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1. 发明授权

US06703446B2 Hetero-telechelic polymers and processes for making same 失效
标题翻译：杂环聚合物和制备相同的方法
公开(公告)号：US06703446B2
公开(公告)日：2004-03-09
申请号：US10176816
申请日：2002-06-21
申请人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
发明人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F29704
CPC分类号： C08F36/04 , C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/34 , C08F12/04 , C08F2810/40 , C08F112/08
摘要： Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.
摘要翻译：具有下式的异烟酰基聚合物：其中FG是被保护或未被保护的官能团; Q是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; d为10〜200的整数; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R 1 R 2 R 3）] x是保护基，其中A是选自元素周期表Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含低级烷基的低级烷基烷基，低级烷硫基和低级二烷基氨基，环烷基和取代环烷基，含有5至12个碳原子; 并且x取决于J的化合价，并且当J是氮时，当J是氧或硫时，J的值是不同的，条件是J和FG不相同，并且其制备方法。

2. 发明授权

US06699939B2 Hetero-telechelic polymers and processes for making same 失效
公开(公告)号：US06699939B2
公开(公告)日：2004-03-02
申请号：US10176723
申请日：2002-06-21
申请人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
发明人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F29704
CPC分类号： C08F36/04 , C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/34 , C08F12/04 , C08F2810/40 , C08F112/08
摘要： Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.

3. 发明授权

US06221991B1 Methacrylate and acrylate polymers and processes for making same 失效
标题翻译：甲基丙烯酸酯和丙烯酸酯聚合物及其制备方法
公开(公告)号：US06221991B1
公开(公告)日：2001-04-24
申请号：US09109210
申请日：1998-06-30
申请人： Robert J. Letchford , James A. Schwindeman , Conrad W. Kamienski , Roderic P. Quirk
发明人： Robert J. Letchford , James A. Schwindeman , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F2054
CPC分类号： C08F20/56 , C08F4/46 , C08F4/72 , C08F8/00 , C08F20/14 , C08F20/18 , C08F20/42 , C08F2810/40 , C08G81/021 , C08F120/14
摘要： Polar polymers having the following formula: FG-(Q)d-Rn-Z-J-[A(R1R2R3)]x (I) wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitrites of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, and living anionic polymerization processes for preparing the same.
摘要翻译：具有下式的极性聚合物：其中FG是H或被保护或未被保护的官能团; Q是通过掺入选自丙烯酸和甲基丙烯酸的酯，酰胺和亚硝酸盐的极性化合物及其混合物衍生的极性烃基; d为10〜2000的整数， R是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; n为0〜5的整数， Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R 1 R 2 R 3）] x是保护基，其中A是选自元素周期表Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J为氮时J为氧或硫时为2，并且当用于制备其的活性阴离子聚合方法时，其为不同的。

4. 发明授权

US5900464A Processes for making methacrylate and acrylate polymers 失效
标题翻译：制备甲基丙烯酸酯和丙烯酸酯聚合物的方法
公开(公告)号：US5900464A
公开(公告)日：1999-05-04
申请号：US677793
申请日：1996-07-10
申请人： Robert J. Letchford , James A. Schwindeman , Conrad W. Kamienski , Roderic P. Quirk
发明人： Robert J. Letchford , James A. Schwindeman , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F4/46 , C08F4/72 , C08F8/00 , C08F20/14 , C08F20/18 , C08F20/42 , C08F20/56 , C08G81/02 , C08L31/02 , C08F297/02
CPC分类号： C08F20/56 , C08F20/14 , C08F20/18 , C08F20/42 , C08F4/46 , C08F4/72 , C08F8/00 , C08G81/021 , C08F2810/40
摘要： Polar polymers having the following formula:FG--(Q).sub.d --R.sub.n --Z--J--�A(R.sup.1 R.sup.2 R.sup.3)!.sub.x(I)wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitriles of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; �A(R.sup.1 R.sup.2 R.sup.3)!.sub.x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, and living anionic polymerization processes for preparing the same.
摘要翻译：具有下式的极性聚合物：FG-（Q）d-Rn-Z-J- [A（R1R2R3）] x（I）其中FG是H或被保护或未被保护的官能团; Q是通过掺入选自丙烯酸和甲基丙烯酸的酯，酰胺和腈的极性化合物及其混合物衍生的极性烃基; d为10〜2000的整数， R是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; n为0〜5的整数， Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R 1 R 2 R 3）] x是保护基，其中A是选自元素周期表Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J为氮时J为氧或硫时为2，并且当用于制备其的活性阴离子聚合方法时，其为不同的。

5. 发明授权

US6160054A Hetero-telechelic polymers and processes for making same 失效
标题翻译：杂环聚合物和制备相同的方法
公开(公告)号：US6160054A
公开(公告)日：2000-12-12
申请号：US687111
申请日：1996-07-18
申请人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
发明人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/00 , C08F12/04 , C08F36/04 , C08F297/04 , C08F8/30 , C08F8/46
CPC分类号： C08F36/04 , C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/34 , C08F12/04 , C08F2810/40 , C08F112/08
摘要： Hetero-telechelic polymers having the formula:FG--(Q).sub.d --Z--J--[A(R.sup.1 R.sup.2 R.sup.3)].sub.x (I)wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R.sup.1 R.sup.2 R.sup.3)].sub.x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.
摘要翻译：具有式FG-（Q）d-Z-J- [A（R 1 R 2 R 3）] x（I）的异烟酰基聚合物，其中FG是受保护或未被保护的官能团; Q是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; d为10〜200的整数; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R1R2R3）] x为保护基，其中A为选自元素周期表第Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J是氮时，当J是氧或硫时，J的值是不同的，条件是J和FG不相同，并且其制备方法。

6. 发明授权

US06184309B2 Selected deprotection of protected functional polymers 失效
标题翻译：保护的官能聚合物的选择脱保护
公开(公告)号：US06184309B2
公开(公告)日：2001-02-06
申请号：US09207226
申请日：1998-12-08
申请人： James A. Schwindeman , John F. Engel , Eric J. Granger , Conrad W. Kamienski , Roderic P. Quirk
发明人： James A. Schwindeman , John F. Engel , Eric J. Granger , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F800
CPC分类号： C08C19/00 , C08F8/00 , C08F2810/40 , C08F112/08 , C08F120/14
摘要： A process for removing a protecting group from a polymer. Protected functional groups of a polymer may be deprotected by treating the polymer in the presence of an acid catalyst, including organic acids, mineral acids, heterogeneous acid systems, Lewis acids, and fluoride ion sources.
摘要翻译：从聚合物中除去保护基团的方法。通过在酸催化剂存在下处理聚合物，包括有机酸，无机酸，多相酸体系，路易斯酸和氟离子源，可以将保护的聚合物的官能团脱保护。

7. 发明授权

US5780551A Telechelic polymers from mixed initiator 失效
标题翻译：来自混合引发剂的远端聚合物
公开(公告)号：US5780551A
公开(公告)日：1998-07-14
申请号：US657084
申请日：1996-06-03
申请人： John F. Engel , James A. Schwindeman , Roderic P. Quirk , Conrad W. Kamienski
发明人： John F. Engel , James A. Schwindeman , Roderic P. Quirk , Conrad W. Kamienski
IPC分类号： C08C19/44 , C08F4/46 , C08F12/06 , C08F36/04 , C08F297/04 , C08G64/18 , C08G81/02
CPC分类号： C08G81/022 , C08C19/44 , C08F12/06 , C08F297/044 , C08F36/04 , C08F4/461 , C08G64/18
摘要： This invention concerns novel, unsymmetrically protected, telechelically functionalized linear and star or multi-arm polymers, their optionally hydrogenated analogues, the polymers produced by selective removal of the protecting groups, the segmented block polymers produced by further reaction of these selectively deprotected polymers with selected comonomers, and the processes to prepare these polymers.
摘要翻译：本发明涉及新颖的，不对称保护的，电视功能化的线性和星形或多臂聚合物，它们任选氢化的类似物，通过选择性去除保护基产生的聚合物，通过这些选择性去保护的聚合物与所选择的进一步反应产生的分段嵌段聚合物共聚单体，以及制备这些聚合物的方法。

8. 发明授权

US5919870A Functional telechelic star polymers 失效
标题翻译：功能遥爪星形聚合物
公开(公告)号：US5919870A
公开(公告)日：1999-07-06
申请号：US660658
申请日：1996-06-05
申请人： Robert J. Letchford , Conrad W. Kamienski , James A. Schwindeman
发明人： Robert J. Letchford , Conrad W. Kamienski , James A. Schwindeman
IPC分类号： C08C19/44 , C08F4/46 , C08F4/72 , C08F8/00 , C08F36/04 , C08F4/08 , C08F36/06
CPC分类号： C08F36/04 , C08C19/44 , C08F4/46 , C08F4/72
摘要： Protected functional initiators have been demonstrated to polymerize dienes and alkenyl substituted aromatics. The resultant living anions were linked with a coupling agent, such as divinylbenzene or tin tetrachloride, to afford a protected functionalized star polymer. Subsequent deprotection afforded a star polymer, with functional groups on the end of each arm of the star. The star polymer could be hydrogenated before or after removal of the protecting groups. The newly liberated functional groups can participate in further polymerization chemistry.
摘要翻译：已经证明保护的官能引发剂聚合二烯和烯基取代的芳族化合物。所得活性阴离子与偶联剂如二乙烯基苯或四氯化锡连接，得到受保护的官能化星形聚合物。随后的脱保护得到星形聚合物，其中每个臂的末端具有官能团。星形聚合物可以在除去保护基团之前或之后被氢化。新释放的官能团可以参与进一步的聚合化学。

9. 发明授权

US5654371A Anionic polymerization process using functionalized initiators 失效
标题翻译：使用官能化引发剂的阴离子聚合方法
公开(公告)号：US5654371A
公开(公告)日：1997-08-05
申请号：US460308
申请日：1995-06-02
申请人： James A. Schwindeman , Conrad W. Kamienski , Robert C. Morrison
发明人： James A. Schwindeman , Conrad W. Kamienski , Robert C. Morrison
IPC分类号： C08C19/44 , C08F4/08 , C08F4/46 , C08F4/48 , C08F12/04 , C08F12/06 , C08F36/04 , C08F279/02 , C08F8/00
CPC分类号： C08C19/44 , C08F12/04 , C08F12/06 , C08F279/02 , C08F36/04 , C08F4/46
摘要： A process for the preparation of hydrocarbon solutions of monofunctional ether initiators of the following general structure:M--Q.sub.n --Z--OA(R.sup.1 R.sup.2 R.sup.3) (II)wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenylsubstituted aromatic hydrocarbons; Z is defined as a branched or straight chain hydrocarbon tether or connecting group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, aryl or substituted aryl groups, and n is an integer from 1 to 5. monofunctional ethers produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译：一种制备以下一般结构的单官能醚引发剂的烃溶液的方法：M-Qn-Z-OA（R1R2R3）（Ⅱ）其中M定义为碱金属，选自锂，钠和钾，Q是通过引入选自共轭二烯烃和烯基取代的芳族烃的化合物衍生的饱和或不饱和烃基; Z定义为含有3-25个碳原子的支链或直链烃系链或连接基团，任选含有芳基或取代的芳基; A是选自元素周期表Ⅳa的元素，R 1，R 2和R 3独立地选自氢，烷基，取代的烷基，芳基或取代的芳基，n是1至5的整数。聚合过程中引发剂的使用以及通过聚合方法制备的聚合物。

10. 发明授权

US5605872A Functionalized amine initiators for anionic polymerization 失效
标题翻译：用于阴离子聚合的官能化胺引发剂
公开(公告)号：US5605872A
公开(公告)日：1997-02-25
申请号：US459585
申请日：1995-06-02
申请人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
发明人： John F. Engel , Conrad W. Kamienski , James A. Schwindeman , Randy W. Hall , Robert C. Morrison , B. Troy Dover
IPC分类号： C08F4/46 , C08F4/48 , C08F12/04 , C08F36/04 , B01J31/12 , B01J31/18
CPC分类号： C08F12/04 , C08F36/04
摘要： A process for the preparation of hydrocarbon solutions of monofunctional amine initiators of the following general structures: ##STR1## wherein M is defined as an alkali metal, selected from the group consisting of lithium, sodium and potassium, Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons and alkenyl substituted aromatic hydrocarbons; Z is a hydrocarbon tether group which contains 3-25 carbon atoms; A is an element selected from Group IVa of the periodic table and R.sup.1, R.sup.2, and R.sup.3 are independently selected from hydrogen, alkyl, substituted alkyl, cycloalkyl, aryl or substituted aryl groups, m is an integer from 0 to 7, and n is an integer from 1 to 5, monofunctional amine initiators produced by the process, use of the initiators in a polymerization process and polymers produced by the polymerization process.
摘要翻译：制备以下一般结构的单官能胺引发剂的烃溶液的方法：MQnZN（A（R1R2R3））2金属，选自锂，钠和钾，Q是衍生的饱和或不饱和烃基通过并入选自共轭二烯烃和烯基取代的芳族烃的化合物; Z是含有3-25个碳原子的烃系链基团; A是选自元素周期表IVa的元素，R1，R2和R3独立地选自氢，烷基，取代的烷基，环烷基，芳基或取代的芳基，m是0-7的整数，n是 1至5的整数，通过该方法制备的单官能胺引发剂，在聚合方法中使用引发剂和通过聚合方法制备的聚合物。

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