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    • 5. 发明授权
    • Fluorescent compounds for use in industrial water systems
    • 用于工业水系统的荧光化合物
    • US06358746B1
    • 2002-03-19
    • US09436189
    • 1999-11-08
    • Barbara E. MoriartyJerry L. Reddinger
    • Barbara E. MoriartyJerry L. Reddinger
    • G01N3700
    • C07D471/04G01N33/1826Y10T436/12Y10T436/13
    • Fluorescent compounds of the formula: wherein R1 and R2 are either both SO3M, or one of R1 and R2 is SO3M and the other is COOM, where M is selected from the group consisting of H, Na, K, Rb, Cs, Li or ammonium, are described and claimed. These inert flurorescent compounds have been found to be resistant to oxidizing biocides. One process for making these compounds is described and claimed as the condensation between a 1,8-naphthalic anhydride possessing the desired functionalities and the appropriately substituted o-phenylene diamine. Alternatively, o-amino-nitro-aromatics may be condensed with the various 1,8-naphthalic anhydrides when the in situ reduction of the nitro group is accomplished with a suitable reducing agent such as iron powder. The resulting fluorescent compounds can be used as inert fluorescent tracers in industrial water systems.
    • 下式的荧光化合物:其中R 1和R 2都是SO 3 M,或者R 1和R 2中的一个是SO 3 M,另一个是COOM,其中M选自H,Na,K,Rb,Cs,Li或 铵,被描述和要求保护。 已发现这些惰性荧光化合物对氧化杀生物剂具有抗性。 一种制备这些化合物的方法被描述和要求保护为具有所需官能度的1,8-萘二甲酸酐与适当取代的邻苯二胺之间的缩合。 或者,当硝基的原位还原用合适的还原剂如铁粉末完成时,邻氨基 - 硝基 - 芳族化合物可与各种1,8-萘二酸酐缩合。 所得荧光化合物可用作工业水系统中的惰性荧光示踪剂。
    • 7. 发明授权
    • Autocycle control of cooling water systems
    • 自动循环控制冷却水系统
    • US06280635B1
    • 2001-08-28
    • US09562603
    • 2000-05-01
    • Barbara E. MoriartyDennis P. BakalikRonald V. DavisJohn E. HootsRobert W. Shiely
    • Barbara E. MoriartyDennis P. BakalikRonald V. DavisJohn E. HootsRobert W. Shiely
    • C02F100
    • G01N17/008C02F1/008C02F5/08C02F2103/023C02F2209/40C02F2303/08C02F2303/20G01N33/18G01N33/1853G01N33/1866Y10T137/0329
    • An autocycle method to control a cooling water system comprising the steps of: a) adding a treatment product to said cooling water system, with said treatment product comprising inert tracer and tagged treatment polymer in a set proportion; b) providing a sufficient number of fluorometers, c) using said sufficient number of fluorometers to measure the fluorescent signal of said inert tracer and the fluorescent signal of said tagged treatment polymer in the water from the cooling water system; d) using these measured fluorescent signals from step c) to determine the amount of said tagged treatment polymer present in said cooling water system; e) comparing the amount of said tagged treatment polymer present to the amount of tagged treatment polymer being fed into the system to determine the consumption of said tagged treatment polymer; and f) using said consumption of said tagged treatment polymer to control the concentration cycles of said cooling water system, with the proviso that said control is implemented by linking any or all of the following parameters i) the flowrate of the make-up water to the cooling water system; ii) the flowrate of the treatment product comprising inert tracer and tagged treatment polymer, iii) frequency and amount of blowdown flowrate from the cooling water system; iv) overall water flowrate through the cooling tower; v) overall volume of water in the cooling tower; and vi) composition of makeup water; to the consumption of said tagged treatment polymer, with the provisos that: &agr;) the minimum flowrate of treatment product comprising inert tracer and tagged treatment polymer must be sufficient to supply the cooling water system with the requisite amount of tagged treatment product; and &bgr;) when control is implemented by linking flowrates, the flowrates are balanced.
    • 一种用于控制冷却水系统的自动循环方法,包括以下步骤:a)向所述冷却水系统中加入处理产物,所述处理产物包含惰性示踪剂和标记处理聚合物,其设定比例; b)提供足够数量的荧光计 c)使用所述足够数量的荧光计测量来自冷却水系统的所述惰性示踪剂的荧光信号和所述标记的处理聚合物的荧光信号; d)使用来自步骤c)的这些测量的荧光信号来确定 存在于所述冷却水体系中的所述标记的处理聚合物的量; e)将所述标记的处理聚合物的存在量与进料到系统中的标记处理聚合物的量进行比较,以确定所述标记的处理聚合物的消耗; 以及f)使用所述标记的处理聚合物的所述消耗来控制所述冷却水系统的浓缩循环,条件是通过将补充水的流量与冷却水的任何或全部连接来实现所述控制 水系统; ii)包含惰性示踪剂和标记处理聚合物的处理产品的流量,iii)来自冷却水系统的排放流量的频率和量; iv)通过冷却塔的总体水流量; v)总体积的水 冷却塔; 和)维生素水的组成;对所述标记的处理聚合物的消耗,条件是:α)包含惰性示踪剂和带标签的处理聚合物的处理产物的最小流速必须足以向冷却水系统提供必需量的 标记治疗产品; andbeta)当通过连接流量来实现控制时,流量平衡。