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1. 发明授权

US5432286A Substituted thieno[3,2-b]thiophenes and their use 失效
标题翻译：取代噻吩并[3,2-b]噻吩及其用途
公开(公告)号：US5432286A
公开(公告)日：1995-07-11
申请号：US133502
申请日：1993-10-07
申请人： Ivan Cabrera , Uwe Falk , Werner Hickel , Donald Lupo , Ude Scheunemann , Peter Boldt , Martin Blenkle
发明人： Ivan Cabrera , Uwe Falk , Werner Hickel , Donald Lupo , Ude Scheunemann , Peter Boldt , Martin Blenkle
IPC分类号： B05D1/20 , C07D495/04 , G02F1/35 , G02F1/355 , G02F1/361 , G02F1/365 , G02F1/37 , C07D493/04
CPC分类号： C07D495/04 , B05D1/202 , B82Y20/00 , B82Y30/00 , B82Y40/00 , G02F1/3614 , G02F1/3618
摘要： Substituted thieno[3,2-b]thiophenes, processes for their preparation and their useCompounds of the formula I ##STR1## in which R is a C.sub.1 - to C.sub.22 -alkyl radical,A.sup.1 and A.sup.2 are hydrogen or methyl orA.sup.1 is hydrogen and A.sup.2 is the nitro group, andB is the cyano group, the nitro group or an electron-attracting organic group having a double bond which is in conjugation with the thieno[3,2-b]thiophene ring system,have a high dipole moment and a high polarizability and are suitable for purposes of nonlinear optics. If R in the formula I is a C.sub.12 - to C.sub.22 -alkyl radical, monomolecular layers can be applied to a substrate by the Langmuir-Blodgett method. The resulting layer elements are suitable, inter alia, as waveguides.
摘要翻译：取代的噻吩并[3,2-b]噻吩，其制备方法及用途其中R为C 1至C 22 - 烷基的式I的化合物，A 1和A 2为氢或甲基或A 1为氢和A2是硝基，B是氰基，硝基或具有与噻吩并[3,2-b]噻吩环体系共轭的双键的吸电子有机基团具有高的偶极矩和高极化性，适用于非线性光学。如果式I中的R是C 12 -C 22烷基，则可以通过Langmuir-Blodgett法将单分子层施加到基底上。所得到的层元件尤其适用于波导。

2. 发明授权

US5684165A Substituted thieno�3,2b!thiophenes and their use 失效
标题翻译：取代噻吩并[3,2b]噻吩及其用途
公开(公告)号：US5684165A
公开(公告)日：1997-11-04
申请号：US423006
申请日：1995-04-14
申请人： Ivan Cabrera , Uwe Falk , Werner Hickel , Donald Lupo , Ude Scheunemann , Peter Boldt , Martin Blenkle
发明人： Ivan Cabrera , Uwe Falk , Werner Hickel , Donald Lupo , Ude Scheunemann , Peter Boldt , Martin Blenkle
IPC分类号： B05D1/20 , C07D495/04 , G02F1/35 , G02F1/355 , G02F1/361 , G02F1/365 , G02F1/37 , G02B6/02
CPC分类号： C07D495/04 , B05D1/202 , B82Y20/00 , B82Y30/00 , B82Y40/00 , G02F1/3614 , G02F1/3618
摘要： Compounds of the formula I ##STR1## in which R is a C.sub.1 - to C.sub.22 -alkyl radical, A.sup.1 and A.sup.2 are hydrogen or methyl or, A.sup.1 is hydrogen and A.sup.2 is the nitro group, and B is the cyano group, the nitro group or an electron-attracting organic group having a double bond which is in conjugation with the thieno�3,2-b!thiophene ring system, have a high dipole moment and a high polarizability and are suitable for purposes of nonlinear optics. If R in the formula I is a C.sub.12 - to C.sub.22 -alkyl radical, monomolecular layers can be applied to a substrate by the Langmuir-Blodgett method. The resulting layer elements are suitable, inter alia, as waveguides.
摘要翻译：其中R是C 1〜C 22 - 烷基的式I的化合物，A 1和A 2为氢或甲基，或者A 1为氢，A 2为硝基，B为氰基，硝基基团或具有与噻吩并[3,2-b]噻吩环体系共轭的双键的吸电子有机基团具有高偶极矩和高极化性，并且适用于非线性光学的目的。如果式I中的R是C 12 -C 22烷基，则可以通过Langmuir-Blodgett法将单分子层施加到基底上。所得到的层元件尤其适用于波导。

3. 发明授权

US5517350A Optical component based on Langmuir-Blodgett layers 失效
标题翻译：基于Langmuir-Blodgett层的光学元件
公开(公告)号：US5517350A
公开(公告)日：1996-05-14
申请号：US366022
申请日：1994-12-29
申请人： Ivan Cabrera , Uwe Falk , Werner Hickel , Donald Lupo , Andreas Mayer , Georg Pawlowski , Ude Scheunemann
发明人： Ivan Cabrera , Uwe Falk , Werner Hickel , Donald Lupo , Andreas Mayer , Georg Pawlowski , Ude Scheunemann
IPC分类号： B32B7/02 , C08J5/18 , C08L101/00 , G02F1/35 , G02F1/355 , G02F1/361
CPC分类号： G02F1/3618 , B82Y20/00 , G02F1/3616
摘要： An optical component comprises an electromagnetic radiation-transparent polymeric medium having a second-order susceptibility of at least 10.sup.-9 electrostatic units where this polymeric medium comprises compounds having polar-aligned noncentrosymmetric molecular dipoles which have as structural element an electron acceptor which is bound to an electron donor via a conjugated .pi.-electron system, which makes possible an oscillation of the molecular dipole between a ground state having a first dipole moment and an electronically excited state having a second dipole moment different from the first, and the nonionic polymeric medium comprises an alternating arrangement of at least one Langmuir-Blodgett film each of at least two different nonionic polymers having nonlinear optical properties. Besides high mechanical and chemical stability the optical component of the invention has excellent nonlinear optical properties, for example frequency-doubling.
摘要翻译：光学部件包括具有至少10-9个静电单元的二阶易感性的电磁辐射透明聚合物介质，其中该聚合物介质包含具有极性取向的非中心对称分子偶极子的化合物，其具有作为结构元件的电子受体，其结合到通过共轭π电子系统的电子给体，其使得可能在具有第一偶极矩的基态和具有不同于第一偶极矩的第二偶极矩的电子激发态之间的分子偶极子的振荡，并且非离子聚合物介质包括具有至少两种具有非线性光学性质的至少两种不同的非离子聚合物的至少一种Langmuir-Blodgett膜的交替排列。除了高机械和化学稳定性外，本发明的光学部件具有优异的非线性光学性质，例如倍频。

4. 发明申请

US20050070653A1 High-solids aqueous dispersions their preparation and use 审中-公开
标题翻译：高固体含水分散其制备和使用
公开(公告)号：US20050070653A1
公开(公告)日：2005-03-31
申请号：US10946958
申请日：2004-09-22
申请人： Gregor Apitz , Ivan Cabrera
发明人： Gregor Apitz , Ivan Cabrera
IPC分类号： C09K3/10 , C04B40/00 , C08F2/22 , C08K3/32 , C08L57/00 , C09J11/04 , C09J133/10 , C09J133/12 , C09J157/00 , C09J157/08 , C08L1/00
CPC分类号： C09J11/04 , C04B40/0039 , C04B2111/00672 , C04B2111/60 , C04B2111/70 , C04B22/16 , C04B24/2641 , C04B24/2688
摘要： High-solids aqueous polymer dispersions, their preparation and use A description is given of an aqueous polymer dispersion derived from at least one ethylenically unsaturated monomer and with a solids content of at least 60% by weight, based on the polymer dispersion. The polymer dispersion comprises at least one salt of a phosphorus acid. The preparation takes place by free-radical emulsion polymerization of at least one ethylenically unsaturated monomer in aqueous phase in the presence of at least one emulsifier, at least one initiator and at least one salt of a phosphorus acid. With the process it is possible to prepare aqueous polymer dispersions having a high solids content in combination with a low viscosity, these polymer dispersions being suitable for formulating adhesives.
摘要翻译：高固体含水聚合物分散体，它们的制备和应用描述了基于聚合物分散体的衍生自至少一种烯属不饱和单体的水性聚合物分散体和至少60重量％的固体含量。聚合物分散体包含至少一种磷酸盐。在至少一种烯属不饱和单体在至少一种乳化剂，至少一种引发剂和至少一种磷酸盐的存在下，在水相中通过自由基乳液聚合进行制备。通过该方法，可以制备具有高固含量的含水聚合物分散体与低粘度的组合，这些聚合物分散体适用于配制粘合剂。

5. 发明授权

US06197729B1 Substituted cyclohexylaminopyrimidines 失效
标题翻译：取代的环己基氨基嘧啶
公开(公告)号：US06197729B1
公开(公告)日：2001-03-06
申请号：US09363721
申请日：1999-07-29
申请人： Martin Märkl , Wolfgang Schaper , Oswald Ort , Harald Jakobi , Ralf Braun , Gerhard Krautstrunk , Ulrich Sanft , Werner Bonin , Herbert Stark , Sergej Pasenok , Ivan Cabrera
发明人： Martin Märkl , Wolfgang Schaper , Oswald Ort , Harald Jakobi , Ralf Braun , Gerhard Krautstrunk , Ulrich Sanft , Werner Bonin , Herbert Stark , Sergej Pasenok , Ivan Cabrera
IPC分类号： A01N4354
CPC分类号： C07D239/42 , A01N43/54 , C07D239/47
摘要： Compounds of formula I where R1 is hydrogen, chlorine, fluorine or methyl, R2 and R3, which may be the same or different from each other, are hydrogen, halogen, cyano, (C1-C4)-alkyl, vinyl, ethynyl, (C1-C4)-alkoxy, (C1-C4)-alkoxy-(C1-C4)-alkyl, fluorovinyl or fluoroethyl, or R2 and R3 together with the linking carbon atoms form a benzo ring, and R4 is (C2-C4)-alkyl, (C2-C4)-alkenyl or (C3-C4)-alkinyl, each of which is substituted by at least two fluorine atoms and optionally substituted by C1-4-alkoxy, cyanomethoxy, (C3-C4)-alkenyloxy or (C3-C4)-alkinyloxy, are useful as pesticides, especially against insects, acarids and fungi. The invention includes a novel process for fluorinating certain pyrimidines.
摘要翻译：式I的化合物，其中R 1是氢，氯，氟或甲基，R 2和R 3可以相同或不同，是氢，卤素，氰基，（C 1 -C 4） - 烷基，乙烯基，乙炔基，（C1- C4） - 烷氧基，（C1-C4） - 烷氧基 - （C1-C4） - 烷基，氟乙烯基或氟乙基，或R2和R3与连接碳原子一起形成苯并环，R 4是（C 2 -C 4） - 烷基，（（C 3 -C 4） - 炔基，（C 3 -C 4） - 炔基，其各自被至少两个氟原子取代并任选被C 1-4 - 烷氧基取代，氰基甲氧基，（C 3 -C 4） - 炔基氧基或（C 3 -C 4 ） - 烷氧基，可用作农药，特别是昆虫，螨类和真菌。本发明包括用于氟化某些嘧啶的新方法。

6. 发明申请

US20100144925A1 Plasters and Renders and Paints, Copolymer Dispersions and Their Use 有权
标题翻译：灰泥和涂料，共聚物分散体及其用途
公开(公告)号：US20100144925A1
公开(公告)日：2010-06-10
申请号：US12444035
申请日：2007-09-21
申请人： Ivan Cabrera , Thomas Fichtner , Stephan Krieger , Marc Theodorus Ratering
发明人： Ivan Cabrera , Thomas Fichtner , Stephan Krieger , Marc Theodorus Ratering
IPC分类号： C08K7/00 , C08L43/04 , C08L83/00 , C08K3/26 , C08K3/34 , C08K3/22 , C08K5/3417
CPC分类号： C04B26/02 , C04B28/26 , C09D133/14 , C09D143/02 , C09D143/04 , C04B14/06 , C04B14/062 , C04B14/20 , C04B14/28 , C04B20/008 , C04B24/42 , C04B2103/54 , C04B24/2688 , C04B14/30 , C04B14/305 , C04B14/308 , C04B24/12 , C04B24/2641
摘要： Compositions containing selected polymer dispersions, colloidal silica, fillers and pigments are described.These can be formulated to give plasters and renders or paints which are distinguished by excellent abrasion resistance, little tendency to soiling, high water vapor permeability, good adhesion and good weathering stability. The compositions according to the invention can be processed to give plasters and renders or paints which have a nanostructured surface and which differ from conventionally produced surfaces.
摘要翻译：描述了包含所选聚合物分散体，胶体二氧化硅，填料和颜料的组合物。这些可以配制成具有优异的耐磨性，少的污染倾向，高透湿性，良好的粘合性和良好的耐候稳定性的膏药和油漆。根据本发明的组合物可以加工成具有具有纳米结构表面并且与常规生产的表面不同的灰泥和涂料或涂料。

7. 发明申请

US20090203814A1 Aqueous Plastic Dispersions, Method for Producing the Same and Their Use 有权
标题翻译：水性塑料分散体，其制备方法及其用途
公开(公告)号：US20090203814A1
公开(公告)日：2009-08-13
申请号：US11994881
申请日：2006-06-27
申请人： Harald Petri , Ivan Cabrera
发明人： Harald Petri , Ivan Cabrera
IPC分类号： C09D167/00 , C08L1/00 , C08L3/02 , C08K5/3415 , C08K5/5317 , C08K5/41 , C08K5/06 , C08F263/02 , C08K3/00 , C09J167/00
CPC分类号： C08F2/24 , C08F263/02 , C08L51/003 , C08L53/00 , C08L2205/02 , C09D143/04 , C09D151/003 , C09D153/00 , C08L2666/02 , C08L2666/04
摘要： Multistage polymers predominantly stabilized by nonionic emulsifiers and derived from hard and soft monomer compositions containing vinyl esters, of which at least one monomer composition must contain an unsaturated compromisable organosilicon compound, are described.The plastic dispersions can be used as binders in emulsion paints and finishes and impart to these excellent scrub resistance in addition to good blocking resistance.
摘要翻译：主要由非离子乳化剂稳定并衍生自含有乙烯基酯的硬和软单体组合物的多级聚合物，其中至少一种单体组合物必须含有不饱和的有害硅化合物。塑料分散体可以用作乳液漆和表面处理剂中的粘合剂，并赋予这些优异的耐擦洗性以及良好的抗粘连性。

8. 发明申请

US20080214722A1 Coating Agent With High Abrasion Resistance Method For Production And Application Thereof 审中-公开
标题翻译：具有高耐磨性的涂层剂生产和应用
公开(公告)号：US20080214722A1
公开(公告)日：2008-09-04
申请号：US11912066
申请日：2006-04-10
申请人： Harald Petri , Ivan Cabrera
发明人： Harald Petri , Ivan Cabrera
IPC分类号： C08L23/00
CPC分类号： C08F218/08 , C08L2312/08 , C09D5/024 , C09D131/04
摘要： A description is given of coating compositions comprising at least one pigment and/or filler and at least one aqueous dispersion of a selected emulsifier-stabilized vinyl ester copolymer which comprises as its stabilizer a mixture of at least one nonionic emulsifier and at least one salt of a bisester of a sulfonated dicarboxylic acid having 4 to 8 carbon atoms.The coating compositions formulated with these binders feature high scrub resistance.
摘要翻译：给出了包含至少一种颜料和/或填料的至少一种颜料和/或填料和至少一种所选择的乳化剂稳定的乙烯基酯共聚物的水性分散体的涂料组合物的描述，其包含至少一种非离子乳化剂和至少一种非离子乳化剂的盐的混合物作为其稳定剂具有4至8个碳原子的磺化二羧酸的双酯。用这些粘合剂配制的涂料组合物具有高耐擦洗性。

9. 发明授权

US5356752A Compounds with acid-labile protective groups useful in positive-working radiation-sensitive mixtures 失效
标题翻译：具有酸性不稳定保护基的化合物可用于正性辐射敏感混合物
公开(公告)号：US5356752A
公开(公告)日：1994-10-18
申请号：US920848
申请日：1992-07-28
申请人： Ivan Cabrera , Walter Spiess , Georg Pawlowski
发明人： Ivan Cabrera , Walter Spiess , Georg Pawlowski
IPC分类号： B01J27/055 , B01J31/08 , B01J31/24 , C07B61/00 , C07C68/06 , C07C69/96 , C07C205/43 , C07C233/69 , C07C255/54 , C07C309/73 , C07C311/24 , C09K9/02 , G03F7/004 , G03C1/492
CPC分类号： G03F7/0045 , C07C69/96 , Y02P20/55
摘要： Disclosed are compounds of the formula I ##STR1## in which X is a phenyl, [1]naphthyl or [2]naphthyl radical each substituted by at least one tert.-butoxycarbonyloxy group and, if appropriate, having one or more than one additional substituent,R.sup.1 is a hydrogen atom, a (C.sub.1 -C.sub.6)-alkyl radical, a (C.sub.6 -C.sub.10)-aryl radical or one of the radicals X andR.sup.2 and R.sup.3 are identical or different and are a (C.sub.1 -C.sub.12)-alkyl radical in which, if appropriate, up to three methylene groups are replaced by bridge members having at least one hetero atom, such as --O--, --S--, --NR.sup.4 --, --CO--, --CO--O--, --CO--NH--, --O--CO--NH--, --NH--CO--NH--, --CO--NH--CO--, --SO.sub.2 --, --SO.sub.2 --O-- or --SO.sub.2 --NH--, a (C.sub.3 -C.sub.12)-alkenyl, (C.sub.3 -C.sub.12)-alkynyl, (C.sub.4 -C.sub.12)-cycloalkyl, (C.sub.4 -C.sub.12)-cycloalkenyl or (C.sub.8 -C.sub.16)-aralkyl radical in which, if appropriate, up to three methylene groups of the aliphatic moiety are replaced by bridge members of the abovementioned type and which can be substituted in the aromatic moiety by fluorine, chlorine or bromine atoms or by (C.sub.1 -C.sub.4)-alkyl, (C.sub.1 -C.sub.4)-alkoxy, nitro, cyano or tert.-butoxycarbonyloxy groups,R.sup.4 being an acyl radical, especially a (C.sub.1 -C.sub.6)-alkanoyl radical.
摘要翻译：公开了式I的化合物，其中X是苯基，[1]萘基或[2]萘基，其各自被至少一个叔丁氧羰基氧基取代，并且如果合适，具有一个或多于一个另外的取代基，R 1是氢原子，（C 1 -C 6） - 烷基，（C 6 -C 10） - 芳基或基团X和R 2和R 3中的一个相同或不同，并且是（C 1 -C 12） - 烷基，其中如果合适，最多三个亚甲基被具有至少一个杂原子的桥连构件替代，例如-O - ， - S - ， - NR 4 - ， - CO - ， - CO-O-， - CO-NH-，-O-CO-NH-，-NH-CO-NH-，-CO-NH-CO-，-SO2-，-SO2-O-或-SO2-NH-，（C3-C12 ） - 烯基，（C 3 -C 12） - 炔基，（C 4 -C 12） - 环烷基，（C 4 -C 12） - 环烯基或（C 8 -C 16） - 芳烷基，其中如果合适，最多三个亚烷基部分被上述类型的桥连体取代，并且可以在芳族部分被氟，氯或溴原子取代，或被（C 1 -C 4） - 烷基 1，（C 1 -C 4） - 烷氧基，硝基，氰基或叔丁氧基羰基氧基，R 4是酰基，特别是（C 1 -C 6） - 烷酰基。

10. 发明授权

US5354643A Oligomeric compounds with acid-labile protective groups useful in positive-working radiation-sensitive mixture 失效
标题翻译：具有酸性不稳定保护基团的低聚化合物可用于正性辐射敏感混合物
公开(公告)号：US5354643A
公开(公告)日：1994-10-11
申请号：US920633
申请日：1992-07-28
申请人： Ivan Cabrera , Georg Pawlowski
发明人： Ivan Cabrera , Georg Pawlowski
IPC分类号： C08G65/34 , G03F7/004 , G03F7/039 , H01L21/027 , G03C1/492
CPC分类号： G03F7/0045 , G03F7/039
摘要： Disclosed are compounds of the formula I ##STR1## in which X is a phenyl, [1]naphthyl or [2]naphthyl radical each substituted by at least one tert.-butoxycarbonyloxy group and, if appropriate, having one or more than one additional substituent,R.sup.1 is a hydrogen atom, a (C.sub.1 -C.sub.6)-alkyl radical, a (C.sub.6 -C.sub.10)-aryl radical or one of the radicals X andR.sup.2 is a (C.sub.4 -C.sub.12)-alkylene, (C.sub.4 -C.sub.12)-alkenylene or (C.sub.4 -C.sub.12)-alkynylene group in which, if appropriate, up to three methylene groups are replaced by bridge members having at least one hetero atom, such as --O--, --S--, --NR.sup.3 --, --CO--, --CO--O--, --CO--NH--, --O--CO--NH--, --NH--CO--NH--, --CO--NH--CO--, --SO.sub.2 --, --SO.sub.2 --O-- or --SO.sub.2 --NH--, a (C.sub.4 -C.sub.12)-cycloalkylene, (C.sub.4 -C.sub.12)-cycloalkenylene or (C.sub.8 -C.sub.16)-arylenebisalkyl radical in which, if appropriate, up to three methylene groups of the aliphatic moiety are replaced by bridge members of the above-mentioned type and which can be substituted in the aromatic moiety by fluorine, chlorine or bromine atoms or by (C.sub.1 -C.sub.4)-alkyl, (C.sub.1 -C.sub.4)-alkoxy, nitro, cyano or tert.-butoxycarbonyloxy groups,R.sup.3 being an acyl radical, especially a (C.sub.1 -C.sub.6)-alkanoyl radical, andn being an integer from 2 to 50, preferably from 5 to 20.
摘要翻译：公开了式I的化合物，其中X是苯基，[1]萘基或[2]萘基，其各自被至少一个叔丁氧羰基氧基取代，并且如果合适，具有一个或多于一个另外的取代基，R 1是氢原子，（C 1 -C 6） - 烷基，（C 6 -C 10） - 芳基或基团X和R 2之一是（C 4 -C 12） - 亚烷基，（C 4 -C 12） - 亚烯基或（C 4 -C 12） - 亚炔基，其中如果合适的话最多三个亚甲基被具有至少一个杂原子的桥连构件替代，例如-O - ， - S - ， - NR 3 - ， - CO - ，-CO-O-，-CO-NH-，-O-CO-NH-，-NH-CO-NH-，-CO-NH-CO-，-SO2-，-SO2-O-或-SO2 -NH-，（C 4 -C 12） - 亚环烷基，（C 4 -C 12） - 亚环烯基或（C 8 -C 16） - 亚芳基双烷基，其中如果合适的话，脂族部分的多至三个亚甲基被可以在芳族部分被氟，氯或溴原子或（C 1 -C 4） - 烷基，（C 1 -C 4） - 烷基取代的上述类型 xy，硝基，氰基或叔丁氧基羰基氧基，R 3是酰基，特别是（C 1 -C 6） - 烷酰基，n是2至50，优选5至20的整数。

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