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    • 2. 发明申请
    • METHOD OF PREPARING CARBON-COATED MANGANOUS OXIDE AND CARBON-COATED MANGANOUS OXIDE PREPARED USING THE METHOD
    • 使用该方法制备碳化锰氧化物和碳化锰氧化物的方法
    • US20160145445A1
    • 2016-05-26
    • US14946800
    • 2015-11-20
    • Jianhong LIU
    • Jianhong LIUQianling ZHANGChuanxin HEChuhong LIAO
    • C09D5/16B05D3/02B05D3/00B05D1/18
    • C09D5/1618A01N59/16B05D1/18B05D3/007B05D3/0272B63B59/04C08K9/02C09D5/1612C09D7/62A01N25/10
    • A method of preparing carbon-coated manganous oxide, the method including: (1) preparing a liquid polyacrylonitrile (LPAN) solution as a carbon source, stirring the LPAN solution at between 100 and 200° C. to yield a cyclized polyacrylonitrile solution; (2) heating the cyclized LPAN solution at between 200 and 300° C. to yield a thermally-oxidized polyacrylonitrile (OPAN) having a ladder structure; (3) mixing the thermally-oxidized polyacrylonitrile with a manganese compound, to yield a mixture, and adding a solvent to the mixture, uniformly mixing, to yield a polyacrylonitrile coated manganese compound; (4) drying the polyacrylonitrile coated manganese compound until the solvent is evaporated completely and the polyacrylonitrile coated on the manganese compound is crosslinked to form a solid, to yield a carbonized precursor coated manganese compound; and (5) calcining the carbonized precursor coated manganese compound in the presence of an inert gas flow, to yield a carbon-coated manganous oxide.
    • 一种制备碳涂覆的二氧化锰的方法,该方法包括:(1)制备作为碳源的液体聚丙烯腈(LPAN)溶液,在100-200℃下搅拌LPAN溶液,得到环化的聚丙烯腈溶液; (2)在200-300℃之间加热环化的LPAN溶液,得到具有梯形结构的热氧化聚丙烯腈(OPAN); (3)将热氧化聚丙烯腈与锰化合物混合,得到混合物,向混合物中加入溶剂均匀混合,得到聚丙烯腈包覆的锰化合物; (4)干燥包覆的聚丙烯腈的锰化合物,直到溶剂完全蒸发,涂覆在锰化合物上的聚丙烯腈交联以形成固体,得到碳化前体包被的锰化合物; 和(5)在惰性气流的存在下煅烧碳化前体包覆的锰化合物,得到碳涂覆的二氧化锰。
    • 3. 发明申请
    • GRAPHENE MATERIAL AND METHOD OF PREPARING THE SAME
    • 石墨材料及其制备方法
    • US20160068396A1
    • 2016-03-10
    • US14848274
    • 2015-09-08
    • Jianhong LIU
    • Jianhong LIUQianling ZHANGChuanxin HEJian XUChao HU
    • C01B31/04
    • C01B31/0446C01B32/182C01B32/184
    • A method of preparing a graphene material. The method includes: (1) preparing a liquid polyacrylonitrile (LPAN) solution, stirring the LPAN solution to yield a cyclized polyacrylonitrile solution; (2) stirring the cyclized LPAN solution at between 200 and 300° C. to yield a thermally-oxidized polyacrylonitrile; (3) grinding and sieving the thermally-oxidized polyacrylonitrile, and drying a resulting product at room temperature, to yield a thermally-oxidized precursor; (4) calcining the thermally-oxidized precursor in the presence of an inert gas flow of between 10 and 500 mL/min for between 1 and 24 hrs at the temperature of between 400 and 1000° C., to yield a carbonized precursor; and (5) calcining the carbonized precursor in the presence of an inert gas flow of between 10 and 500 mL/min for between 1 and 10 hrs at the temperature of between 1000 and 3000° C., to yield a graphene material.
    • 一种制备石墨烯材料的方法。 该方法包括:(1)制备液态聚丙烯腈(LPAN)溶液,搅拌LPAN溶液,得到环化聚丙烯腈溶液; (2)在200-300℃下搅拌环化的LPAN溶液,得到热氧化聚丙烯腈; (3)研磨和筛分热氧化聚丙烯腈,并在室温下干燥所得产物,得到热氧化前体; (4)在惰性气体流量为10-500mL / min的条件下,在400-1000℃的温度下煅烧1小时至24小时的热氧化前驱物,得到碳化前体; 和(5)在1000-5000℃的温度下,在10-500mL / min的惰性气流存在下煅烧碳化的前体1至10小时,以产生石墨烯材料。
    • 5. 发明申请
    • METHOD OF PREPARING GRAPHENE-COATED ALUMINA AND GRAPHENE-COATED ALUMINA PREPARED USING THE METHOD
    • 使用该方法制备石墨包覆的氧化铝和石墨涂覆的氧化铝的方法
    • US20160189819A1
    • 2016-06-30
    • US14981989
    • 2015-12-29
    • Jianhong LIU
    • Jianhong LIUQianling ZHANGChuanxin HEChuhong LIAO
    • H01B1/02H01B13/00C09K5/14
    • H01B1/02C09K5/14
    • A method of preparing graphene-coated alumina, the method including: (1) preparing a liquid polyacrylonitrile (LPAN) solution, stirring the LPAN solution at between 100 and 200° C. to yield a cyclized polyacrylonitrile solution; (2) heating the cyclized LPAN solution at between 200 and 300° C. to yield a thermally-oxidized polyacrylonitrile (OPAN) having a ladder structure; (3) mixing the thermally-oxidized polyacrylonitrile with an aluminum compound, to yield a mixture, and adding a solvent to the mixture, uniformly mixing, to yield a polyacrylonitrile-coated aluminum compound; (4) drying the polyacrylonitrile-coated aluminum compound until the solvent is evaporated, to yield a carbonized precursor-coated aluminum compound; and (5) calcining the carbonized precursor-coated aluminum compound in the presence of an inert gas flow, to yield graphene-coated alumina.
    • 一种制备石墨烯涂层氧化铝的方法,所述方法包括:(1)制备液体聚丙烯腈(LPAN)溶液,在100-200℃之间搅拌LPAN溶液,得到环化聚丙烯腈溶液; (2)在200-300℃之间加热环化的LPAN溶液,得到具有梯形结构的热氧化聚丙烯腈(OPAN); (3)将热氧化聚丙烯腈与铝化合物混合,得到混合物,向混合物中加入溶剂均匀混合,得到聚丙烯腈涂覆的铝化合物; (4)干燥聚丙烯腈涂覆的铝化合物直到溶剂蒸发,得到碳化前体涂覆的铝化合物; 和(5)在惰性气体流的存在下煅烧碳化前体涂覆的铝化合物,得到石墨烯涂覆的氧化铝。