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1. 发明授权

US06184309B2 Selected deprotection of protected functional polymers 失效
标题翻译：保护的官能聚合物的选择脱保护
公开(公告)号：US06184309B2
公开(公告)日：2001-02-06
申请号：US09207226
申请日：1998-12-08
申请人： James A. Schwindeman , John F. Engel , Eric J. Granger , Conrad W. Kamienski , Roderic P. Quirk
发明人： James A. Schwindeman , John F. Engel , Eric J. Granger , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F800
CPC分类号： C08C19/00 , C08F8/00 , C08F2810/40 , C08F112/08 , C08F120/14
摘要： A process for removing a protecting group from a polymer. Protected functional groups of a polymer may be deprotected by treating the polymer in the presence of an acid catalyst, including organic acids, mineral acids, heterogeneous acid systems, Lewis acids, and fluoride ion sources.
摘要翻译：从聚合物中除去保护基团的方法。通过在酸催化剂存在下处理聚合物，包括有机酸，无机酸，多相酸体系，路易斯酸和氟离子源，可以将保护的聚合物的官能团脱保护。

2. 发明授权

US5780551A Telechelic polymers from mixed initiator 失效
标题翻译：来自混合引发剂的远端聚合物
公开(公告)号：US5780551A
公开(公告)日：1998-07-14
申请号：US657084
申请日：1996-06-03
申请人： John F. Engel , James A. Schwindeman , Roderic P. Quirk , Conrad W. Kamienski
发明人： John F. Engel , James A. Schwindeman , Roderic P. Quirk , Conrad W. Kamienski
IPC分类号： C08C19/44 , C08F4/46 , C08F12/06 , C08F36/04 , C08F297/04 , C08G64/18 , C08G81/02
CPC分类号： C08G81/022 , C08C19/44 , C08F12/06 , C08F297/044 , C08F36/04 , C08F4/461 , C08G64/18
摘要： This invention concerns novel, unsymmetrically protected, telechelically functionalized linear and star or multi-arm polymers, their optionally hydrogenated analogues, the polymers produced by selective removal of the protecting groups, the segmented block polymers produced by further reaction of these selectively deprotected polymers with selected comonomers, and the processes to prepare these polymers.
摘要翻译：本发明涉及新颖的，不对称保护的，电视功能化的线性和星形或多臂聚合物，它们任选氢化的类似物，通过选择性去除保护基产生的聚合物，通过这些选择性去保护的聚合物与所选择的进一步反应产生的分段嵌段聚合物共聚单体，以及制备这些聚合物的方法。

3. 发明授权

US06703446B2 Hetero-telechelic polymers and processes for making same 失效
标题翻译：杂环聚合物和制备相同的方法
公开(公告)号：US06703446B2
公开(公告)日：2004-03-09
申请号：US10176816
申请日：2002-06-21
申请人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
发明人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F29704
CPC分类号： C08F36/04 , C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/34 , C08F12/04 , C08F2810/40 , C08F112/08
摘要： Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.
摘要翻译：具有下式的异烟酰基聚合物：其中FG是被保护或未被保护的官能团; Q是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; d为10〜200的整数; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R 1 R 2 R 3）] x是保护基，其中A是选自元素周期表Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含低级烷基的低级烷基烷基，低级烷硫基和低级二烷基氨基，环烷基和取代环烷基，含有5至12个碳原子; 并且x取决于J的化合价，并且当J是氮时，当J是氧或硫时，J的值是不同的，条件是J和FG不相同，并且其制备方法。

4. 发明授权

US6160054A Hetero-telechelic polymers and processes for making same 失效
标题翻译：杂环聚合物和制备相同的方法
公开(公告)号：US6160054A
公开(公告)日：2000-12-12
申请号：US687111
申请日：1996-07-18
申请人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
发明人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/00 , C08F12/04 , C08F36/04 , C08F297/04 , C08F8/30 , C08F8/46
CPC分类号： C08F36/04 , C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/34 , C08F12/04 , C08F2810/40 , C08F112/08
摘要： Hetero-telechelic polymers having the formula:FG--(Q).sub.d --Z--J--[A(R.sup.1 R.sup.2 R.sup.3)].sub.x (I)wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R.sup.1 R.sup.2 R.sup.3)].sub.x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.
摘要翻译：具有式FG-（Q）d-Z-J- [A（R 1 R 2 R 3）] x（I）的异烟酰基聚合物，其中FG是受保护或未被保护的官能团; Q是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; d为10〜200的整数; Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R1R2R3）] x为保护基，其中A为选自元素周期表第Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J是氮时，当J是氧或硫时，J的值是不同的，条件是J和FG不相同，并且其制备方法。

5. 发明授权

US06699939B2 Hetero-telechelic polymers and processes for making same 失效
公开(公告)号：US06699939B2
公开(公告)日：2004-03-02
申请号：US10176723
申请日：2002-06-21
申请人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
发明人： James A. Schwindeman , Robert J. Letchford , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F29704
CPC分类号： C08F36/04 , C08C19/44 , C08F4/46 , C08F4/48 , C08F4/72 , C08F8/34 , C08F12/04 , C08F2810/40 , C08F112/08
摘要： Hetero-telechelic polymers having the formula: FG—(Q)d—Z—J—[A(R1R2R3)]x (I) wherein FG is a protected or non-protected functional group; Q is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; d is an integer from 10 to 200; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, wherein A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, with the proviso J and FG are not the same, and processes for making the same.

6. 发明授权

US06221991B1 Methacrylate and acrylate polymers and processes for making same 失效
标题翻译：甲基丙烯酸酯和丙烯酸酯聚合物及其制备方法
公开(公告)号：US06221991B1
公开(公告)日：2001-04-24
申请号：US09109210
申请日：1998-06-30
申请人： Robert J. Letchford , James A. Schwindeman , Conrad W. Kamienski , Roderic P. Quirk
发明人： Robert J. Letchford , James A. Schwindeman , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F2054
CPC分类号： C08F20/56 , C08F4/46 , C08F4/72 , C08F8/00 , C08F20/14 , C08F20/18 , C08F20/42 , C08F2810/40 , C08G81/021 , C08F120/14
摘要： Polar polymers having the following formula: FG-(Q)d-Rn-Z-J-[A(R1R2R3)]x (I) wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitrites of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; [A(R1R2R3)]x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R1, R2, and R3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, and living anionic polymerization processes for preparing the same.
摘要翻译：具有下式的极性聚合物：其中FG是H或被保护或未被保护的官能团; Q是通过掺入选自丙烯酸和甲基丙烯酸的酯，酰胺和亚硝酸盐的极性化合物及其混合物衍生的极性烃基; d为10〜2000的整数， R是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; n为0〜5的整数， Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R 1 R 2 R 3）] x是保护基，其中A是选自元素周期表Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J为氮时J为氧或硫时为2，并且当用于制备其的活性阴离子聚合方法时，其为不同的。

7. 发明授权

US5900464A Processes for making methacrylate and acrylate polymers 失效
标题翻译：制备甲基丙烯酸酯和丙烯酸酯聚合物的方法
公开(公告)号：US5900464A
公开(公告)日：1999-05-04
申请号：US677793
申请日：1996-07-10
申请人： Robert J. Letchford , James A. Schwindeman , Conrad W. Kamienski , Roderic P. Quirk
发明人： Robert J. Letchford , James A. Schwindeman , Conrad W. Kamienski , Roderic P. Quirk
IPC分类号： C08F4/46 , C08F4/72 , C08F8/00 , C08F20/14 , C08F20/18 , C08F20/42 , C08F20/56 , C08G81/02 , C08L31/02 , C08F297/02
CPC分类号： C08F20/56 , C08F20/14 , C08F20/18 , C08F20/42 , C08F4/46 , C08F4/72 , C08F8/00 , C08G81/021 , C08F2810/40
摘要： Polar polymers having the following formula:FG--(Q).sub.d --R.sub.n --Z--J--�A(R.sup.1 R.sup.2 R.sup.3)!.sub.x(I)wherein FG is H or a protected or non-protected functional group; Q is a polar hydrocarbyl group derived by incorporation of a polar compound selected from group consisting of esters, amides, and nitriles of acrylic and methacrylic acid, and mixtures thereof; d is an integer from 10 to 2000; R is a saturated or unsaturated hydrocarbyl group derived by incorporation of a compound selected from the group consisting of conjugated diene hydrocarbons, alkenylsubstituted aromatic hydrocarbons, and mixtures thereof; n is an integer from 0 to 5; Z is a branched or straight chain hydrocarbon group which contains 3-25 carbon atoms, optionally containing aryl or substituted aryl groups; J is oxygen, sulfur, or nitrogen; �A(R.sup.1 R.sup.2 R.sup.3)!.sub.x is a protecting group, in which A is an element selected from Group IVa of the Periodic Table of Elements; R.sup.1, R.sup.2, and R.sup.3 are each independently selected from the group consisting of hydrogen, alkyl, substituted alkyl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, aryl or substituted aryl groups containing lower alkyl, lower alkylthio, and lower dialkylamino groups, and cycloalkyl and substituted cycloalkyl containing 5 to 12 carbon atoms; and x is dependent on the valence of J and varies from one when J is oxygen or sulfur to two when J is nitrogen, and living anionic polymerization processes for preparing the same.
摘要翻译：具有下式的极性聚合物：FG-（Q）d-Rn-Z-J- [A（R1R2R3）] x（I）其中FG是H或被保护或未被保护的官能团; Q是通过掺入选自丙烯酸和甲基丙烯酸的酯，酰胺和腈的极性化合物及其混合物衍生的极性烃基; d为10〜2000的整数， R是通过引入选自共轭二烯烃，烯基取代的芳族烃及其混合物的化合物衍生的饱和或不饱和烃基; n为0〜5的整数， Z是含有3-25个碳原子的支链或直链烃基，任选含有芳基或取代的芳基; J是氧，硫或氮; [A（R 1 R 2 R 3）] x是保护基，其中A是选自元素周期表Ⅳa族的元素; R 1，R 2和R 3各自独立地选自氢，烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的取代烷基，含有低级烷基，低级烷硫基和低级二烷基氨基的芳基或取代芳基和含有5至12个碳原子的环烷基和取代的环烷基; 并且x取决于J的化合价，并且当J为氮时J为氧或硫时为2，并且当用于制备其的活性阴离子聚合方法时，其为不同的。

8. 发明授权

US07235615B2 Synthetic polymers with highly-functionalized liquid-rubber chain-end moieties 有权
标题翻译：具有高官能化液体 - 橡胶链端部分的合成聚合物
公开(公告)号：US07235615B2
公开(公告)日：2007-06-26
申请号：US10782432
申请日：2004-02-18
申请人： Roderic P. Quirk , Jin-Ping Zhou
发明人： Roderic P. Quirk , Jin-Ping Zhou
IPC分类号： C08F4/48 , C08F36/06
CPC分类号： C08F297/04 , C08C19/30 , C08C19/44 , C08F8/00 , C08F297/02 , C08F12/08
摘要： A method is provided for synthesizing a polymer that has highly-functionalized chain-end moieties. The method functionalizes liquid rubber to terminate a metallic or organometallic initiated living polymer. After the living polymer has been terminated with the functionalized liquid rubber, the functionalities on the residue of the liquid rubber are preferably modified to yield more advantageous functionalities.
摘要翻译：提供了一种合成具有高度官能化的链端部分的聚合物的方法。该方法使液体橡胶功能化以终止金属或有机金属引发的活性聚合物。活性聚合物用功能化液体橡胶终止后，液态橡胶残余物的功能性被优选地改性以产生更有利的功能。

9. 发明授权

US5798418A Star polymers from mixed initiators 失效
标题翻译：混合引发剂的星形聚合物
公开(公告)号：US5798418A
公开(公告)日：1998-08-25
申请号：US683487
申请日：1996-07-18
申请人： Roderic P. Quirk
发明人： Roderic P. Quirk
IPC分类号： C08C19/44 , C08F4/46 , C08F4/72 , C08F12/06 , C08F36/04 , C08F297/04 , C08G81/02 , C08G83/00 , C08F6/00
CPC分类号： C08G83/00 , C08C19/44 , C08F12/06 , C08F297/044 , C08F36/04 , C08F4/461 , C08F4/72 , C08G81/022
摘要： The present invention provides novel, multi-arm or star-shaped polymers having mixed protected functional and non-functional ends, their optionally hydrogenated analogues, and the polymers produced by removal of the protecting groups. The invention also provides a process for the preparation of novel multi-arm or star-shaped polymers having branched-end functionality on some, but not all, of the branches. The multi-arm or star polymers of this invention are produced from more than one type of initiator, i.e., from both functional and non-functional initiators which, by design, incorporates both desired physical properties associated with multi-arm or star polymers with non-functional branch-ends and the versatility of functional branch end multi-arm or star polymers.
摘要翻译：本发明提供具有混合保护的官能和非官能末端的新型多臂或星形聚合物，它们任选氢化的类似物，以及通过除去保护基产生的聚合物。本发明还提供了一种制备新颖的多臂或星形聚合物的方法，其在一些但不是全部的分支上具有支链官能团。本发明的多臂或星形聚合物由多于一种类型的引发剂生产，即从功能性和非功能性引发剂两者产生，其通过设计将包含与多臂或星形聚合物相关的所需物理性能与非 - 功能分支端和功能性分支端多臂或星形聚合物的多功能性。

10. 发明授权

US09238765B2 Hydrogenated alkenyl aromatic-diene copolymers containing comonomers having silyl hydride units and their functionalized analogs 有权
标题翻译：含有具有甲硅烷基氢化物单元及其官能化类似物的共聚单体的氢化烯基芳族 - 二烯共聚物
公开(公告)号：US09238765B2
公开(公告)日：2016-01-19
申请号：US14380932
申请日：2012-02-29
申请人： Sergio Corona Galvan , Diana Martinez Wichtel , Luis Serrano Aviles , Montserrat Fernandez Munoz , Roderic P. Quirk , Vijay Chavan , Jonathan Janoski
发明人： Sergio Corona Galvan , Diana Martinez Wichtel , Luis Serrano Aviles , Montserrat Fernandez Munoz , Roderic P. Quirk , Vijay Chavan , Jonathan Janoski
IPC分类号： C08L19/02 , C09J153/00 , C08C19/02 , C08C19/25 , C08C19/44 , C08F293/00 , C08F297/04 , C09D153/00
CPC分类号： C09J153/005 , C08C19/02 , C08C19/25 , C08C19/44 , C08F293/005 , C08F297/04 , C09D153/005
摘要： The present invention relates primarily to polymers comprising at least one alkenyl aromatic monomer, at least one conjugated diene monomer, and at least one monomer containing silyl hydride moieties, characterized in that said polymers are hydrogenated and preferably functionalized by hydrosilylation reactions between the silyl hydride groups on the polymer chain and the multiple bonds of any alkene or alkyne compound. Besides the described products, this invention comprises their synthesis processes and their uses, especially as thermofusible adhesives, in plastics impact modification, and in chain-extension reactions to obtain new materials, among others.
摘要翻译：本发明主要涉及包含至少一种烯基芳族单体，至少一种共轭二烯单体和至少一种含甲硅烷基氢化物部分的单体的聚合物，其特征在于所述聚合物被氢化并优选通过甲硅烷基氢化物基团之间的氢化硅烷化反应在聚合物链和任何烯烃或炔化合物的多重键上。除了所描述的产品外，本发明包括其合成方法及其用途，特别是作为热熔粘合剂，在塑料冲击改性中，以及在延伸反应中获得新材料等。

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