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1. 发明授权

US4895755A Halogenated advanced epoxy resins 失效
标题翻译：卤化高级环氧树脂
公开(公告)号：US4895755A
公开(公告)日：1990-01-23
申请号：US259449
申请日：1988-10-14
申请人： Jody R. Berman , Chun S. Wang , Louis L. Walker , Abel Mendoza
发明人： Jody R. Berman , Chun S. Wang , Louis L. Walker , Abel Mendoza
IPC分类号： C07C37/62 , C07D303/24 , C08G59/06 , C08G59/30 , C08G59/32 , H05K1/03
CPC分类号： C08G59/30 , C07C37/62 , C07D303/24 , C08G59/066 , C08G59/3218 , H05K1/0326 , Y10T428/31522 , Y10T428/31529 , Y10T442/2434 , Y10T442/2992
摘要： Advanced epoxy resins are disclosed which result from the reaction of a relatively low molecular weight epoxy resin and a polyhydric phenol wherein at least one of the reactants contains at least one halogen atom which is meta with respect to a glycidyl ether group or a hydroxyl group attached to an aromatic ring. These advanced epoxy resins, when cured with a suitable curing agent, possess an improvement as compared to an advanced epoxy resin containing halogen atoms which are ortho with respect to a glycidyl ether group in at least one of thermal stability, glass transition temperature, relationship of viscosity to molecular weight and resistance to forming hydrolyzed halides in the presence of a refluxing solution of an alkali metal hydroxide.
摘要翻译：公开了先进的环氧树脂，其由相对低分子量的环氧树脂和多元酚的反应产生，其中至少一种反应物含有至少一个相对于缩水甘油醚基团或羟基的元素的卤素原子到一个芳香环。这些先进的环氧树脂在用适当的固化剂固化时具有改进，与在热稳定性，玻璃化转变温度，玻璃化转变温度的关系中，相对于缩水甘油基醚基相邻的卤素原子的先进环氧树脂相比，在碱金属氢氧化物的回流溶液存在下，粘度对分子量和耐水解卤化物的抗性。

2. 发明授权

US4727119A Halogenated epoxy resins 失效
标题翻译：卤化环氧树脂
公开(公告)号：US4727119A
公开(公告)日：1988-02-23
申请号：US907706
申请日：1986-09-15
申请人： Jody R. Berman , Chun S. Wang , Louis L. Walker , Abel Mendoza
发明人： Jody R. Berman , Chun S. Wang , Louis L. Walker , Abel Mendoza
IPC分类号： C08G59/14 , C07C37/62 , C07D303/24 , C08G59/06 , C08G59/30 , C08G59/32 , C08L63/00 , H05K1/03
CPC分类号： C07D303/24 , C07C37/62 , C08G59/066 , C08G59/30 , C08G59/3218 , H05K1/0326
摘要： Halogenated aromatic epoxy resins are disclosed wherein the halogen atoms are in the meta position with respect to a glycidyl ether group attached to an aromatic ring.Advanced epoxy resins are disclosed which result from the reaction of a relatively low molecular weight epoxy resin and a polyhydric phenol wherein at least one of the reactants contains at least one halogen atom which is meta with respect to a glycidyl ether group or a hydroxyl group attached to an aromatic ring. These advanced epoxy resins, when cured with a suitable curing agent, possess an improvement as compared to an advanced epoxy resin containing halogen atoms which are ortho with respect to a glycidyl ether group in at least one of thermal stability, glass transition temperature, relationship of viscosity to molecular weight and resistance to forming hydrolyzed halides in the presence of a refluxing solution of an alkali metal hydroxide.
摘要翻译：公开了卤化芳族环氧树脂，其中卤素原子相对于连接到芳族环上的缩水甘油醚基团处于间位。公开了先进的环氧树脂，其由相对低分子量的环氧树脂和多元酚的反应产生，其中至少一种反应物含有至少一个相对于缩水甘油醚基团或羟基的元素的卤素原子到一个芳香环。这些先进的环氧树脂在用适当的固化剂固化时具有改进，与在热稳定性，玻璃化转变温度，玻璃化转变温度的关系中，相对于缩水甘油基醚基相邻的卤素原子的先进环氧树脂相比，在碱金属氢氧化物的回流溶液存在下，粘度对分子量和耐水解卤化物的抗性。

3. 发明授权

US4684700A Advanced epoxy resins prepared from triglycidyl ethers and dihydri phenols 失效
标题翻译：由三缩水甘油醚和二氢苯酚制备的先进环氧树脂
公开(公告)号：US4684700A
公开(公告)日：1987-08-04
申请号：US829364
申请日：1986-02-14
申请人： Chun S. Wang , Wuu N. Chen , Robert L. Bowden , Jody R. Berman
发明人： Chun S. Wang , Wuu N. Chen , Robert L. Bowden , Jody R. Berman
IPC分类号： C08G59/06 , C08G59/14 , C08G59/62 , H01B3/40 , C08G59/32
CPC分类号： H01B3/40 , C08G59/066 , Y10S428/901 , Y10T428/24917 , Y10T428/31511
摘要： Advanced epoxy resin products are prepared by reacting a triglycidyl ether of a trihydric phenol such as the triglycidyl ether of 1,1,1-tri(hydroxyphenyl)methane with a dihydric phenol such as bisphenol A. These advanced epoxy resins are non-sintering solid resins useful in the preparation of electrical potting or molding compositions.
摘要翻译：先进的环氧树脂产物是通过三元酚的三缩水甘油醚（如1,1,1-三羟基苯基）甲烷的三缩水甘油醚与双酚A等二元酚反应来制备的。这些先进的环氧树脂是非烧结固体可用于制备电灌封或模塑组合物的树脂。

4. 发明授权

US5028668A Adducts of metabrominated phenols and polyfunctional epoxides 失效
标题翻译：代谢酚和多官能环氧化物的加合物
公开(公告)号：US5028668A
公开(公告)日：1991-07-02
申请号：US549177
申请日：1990-07-06
申请人： Chun S. Wang , Abel Mendoza
发明人： Chun S. Wang , Abel Mendoza
IPC分类号： C07D303/24 , C08G59/14 , C08G59/36 , H01B3/40 , H01L23/29
CPC分类号： C07D303/24 , C08G59/1444 , C08G59/145 , C08G59/36 , H01B3/40 , H01L23/293 , H01L2924/0002
摘要： Adducts of metabrominated monophenols such as 3,5-dibromo-2,4,6-trimethylphenol and multifunctional epoxides such as cresol-formaldehyde epoxy novolac resins are disclosed to be useful in formulations for encapsulating electronic components.
摘要翻译：公开了代谢溴化单酚如3,5-二溴-2,4,6-三甲基苯酚和多官能环氧化物如甲酚 - 甲醛环氧酚醛清漆树脂的加合物，用于封装电子部件的制剂中。

5. 发明授权

US4892925A Process for preparing phenolic hydroxyl-containing compounds from 2,6-dibromo-3,5-dialkyl-4-hydroxybenzyl ethers 失效
标题翻译：从2,6-二溴-3,5-二烷基-4-羟基苄基醚制备含酚羟基化合物的方法
公开(公告)号：US4892925A
公开(公告)日：1990-01-09
申请号：US300460
申请日：1989-01-23
申请人： Chun S. Wang , Abel Mendoza , David B. Fritz
发明人： Chun S. Wang , Abel Mendoza , David B. Fritz
IPC分类号： C07D303/22 , C07C43/23 , C07D303/27 , C08G59/06 , C08G59/14 , C08G59/30 , C08G59/40 , C08K7/04 , C08L63/00
CPC分类号： C07C43/23 , C08G59/066 , C08G59/30
摘要： 2,6-dibromo-3,5-dialkyl-4-hydroxybenzyl ethers, glycidyl ethers thereof and reaction products with phenolic hydroxyl-containing compounds, and glycidyl ethers of the resulting new phenolic hydroxyl-containing compounds.

6. 发明授权

US4731423A Meta-halo-phenolic alkylation products and epoxy systems 失效
标题翻译：元 - 卤酚烷基化产物和环氧体系
公开(公告)号：US4731423A
公开(公告)日：1988-03-15
申请号：US896480
申请日：1986-08-13
申请人： Abel Mendoza , Chun S. Wang , Eric E. Bancroft , David B. Fritz
发明人： Abel Mendoza , Chun S. Wang , Eric E. Bancroft , David B. Fritz
IPC分类号： C07D215/16 , C07C39/367 , C07C39/38 , C07C39/42 , C07C211/52 , C07C235/16 , C07C235/88 , C07C271/28 , C07C271/30 , C07D217/02 , C07D237/28 , C08F8/20 , C08G8/28 , C08G59/02 , C08G59/08 , C08G59/30 , C08G59/36 , C08G64/42 , C08G59/06 , C07C39/12
CPC分类号： C07C39/42 , C07C39/367 , C08G59/08 , C08G59/30
摘要： Titled materials and their preparation. The materials contain a moiety such as, for example, 4-oxy-3,5-dimethyl-2,6-dibromobenzyl which can impart a high degree of thermal and hydrolytic stability to the materials, for example, epoxy thermosets such as in electronic encapsulations. For example, when used in electronic encapsulation formulations, these materials can provide a substantial increase in electronic device reliability. Their preparation involves an alkylation of an aromatic ring, for example, such as a Friedel-Crafts alkylation with 4-bromomethyl-3,5-dibromo-2,6-dimethylphenol or with 4-hydroxymethyl-3,5-dibromo-2,6-dimethylphenol.

7. 发明授权

US4975500A Adducts of metabrominated phenols and polyfunctional epoxides 失效
公开(公告)号：US4975500A
公开(公告)日：1990-12-04
申请号：US440149
申请日：1989-11-22
申请人： Chun S. Wang , Abel Mendoza
发明人： Chun S. Wang , Abel Mendoza
IPC分类号： C07D303/24 , C08G59/14 , C08G59/36 , H01B3/40 , H01L23/29
CPC分类号： H01B3/40 , C07D303/24 , C08G59/1444 , C08G59/145 , C08G59/36 , H01L23/293 , H01L2924/0002
摘要： Adducts of metabrominated monophenols such as 3,5-dibromo-2,4,6-trimethylphenol and multifunctional epoxides such as cresol-formaldehyde epoxy novolac resins are disclosed to be useful in formulations for encapsulating electronic components.

8. 发明授权

US4914185A Adducts of metabrominated phenols and polyfunctional epoxides 失效
公开(公告)号：US4914185A
公开(公告)日：1990-04-03
申请号：US851996
申请日：1986-04-14
申请人： Chun S. Wang , Abel Mendoza
发明人： Chun S. Wang , Abel Mendoza
IPC分类号： C07D303/24 , C08G59/00 , C08G59/04 , C08G59/14 , C08G59/18 , C08G59/20 , C08G59/36 , C08K5/13 , C08L63/00 , H01B3/40 , H01L23/29 , H01L23/31
CPC分类号： C08G59/145 , C07D303/24 , C08G59/1444 , C08G59/36 , H01B3/40 , H01L23/293 , H01L2924/0002
摘要： Adducts of metabrominated monophenols such as 3,5-dibromo-2,4,6-trimethylphenol and multifunctional epoxides such as cresol-formaldehyde epoxy novolac resins are disclosed to be useful in formulations for encapsulating electronic components.

9. 发明授权

US5098963A Adducts of metabrominated phenols and polyfunctional epoxides 失效
标题翻译：代谢酚和多官能环氧化物的加合物
公开(公告)号：US5098963A
公开(公告)日：1992-03-24
申请号：US652845
申请日：1991-02-08
申请人： Chun S. Wang , Abel Mendoza
发明人： Chun S. Wang , Abel Mendoza
IPC分类号： C07D303/24 , C08G59/14 , C08G59/36 , H01B3/40 , H01L23/29
CPC分类号： C08G59/145 , C07D303/24 , C08G59/1444 , C08G59/36 , H01B3/40 , H01L23/293 , H01L2924/0002
摘要： Adducts of metabrominated monophenols such as 3,5-dibromo-2,4,6-trimethylphenol and multifunctional epoxides such as cresol-formaldehyde epoxy novolac resins are disclosed to be useful in formulations for encapsulating electronic components.
摘要翻译：公开了代谢溴化单酚如3,5-二溴-2,4,6-三甲基苯酚和多官能环氧化物如甲酚 - 甲醛环氧酚醛清漆树脂的加合物，用于封装电子部件的制剂中。

10. 发明授权

US4778863A Preparation of epoxy resins having low undesirable halogen content 失效
标题翻译：制备具有低期望卤素含量的环氧树脂
公开(公告)号：US4778863A
公开(公告)日：1988-10-18
申请号：US85035
申请日：1987-08-13
申请人： Chun S. Wang , Zeng-kun Liao
发明人： Chun S. Wang , Zeng-kun Liao
IPC分类号： C08G59/00 , C07D301/27 , C08G59/02 , C08G59/04 , C08G59/18 , C08G59/68 , C08G59/06 , C08G59/08
CPC分类号： C08G59/02
摘要： Glycidyl derivatives of compounds containing --OH, --NH.sub.2 and/or --COOH groups are prepared by reacting in the presence of a mixture of solvents, at least one of which is a polar aprotic solvent, an excess of an epihalohydrin with a compound containing --OH, --NH.sub.2 and/or --COOH groups while continuously or incrementally adding an alkali metal hydroxide to the mixture and removing water from the reaction by codistillation with epihalohydrin and the solvents.

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