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    • 5. 发明授权
    • High-corrosion-resistant martensitic stainless steel having excellent
weldability and process for producing the same
    • 具有优异焊接性的高耐腐蚀马氏体不锈钢及其制造方法
    • US5716465A
    • 1998-02-10
    • US649701
    • 1996-08-27
    • Takuya HaraAsahi HitoshiHiroshi TamehiroTaro MurakiAkira Kawakami
    • Takuya HaraAsahi HitoshiHiroshi TamehiroTaro MurakiAkira Kawakami
    • C21D1/18C21D8/02C22C38/42
    • C22C38/42C21D8/0205C21D1/18C21D2211/008
    • A high-corrosion-resistant martensitic stainless steel possessing excellent weldability and SSC resistance, having a tempered martensitic structure, characterized by comprising steel constituents satisfying by weight C: 0.005 to 0.035%, Si: not more than 0.50%, Mn: 0.1 to 1.0%, P: not more than 0.03%, S: not more than 0.005%, Mo: 1.0 to 3.0%, Cu: 1.0 to 4.0%, Ni: 1.5 to 5.0%, Al: not more than 0.06%, N: not more than 0.01%, and Cr satisfying a requirement represented by the formula 13>Cr+1.6Mo.gtoreq.8, C+N.gtoreq.0.03, 40C+34N+Ni+0.3Cu-1.1Cr-1.8 Mo.gtoreq.10, or further comprising at least one element selected from the group consisting of Ti: 0.05 to 0.1%, Zr: 0.01 to 0.2%, Ca: 0.001 to 0.02%, and REM: 0.003 to 0.4%, with the balance consisting essentially of Fe. A process for producing a martensitic stainless steel, comprising the steps of: subjecting a steel plate, produced by hot-rolling a stainless steel slab having the above composition, to austenitization at a temperature of Ac.sub.3 point to 1000.degree. C. to harden the steel plate; subjecting the hardened steel plate to final tempering at a temperature of 550.degree. C. to Ac.sub.1 point; and cold-rolling the steel plate.
    • PCT No.PCT / JP95 / 01950 Sec。 371日期:1996年8月27日 102(e)日期1996年8月27日PCT提交1995年9月27日PCT公布。 公开号WO96 / 10654 日期1996年4月11日具有回火马氏体组织的耐焊接性和耐SSC性优异的高耐腐蚀马氏体系不锈钢,其特征在于,含有C:0.005〜0.035%,Si:0.50%以下, Mn:0.1〜1.0%,P:0.03%以下S:0.005%以下,Mo:1.0〜3.0%,Cu:1.0〜4.0%,Ni:1.5〜5.0%,Al:0.06以下 %,N:0.01以下,Cr满足式13> Cr + 1.6Mo> / = 8,C + N> = 0.03,40C + 34N + Ni + 0.3Cu-1.1Cr- 或者还包含选自Ti:0.05〜0.1%,Zr:0.01〜0.2%,Ca:0.001〜0.02%,REM:0.003〜0.4%的至少一种元素,与 余量基本上由Fe组成。 一种马氏体不锈钢的制造方法,其特征在于,包括以下步骤:将具有上述组成的不锈钢板进行热轧制成的钢板在Ac 3点〜1000℃的温度下进行奥氏体化,使钢 盘子; 使淬火钢板在550℃至Ac1点的温度下进行最终回火; 并冷轧钢板。
    • 6. 发明授权
    • Method for producing ultra-high strength, weldable steels with superior toughness
    • 具有优异韧性的超高强度,可焊接钢的生产方法
    • US06248191B1
    • 2001-06-19
    • US09123858
    • 1998-07-28
    • Michael J. LutonJayoung KooNarasimha-Rao V. BangaruClifford W. PetersenHiroshi TamehiroHitoshi AsahiTakuya HaraMasaaki Sugiyama
    • Michael J. LutonJayoung KooNarasimha-Rao V. BangaruClifford W. PetersenHiroshi TamehiroHitoshi AsahiTakuya HaraMasaaki Sugiyama
    • C21D800
    • C21D6/005C21D1/19C21D8/0226C21D2211/002C21D2211/008
    • A method is provided for producing an ultra-high strength steel having a tensile strength of at least about 900 MPa (130 ksi), a toughness as measured by Charpy V-notch impact test at −40° C. (−40° F.) of at least about 120 joules (90 ft-lbs), and a microstructure comprising predominantly fine-grained lower bainite, fine-grained lath martensite, or mixtures thereof, transformed from substantially unrecrystallized austenite grains and comprising iron and specified weight percentages of the additives: carbon, silicon, manganese, copper, nickel, niobium, vanadium, molybdenum, chromium, titanium, aluminum, calcium, Rare Earth Metals, and magnesium. A steel slab is heated to a suitable temperature; the slab is reduced to form plate in one or more hot rolling passes in a first temperature range in which austenite recrystallizes; said plate is further reduced in one or more hot rolling passes in a second temperature range below said first temperature range and above the temperature at which austenite begins to transform to ferrite during cooling; said plate is quenched to a suitable Quench Stop Temperature; and said quenching is stopped and said plate is allowed to air cool to ambient temperature.
    • 提供一种制造抗拉强度为至少约900MPa(130ksi)的超高强度钢,-40℃下通过夏比V-缺口冲击试验测得的韧性的方法(-40°F) )至少约120焦耳(90ft-lbs),以及由基本上未再结晶的奥氏体晶粒转化并且包含铁和特定重量百分比的主要由细晶粒的下贝氏体,细粒状板条马氏体或其混合物组成的微结构, 添加剂:碳,硅,锰,铜,镍,铌,钒,钼,铬,钛,​​铝,钙,稀土金属和镁。 将钢坯加热到合适的温度; 在奥氏体再结晶的第一温度范围内,在一个或多个热轧道中,将板坯还原成板; 所述板在一个或多个热轧道中在低于所述第一温度范围和高于在冷却期间奥氏体开始转变为铁素体的温度的温度范围内进一步减小; 所述板淬火至合适的淬火停止温度; 并且停止淬火,并使所述板空气冷却至环境温度。
    • 7. 发明授权
    • Ultra-high strength, weldable, boron-containing steels with superior toughness
    • 超高强度,可焊接,具有优异韧性的含硼钢
    • US06228183B1
    • 2001-05-08
    • US09123791
    • 1998-07-28
    • Narasimha-Rao V. BangaruJayoung KooMichael J. LutonClifford W. PetersenHiroshi TamehiroHitoshi AsahiTakuya HaraYoshio Terada
    • Narasimha-Rao V. BangaruJayoung KooMichael J. LutonClifford W. PetersenHiroshi TamehiroHitoshi AsahiTakuya HaraYoshio Terada
    • C22C3814
    • C22C38/06C21D1/19C21D8/00C21D2211/002C21D2211/008C22C38/04C22C38/12C22C38/14
    • An ultra-high strength boron-containing steel having a tensile strength of at least about 900 MPa (130 ksi), a toughness as measured by Charpy V-notch impact test at −40° C. (−40° F.) of at least about 120 joules (90 ft-lbs), and a microstructure comprising predominantly fine-grained lower bainite, fine-grained lath martensite, or mixtures thereof, transformed from substantially unrecrystallized austenite grains and comprising iron and specified weight percentages of the additives: carbon, silicon, manganese, copper, nickel, niobium, vanadium, molybdenum, chromium, titanium, aluminum, calcium, Rare Earth Metals, and magnesium, is prepared by heating a steel slab to a suitable temperature; reducing the slab to form plate in one or more hot rolling passes in a first temperature range in which austenite recrystallizes; further reducing said plate in one or more hot rolling passes in a second temperature range below said first temperature range and above the temperature at which austenite begins to transform to ferrite during cooling; quenching said plate to a suitable Quench Stop Temperature; and stopping said quenching and allowing said plate to air cool to ambient temperature.
    • 具有至少约900MPa(130ksi)拉伸强度的超高强度含硼钢,在-40℃(-40°F)下通过夏比V-缺口冲击试验测得的韧性 至少约120焦耳(90ft-lbs),以及由基本上未再结晶的奥氏体晶粒转化并且包含铁和特定重量百分比的添加剂的主要包含细粒度的下贝氏体,细粒状板条马氏体或其混合物的微观结构:碳 通过将钢坯加热到合适的温度来制备硅,锰,铜,镍,铌,钒,钼,铬,钛,​​铝,钙,稀土金属和镁, 在奥氏体重结晶的第一温度范围内,在一个或多个热轧道中将板坯还原成板; 在低于所述第一温度范围的第二温度范围内并且高于在冷却期间奥氏体开始转变为铁素体的温度的一个或多个热轧道中进一步减少所述板; 将所述板淬火至合适的淬火停止温度; 并停止所述淬火并允许所述板空气冷却至环境温度。
    • 8. 发明授权
    • Super-high-strength line pipe excellent in low temperature toughness and production method thereof
    • 低温韧性优异的超高强度线管及其制造方法
    • US06532995B1
    • 2003-03-18
    • US09478653
    • 2000-01-06
    • Hitoshi AsahiHiroshi TamehiroTakuya HaraYoshio TeradaShigeru OhkitaKunio Koyama
    • Hitoshi AsahiHiroshi TamehiroTakuya HaraYoshio TeradaShigeru OhkitaKunio Koyama
    • F16L900
    • C22C38/12C22C38/04C22C38/08C22C38/44C22C38/46C22C38/58Y10T29/18
    • To provide a super-high strength line pipe that is excellent in low temperature toughness, can be field welded easily, and has a tensile strength of at least 900 MPa (exceeding ×100 of the API standard), and a production method thereof. The present invention relates to a super-high strength line pipe produced by shaping a steel plate into a pipe shape and arc welding seam portions, the strength of a base steel portion is 900 to 1,100 MPa and the strength of the weld metal is higher than the base steel strength −100 MPa. In the steel pipe, the Ni content of the weld metal is higher by at least 1% than that of the base steel. The combination of the chemical components of the steel plate with those of the weld metal, for accomplishing these steel pipes by a U&O step is shown concretely. A production method of the steel plate and the welding method for achieving the steel pipe are also described. Furthermore, a method of reducing the strength of the inner surface of the weld metal to restrict cracking at the time of pipe expansion is also shown.
    • 为了提供低温韧性优异的超高强度线管,可以容易地进行现场焊接,并且具有至少900MPa(超过API标准的×100)的拉伸强度及其制造方法。 本发明涉及一种通过将钢板成形为管状和电弧焊缝部而制造的超高强度线管,基部钢的强度为900〜1100MPa,焊接金属的强度高于 基钢强度-100MPa。 在钢管中,焊接金属的Ni含量比基体钢高1%以上。 具体地说,钢板的化学成分与焊接金属的化学成分的组合,通过U&O工序来实现这些钢管。 还描述了钢板的制造方法和用于实现钢管的焊接方法。 此外,还示出了降低焊接金属内表面的强度以限制管膨胀时的开裂的方法。
    • 9. 发明授权
    • Ultra-high strength, weldable, essentially boron-free steels with superior toughness
    • 超高强度,可焊接,基本上无硼钢,韧性优越
    • US06224689B1
    • 2001-05-01
    • US09123859
    • 1998-07-28
    • Jayoung KooMichael J. LutonNarasimha-Rao V. BangaruClifford W. PetersenHiroshi TamehiroHitoshi AsahiTakuya HaraYoshio Terada
    • Jayoung KooMichael J. LutonNarasimha-Rao V. BangaruClifford W. PetersenHiroshi TamehiroHitoshi AsahiTakuya HaraYoshio Terada
    • C22C3812
    • C22C38/08C21D1/19C21D2211/002C21D2211/005C22C38/04C22C38/12C22C38/14
    • An ultra-high strength essentially boron-free steel having a tensile strength of at least about 900 MPa (130 ksi), a toughness as measured by Charpy V-notch impact test at −40° C. (−40° F.) of at least about 120 joules (90 ft-lbs), and a microstructure comprising predominantly fine-grained lower bainite, fine-grained lath martensite, or mixtures thereof, transformed from substantially unrecrystallized austenite grains and comprising iron and specified weight percentages of the additives: carbon, silicon, manganese, copper, nickel, niobium, vanadium, molybdenum, chromium, titanium, aluminum, calcium, Rare Earth Metals, and magnesium, is prepared by heating a steel slab to a suitable temperature; reducing the slab to form plate in one or more hot rolling passes in a first temperature range in which austenite recrystallizes; further reducing said plate in one or more hot rolling passes in a second temperature range below said first temperature range and above the temperature at which austenite begins to transform to ferrite during cooling; quenching said plate to a suitable Quench Stop Temperature; and stopping said quenching and allowing said plate to air cool to ambient temperature.
    • 具有至少约900MPa(130ksi)拉伸强度的超高强度基本上不含硼的钢,在-40℃(-40°F)下通过夏比V-缺口冲击试验测得的韧性 至少约120焦耳(90ft-lbs),以及由基本上未再结晶的奥氏体晶粒转化并且包含铁和特定重量百分比的添加剂的主要包含细粒度的下贝氏体,细粒状板条马氏体或其混合物的显微组织: 通过将钢坯加热到合适的温度来制备碳,硅,锰,铜,镍,铌,钒,钼,铬,钛,​​铝,钙,稀土金属和镁。 在奥氏体重结晶的第一温度范围内,在一个或多个热轧道中将板坯还原成板; 在低于所述第一温度范围的第二温度范围内并且高于在冷却期间奥氏体开始转变为铁素体的温度的一个或多个热轧道中进一步减少所述板; 将所述板淬火至合适的淬火停止温度; 并停止所述淬火并允许所述板空气冷却至环境温度。