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1. 发明授权

US5746916A Microporous membrane made of non-crystalline polymers and method of producing the same 失效
标题翻译：由非结晶聚合物制成的微孔膜及其制造方法
公开(公告)号：US5746916A
公开(公告)日：1998-05-05
申请号：US377706
申请日：1995-01-25
申请人： Jun Kamo , Seiya Koyanagi , Miho Kawai
发明人： Jun Kamo , Seiya Koyanagi , Miho Kawai
IPC分类号： B01D67/00 , B01D69/02 , B01D71/64 , B01D71/68 , B01D33/21 , B29C65/00
CPC分类号： B01D67/0088 , B01D67/0027 , B01D67/003 , B01D69/02 , B01D69/08 , B01D71/64 , B01D71/68 , B01D2323/12 , B01D2323/30 , B01D2325/36
摘要： A microporous membrane made of a non-crystalline polymer having, within its wall, microfibrils and slit-like micropores which are oriented in the lengthwise direction of the membrane, said slit-like micropores communicating from one surface to the other surface of the membrane, and forming a stacked construction. This membrane has a high flux value of AFR and WFR, excellent heat-, solvent-, and pressure-resistance, and a high mechanical strength, and does not contain any undesirable materials which eluate during use. This membrane is thus useful as a multi-purpose separation membrane, such as for medical uses, food industries, purification of water or air, and the separation of hot liquids.
摘要翻译：由非晶体聚合物构成的微多孔膜在其壁内具有在膜的长度方向上定向的微原纤维和狭缝状微孔，所述狭缝状微孔从膜的一个表面连通到另一个表面，并形成堆叠结构。该膜具有高的AFR和WFR通量值，具有优异的耐热性，耐溶剂性和耐压性，并且具有高机械强度，并且在使用过程中不含任何不希望的洗脱液。因此，该膜可用作多用途分离膜，例如用于医疗用途，食品工业，水或空气净化以及热液体的分离。

2. 发明授权

US06316548B1 (Meth)acrylic premix, (meth)acrylic SMC or BMC, and process producing (meth)acrylic artificial marble 失效
标题翻译：（甲基）丙烯酸类预混物，（甲基）丙烯酸系SMC或BMC，以及（甲基）丙烯酸类人造大理石的制造方法
公开(公告)号：US06316548B1
公开(公告)日：2001-11-13
申请号：US09418362
申请日：1999-10-14
申请人： Seiya Koyanagi , Katsumi Yonekura , Shinji Saiki , Kentaro Hayashi , Yuichiro Kishimoto
发明人： Seiya Koyanagi , Katsumi Yonekura , Shinji Saiki , Kentaro Hayashi , Yuichiro Kishimoto
IPC分类号： C08L3306
CPC分类号： C04B26/06 , C04B2111/545 , C08F265/06 , Y10S525/902 , C04B40/0071 , C04B40/0082 , C08F2/02
摘要： A (meth)acrylic premix comprising a (meth)acrylic resin composition (A) containing a (meth)acrylic monomer (a) and a (meth)acrylic polymer (b), an inorganic filler (B), and a curing agent (C), wherein, the component (a) is a (meth)acrylate having a bicyclo ring, fluorine atom, cyclic ether, cyclohexane ring or tricyclo ring, and the component (C) is a radical polymerization initiator having a 10 hours half-life temperature of 75° C. or more; an acrylic SMC or BMC comprising this (meth)acrylic premix and a thickening agent; and a method for producing (meth)acrylic artificial marble, wherein this (meth)acrylic SMC or BMC is cured with being pressurized and heated at a temperature in the range from 105 to 150° C., are provided. These are useful for producing (meth)acrylic artificial marble having various excellent physical properties such as appearance, dimension stability, hot water resistance, weatherability.
摘要翻译：包含（甲基）丙烯酸系单体（a）和（甲基）丙烯酸系聚合物（b）的无机填料（B）和固化剂（甲基）丙烯酸系单体 C），其中，（a）成分为具有双环，（氟原子），环状醚，环己烷环或三环的（甲基）丙烯酸酯，（C）成分为半衰期为10小时的自由基聚合引发剂，生活温度75℃以上; 包含该（甲基）丙烯酸类预混物的丙烯酸SMC或BMC和增稠剂; 和（甲基）丙烯酸类人造大理石的制造方法，其中，所述（甲基）丙烯酸系SMC或BMC在105〜150℃的温度下被加压和加热而固化。这些可用于生产具有各种优异物理性质（如外观，尺寸稳定性，耐热水性，耐候性）的（甲基）丙烯酸人造大理石。

3. 发明授权

US06265467B1 Acrylic SMC or BMC, production thereof, method for producing acrylic artificial marble, and thickening agent 失效
标题翻译：丙烯酸SMC或BMC，其制备方法，丙烯酸人造大理石的制造方法和增稠剂
公开(公告)号：US06265467B1
公开(公告)日：2001-07-24
申请号：US09537284
申请日：2000-03-29
申请人： Seiya Koyanagi , Katsumi Yonekura , Shinji Saiki , Kentaro Hayashi , Yoshihito Nakahara , Yuichiro Kishimoto
发明人： Seiya Koyanagi , Katsumi Yonekura , Shinji Saiki , Kentaro Hayashi , Yoshihito Nakahara , Yuichiro Kishimoto
IPC分类号： C08K300
CPC分类号： C08J5/00 , B29C47/0019 , B29C47/1027 , B29C47/1045 , B29C47/1081 , B29C47/364 , B29C47/366 , B29C47/367 , B29C47/369 , B29C47/38 , B29C70/50 , B29K2033/04 , B29K2033/12 , B29K2105/06 , B29K2105/16 , C08J2333/06 , C08J2351/00
摘要： An acrylic SMC or BMC, in which when a polymer powder (C) having a bulk density in the range from 0.1 to 0.7 g/ml, an oil absorption of lin-seed oil in the range from 60 to 200 mi/100 g, a degree of swelling by methyl methacrylate is 16-fold or more and a specific surface area in the range from 1 to 100 m2/g is added as a thickening agent, hot water resistance is improved by using a polymer powder (C1) containing no surfactant, a polymer powder (C2) containing as a constituent component a reactive surfactant, or thickening speed is controlled by using a non-cross linked polymer powder (C3) having a Mw from 100,000 to 2,500,000, a non-crosslinked polymer powder (C4) having a Ma from 2,500,000 to 5,000,000, a crosslinked polymer powder (C5) and a polymer powder (D) having a specific surface area from 0.01 m2/g to 1 m2/g; a production method thereof; a method for producing acrylic artificial marble in which components are extruded by a kneading extruder (9) into given shape; and a thickening agent.
摘要翻译：丙烯酸类SMC或BMC，其中当体积密度为0.1- 0.7g / ml的聚合物粉末（C），林籽油的吸油量为60-200ml / 100g时，甲基丙烯酸甲酯的溶胀度为16倍以上，作为增稠剂添加1〜100m 2 / g的比表面积，通过使用不含有高分子粉末（C1）的聚合物粉末表面活性剂，含有作为构成成分的反应性表面活性剂的聚合物粉末（C2）或增稠速度通过使用Mw为100,000〜2,500,000的非交联聚合物粉末（C3），非交联聚合物粉末（C4 ）具有2,500,000至5,000,000的Ma，交联聚合物粉末（C5）和比表面积为0.01m 2 / g至1m 2 / g的聚合物粉末（D）; 其制造方法; 制造丙烯酸类人造大理石的方法，其中通过捏合挤出机（9）将组分挤出成为给定形状; 和增稠剂。

4. 发明授权

US06451910B1 Acrylic premix, acrylic artificial marble and production method thereof 失效
标题翻译：丙烯酸预混料，丙烯酸人造大理石及其制备方法
公开(公告)号：US06451910B1
公开(公告)日：2002-09-17
申请号：US09698046
申请日：2000-10-30
申请人： Seiya Koyanagi , Shinji Saiki , Yuichiro Kishimoto
发明人： Seiya Koyanagi , Shinji Saiki , Yuichiro Kishimoto
IPC分类号： C08K511
CPC分类号： C04B26/06 , C04B2111/545 , C08F222/1006 , C08F222/20 , C08F290/062 , C04B14/06 , C04B14/22 , C04B14/28 , C04B14/303 , C04B18/022 , C04B40/0259 , C04B40/0263
摘要： An acrylic premix comprising 10 to 90% by weight of (A) an acrylic resin composition consisting of an acrylic mono-functional monomer (a1), an acrylic poly-functional monomer (a2) containing at least one compound represented by any of the following general formulae (I) to (IV), and an acrylic polymer (b); 10 to 90% by weight of an inorganic filler (B); and 0.01 to 10 parts by weight of a curing agent (C) based on 100 parts by weight of the total amount of the components (A) and (B); acrylic artificial marble using the same; and a method for producing the same. The premix is useful for providing an acrylic SMC or BMC having excellent molding property at high temperature, molding processability, thickening property and storage stability.
摘要翻译：一种丙烯酸类预混物，其包含10至90重量％的（A）由丙烯酸单官能单体（a1），含有至少一种由以下任何一种表示的化合物的丙烯酸多官能单体（a2）组成的丙烯酸树脂组合物通式（I）〜（IV）和丙烯酸类聚合物（b）; 10〜90重量％的无机填料（B）; 和基于100重量份的组分（A）和（B）的总量的固化剂（C）为0.01至10重量份; 丙烯酸人造大理石使用相同; 及其制造方法。预混物可用于提供在高温下具有优异成型性能，成型加工性，增稠性和储存稳定性的丙烯酸系SMC或BMC。

5. 发明授权

US06323259B1 Acrylic resin composition, acrylic premix, process for producing acrylic artificial marble and thickening agent 失效
标题翻译：丙烯酸树脂组合物，丙烯酸预混物，丙烯酸人造大理石和增稠剂的制备方法
公开(公告)号：US06323259B1
公开(公告)日：2001-11-27
申请号：US09174152
申请日：1998-10-19
申请人： Yukihiro Ikegami , Seiya Koyanagi , Yuichiro Kishimoto , Yoshihito Nakahara
发明人： Yukihiro Ikegami , Seiya Koyanagi , Yuichiro Kishimoto , Yoshihito Nakahara
IPC分类号： C08F22020
CPC分类号： C08F265/06 , C04B26/06 , C04B2111/00129 , C04B2111/545 , C08F285/00 , Y10S525/934 , Y10S526/909 , Y10S526/932 , C04B16/04 , C04B40/00 , C04B40/0259 , C04B40/0263 , C04B2103/0047 , C04B2103/0058 , C08F2/02 , C08F220/14
摘要： The present invention is directed to an acrylic resin composition obtained by adding a non-crosslinked polymer powder having a bulk density within the range from 0.1 to 0.7 g/ml, an oil absorption based on linseed oil within the range from 60 to 200 ml/100 g and a degree of swelling by methyl methacrylate of 16-fold or more as a thickening agent to acrylic syrup; and acrylic premix obtained by mixing an inorganic filler with this composition; and acrylic premix obtained by extruding constituent components by a kneading extruder to continuously form the mixture; and a method for producing an acrylic artificial marble in which these acrylic premixes are cured.
摘要翻译：本发明涉及一种丙烯酸树脂组合物，其通过将堆积密度在0.1〜0.7g / ml范围内的非交联聚合物粉末，基于亚麻籽油的吸油率在60〜200ml / 100g，甲基丙烯酸甲酯为16倍以上，作为增稠剂使丙烯酸浆液膨胀的程度; 和通过将无机填料与该组合物混合而获得的丙烯酸类预混物; 丙烯酸类预混物，通过捏合挤出机挤出构成成分而连续地形成混合物; 以及这些丙烯酸类预混物固化的丙烯酸类人造大理石的制造方法。

6. 发明授权

US5356754A Crosslinking curable resin composition 失效
标题翻译：交联固化性树脂组合物
公开(公告)号：US5356754A
公开(公告)日：1994-10-18
申请号：US950500
申请日：1992-09-25
申请人： Kenji Kushi , Ken-ichi Inukai , Takayuki Iseki , Seiya Koyanagi
发明人： Kenji Kushi , Ken-ichi Inukai , Takayuki Iseki , Seiya Koyanagi
IPC分类号： C08G65/332 , G03F7/027 , G03F7/033 , G03C1/73
CPC分类号： C08G65/3322 , G03F7/027 , G03F7/033 , C08G2650/16 , C08G2650/20 , C08L2312/00
摘要： A photopolymerizable or radiation polymerizable alkaline developing crosslinking curable resin composition possessing superior antiplating properties and a short stripping period, in which the stripped plate is not easily dissolved in the stripping fluid, and which is comprising:(a) 5-30 parts by weight of at least one compound possessing in one molecule on the average 1.5 or more (meth)acryloyloxy groups, which is obtained by reacting (meth)acrylic acid with a reaction product formed by adding, to a polyatomic alcohol possessing 3 or more OH groups in one molecule, an alkylene oxide containing propylene oxide in an amount of 67% molar or greater in an amount of 5-12 moles per mole of OH group in the aforementioned polyatomic alcohol,(b) 5-30 parts by weight of at least one crosslinkable monomer other than that stated above in (a) , possessing in one molecule 2 or more ethylenically unsaturated groups,(c) 45-75 parts by weight of a thermoplastic polymer for use as a binder, the thermoplastic polymer in turn being formed of 15-35 wt % of at least one .alpha., .beta.-unsaturated carboxyl group containing a monomer having 3-15 carbon atoms, and 65-85 wt % of another copolymerizable monomer, and(d) 0-10 parts by weight of a photopolymerization initiator.
摘要翻译：一种可光聚合或可辐照聚合的碱性显影交联可固化树脂组合物，其具有优异的抗剥落性能和短的剥离时间，其中剥离板不容易溶解在剥离液中，并且其包含：（a）5-30重量份至少一种在一个分子中具有平均1.5个或更多个（甲基）丙烯酰氧基的化合物，其通过使（甲基）丙烯酸与通过在一个具有3个或更多个OH基团的多原子醇中加入形成的反应产物分子，在上述多原醇中每摩尔OH基团为5-12摩尔量的67摩尔％以上的环氧丙烷的环氧烷烃，（b）5-30重量份的至少一种可交联的具有上述（a）中所述的单体，在一个分子中具有2个或更多个烯属不饱和基团，（c）45-75重量份用作粘合剂的热塑性聚合物，其它另外，塑性聚合物又由15-35重量％的至少一种含有3-15个碳原子的单体的α，β-不饱和羧基和65-85重量％的另一个可共聚单体形成，和（d）0- 10重量份的光聚合引发剂。

7. 发明授权

US5149776A Cross-linking hardenable resin composition, metal laminates thereof and metal surface processing method therewith 失效
标题翻译：交联的可再生树脂组合物，其金属层压材料和金属表面处理方法
公开(公告)号：US5149776A
公开(公告)日：1992-09-22
申请号：US614123
申请日：1990-11-16
申请人： Kenji Kushi , Ken-ichi Inukai , Takayuki Iseki , Seiya Koyanagi , Yasuyuki Fujimoto
发明人： Kenji Kushi , Ken-ichi Inukai , Takayuki Iseki , Seiya Koyanagi , Yasuyuki Fujimoto
IPC分类号： C08F2/44 , C08F2/48 , C09D4/00 , C09D133/04 , C09D133/08 , G03F7/033
CPC分类号： G03F7/033
摘要： A photopolymerizing cross-linking hardenable resin composition is disclosed which is comprised of a binder resin, cross-linking monomer and photopolymerization initiator. The composition of each of the above mentioned components is such that dry film resist incorporating the resin composition of the present invention and used in processes for selective etching and plating of printed circuit boards can be developed in weak aqueous alkaline solution after selective exposure to light. In this way, the efficient and economical manufacture of high definition printed circuit boards is made possible. Additionally, dry film resist incorporating the photopolymerizing cross-linking hardenable resin composition of the present invention lends to easy handling and storage characteristics.

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