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    • 7. 发明申请
    • CATALYST COMPOSITION FOR PRODUCTION OF FLEXIBLE POLYURETHANE FOAM
    • 用于生产柔性聚氨酯泡沫的催化剂组合物
    • US20100113634A1
    • 2010-05-06
    • US12528655
    • 2008-02-27
    • Katsumi TokumotoYutaka Tamano
    • Katsumi TokumotoYutaka Tamano
    • C08G18/18C08J9/00B01J31/02
    • C08G18/7621C08G18/161C08G18/168C08G18/1808C08G18/1825C08G18/2027C08G18/2063C08G18/3281C08G18/409C08G18/48C08G18/6688C08G18/7657C08G2101/0008C08G2101/005C08G2101/0083C08L83/00
    • To provide a catalyst composition for production of a flexible or semirigid polyurethane foam excellent in air permeability, and a method for producing a polyurethane foam by using it.A catalyst composition for production of a flexible polyurethane foam, which comprises (A) an amine compound of the following formula (1), and (B) an amine compound of the following formula (2) and/or the following formula (3), wherein the weight ratio of (A)/(B) is within a range of from 95/5 to 5/95: in the above formula (1), A is an oxygen atom or a nitrogen atom to which one methyl group is bonded, and R1 is a methyl group or a hydroxyethyl group; in the above formulae (2) and (3), each of R1, R2, R3, R4, R5, R6 and R7 which are independent of one another, is a hydrogen atom or a C1-6 saturated or unsaturated hydrocarbon group, R8 is a hydrogen atom, a methyl group, a methoxy group, a hydroxyl group, an amino group, a monomethylamino group, a monoethylamino group or a dimethylamino group, a is an integer of from 1 to 4, and each of m and n which are independent of each other, is an integer of from 0 to 4, provided that when one or more substituents selected from R1, R2 and R5 are not hydrogen atoms, R8 is an amino group, a monomethylamino group or a monoethylamino group, and any two substituents of from R1 to R8 may be optionally bonded via a carbon atom, an oxygen atom or a nitrogen atom to form a hetero ring.
    • 提供用于生产透气性优异的柔性或半刚性聚氨酯泡沫的催化剂组合物,以及通过使用聚氨酯泡沫塑料的方法。 一种用于生产软质聚氨酯泡沫的催化剂组合物,其包含(A)下式(1)的胺化合物和(B)下式(2)和/或下式(3)的胺化合物, 其中,上述式(1)中,(A)/(B)的重量比在95/5〜5/95的范围内,A是氧原子或一个甲基的氮原子 R 1为甲基或羟乙基; 在上述式(2)和(3)中,R 1,R 2,R 3,R 4,R 5,R 6和R 7彼此独立地为氢原子或C 1-6饱和或不饱和烃基,R 8 是氢原子,甲基,甲氧基,羟基,氨基,单甲基氨基,单乙基氨基或二甲基氨基,a为1〜4的整数,m和n分别为 如果一个或多个选自R 1,R 2和R 5的取代基不是氢原子,则R 8为氨基,单甲氨基或单乙氨基,任何 可以通过碳原子,氧原子或氮原子任意地键合从R 1至R 8的两个取代基以形成杂环。
    • 8. 发明授权
    • Amine catalyst for producing rigid polyurethane foam
    • 用于生产硬质聚氨酯泡沫的胺催化剂
    • US06384097B1
    • 2002-05-07
    • US09938490
    • 2001-08-27
    • Katsumi TokumotoYutaka TamanoShuichi Okuzono
    • Katsumi TokumotoYutaka TamanoShuichi Okuzono
    • C08G1818
    • C08G18/1875C08G2101/0008C08G2101/0025C08G2101/005C08G2105/02
    • An amine catalyst for production of a polyurethane and a polyisocyanurate is provided which comprises a quaternary ammonium compound represented by General Formula (1): where R1 to R6 are independently a linear or branched saturated hydrocarbon group of 1 to 4 carbon atoms; R7 and R8 are independently a linear or branched, saturated or unsaturated hydrocarbon group of 2 to 12 carbon atoms; n is a number of 0 to 3, provided that at n=0 any one of R1, R2 and R3, and R5 and/or R6 may be linked together to form a heterocycle, or at n=1, 2, or 3, R5 or R6 and R4 may be linked together to form a heterocycle; A is a carbonate group or an organic acid group; and X is number of 1 to 2. The catalyst has high activity in formation of polyurethane foams and polyisocyanurate foams, having less odor, and producing foams of high fire retardance, having high curability, high retarding effect, and low corrosiveness.
    • 提供了用于生产聚氨酯和聚异氰脲酸酯的胺催化剂,其包含由通式(1)表示的季铵化合物:其中R 1至R 6独立地为具有1至4个碳原子的直链或支链饱和烃基; R 7和R 8独立地是2至12个碳原子的直链或支链,饱和或不饱和的烃基; n是0至3的数,条件是在n = 0时,R 1,R 2和R 3以及R 5和/或R 6中的任何一个可以连接在一起形成杂环,或者n = 1,2或3, R5或R6和R4可以连接在一起形成杂环; A是碳酸酯基或有机酸基; X为1〜2的数量。催化剂形成聚氨酯泡沫和聚异氰脲酸酯泡沫体的气味较少,具有较少的气味,并产生高阻燃性,高固化性,高延迟效果和低腐蚀性的高阻燃性。
    • 10. 发明授权
    • Process for producing polyurethane and polyisocyanurate
    • 生产聚氨酯和聚异氰脲酸酯的方法
    • US06384177B1
    • 2002-05-07
    • US09938488
    • 2001-08-27
    • Katsumi TokumotoYutaka TamanoShuichi Okuzono
    • Katsumi TokumotoYutaka TamanoShuichi Okuzono
    • C08G1818
    • C08G18/1875C08G2101/0008C08G2101/0025C08G2101/005C08G2105/02
    • An amine catalyst for production of a polyurethane and a polyisocyanurate is provided which comprises a quaternary ammonium compound represented by General Formula (1): where R1 to R6 are independently a linear or branched saturated hydrocarbon group of 1 to 4 carbon atoms; R7 and R8 are independently a linear or branched, saturated or unsaturated hydrocarbon group of 2 to 12 carbon atoms; n is a number of 0 to 3, provided that at n=o any one of R1, R2 and R3, and R5 and/or R6 may be linked together to form a heterocycle, or at n=1, 2, or 3, R5 or R6 and R4 may be linked together to form a heterocycle; A is a carbonate group or an organic acid group; and X is number of 1 to 2. The catalyst has high activity in formation of polyurethane foams and polyisocyanurate foams, having less odor, and producing foams of high fire retardance, having high curability, high retarding effect, and low corrosiveness.
    • 提供了用于生产聚氨酯和聚异氰脲酸酯的胺催化剂,其包含由通式(1)表示的季铵化合物:其中R 1至R 6独立地为具有1至4个碳原子的直链或支链饱和烃基; R 7和R 8独立地是2至12个碳原子的直链或支链,饱和或不饱和的烃基; n是0至3的数,条件是在n = 0时,R 1,R 2和R 3中的任一个,以及R 5和/或R 6可以连接在一起形成杂环,或者n = 1,2或3, R5或R6和R4可以连接在一起形成杂环; A是碳酸酯基或有机酸基; X为1〜2的数量。催化剂形成聚氨酯泡沫和聚异氰脲酸酯泡沫体的气味较少,具有较少的气味,并产生高阻燃性,高固化性,高延迟效果和低腐蚀性的高阻燃性。