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1. 发明授权

US4349520A Continuous hydrolysis of ketoxime 失效
标题翻译：连续水解酮肟
公开(公告)号：US4349520A
公开(公告)日：1982-09-14
申请号：US295347
申请日：1981-08-24
申请人： John H. Bonfield , Stylianos Sifniades , Harry E. Ulmer
发明人： John H. Bonfield , Stylianos Sifniades , Harry E. Ulmer
IPC分类号： C01B21/14 , C07C45/00 , C07C45/42 , C07C49/04 , C07C49/385 , C07C67/00
CPC分类号： C01B21/1454 , C01B21/1409 , C07C45/42
摘要： A mixture of ketoxime such as methyl ethyl ketone oxime (MEKO), an inorganic acid such as sulfuric acid and optionally water is fed to an intermediate point of a fractional distillation column. Steam is fed to the base of the column and operating conditions are sufficient to produce the corresponding ketone (e.g. methyl ethyl ketone) or its water azeotrope as the overhead product and the corresponding hydroxylammonium salt (e.g. the sulfate) as the bottoms. Crystallization of the salt from the bottoms leaves a mother liquor which may be recycled to a reboiler from which the steam is generated.
摘要翻译：将诸如甲基乙基酮肟（MEKO），无机酸如硫酸和任选的水的酮肟的混合物进料到分馏塔的中间点。将蒸汽进料到塔的底部，并且操作条件足以产生相应的酮（例如甲基乙基酮）或其作为塔顶产物的水共沸物和相应的羟基铵盐（例如硫酸盐）作为塔底产物。盐从底部的结晶离开母液，可以将其再循环到再沸器中，蒸发生成。

2. 发明授权

US4705904A Vapor phase synthesis of hexafluoroisobutylene 失效
公开(公告)号：US4705904A
公开(公告)日：1987-11-10
申请号：US820896
申请日：1986-01-17
申请人： John H. Bonfield , Harry E. Ulmer
发明人： John H. Bonfield , Harry E. Ulmer
IPC分类号： C07C17/26 , C07C45/58 , C07D303/48
CPC分类号： C07D303/48 , C07C17/26 , C07C45/58
摘要： A vapor phase synthesis of hexafluoroisobutylene, which comprises contacting in the vapor phase in a catalyst zone, B, of a reactor hexafluoropropylene oxide with a fluorinated catalyst such as fluorinated silica-alumina at a temperature of about 400.degree.-600.degree. C. for a residence time sufficient to form a vapor stream comprising hexafluoroacetone which is thereafter directly contacted in a heating zone of the reactor with a vapor stream comprising a keytone-generating compound such as acetic anhydride at a temperature of about 500.degree.-700.degree. C. for a residence time sufficient to form a stream comprising hexafluoroisobutylene, substantially-free of perfluoroisobutylene and recovering the hexafluoroisobutylene product is disclosed. A direct one reactor vapor phase synthesis of hexafluoroisobutylene which comprises (a) contacting, in the vapor phase, hexafluoropropene with less than a stoichiometric amount of oxygen required to convert substantially all the hexafluoroisopropene into hexafluoropropylene oxide in the presence of a fluorinated catalyst such as fluorinated silica-alumina at a temperature of about 400.degree.-600.degree. C. for a time sufficient to form a vapor stream comprising hexafluoropropylene oxide substantially-free of oxygen; (b) directly contacting said vapor stream, in a catalyst zone, B, containing a fluorinated catalyst which is preferably the same as used in catalyst zone, A, at a temperature of about 400.degree.-650.degree., preferably about 500.degree.-650.degree. C. for a time sufficient to form a vapor stream comprising hexafluoroacetone; (c) directly contacting the vapor stream comprising hexafluroacetone with a vaporized compound such as acetic anhydride at a temperature of about 500.degree.-700.degree. C., preferably about 600.degree. C. for a time sufficient to form a vapor stream comprising hexafluoroisobutylene, substantially-free of perfluoroisobutylene; and (d) recovering hexafluoroisobutylene is also disclosed.

3. 发明授权

US5190565A Sulfonated 2-(2'-hydroxyaryl)-2H-benzotriazoles and/or sulfonated aromatic formaldehyde condensates and their use to improve stain resistance and dye lightfasteness 失效
标题翻译：磺化的2-（2'-羟基芳基）-2H-苯并三唑和/或磺化的芳族甲醛缩合物及其用于改善耐污染性和染料耐光性
公开(公告)号：US5190565A
公开(公告)日：1993-03-02
申请号：US650400
申请日：1991-02-01
申请人： Morris B. Berenbaum , John H. Bonfield , Charles J. Cole , Paul W. Harris , Thomas P. J. Izod , Harry E. Ulmer , Frederick R. Hopf , James T. Yardley , Karen M. Bland
发明人： Morris B. Berenbaum , John H. Bonfield , Charles J. Cole , Paul W. Harris , Thomas P. J. Izod , Harry E. Ulmer , Frederick R. Hopf , James T. Yardley , Karen M. Bland
IPC分类号： C07D249/20 , D06M13/256 , D06M13/352 , D06M13/355 , D06M15/41 , D06P1/56 , D06P1/642
CPC分类号： C07D249/20 , D06M13/256 , D06M13/352 , D06M13/355 , D06M15/412 , D06P1/56 , D06P1/6426 , D06M2101/34 , Y10S8/924
摘要： A new class of sulfonated 2-(2'-hydroxyaryl)-2H-benzotriazole compounds and method for using them and other sulfonated hydroxyaryl benzotriazoles on nylon fibers to improve stain resistance and dye lightfastness has been discovered. A process is provided for improving stain resistance of nylon fibers by treatment with sulfonated aromatic-formaldehyde condensate and fluorinated dry soil resist agents.
摘要翻译：已经发现了一类新的磺化2-（2'-羟基芳基）-2H-苯并三唑化合物及其在尼龙纤维上的使用及其它磺化羟基芳基苯并三唑的方法，以提高耐污染性和耐染色性。提供了一种通过用磺化芳族 - 甲醛缩合物和氟化干土抗蚀剂处理来改善尼龙纤维的耐污性的方法。

4. 发明授权

US4990623A Sulfonated 2-(2'-hydroxyaryl)-2H-benzotriazoles and/or sulfonated aromatic formaldehyde condensates 失效
标题翻译：磺化2-（2'-羟基芳基）-2H-苯并三唑和/或磺化芳族甲醛缩合物
公开(公告)号：US4990623A
公开(公告)日：1991-02-05
申请号：US384234
申请日：1989-07-24
申请人： Morris B. Berenbaum , John H. Bonfield , Charles J. Cole , Paul W. Harris , Thomas P. J. Izod , Harry E. Ulmer , Frederick R. Hopf , James T. Yardley , Karen M. Bland
发明人： Morris B. Berenbaum , John H. Bonfield , Charles J. Cole , Paul W. Harris , Thomas P. J. Izod , Harry E. Ulmer , Frederick R. Hopf , James T. Yardley , Karen M. Bland
IPC分类号： C07D249/20 , D06M13/256 , D06M13/352 , D06M13/355 , D06M15/41 , D06P1/56 , D06P1/642
CPC分类号： C07D249/20 , D06M13/256 , D06M13/352 , D06M13/355 , D06M15/412 , D06P1/56 , D06P1/6426 , D06M2101/34
摘要： A new class of sulfonated 2-(2'-hydroxyaryl)-2H-benzotriazole compounds and method for using them and other sulfonated hydroxyaryl benzotriazoles on nylon fibers to improve stain resistance and dye lightfastness has been discovered. A process is provided for improving stain resistance of nylon fibers by treatment with sulfonated aromatic-formaldehyde condensate and fluorinated dry soil resist agents.
摘要翻译：已经发现了一类新的磺化2-（2'-羟基芳基）-2H-苯并三唑化合物及其在尼龙纤维上的使用及其它磺化羟基芳基苯并三唑的方法，以提高耐污染性和耐染色性。提供了一种通过用磺化芳族 - 甲醛缩合物和氟化干土抗蚀剂处理来改善尼龙纤维的耐污性的方法。

5. 发明授权

US4237069A Production of alpha-hydroxy oximes 失效
标题翻译：生产α-羟基肟
公开(公告)号：US4237069A
公开(公告)日：1980-12-02
申请号：US54205
申请日：1979-07-02
申请人： Harry E. Ulmer , Chempolil T. Mathew
发明人： Harry E. Ulmer , Chempolil T. Mathew
IPC分类号： C07C251/34 , C07C67/00 , C07C239/00 , C07C131/00
CPC分类号： C07C249/08
摘要： An alpha-halo-aldehyde is reacted in aqueous media with an hydroxylamine-generating reagent at a pH between about 2 and about 9 to form the corresponding alpha-hydroxy-oxime. The products are useful as stabilizers and as complexing agents and as intermediates to unsaturated oximes, unsaturated nitriles and carbamate-type pesticides.
摘要翻译：在含水介质中的α-卤代醛与产生羟胺的试剂在约2至约9之间的pH下反应以形成相应的α-羟基 - 肟。该产品可用作稳定剂和络合剂以及作为不饱和肟，不饱和腈和氨基甲酸酯类农药的中间体。

6. 发明授权

US4407783A Producing silane from silicon tetrafluoride 失效
标题翻译：从四氟化硅生产硅烷
公开(公告)号：US4407783A
公开(公告)日：1983-10-04
申请号：US408408
申请日：1982-08-16
申请人： Harry E. Ulmer , Donald Pickens , Forrest J. Rahl , Philip A. Lefrancois
发明人： Harry E. Ulmer , Donald Pickens , Forrest J. Rahl , Philip A. Lefrancois
IPC分类号： C10M101/00 , C01B33/04
CPC分类号： C01B33/043
摘要： Silicon tetrafluoride is reacted with sodium hydride in a cyclic ether reaction medium such as tetrahydrofuran or 1,4-dioxane or in dimethoxyethane. Sodium aluminum hydride is dissolved in the solvent and catalyzes the reaction in amounts of 4-25%, by weight of combined sodium hydride and sodium aluminum hydride.
摘要翻译：四氟化硅与氢化钠在环醚反应介质如四氢呋喃或1,4-二恶烷或二甲氧基乙烷中反应。将氢化铝钠溶解在溶剂中，以4-25％（重量）的氢化钠和氢化钠铝的量催化反应。

7. 发明授权

US4380660A Producing alkoxysilanes and alkoxy-oximinosilanes 失效
标题翻译：生产烷氧基硅烷和烷氧基 - 肟基硅烷
公开(公告)号：US4380660A
公开(公告)日：1983-04-19
申请号：US394353
申请日：1982-07-01
申请人： Chempolil T. Mathew , Harry E. Ulmer
发明人： Chempolil T. Mathew , Harry E. Ulmer
IPC分类号： C07F7/04 , C07F7/08 , C07F7/18 , C07F7/10
CPC分类号： C07F7/188 , C07F7/0892
摘要： A silicon halide such as methyl trichlorosilane is reacted with an alcohol such as isopropanol and an oxime such as methyl ethyl ketone oxime. Byproduct oxime hydrohalide is formed in all cases. With higher amounts of alcohol, alkoxysilane (e.g. methyl triisopropoxysilane) is the sole or major product. With lower amounts of alcohol, alkoxy-oxminosilanes (e.g. methyl diisopropoxy(methyl ethyl ketoximo)silane and methyl isopropoxy bis(methyl ethyl ketoximo)silane) are the major products.
摘要翻译：将诸如甲基三氯硅烷的卤化硅与醇如异丙醇和肟如甲基乙基酮肟反应。在所有情况下都形成副产物肟氢卤化物。对于较高量的醇，烷氧基硅烷（例如甲基三异丙氧基硅烷）是唯一的或主要的产物。使用较少量的醇，烷氧基 - 恶臭硅烷（例如甲基二异丙氧基（甲基乙基酮肟基）硅烷和甲基异丙氧基双（甲基乙基酮肟基）硅烷）是主要产物。

8. 发明授权

US4187386A Cyclization of 1,5-hexadiene to cyclohexene 失效
标题翻译： 1,5-己二烯环化成环己烯
公开(公告)号：US4187386A
公开(公告)日：1980-02-05
申请号：US974397
申请日：1978-12-29
申请人： George D. Lockyer, Jr. , Dennis E. Burd , Richard F. Sweeney , Bernard Sukornick , Harry E. Ulmer
发明人： George D. Lockyer, Jr. , Dennis E. Burd , Richard F. Sweeney , Bernard Sukornick , Harry E. Ulmer
IPC分类号： C07C5/31 , C07C13/20
CPC分类号： C07C5/31
摘要： 1,5-Hexadiene is cyclized to cyclohexene by contacting 1,5-hexadiene with a mixture of a first catalyst selected from the group consisting of chromium oxides, chromium chlorides, chromium bromides, molybdenum oxides, molybdenum chlorides, molybdenum bromides, tungsten oxides, tungsten chlorides, tungsten bromides, iron oxides, cobalt oxides, nickel oxides, elemental sulfur, SiO.sub.2, Al.sub.2 O.sub.3, vanadium metal, vanadium oxides, VOF.sub.3, and mixtures thereof, and a second catalyst selected from a tin (IV) halide and mixtures thereof.
摘要翻译：通过使1,5-己二烯与选自铬氧化物，氯化铬，溴化铬，氧化钼，氯化钼，溴化钼，氧化钨等的第一种催化剂的混合物接触，将1,5-己二烯环化成环己烯，氯化钨，溴化钨，氧化铁，氧化钴，氧化镍，元素硫，SiO 2，Al 2 O 3，钒金属，氧化钒，VOF 3及其混合物，以及选自卤化锡（IV）及其混合物的第二种催化剂。

9. 发明授权

US4551323A Preparation of alcoholic hydroxylamine solution from hydroxylammonium sulfate 失效
公开(公告)号：US4551323A
公开(公告)日：1985-11-05
申请号：US437920
申请日：1982-11-01
申请人： Chempolil T. Mathew , Harry E. Ulmer
发明人： Chempolil T. Mathew , Harry E. Ulmer
IPC分类号： C01B21/14 , C07C51/41 , C07C67/00 , C07C239/00 , C07C251/32 , C07C259/06
CPC分类号： C07C51/412 , C01B21/1445 , C01B21/1454
摘要： Solid hydroxylammonium sulfate is reacted with an alcohol solution of an alkali metal hydroxide or alkoxide to produce an alcoholic hydroxylamine liquid phase and a sulfate-containing solid phase. The liquid phase may be used for further reactions such as oxidations, hydroxamic acid production or neutralization to other hydroxylammonium salts. The different bases behave differently with regard to suitable and preferable solvents and temperatures.

10. 发明授权

US4203923A Method for promotion of phenol hydrogenation 失效
标题翻译：苯酚氢化促进方法
公开(公告)号：US4203923A
公开(公告)日：1980-05-20
申请号：US667760
申请日：1976-03-17
申请人： Chuen Y. Yeh , Harry E. Ulmer
发明人： Chuen Y. Yeh , Harry E. Ulmer
IPC分类号： C07C29/20 , C07C45/00 , C07C41/00
CPC分类号： C07C29/20 , C07C45/006 , C07C2101/14
摘要： A method for promoting the hydrogenation of phenol to cyclohexanone in the presence of a non-promoted palladium catalyst which comprises effecting the hydrogenation reaction in the presence of an in situ promoter selected from the group consisting of alkalie metal and alkaline earth metal chlorides, fluorides, bicarbonates, carbonates, hydroxides and nitrates, ammonia, ammonium hydroxide, secondary amines and mixtures thereof.
摘要翻译：一种在非促进的钯催化剂存在下促进苯酚氢化成环己酮的方法，该方法包括在存在选自碱金属和碱土金属氯化物，氟化物的原位促进剂的情况下进行氢化反应，碳酸氢盐，碳酸盐，氢氧化物和硝酸盐，氨，氢氧化铵，仲胺及其混合物。

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