon nanofibers. The active material cores have the carbon nanofibers therebetween.
摘要翻译：非水电解质二次电池用负极具有包含复合负极活性物质的混合层，所述复合负极活性物质由能够至少锂离子充放电的活性物质芯构成; 碳纳米纤维; 和催化剂元素。碳纳米纤维附着在活性物质芯的表面上。催化剂元素是选自铜，铁，钴，镍，钼和锰中的至少一种，并促进碳纳米纤维的生长。活性材料芯在其间具有碳纳米纤维。

6. 发明授权

US08048569B2 Non-aqueous electrolyte secondary battery 失效
标题翻译：非水电解质二次电池
公开(公告)号：US08048569B2
公开(公告)日：2011-11-01
申请号：US12030411
申请日：2008-02-13
申请人： Masato Fujikawa , Masaya Ugaji , Takayuki Shirane , Kaoru Inoue
发明人： Masato Fujikawa , Masaya Ugaji , Takayuki Shirane , Kaoru Inoue
IPC分类号： H01M4/13
CPC分类号： H01M10/0525 , H01M4/70 , H01M4/75 , H01M4/78
摘要： A non-aqueous electrolyte secondary battery comprising a negative electrode having a current collector provided with convex portions and concave portions on both surfaces, a first columnar body formed in a tilting orientation on the convex portion on one of the surfaces of the current collector, and a second columnar body formed in a tilting orientation on the convex portion on the other surface, a positive electrode having a positive electrode current collector provided with a positive electrode mixture layer containing a positive electrode active material capable of reversibly inserting and extracting lithium ions on both surfaces, and a separator interposed between the positive electrode and the negative electrode in a confronting manner, wherein the first columnar body and the second columnar body on the negative electrode are tilted to an orthogonal direction of a winding direction of the current collector.
摘要翻译：一种非水电解质二次电池，包括具有集电体的负极，所述集电器在两个表面上设置有凸部和凹部，在所述集电体的一个表面上的所述凸部上以倾斜取向形成的第一柱状体，以及在另一个表面的凸部上以倾斜取向形成的第二柱状体，具有正极集电体的正极，该正极集电体设置有包含能够在两者上可逆地插入和提取锂离子的正极活性物质的正极合剂层表面和以相对方式夹在正极和负极之间的隔膜，其中负极上的第一柱状体和第二柱状体沿着集电体的卷绕方向的正交方向倾斜。

7. 发明授权

US08102152B2 Deterioration detecting method and deterioration suppressing method for rechargeable lithium batteries, deterioration detector, deterioration suppressor, battery pack, and charger 有权
标题翻译：劣化检测方法和可再充电锂电池的劣化抑制方法，劣化检测器，劣化抑制器，电池组和充电器
公开(公告)号：US08102152B2
公开(公告)日：2012-01-24
申请号：US12161104
申请日：2008-01-09
申请人： Masaya Ugaji , Takayuki Shirane , Kaoru Inoue
发明人： Masaya Ugaji , Takayuki Shirane , Kaoru Inoue
IPC分类号： H02J7/00 , H01M10/48 , G01N27/416 , H01M2/24
CPC分类号： G01R31/3679 , G01R31/3665 , H01M4/134 , H01M10/052 , H01M10/0585 , H01M10/44 , H01M10/48
摘要： According to a deterioration detecting method for rechargeable lithium batteries, battery voltages of a rechargeable lithium battery before and after the completion of charging or discharging are measured. An evaluation value is calculated based on the measured battery voltages. This evaluation value is compared with a reference value of the rechargeable lithium battery stored in advance. A deterioration level of the rechargeable lithium battery is estimated based on this comparison result. In addition, further deterioration can be suppressed by controlling charging and discharging of the rechargeable lithium battery based on the estimated deterioration level.
摘要翻译：根据可再充电锂电池的劣化检测方法，测量在充电或放电完成之前和之后的可充电锂电池的电池电压。基于测量的电池电压计算评估值。该评价值与预先存储的可再充电锂电池的基准值进行比较。基于该比较结果估计可再充电锂电池的劣化程度。另外，通过基于估计的劣化水平控制可再充电锂电池的充电和放电，可以抑制进一步的劣化。

8. 发明申请

US20090123840A1 Non-Aqueous Electrolyte Secondary Battery 审中-公开
标题翻译：非水电解液二次电池
公开(公告)号：US20090123840A1
公开(公告)日：2009-05-14
申请号：US11792385
申请日：2006-12-14
申请人： Takayuki Shirane , Katsumi Kashiwagi , Kaoru Inoue
发明人： Takayuki Shirane , Katsumi Kashiwagi , Kaoru Inoue
IPC分类号： H01M4/02 , H01M4/38 , H01M4/48 , H01M10/40
CPC分类号： H01M10/0587 , H01M2/0222 , H01M4/131 , H01M4/134 , H01M4/1391 , H01M4/1395 , H01M4/382 , H01M4/483 , H01M4/587 , H01M4/62 , H01M4/625 , H01M4/70 , H01M10/052 , H01M2004/021 , H01M2004/025 , H01M2004/027
摘要： A non-aqueous electrolyte secondary battery includes a negative electrode, a positive electrode, and a non-aqueous electrolyte interposed therebetween. On at least one side of a current collector of the negative electrode, is formed a negative-electrode mixture layer containing an active material capable of storing and emitting at least lithium ions. The negative-electrode mixture layer has a plurality of mixture-layer expansion-absorbing grooves formed parallel to each other in such a manner as to expose the current collector. The mixture-layer expansion-absorbing grooves are formed in the position facing the positive-electrode mixture layer.
摘要翻译：非水电解质二次电池包括负极，正极和介于其间的非水电解质。在负极的集电体的至少一侧，形成含有能够至少存储和发射锂离子的活性物质的负极混合层。负极复合层具有以使露出集电体的方式彼此平行地形成的多个混合层膨胀吸收槽。混合层膨胀吸收槽形成在面对正极混合层的位置。

9. 发明授权

US09059475B2 Lithium secondary battery 有权
标题翻译：锂二次电池
公开(公告)号：US09059475B2
公开(公告)日：2015-06-16
申请号：US12439280
申请日：2008-01-10
申请人： Masaya Ugaji , Kaoru Inoue , Takayuki Shirane
发明人： Masaya Ugaji , Kaoru Inoue , Takayuki Shirane
IPC分类号： H01M10/052 , H01M4/13 , H01M4/134 , H01M4/1395 , H01M4/485 , H01M10/44 , H01M10/0525 , H01M4/02
CPC分类号： H01M10/052 , H01M4/134 , H01M4/1395 , H01M4/485 , H01M10/0525 , H01M10/44 , H01M2004/027 , Y02E60/122
摘要： A negative electrode of a lithium secondary battery has a negative electrode active material including at least one element of silicon and tin. Capacities of the positive electrode and the negative electrode of the lithium secondary battery are set as follows. In a completely charged state of the lithium secondary battery charged by a predetermined charging method, the positive electrode active material and the negative electrode active material are in a first partially charged state, respectively. In a completely discharged state of the lithium secondary battery discharged by a predetermined discharging method, the negative electrode active material is in a second partially charged state.
摘要翻译：锂二次电池的负极具有包含硅和锡的至少一种元素的负极活性物质。锂二次电池的正极和负极的容量设定如下。在通过预定充电方法充电的锂二次电池的完全充电状态下，正极活性物质和负极活性物质分别处于第一部分充电状态。在通过预定的放电方法放电的锂二次电池的完全放电状态下，负极活性物质处于第二部分充电状态。

10. 发明申请

US20090317721A1 NON-AQUEOUS ELECTROLYTE SECONDARY BATTERY 失效
标题翻译：非水电解质二次电池
公开(公告)号：US20090317721A1
公开(公告)日：2009-12-24
申请号：US12064307
申请日：2007-08-31
申请人： Takayuki Shirane , Kaoru Inoue , Masaya Ugaji
发明人： Takayuki Shirane , Kaoru Inoue , Masaya Ugaji
IPC分类号： H01M4/58
CPC分类号： H01M10/0525 , H01M4/13 , H01M4/134 , H01M4/1395 , H01M2004/021
摘要： A non-aqueous electrolyte secondary battery has at least negative electrode, a positive electrode, and a separator between the positive electrode and negative electrode. Negative electrode has columnar first negative electrode active materials that are discretely formed on the outer peripheral surface of negative electrode current collector in the winding direction and can reversibly insert and extract lithium ions, and columnar second negative electrode active materials discretely formed on the inner peripheral surface. The positive electrode has positive electrode mixture layers containing a positive electrode active material capable of reversibly inserting and extracting lithium ions, on both surfaces of a positive electrode current collector. The difference between the porosity generated between first negative electrode active materials in negative electrode and that generated between the second negative electrode active materials in winding is set within 1.1%.
摘要翻译：非水电解质二次电池在正极和负极之间至少具有负极，正极和隔板。负极具有柱状的第一负极活性物质，其沿着卷绕方向离散地形成在负极集电体的外周面上，并且能够可逆地插入和提取锂离子，并且离散地形成在内周面上的柱状第二负极活性物质。正极具有在正极集电体的两面上含有可逆地插入和提取锂离子的正极活性物质的正极合剂层。在负极中的第一负极活性物质和绕组中的第二负极活性物质之间产生的孔隙率之间的差设定在1.1％以内。

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