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    • 3. 发明授权
    • Block copolymer compositions containing substantially inert thermoelastic extenders
    • 含有基本上惰性的热弹性增量剂的嵌段共聚物组合物
    • US06403710B1
    • 2002-06-11
    • US09690039
    • 2000-10-16
    • Wasif K. AhmedStephen R. BetsoAntonio BatistiniMartin J. GuestThoi H. HoDeepak R. ParikhGeorge W. KnightRajen M. Patel
    • Wasif K. AhmedStephen R. BetsoAntonio BatistiniMartin J. GuestThoi H. HoDeepak R. ParikhGeorge W. KnightRajen M. Patel
    • C08L900
    • C09D153/02C08L23/0815C08L53/02C08L2314/06C08L2666/02C08L2666/04C09J153/02
    • The present invention is at least a two-component thermoplastic elastomeric composition comprising at least one block copolymer wherein the composition has essentially the same comparative elasticity, high temperature serviceability and hardness as the unmodified, undiluted (neat) block copolymer portion of the composition. The composition also shows enhanced thermal stability and processibility and is well suited for fabricating elastic moldings, films and fibers as well as for formulating with asphalts, adhesives and sealants. The novel thermoplastic elastomeric composition comprises (a) from about 50 to about 99 percent by weight of at least one block copolymer and (b) about 1 to about 50 percent by weight of at least one ethylene interpolymer having a density from about 0.855 g/cc to about 0.905 g/cc, wherein the ethylene interpolymer in the amount employed is a substantially inert extender of the block copolymer and the composition is further characterized as having: i. storage moduli throughout the range of −26° C. to 24° C. of less than about 3.5×109 dynes/cm2, ii. a ratio of storage modulus at −26° C. to storage modulus at 24° C. of less than about 4, and iii. storage moduli at −26° C. and 24° C. about 0.2 to about 3 times higher than the storage moduli at −26° C. and 24° C., respectively, of the neat block copolymer portion of the composition.
    • 本发明是至少一种包含至少一种嵌段共聚物的双组分热塑性弹性体组合物,其中组合物与组合物未未改性的未稀释(纯)嵌段共聚物部分具有基本上相同的比较弹性,高温可使用性和硬度。 该组合物还显示出增强的热稳定性和加工性,并且非常适用于制造弹性模制品,薄膜和纤维,以及用沥青,粘合剂和密封剂配制。 新型热塑性弹性体组合物包含(a)约50至约99重量%的至少一种嵌段共聚物和(b)约1至约50重量%的至少一种乙烯互聚物,其密度约为0.855克/ cc至约0.905g / cc,其中所用量的乙烯互聚物是嵌段共聚物的基本惰性的增量剂,组合物进一步表征为具有: 在-26℃至24℃的范围内的储存模量小于约3.5×10 9达因/厘米2,ii。 在-26℃下的储能模量与24℃下的储能模量的比小于约4,和iii。 在-26℃和24℃下的储存模量分别比组合物的纯嵌段共聚物部分的-26℃和24℃下的储存模量高约0.2至约3倍。
    • 6. 发明授权
    • Foam structures of ethylenic polymer material having enhanced toughness
and elasticity and process for making
    • 具有增强的韧性和弹性的乙烯聚合物材料的泡沫结构和制备方法
    • US5369136A
    • 1994-11-29
    • US226150
    • 1994-04-11
    • Chung P. ParkJames C. StevensGeorge W. Knight
    • Chung P. ParkJames C. StevensGeorge W. Knight
    • C08J9/14C08J9/18
    • C08J9/14C08J2323/16Y10S526/943
    • Disclosed is an ethylenic polymer foam structure comprising an ethylenic polymer material. The ethylenic polymer material contains a substantially linear ethylenic polymer having: a) a melt flow ratio, I.sub.10 /I.sub.2, .gtoreq.5.63; b) a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation M.sub.w /M.sub.n .gtoreq.(I.sub.10 /I.sub.2)-4.63; and c) a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I.sub.2 and M.sub.w /M.sub.n. The foam structures have toughness and elasticity similar to those formed from conventional LLDPE without the poor dimensional stability and foam quality associated with those structures. The foam structures have foam quality similar to those made with conventional LDPE but with enhanced toughness and elasticity. Further disclosed is a process for making the above foam structure and making it in a foam bead form. Further disclosed is a process for making an article of the foam beads.
    • 公开了一种含烯属聚合物材料的乙烯聚合物泡沫结构。 烯属聚合物材料包含基本上线性的乙烯性聚合物,其具有:a)熔体流动比,I10 / I2,= 5.63; b)分子量分布,Mw / Mn,由方程式Mw / Mn定义(I10 / I2)-4.63; 和c)在具有大约相同的I2和Mw / Mn的线性烯烃聚合物的表面熔融断裂开始时,表面熔融断裂开始时的临界剪切速率比临界剪切速率大至少50%。 泡沫结构具有类似于由常规LLDPE形成的那些的韧性和弹性,而没有与这些结构相关联的差的尺寸稳定性和泡沫质量。 泡沫结构的泡沫质量与常规LDPE制成的泡沫质量相似,但具有增强的韧性和弹性。 进一步公开的是制造上述泡沫结构并使其成泡沫珠形式的方法。 进一步公开的是制造泡沫珠的制品的方法。
    • 7. 发明授权
    • Foam structures of ethylenic polymer material having enhanced toughness
and elasticity and process for making
    • 具有增强的韧性和弹性的乙烯聚合物材料的泡沫结构和制备方法
    • US5340840A
    • 1994-08-23
    • US54330
    • 1993-04-28
    • Chung P. ParkJames C. StevensGeorge W. Knight
    • Chung P. ParkJames C. StevensGeorge W. Knight
    • C08J9/14C08J9/18
    • C08J9/14C08J2323/16Y10S526/943
    • Disclosed is an ethylenic polymer foam structure comprising an ethylenic polymer material. The ethylenic polymer material contains a substantially linear ethylenic polymer having: a) a melt flow ratio, I.sub.10 I.sub.2, .gtoreq.5.63; b) a molecular weight distribution, M.sub.w /M.sub.n, defined by the equation M.sub.w /M.sub.n .ltoreq.(I.sub.10 /I.sub.2)-4.63; and c) a critical shear rate at onset of surface melt fracture of at least 50 percent greater than the critical shear rate at the onset of surface melt fracture of a linear olefin polymer having about the same I.sub.2 and M.sub.w /M.sub.n. The foam structures have toughness and elasticity similar to those formed from conventional LLDPE without the poor dimensional stability and foam quality associated with those structures. The foam structures have foam quality similar to those made with conventional LDPE but with enhanced toughness and elasticity. Further disclosed is a process for making the above foam structure and making it in a foam bead form. Further disclosed is a process for making an article of the foam beads.
    • 公开了一种含烯属聚合物材料的乙烯聚合物泡沫结构。 烯属聚合物材料包含基本上线性的乙烯类聚合物,其具有:a)熔体流动比,I10I2,≥5.63; b)分子量分布,Mw / Mn,由方程式Mw / Mn定义(I10 / I2)-4.63; 和c)在具有大约相同的I2和Mw / Mn的线性烯烃聚合物的表面熔融断裂开始时,表面熔融断裂开始时的临界剪切速率比临界剪切速率大至少50%。 泡沫结构具有类似于由常规LLDPE形成的那些的韧性和弹性,而没有与这些结构相关联的差的尺寸稳定性和泡沫质量。 泡沫结构的泡沫质量与常规LDPE制成的泡沫质量相似,但具有增强的韧性和弹性。 进一步公开的是制造上述泡沫结构并使其成泡沫珠形式的方法。 进一步公开的是制造泡沫珠的制品的方法。
    • 9. 发明授权
    • Block copolymer compositions containing substantially inert thermoelastic extenders
    • 含有基本上惰性的热弹性增量剂的嵌段共聚物组合物
    • US06184290B2
    • 2001-02-06
    • US08979388
    • 1997-11-26
    • Wasif K. AhmedAntonio BatistiniStephen R. BetsoMartin J. GuestThoi H. HoGeorge W. KnightDeepak R. ParikhRajen M. Patel
    • Wasif K. AhmedAntonio BatistiniStephen R. BetsoMartin J. GuestThoi H. HoGeorge W. KnightDeepak R. ParikhRajen M. Patel
    • C08L4700
    • C09D153/02C08L23/0815C08L53/02C08L2314/06C08L2666/02C08L2666/04C09J153/02
    • The present invention is at least a two-component thermoplastic elastomeric composition comprising at least one block copolymer wherein the composition has essentially the same comparative elasticity, high temperature serviceability and hardness as the unmodified, undiluted (neat) block copolymer portion of the composition. The composition also shows enhanced thermal stability and processibility and is well suited for fabricating elastic moldings, films and fibers as well as for formulating with asphalts, adhesives and sealants. The novel thermoplastic elastomeric composition comprises (a) from about 50 to about 99 percent by weight of at least one block copolymer and (b) about 1 to about 50 percent by weight of at least one ethylene interpolymer having a density from about 0.855 g/cc to about 0.905 g/cc, wherein the ethylene interpolymer in the amount employed is a substantially inert extender of the block copolymer and the composition is further characterized as having: i. storage moduli throughout the range of −26° C. to 24° C. of less than about 3.5×109 dynes/cm2, ii. a ratio of storage modulus at −26° C. to storage modulus at 24° C. of less than about 4, and iii. storage moduli at −26° C. and 24° C. about 0.2 to about 3 times higher than the storage moduli at −26° C. and 24° C., respectively, of the neat block copolymer portion of the composition.
    • 本发明是至少一种包含至少一种嵌段共聚物的双组分热塑性弹性体组合物,其中组合物与组合物未未改性的未稀释(纯)嵌段共聚物部分具有基本上相同的比较弹性,高温可使用性和硬度。 该组合物还显示出增强的热稳定性和加工性,并且非常适用于制造弹性模制品,薄膜和纤维,以及用沥青,粘合剂和密封剂配制。 新型热塑性弹性体组合物包含(a)约50至约99重量%的至少一种嵌段共聚物和(b)约1至约50重量%的至少一种乙烯互聚物,其密度约为0.855克/ cc至约0.905g / cc,其中所用量的乙烯互聚物是嵌段共聚物的基本惰性的增量剂,组合物进一步表征为具有: 在-26℃至24℃的范围内的储存模量小于约3.5×10 9达因/厘米2,ii。 在-26℃下的储能模量与24℃下的储能模量的比小于约4,和iii。 在-26℃和24℃下的储存模量分别比组合物的纯嵌段共聚物部分的-26℃和24℃下的储存模量高约0.2至约3倍。