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1. 发明授权

US4009307A Polyurea-urethane coatings 失效
标题翻译：聚脲 - 聚氨酯涂料
公开(公告)号：US4009307A
公开(公告)日：1977-02-22
申请号：US599242
申请日：1975-07-24
申请人： J. Alden Erikson , Ken W. Niederst
发明人： J. Alden Erikson , Ken W. Niederst
IPC分类号： B05D7/06 , C08G18/10 , C08G18/75 , C08G18/80 , B05D3/02
CPC分类号： C08G18/10 , C08G18/755 , C08G18/8009
摘要： Coating compositions which form polyurea-urethane coatings having excellent chemical and physical properties are prepared by blending (a) from about 2 percent to about 80 percent by weight of resin solids of an isocyanate-terminated polyurethane prepolymer consisting essentially of the reaction product of an organic diisocyanate and an organic diol, wherein said prepolymer is prepared at an NCO/OH ratio of from 2:1 to about 4:3, (b) from about 2 percent to about 60 percent by weight resin solids of an isocyanate-terminated polyurethane prepolymer consisting essentially of the reaction product of 1-isocyanato-3-isocyanatomethyl-3,5,5-trimethylcyclohexane and a mixture of aliphatic polyols wherein at least about 30 mole percent of the total hydroxyl groups supplied by said mixture of polyols is supplied by an aliphatic polyol having at least three hydroxyl groups and wherein said prepolymer is prepared at an NCO/OH ratio of at least 1.2:1; and (c) from about 20 percent to about 50 percent by weight of resin solids of a polyketimine material consisting essentially of the reaction product of a diketimine compound having the general formula: ##STR1## wherein R is an alkylene group of 2 to 6 carbon atoms and R.sub.1 and R.sub.2 are hydrogen or organic radicals having from 1 to 8 carbon atoms, and a polyisocyanate material selected from the group consisting of an isocyanate-terminated polyurethane prepolymer formed by reacting an organic diisocyanate and an organic diol at an NCO/OH ratio of from about 2:1 to about 4:3 or mixtures of isocyanate-terminated prepolymers and unreacted diisocyanate formed by reacting an organic diisocyanate and an organic diol at an NCO/OH ratio of from about 3:1 to about 5:1, wherein a sufficient amount of said diketimine is reacted with said polyisocyanate compound to produce a polyketimine compound containing essentially no free NCO groups.The polyurea-urethane coatings formed from the compositions of the invention have excellent chemical and physical properties and are particularly useful as coatings for wood.
摘要翻译：形成具有优异化学和物理性能的聚脲 - 聚氨酯涂料的涂料组合物通过将（a）约2％至约80％（重量）的树脂固体的异氰酸酯封端的聚氨酯预聚物基本上由有机二异氰酸酯和有机二醇，其中所述预聚物以2:1至约4:3的NCO / OH比制备，（b）约2重量％至约60重量％的树脂固体异氰酸酯封端的聚氨酯预聚物基本上由1-异氰酸基-3-异氰酸甲酯基-3,5,5-三甲基环己烷和脂族多元醇的混合物的反应产物组成，其中由所述多元醇混合物提供的总羟基的至少约30摩尔％由具有至少三个羟基的脂族多元醇，并且其中所述预聚物以至少1.2:1的NCO / OH比制备; 和（c）约20重量％至约50重量％的树脂固体的聚酮亚胺材料，其主要由以下通式的二酮亚胺化合物的反应产物组成：其中R是2至6个碳原子的亚烷基原子，R 1和R 2是氢或具有1至8个碳原子的有机基团，和多异氰酸酯材料，其选自异氰酸酯封端的聚氨酯预聚物，其通过有机二异氰酸酯和有机二醇以NCO / OH比为约2:1至约4:3或异氰酸酯封端的预聚物和通过有机二异氰酸酯和有机二醇以约3:1至约5:1的NCO / OH比反应形成的未反应的二异氰酸酯的混合物，其中足够量的所述二酮亚胺与所述多异氰酸酯化合物反应以产生基本上不含游离NCO基团的聚酮亚胺化合物。

2. 发明申请

US20080152935A1 BARRIER COATINGS 审中-公开
标题翻译：遮瑕涂层
公开(公告)号：US20080152935A1
公开(公告)日：2008-06-26
申请号：US12045062
申请日：2008-03-10
申请人： John R. Zern , Ken W. Niederst
发明人： John R. Zern , Ken W. Niederst
IPC分类号： C08G8/02 , B32B27/32
CPC分类号： C08J7/14 , C08G59/4207 , C09D163/00 , Y10T428/31504 , Y10T428/31725 , Y10T428/31786 , Y10T428/31938
摘要： A barrier coating comprising the reaction product of a polymeric material and an acid is disclosed. Methods for improving the barrier of a substrate, and substrates treated according to this method are also disclosed.
摘要翻译：公开了包含聚合物材料和酸的反应产物的阻隔涂层。还公开了改善基板的屏障的方法以及根据该方法处理的基板。

3. 发明授权

US5491204A Gas barrier coating from reacting polyamine, alkanolamine and polyepoxide 失效
标题翻译：来自多胺，链烷醇胺和聚环氧化物的气体阻隔涂层
公开(公告)号：US5491204A
公开(公告)日：1996-02-13
申请号：US429442
申请日：1995-04-27
申请人： Richard M. Nugent, Jr. , Ken W. Niederst , Jerome A. Seiner
发明人： Richard M. Nugent, Jr. , Ken W. Niederst , Jerome A. Seiner
IPC分类号： C08G59/18 , C08G59/50 , C08J7/04 , C09D163/00
CPC分类号： C08J7/047 , C08G59/184 , C09D163/00 , C08J2463/00 , Y10T428/1324 , Y10T428/1341 , Y10T428/1352 , Y10T428/1379 , Y10T428/1383 , Y10T428/139 , Y10T428/1393 , Y10T428/31507 , Y10T428/31511 , Y10T428/31786 , Y10T428/31855
摘要： Barrier materials for reducing the permeability of plastic packaging materials are provided, characterized as containing at least about seven percent by weight amine nitrogen, or a total of at least about 17 percent amine nitrogen plus hydroxyl groups. The barrier materials exhibit oxygen permeability of less than about 1.5 cc-mil/100 in.sup.2 -day-atmosphere and a carbon dioxide permeability of less than about 15 cc-mil/100 in.sup.2 -day-atmosphere at 23.degree. C. and zero percent relative humidity. The barrier material is formed from a polyepoxide, a polyamine and an alkanolamine. Optionally the polyamine may comprise prereacted polymeric resin formed from a polyepoxide and a polyamine. Multilayer packaging materials and multilayer containers including the polyamine-polyepoxide barrier material are part of the invention.
摘要翻译：提供了用于降低塑料包装材料的渗透性的阻隔材料，其特征在于含有至少约7重量％的胺氮，或总共至少约17个胺氮加羟基。阻隔材料在2天大气中表现出小于约1.5cc密尔/ 100的氧气渗透性，在23℃下在2天大气压下的二氧化碳渗透性小于约15cc-mil / 100，相对于0％湿度。阻挡材料由聚环氧化物，多胺和链烷醇胺形成。任选地，多胺可以包含由聚环氧化物和多胺形成的预反应的聚合物树脂。包括多胺 - 聚环氧化物阻隔材料的多层包装材料和多层容器是本发明的一部分。

4. 发明授权

US5300334A Pressurizable thermoplastic container having an exterior polyurethane layer and its method of making 失效
标题翻译：具有外部聚氨酯层的可加压热塑性容器及其制造方法
公开(公告)号：US5300334A
公开(公告)日：1994-04-05
申请号：US991484
申请日：1992-12-16
申请人： Ken W. Niederst , John R. Zern , Jerome A. Seiner
发明人： Ken W. Niederst , John R. Zern , Jerome A. Seiner
IPC分类号： B65D1/00 , B65D23/08 , B65D25/34 , C08J7/04
CPC分类号： C08J7/047 , B65D23/0814 , C08J2475/00 , Y10T428/1352 , Y10T428/1379 , Y10T428/1386 , Y10T428/31551 , Y10T428/31565
摘要： Pressurizable thermoplastic containers, such as those made from polyethylene terephthalate containing a polyurethane layer on the exterior surface thereof are disclosed. The polyurethane layer which is typically applied by a coating process provides the bottle with resistance to stress cracking. The containers are useful as refillable bottles for carbonated beverages which have a tendency to stress crack.
摘要翻译：公开了可加压热塑性容器，例如由其外表面上含有聚氨酯层的聚对苯二甲酸乙二醇酯制成的那些。通常通过涂覆方法施加的聚氨酯层为瓶子提供抗应力开裂性。这些容器可用作具有压力裂纹倾向的碳酸饮料的可再填充瓶。

5. 发明申请

US20080210120A1 HEAT RELEASABLE COMPOSITE COATINGS AND RELATED METHODS 有权
标题翻译：热释放复合涂料及相关方法
公开(公告)号：US20080210120A1
公开(公告)日：2008-09-04
申请号：US11681407
申请日：2007-03-02
申请人： Richard J. Foukes , Ken W. Niederst , Kevin P. Gallagher , Jackie L. Kulfan
发明人： Richard J. Foukes , Ken W. Niederst , Kevin P. Gallagher , Jackie L. Kulfan
IPC分类号： C09D193/00
CPC分类号： B05D5/00 , B05D7/52 , C08K5/01 , C08K9/10 , C09D5/008 , C09D5/20 , C09D7/69 , C09D7/70 , Y02P20/582
摘要： Disclosed are heat releasable multi-component composite coatings. These coatings include an under coating and an over coating deposited over at least a portion of the under coating. The under coating is deposited from a coating composition that includes a film-forming resin and thermally expandable capsules having an average diameter of 5 to 25 μm. The over coating layer has a 60 degree gloss of no more than 60 gloss units.
摘要翻译：公开了可热分解的多组分复合涂层。这些涂层包括沉积在底涂层的至少一部分上的底涂层和过涂层。底涂层由包括成膜树脂和平均直径为5至25μm的热膨胀胶囊的涂料组合物沉积。外涂层具有不超过60个光泽单位的60度光泽度。

6. 发明授权

US06309757B1 Gas barrier coating of polyamine, polyepoxide and hydroxyaromatic compound 有权
标题翻译：多胺，聚环氧化物和羟基芳族化合物的阻气涂层
公开(公告)号：US06309757B1
公开(公告)日：2001-10-30
申请号：US09505416
申请日：2000-02-16
申请人： Leland H. Carlblom , Cynthia Kutchko , Ken W. Niederst
发明人： Leland H. Carlblom , Cynthia Kutchko , Ken W. Niederst
IPC分类号： B32B0102
CPC分类号： C08J7/047 , C08G59/56 , C08G59/62 , C08J2463/00 , Y10T428/1334 , Y10T428/139 , Y10T428/31511 , Y10T428/31725 , Y10T428/31786 , Y10T428/31855 , Y10T428/31938
摘要： Gas barrier coating compositions are provided which include a polyamine component, a polyepoxide component and a hydroxy-substituted aromatic compound that is present in an amount sufficient to provide a gas barrier coating having an oxygen permeability less than or equal to 75 percent of the oxygen permeability of the same composition without a hydroxy-substituted aromatic compound. Also provided is a multi-layer packaging material having at least one gas permeable packaging material layer and at least one gas barrier material layer formed from the gas barrier coating composition. Sealable containers are also provided.
摘要翻译：提供了阻气涂层组合物，其包括多胺组分，聚环氧化物组分和羟基取代的芳族化合物，其以足以提供氧透过率小于或等于透氧率的75％的阻气涂层的量存在没有羟基取代的芳族化合物的相同组成。还提供了具有至少一个透气性包装材料层和由阻气涂层组合物形成的至少一个阻气材料层的多层包装材料。还提供可密封的容器。

7. 发明授权

US5728439A Multilayer packaging material for oxygen sensitive food and beverage 失效
标题翻译：用于氧敏感食品和饮料的多层包装材料
公开(公告)号：US5728439A
公开(公告)日：1998-03-17
申请号：US759905
申请日：1996-12-04
申请人： Leland H. Carlblom , Jerome A. Seiner , Ken W. Niederst
发明人： Leland H. Carlblom , Jerome A. Seiner , Ken W. Niederst
IPC分类号： B32B27/38 , B32B27/00 , B65D23/08 , C08G59/50 , C08J7/00 , C08J7/04 , C09D163/00 , B29D22/00 , B32B1/02 , B32B27/08
CPC分类号： C08J7/047 , C08G59/50 , C08J2367/02 , C08J2463/00 , Y10T428/1393 , Y10T428/31511 , Y10T428/31515 , Y10T428/31786
摘要： Disclosed is a multilayer packaging material which is suitable for use as a container for malt beverages and which is tinted so as to block at least 90% of light with wavelengths of electromagnetic radiation ranging from 300 nm to 500 nm. The tinted multilayer packaging materials of the present invention includes: (a) at least one layer of a carbon dioxide (CO.sub.2)-permeable polymeric packaging material, and (b) at least one layer of a CO.sub.2 -treated gas barrier coating, which has an oxygen permeability constant not more than 0.05 cubic centimeter-mil/100 square inches/atmosphere/day. The CO.sub.2 -permeable packaging material can be any polymeric material through which CO.sub.2 can pass and which can be used as a packaging material for food or beverages. The gas barrier coating has an oxygen permeability constant, before CO.sub.2 treatment, of less than 0.3. This gas barrier coating includes the reaction product of a polyamine (A) and a polyepoxide (B). The polyamine (A) can be an initial polyamine or an ungelled polyamine adduct having active amine hydrogens. Polyepoxide (B) can be a polyepoxide having a plurality of glycidyl groups linked to an aromatic member.
摘要翻译：公开了一种多层包装材料，其适用于麦芽饮料的容器，其被着色以阻挡至少90％的具有300nm至500nm的电磁辐射波长的光。本发明的有色多层包装材料包括：（a）至少一层二氧化碳（CO 2） - 可渗透聚合物包装材料，和（b）至少一层经CO 2处理的气体阻隔涂层，其具有氧气渗透常数不大于0.05立方厘米/ 100平方英寸/大气/天。二氧化碳可透过的包装材料可以是CO 2可以通过的任何聚合物材料，其可用作食品或饮料的包装材料。阻气涂层在CO2处理之前的氧气渗透率常数小于0.3。该阻气涂层包括多胺（A）和聚环氧化物（B）的反应产物。多胺（A）可以是具有活性胺氢的初始多胺或未凝胶化的多胺加合物。聚环氧化物（B）可以是具有连接到芳族成员的多个缩水甘油基的聚环氧化物。

8. 发明授权

US5008137A Barrier coatings 失效
标题翻译：阻隔涂层
公开(公告)号：US5008137A
公开(公告)日：1991-04-16
申请号：US367992
申请日：1989-06-19
申请人： Richard M. Nugent, Jr. , Ken W. Niederst , Jerome A. Seiner
发明人： Richard M. Nugent, Jr. , Ken W. Niederst , Jerome A. Seiner
IPC分类号： C08G59/18 , C08J7/04 , C09D163/00
CPC分类号： C08J7/047 , C08G59/184 , C09D163/00 , C08J2463/00 , Y10T428/1341 , Y10T428/1379 , Y10T428/31507 , Y10T428/31511 , Y10T428/31797 , Y10T428/31913 , Y10T428/31938
摘要： Multilayer packaging materials and multilayer containers including a barrier material having excellent resistance to gas permeability are provided. The multilayer packaging materials and containers include at least one permeable polymeric material and at least one layer of a barrier material which is a reaction product of: (i) an ungelled amine-functional polymeric resin, which is a reaction product of a polyamine and a polyfunctional material having at least two functional groups reactive with said polyamine, the ungelled polymeric resin further containing an average of greater than two polyamine moieties per molecule within said resin; and (ii) a material selected from the group consisting of a polyepoxide, a polyoxalate or mixtures thereof, the barrier material characterized as containing at least about four percent by weight amine nitrogen and having an oxygen permeability of less than about 3 cc-mil/100 in.sup.2 -day-atmosphere and a carbon dioxide permeability of less than about 15 cc-mil/100 in.sup.2 -day-atmosphere at 23.degree. C. and zero percent relative humidity. The barrier material can be formed from coating compositions including as co-curable resinous materials, e.g., a polyepoxide and an ungelled amine-functional polymeric resin formed from a polyepoxide and a polyamine having up to about two primary amino nitrogen groups per molecule, the polyamine and polyepoxide present in a reaction mixture at a molar ratio of from about 1.4:1 to about 0.83:1.
摘要翻译：提供了具有优异的耐气体渗透性的阻隔材料的多层包装材料和多层容器。多层包装材料和容器包括至少一种可渗透聚合物材料和至少一层阻隔材料层，其是以下物质的反应产物：（i）未凝胶化的胺官能聚合物树脂，其是多胺和具有至少两个与所述多胺反应的官能团的多官能材料，所述未凝胶化聚合物树脂在所述树脂内每分子平均含有大于两个多胺部分; 所述阻挡材料的特征在于含有至少约4重量％的胺氮并具有小于约3cc-mil / cm 3的氧渗透性， 100天2天气氛，二氧化碳渗透性在23℃和0％相对湿度的2天大气压下小于约15cc密耳/ 100。阻挡材料可以由包括作为共固化树脂材料的涂料组合物形成，例如聚环氧化物和由聚环氧化物形成的未凝胶化的胺官能聚合物树脂和每分子具有多达约两个伯氨基氮基团的多胺，多胺和聚环氧化物以约1.4:1至约0.83:1的摩尔比存在于反应混合物中。

9. 发明授权

US08709141B2 Heat releasable composite coatings and related methods 有权
标题翻译：热可剥离复合涂料及相关方法
公开(公告)号：US08709141B2
公开(公告)日：2014-04-29
申请号：US11681407
申请日：2007-03-02
申请人： Richard J. Foukes , Ken W. Niederst , Kevin P. Gallagher , Jackie L. Kulfan
发明人： Richard J. Foukes , Ken W. Niederst , Kevin P. Gallagher , Jackie L. Kulfan
IPC分类号： C09D193/00 , B05D5/12
CPC分类号： B05D5/00 , B05D7/52 , C08K5/01 , C08K9/10 , C09D5/008 , C09D5/20 , C09D7/69 , C09D7/70 , Y02P20/582
摘要： Disclosed are heat releasable multi-component composite coatings. These coatings include an under coating and an over coating deposited over at least a portion of the under coating. The under coating is deposited from a coating composition that includes a film-forming resin and thermally expandable capsules having an average diameter of 5 to 25 μm. The over coating layer has a 60 degree gloss of no more than 60 gloss units.
摘要翻译：公开了可热分解的多组分复合涂层。这些涂层包括沉积在底涂层的至少一部分上的底涂层和过涂层。底涂层由包括成膜树脂和平均直径为5至25μm的热膨胀胶囊的涂料组合物沉积。外涂层具有不超过60个光泽单位的60度光泽度。

10. 发明授权

US07981515B2 Bis epoxy polyesters and food cans coated with a composition comprising same 有权
标题翻译：双环氧聚酯和涂有包含其的组合物的食品罐
公开(公告)号：US07981515B2
公开(公告)日：2011-07-19
申请号：US11442866
申请日：2006-05-30
申请人： Ronald R. Ambrose , Ken W. Niederst , John M. Dudik , Mary Ann M. Fuhry
发明人： Ronald R. Ambrose , Ken W. Niederst , John M. Dudik , Mary Ann M. Fuhry
IPC分类号： B32B15/08 , C08G59/16 , C08G63/06 , C08L63/00 , C08L63/10 , C08L67/04
CPC分类号： C08G59/182 , C08G63/42 , C08G63/668 , C09D167/00 , Y10T428/13 , Y10T428/31529 , Y10T428/31681 , Y10T428/31786
摘要： Polyesters comprising the reaction product of a polyol and a bis-epoxy reacted with a mono- and/or di-phenolic carboxylic acid and/or ester are disclosed. Food cans coated at least in part on the interior with a composition comprising these polyesters are also disclosed. The composition used on the food cans is substantially free of BPA and BPF and substantially free of BADGE and BFDGE. Food cans coated at least in part on the interior with a composition comprising a polyester having a loss of molecular weight of less than 50% in an acidic medium are also disclosed.
摘要翻译：公开了包含与单 - 和/或二 - 酚羧酸和/或酯反应的多元醇和双环氧化物的反应产物的聚酯。还公开了至少部分地涂覆在内部的包含这些聚酯的组合物的食品罐。用于食品罐的组合物基本上不含BPA和BPF，并且基本上不含BADGE和BFDGE。还公开了至少部分地在内部涂覆有在酸性介质中包含分子量小于50％的聚酯的组合物的食品罐。

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