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1. 发明授权

US07790646B2 Conversion of fine catalyst into coke-like material 有权
标题翻译：细催化剂转化为焦炭状材料
公开(公告)号：US07790646B2
公开(公告)日：2010-09-07
申请号：US12004032
申请日：2007-12-20
申请人： Jose Guitian Lopez , Christopher A. Powers , Donald H. Mohr
发明人： Jose Guitian Lopez , Christopher A. Powers , Donald H. Mohr
IPC分类号： B01J38/02 , B01J38/72 , C22B61/00
CPC分类号： C22B7/009 , C10B57/045 , C10G21/00 , C10G21/003 , C22B3/14 , C22B7/008 , C22B23/026 , C22B34/225 , C22B34/345 , Y02P10/214 , Y02P10/224 , Y02P10/23 , Y02P10/234
摘要： A process for converting fine catalyst slurried in heavy oil into a coke-like material from which catalytic metals can be recovered comprises mixing fine catalyst slurried in heavy oil with solvent, which causes asphaltenes in the heavy oil to precipitate from the heavy oil; separating fine catalyst and precipitated asphaltenes from the heavy oil and solvent; and converting precipitated asphaltenes to a coke-like material by pyrolizing fine catalyst and precipitated asphaltenes separated from the heavy oil.
摘要翻译：将重油中成浆状的细催化剂转化为可回收催化金属的焦炭状材料的方法包括将重质油中制备的细催化剂与溶剂混合，使重质油中的沥青质从重油中沉淀出来; 从重油和溶剂中分离出细小的催化剂和沉淀的沥青质; 并将沉淀的沥青质通过热解细小的催化剂和从重油分离的沉淀的沥青质将沉淀的沥青质转化为焦炭状物质。

2. 发明授权

US07737068B2 Conversion of fine catalyst into coke-like material 有权
标题翻译：细催化剂转化为焦炭状材料
公开(公告)号：US07737068B2
公开(公告)日：2010-06-15
申请号：US12003218
申请日：2007-12-20
申请人： Christopher A. Powers , Donald H. Mohr , Bruce E. Reynolds , Jose Guitian Lopez
发明人： Christopher A. Powers , Donald H. Mohr , Bruce E. Reynolds , Jose Guitian Lopez
IPC分类号： B01J38/02 , B01J38/72
CPC分类号： C10B55/00 , C10B57/005 , C22B7/009 , C22B23/026 , C22B34/225 , C22B34/345 , Y02P10/214 , Y02P10/224 , Y02P10/23
摘要： A process for recovering catalytic metals from fine catalyst slurried in heavy oil comprises pyrolizing fine catalyst slurried in heavy oil to provide one or more lighter oil products and a coke-like material and recovering catalytic metals from the coke-like material.
摘要翻译：用于从重油中制备的细催化剂中回收催化金属的方法包括在重油中制备浆料中的热解微细催化剂以提供一种或多种较轻的油产物和焦炭状物质，并从焦炭状物质回收催化金属。

3. 发明申请

US20090163352A1 Conversion of fine catalyst into coke-like material 有权
标题翻译：细催化剂转化为焦炭状材料
公开(公告)号：US20090163352A1
公开(公告)日：2009-06-25
申请号：US12003218
申请日：2007-12-20
申请人： Christopher A. Powers , Donald H. Mohr , Bruce E. Reynolds , Jose Guitian Lopez
发明人： Christopher A. Powers , Donald H. Mohr , Bruce E. Reynolds , Jose Guitian Lopez
IPC分类号： B01J38/02
CPC分类号： C10B55/00 , C10B57/005 , C22B7/009 , C22B23/026 , C22B34/225 , C22B34/345 , Y02P10/214 , Y02P10/224 , Y02P10/23
摘要： A process for recovering catalytic metals from fine catalyst slurried in heavy oil comprises pyrolizing fine catalyst slurried in heavy oil to provide one or more lighter oil products and a coke-like material and recovering catalytic metals from the coke-like material.
摘要翻译：用于从重油中制备的细催化剂中回收催化金属的方法包括在重油中制备浆料中的热解微细催化剂以提供一种或多种较轻的油产物和焦炭状物质，并从焦炭状物质回收催化金属。

4. 发明申请

US20090159491A1 Conversion of fine catalyst into coke-like material 有权
标题翻译：细催化剂转化为焦炭状材料
公开(公告)号：US20090159491A1
公开(公告)日：2009-06-25
申请号：US12004032
申请日：2007-12-20
申请人： Jose Guitian Lopez , Christopher A. Powers , Donald H. Mohr
发明人： Jose Guitian Lopez , Christopher A. Powers , Donald H. Mohr
IPC分类号： C10C3/00
CPC分类号： C22B7/009 , C10B57/045 , C10G21/00 , C10G21/003 , C22B3/14 , C22B7/008 , C22B23/026 , C22B34/225 , C22B34/345 , Y02P10/214 , Y02P10/224 , Y02P10/23 , Y02P10/234
摘要： A process for converting fine catalyst slurried in heavy oil into a coke-like material from which catalytic metals can be recovered comprises mixing fine catalyst slurried in heavy oil with solvent, which causes asphaltenes in the heavy oil to precipitate from the heavy oil; separating fine catalyst and precipitated asphaltenes from the heavy oil and solvent; and converting precipitated asphaltenes to a coke-like material by pyrolizing fine catalyst and precipitated asphaltenes separated from the heavy oil.
摘要翻译：将重油中成浆状的细催化剂转化为可回收催化金属的焦炭状材料的方法包括将重质油中制备的细催化剂与溶剂混合，使重油中的沥青质从重油中沉淀出来; 从重油和溶剂中分离出细小的催化剂和沉淀的沥青质; 并将沉淀的沥青质通过热解细小的催化剂和从重油分离的沉淀的沥青质将沉淀的沥青质转化为焦炭状物质。

5. 发明授权

US06702937B2 Process for upgrading Fischer-Tropsch products using dewaxing and hydrofinishing 失效
标题翻译：使用脱蜡和加氢精加工提升费 - 托产品的方法
公开(公告)号：US06702937B2
公开(公告)日：2004-03-09
申请号：US10068927
申请日：2002-02-08
申请人： David R. Johnson , Christopher A. Simmons , Donald H. Mohr , Stephen J. Miller , Stephen K. Lee
发明人： David R. Johnson , Christopher A. Simmons , Donald H. Mohr , Stephen J. Miller , Stephen K. Lee
IPC分类号： C10G6902
CPC分类号： C10G65/043 , C10G2400/10
摘要： A process for producing low pour point diesel and lubricating base oil products by bulk dewaxing a C5 plus Fischer-Tropsch syncrude, hydrofinishing the dewaxed intermediate, and recovering 120 degrees C. plus products having improved properties.
摘要翻译：通过大量脱蜡C5加费托合成油，对脱蜡中间体进行加氢精制，回收120℃加上具有改进性能的产品，生产低倾点柴油和润滑基础油产品的方法。

6. 发明授权

US4851380A Process for regenerating sulfur contaminated reforming catalysts 失效
标题翻译：再生硫污染重整催化剂的方法
公开(公告)号：US4851380A
公开(公告)日：1989-07-25
申请号：US80111
申请日：1987-07-31
申请人： Dean A. Van Leirsburg , Donald H. Mohr , Paul W. Tamm , Robert L. Jacobson , Thomas R. Hughes , Charles R. Wilson
发明人： Dean A. Van Leirsburg , Donald H. Mohr , Paul W. Tamm , Robert L. Jacobson , Thomas R. Hughes , Charles R. Wilson
IPC分类号： B01J29/035 , B01J29/90 , C10G11/02 , C10G35/095
CPC分类号： C10G35/095 , B01J29/90 , Y10S502/517
摘要： The present invention is a process for regenerating a sulfur-contaminated, highly selective, large-pore zeolite catalyst. It comprises a multistep process involving exposure of the catalyst to a combination of oxidizing conditions, reducing conditions and treatment with a halogen acid gas. These conditions are effective to agglomerate a Group VIII metal and remove sulfur. Thereafter, the catalyst is oxychlorinated to redisperse the Group VIII metal over the catalyst surface. A carbon removal step is optionally included.
摘要翻译：本发明是一种再生含硫污染的高选择性大孔沸石催化剂的方法。它包括一个多步骤过程，包括将催化剂暴露于氧化条件的组合，还原条件和用卤酸气处理。这些条件对于聚集第Ⅷ族金属并除去硫是有效的。此后，催化剂被氧氯化以将VIII族金属重新分散在催化剂表面上。任选地包括碳去除步骤。

7. 再颁专利

USRE34250E Process for regenerating sulfur contaminated reforming catalysts 失效
公开(公告)号：USRE34250E
公开(公告)日：1993-05-11
申请号：US733704
申请日：1991-07-22
申请人： Dean A. Van Leirsburg , Donald H. Mohr , Paul W. Tamm , Robert L. Jacobson , Thomas R. Hughes , Charles R. Wilson
发明人： Dean A. Van Leirsburg , Donald H. Mohr , Paul W. Tamm , Robert L. Jacobson , Thomas R. Hughes , Charles R. Wilson
IPC分类号： B01J29/90 , B01J38/18 , B01J38/42 , C10G35/095
CPC分类号： B01J38/18 , B01J29/90 , B01J38/42 , C10G35/095
摘要： The present invention is a process for regenerating a sulfur-contaminated, highly selective, large-pore zeolite catalyst. It comprises a multistep process involving exposure of the catalyst to a combination of oxidizing conditions, reducing conditions and treatment with a halogen acid gas. These conditions are effective to agglomerate a Group VIII metal and remove sulfur. Thereafter, the catalyst is oxychlorinated to redisperse the Group VIII metal over the catalyst surface. A carbon removal step is optionally included.

8. 发明授权

US4830732A Reforming using a bound zeolite catalyst 失效
标题翻译：使用结合的沸石催化剂进行重整
公开(公告)号：US4830732A
公开(公告)日：1989-05-16
申请号：US141657
申请日：1988-01-07
申请人： Donald H. Mohr , Charles R. Wilson , Albert S. Behan , Robert L. Chiang , Mark T. Staniulis
发明人： Donald H. Mohr , Charles R. Wilson , Albert S. Behan , Robert L. Chiang , Mark T. Staniulis
IPC分类号： B01J29/60 , B01J29/50 , B01J29/62 , C10G35/06 , C10G35/085 , C10G35/095
CPC分类号： C10G35/095 , B01J29/62 , B01J2229/26 , B01J2229/42
摘要： Reforming to produce aromatics from aliphatics, using a bound zeolite catalyst containing a Group VIII metal such as platinum, has been found to be extremely sensitive to water, even at water concentrations as low as 3 ppm in the feed, unless certain catalysts having a low water sensitivity index are used. The water sensitivity index (WSI) is described and methods for making catalysts with a low WSI are described. The sulfur content of the feed to the reforming/aromatics production process is preferably below 50 parts per billion. The catalyst used in the reforming process is preferably a high crush strength catalyst and is preferably prepared by steps including treating L zeolite with a binding enhancement agent prior to binding with a binder such as silica, silica/alumina or alumina.
摘要翻译：已经发现使用含有VIII族金属如铂的结合的沸石催化剂从脂肪族产生芳族化合物，即使在进料中的低至3ppm的水浓度下，对水也非常敏感，除非某些催化剂具有低的使用水敏感指数。描述了水敏感指数（WSI），并描述了制备低WSI催化剂的方法。重整/芳烃生产过程的进料的硫含量优选低于50ppm。在重整过程中使用的催化剂优选是高抗压强度催化剂，并且优选通过以下步骤制备，所述步骤包括在与粘合剂如二氧化硅，二氧化硅/氧化铝或氧化铝结合之前用结合增强剂处理L沸石。

9. 发明授权

US06703535B2 Process for upgrading fischer-tropsch syncrude using thermal cracking and oligomerization 失效
标题翻译：使用热裂解和低聚提升费 - 托合成原料的方法
公开(公告)号：US06703535B2
公开(公告)日：2004-03-09
申请号：US10125879
申请日：2002-04-18
申请人： David R. Johnson , Christopher A. Simmons , Donald H. Mohr , Stephen J. Miller , Stephen K. Lee , William L. Schinski , Michael S. Driver , William J. Cannella
发明人： David R. Johnson , Christopher A. Simmons , Donald H. Mohr , Stephen J. Miller , Stephen K. Lee , William L. Schinski , Michael S. Driver , William J. Cannella
IPC分类号： C07C204
CPC分类号： C10G2/32 , Y10S208/95
摘要： A process for upgrading a Fischer-Tropsch feedstock which comprises (a) recovering from a Fischer-Tropsch reactor a Fischer-Tropsch wax fraction and a Fischer-Tropsch condensate fraction, wherein the Fischer-Tropsch condensate fraction contains alcohols boiling below about 370° C.; (b) contacting the Fischer-Tropsch condensate fraction with a dehydration catalyst in a dehydration zone under dehydration conditions pre-selected to convert at least some of the alcohols present in said fraction into olefins and recovering a first intermediate effluent from said dehydration zone; (c) pyrolyzing the paraffins in the Fischer-Tropsch wax fraction in a thermal cracking zone under thermal cracking conditions pre-selected to crack the Fischer-Tropsch wax molecules to form olefins and collecting a second intermediate effluent from the thermal cracking zone; (d) passing the first and second intermediate effluents recovered from steps (b) and (c) to an oligomerization zone containing an oligomerization catalyst under oligomerization conditions to form an oligomerization mixture having a higher molecular weight than either of said first and second intermediate effluent; (e) hydrofinishing the oligomerization mixture in a hydrofinishing zone; and (f) recovering from the hydrofinishing zone a C10 plus hydrocarbon product, most preferably a lubricating base oil.
摘要翻译：一种用于升级费 - 托原料的方法，其包括（a）从费 - 托反应器中回收费 - 托蜡馏分和费 - 托冷凝馏分，其中所述费 - 托冷凝馏分含有沸点低于约370℃的醇。（b）在脱水条件下，将脱水催化剂与脱水催化剂接触，预先将所述馏分中存在的至少一些醇转化成烯烃并从所述脱水区回收第一中间体流出物; （c）在热裂解条件下，在热裂解条件下热分解费 - 托蜡馏分中的链烷烃，预热裂解条件以裂解费 - 托蜡分子以形成烯烃并从热裂解区收集第二中间体流出物; （d）在低聚条件下将从步骤（b）和（c）回收的第一和第二中间流出物通入含有低聚催化剂的低聚区以形成具有比所述第一和第二中间流出物 ; （e）在加氢精制区中加氢精制低聚混合物; 和（f）从加氢精制区回收C10加烃产物，最优选润滑基础油。

10. 发明授权

US5106803A Reforming using a bound zeolite catalyst 失效
标题翻译：使用结合的沸石催化剂进行重整
公开(公告)号：US5106803A
公开(公告)日：1992-04-21
申请号：US352399
申请日：1989-05-15
申请人： Donald H. Mohr , Charles P. Wilson , Albert S. Behan , Robert L. Chiang , Mark T. Staniulis
发明人： Donald H. Mohr , Charles P. Wilson , Albert S. Behan , Robert L. Chiang , Mark T. Staniulis
IPC分类号： B01J29/62 , B01J29/72 , C10G35/095
CPC分类号： C10G35/095 , B01J29/62 , B01J2229/26 , B01J2229/42
摘要： Reforming to produce aromatics from aliphatics, using a bond zeolite catalyst containing a Group VIII metal such as platinum, has been found to be extremely sensitive to water, even at water concentrations as low as 3 ppm in the feed, unless certain catalysts having a low water sensitivity index are used. The water sensitivity index (WSI) is described and methods for making catalysts with a low WSI are described. The sulfur content of the feed to the reforming/aromatics production process is preferably below 50 parts per billion. The catalysts used in the reforming process is preferably a high crush strength catalyst and is preferably prepared by steps including treating L zeolite with a binding enhancement agent prior to binding with a binder such as silica, silica/alumina or alumina.
摘要翻译：已经发现使用含有VIII族金属如铂的键沸石催化剂从脂肪族产生芳族化合物，甚至在进料中的低至3ppm的水浓度下，对水是非常敏感的，除非某些催化剂具有低使用水敏感指数。描述了水敏感指数（WSI），并描述了制备低WSI催化剂的方法。重整/芳烃生产过程的进料的硫含量优选低于50ppm。在重整过程中使用的催化剂优选是高抗压强度催化剂，并且优选通过以下步骤制备，包括在与粘合剂例如二氧化硅，二氧化硅/氧化铝或氧化铝结合之前用结合增强剂处理L沸石。

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