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    • 1. 发明授权
    • Method of making bipolar carbon-plastic electrode structure-containing
multicell electrochemical device
    • 制备双极碳 - 塑料电极结构的多电极电化学装置的方法
    • US4164068A
    • 1979-08-14
    • US862174
    • 1977-12-19
    • Joseph A. ShropshireHsue C. Tsien
    • Joseph A. ShropshireHsue C. Tsien
    • H01M6/48H01M10/04
    • H01M6/48H01M10/0418Y10T29/49108Y10T29/4911Y10T29/49114
    • A novel multicell electrochemical device having a plurality of bipolar carbon-plastic electrode structures and a novel method of making the device are described. A plurality of bipolar carbon-plastic electrode structures are formed by first molding thin conductive carbon-plastic sheets from heated mixtures of specified carbon and plastic, and then establishing frames of dielectric plastic material around the sheets and sealing the frames to the sheets so as to render the resulting structures liquid impermeable. A plurality of electrochemical cell elements in addition to the electrode structures, e.g. separators, spacers and the like, are also formed with dielectric plastic frames. The frames of both the electrode structures and the additional elements have projections on at least one surface. The electrode structures and the additional elements are stacked to form a group of items in an electrochemically functional arrangement. The arrangement is such that the projection of each frame contacts a frame surface of the next item in the stack. The items in the stack are joined to one another, e.g. by heat welding or ultrasonic welding, at these areas of contact so as to form a multicell electrochemical device capable of holding liquid therein.
    • 描述了一种具有多个双极碳 - 塑料电极结构的新型多电化学电化学装置和制造该装置的新颖方法。 通过首先从特定碳和塑料的加热混合物成型薄导电碳塑料片,然后在片材周围建立介电塑料材料框架并将框架密封到片材上来形成多个双极碳 - 塑料电极结构,以便 使所得到的结构液体不可渗透。 除了电极结构之外的多个电化学电池元件,例如, 分隔件,间隔件等也由电介质塑料框架形成。 电极结构和附加元件的框架在至少一个表面上具有突起。 电极结构和附加元件被堆叠以形成一组以电化学功能布置的物品。 该布置使得每个框架的突起接触堆叠中的下一个物品的框架表面。 堆叠中的项目彼此连接,例如。 通过热焊接或超声波焊接,在这些接触区域形成能够保持液体的多电化学电化学装置。
    • 4. 发明授权
    • Thin sheet apparatus and a fluid flow device
    • 薄片装置和流体流动装置
    • US4124478A
    • 1978-11-07
    • US766127
    • 1977-02-07
    • Hsue C. TsienJoseph A. ShropshireAgustin F. Venero
    • Hsue C. TsienJoseph A. ShropshireAgustin F. Venero
    • C25B9/00C25B9/20F28F3/08H01M8/02H01M8/24H01M12/02
    • H01M8/246B01D63/082C25B9/20F28F3/083H01M8/0273B01D2313/10B01D2313/12Y10S366/03
    • A thin sheet apparatus is described as having a front and a back and having a central area and a frame area disposed around the central area. The central area is made of a fluid impermeable material having substantially planar surfaces. The frame area contains two sets of supply orifices and drainage orifices which are opposite one another. The frame area also contains a plurality of channels for each orifice which connects the orifice with the central area. The pluralities of channels for the first set of supply orifices and drainage orifices are located on the front of the frame area while the pluralities of channels for the second set of supply orifices and drainage orifices are located on the back. Also described is a fluid flow device which contains a number of stacked groups of elements in which each of the groups contains the above mentioned thin sheet apparatus as well as various plastic sheets having channels connecting the supply orifices and drainage orifices and having membrane separator means for the stacked elements. The fluid flow device is particularly useful as an electrochemical cell in a preferred embodiment in which the central area is made of conductive material and in which the stacked groups of elements contain current collectors at each end.
    • 薄片装置被描述为具有前部和后部并且具有设置在中心区域周围的中心区域和框架区域。 中心区域由具有基本平坦表面的不透液体材料制成。 框架区域包含两组彼此相对的供应孔和排水孔。 框架区域还包括用于将孔口与中心区域连接的每个孔口的多个通道。 第一组供水孔和排水孔的多个通道位于框架区域的前部,而第二组供水孔和排水孔的多个通道位于背面。 还描述了一种流体流动装置,其包含多个堆叠的元件组,其中每个组包含上述薄片装置以及具有连接供给孔和排出孔的通道的各种塑料片,并且具有用于 堆叠元素。 在优选实施例中,流体流动装置特别适用于电化学电池,其中中心区域由导电材料制成,并且其中堆叠的元件组在每个端部都包含集电器。
    • 8. 发明授权
    • Electrically conductive polyolefin compositions
    • 导电聚烯烃组合物
    • US4169816A
    • 1979-10-02
    • US883902
    • 1978-03-06
    • Hsue C. Tsien
    • Hsue C. Tsien
    • H01B1/24H01M4/66H01B1/06H01B1/08
    • H01B1/24H01M4/66H01M4/663H01M4/668
    • This invention provides an electrically conductive polyolefin composition which contains a balanced mixture of fillers which increase the extrudability of the polyolefin composition into shaped articles of improved flex strength and resistance to shrinkage. The amounts of constituents of compositions of this invention, expressed in parts by weight, are as follows: 100 parts of polypropylene-ethylene copolymer, 15.30 parts of carbon black, 0.25 to 1 part of silica, and 1-10 parts of a fiber-reinforcing agent selected from carbon fibers or mixtures of carbon and glass fibers; and when the fiber-reinforcing agent is a mixture of carbon and glass fibers, then the composition shall contain from 1 to 5 parts of glass fibers and from 1 to 5 parts of carbon fibers.
    • 本发明提供了一种导电聚烯烃组合物,其包含平衡的填料混合物,其将聚烯烃组合物的挤出性提高到具有改善的挠曲强度和抗收缩性的成型制品。 以重量份表示的本发明组合物的组分量如下:100份聚丙烯 - 乙烯共聚物,15-30份炭黑,0.25-1份二氧化硅和1-10份 纤维增强剂选自碳纤维或碳和玻璃纤维的混合物; 当纤维增强剂是碳和玻璃纤维的混合物时,组合物应含有1至5份玻璃纤维和1至5份碳纤维。
    • 9. 发明授权
    • Liquid membrane generator
    • 液膜发生器
    • US4201691A
    • 1980-05-06
    • US869837
    • 1978-01-16
    • William J. AsherHsue C. Tsien
    • William J. AsherHsue C. Tsien
    • B01J13/00B01D61/40B01F3/08B01F5/04A61K35/14B01F3/00B01J13/02
    • B01F3/0807B01D61/40B01F5/04B01F5/0476B01F2003/0834B01F2215/0431Y10S261/26Y10S516/924Y10S516/928
    • An apparatus is disclosed for generating a multiple phase dispersion and distributing said multiple phase dispersion as globules in a suspension phase. The apparatus comprises a conduit for introducing a first fluid under pressure into a first zone including a porous fluid dispersing layer. This first zone is in fluid communication with a second zone through the porous fluid dispersing layer. The second zone has introduced into it a second fluid under pressure through inlets. The first fluid is dispersed as bubble-like micro droplets in the second fluid by passage from the first zone through the fluid dispersing layer into the fluid in the second zone. An outlet zone is in contact with the second zone and comprises a perforated nonporous layer having an outer and inner surface and includes a porous flow distribution layer substantially in contact with the inner second zone facing surface of the nonporous layer. The multiple phase dispersion formed in the second zone enters the outlet zone through the porous flow distribution layer and exits the outlet zone as globules of predetermined size through the perforations where the outer surface of said perforated nonporous layer forms an interface with a suspension phase which is immiscible with the second fluid.The instant invention further relates to a process for generating multiple phase dispersions as globules in a suspension phase.
    • 公开了一种用于产生多相色散并将所述多相色散分布为悬浮相中的小球的装置。 该装置包括用于将第一流体在压力下引入包括多孔流体分散层的第一区域的导管。 该第一区域通过多孔流体分散层与第二区域流体连通。 第二个区域通过入口向压力下引入第二个流体。 第一流体通过从第一区域通过流体分散层通入第二区域中的流体而分散成第二流体中的气泡状微滴。 出口区域与第二区域接触并且包括具有外表面和内表面的穿孔无孔层,并且包括基本上与无孔层的内部第二区域面向表面接触的多孔流动分布层。 形成在第二区中的多相分散体通过多孔流分布层进入出口区,并通过穿孔穿过出孔离开出口区,其中所述穿孔无孔层的外表面与悬浮相形成界面 与第二流体不混溶。 本发明还涉及一种在悬浮相中产生作为小球的多相分散体的方法。
    • 10. 发明授权
    • Bipolar carbon-plastic electrode structure-containing multicell
electrochemical device and method of making same
    • 双极碳 - 塑料电极结构的多电化学电化学装置及其制备方法
    • US4125680A
    • 1978-11-14
    • US825605
    • 1977-08-18
    • Joseph A. ShropshireHsue C. Tsien
    • Joseph A. ShropshireHsue C. Tsien
    • H01M6/48
    • H01M6/48
    • A novel multicell electrochemical device having a plurality of bipolar carbon-plastic electrode structures and a novel method of making the device are described. A plurality of bipolar carbon-plastic electrode structures are formed by first molding thin conductive carbon-plastic sheets from heated mixtures of specified carbon and plastic, and then establishing frames of dielectric plastic material around the sheets and sealing the frames to the sheets so as to render the resulting structures liquid impermeable. A plurality of electrochemical cell elements in addition to the electrode structures, e.g. separators, spacers and the like, are also formed with dielectric plastic frames. The frames of both the electrode structures and the additional elements have projections on at least one surface. The electrode structures and the additional elements are stacked to form a group of items in an electrochemically functional arrangement. The arrangement is such that the projection of each frame contacts a frame surface of the next item in the stack. The items in the stack are joined to one another, e.g. by heat welding or ultrasonic welding, at these areas of contact so as to form a multicell electrochemical device capable of holding liquid therein.
    • 描述了一种具有多个双极碳 - 塑料电极结构的新型多电化学电化学装置和制造该装置的新颖方法。 通过首先从特定碳和塑料的加热混合物成型薄导电碳塑料片,然后在片材周围建立介电塑料材料框架并将框架密封到片材上来形成多个双极碳 - 塑料电极结构,以便 使所得到的结构液体不可渗透。 除了电极结构之外的多个电化学电池元件,例如, 分隔件,间隔件等也由电介质塑料框架形成。 电极结构和附加元件的框架在至少一个表面上具有突起。 电极结构和附加元件被堆叠以形成一组以电化学功能布置的物品。 该布置使得每个框架的突起接触堆叠中的下一个物品的框架表面。 堆叠中的项目彼此连接,例如。 通过热焊接或超声波焊接,在这些接触区域形成能够保持液体的多电化学电化学装置。