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    • 4. 发明授权
    • Melt-kneaded products, molded resin products, and production method thereof
    • 熔融捏合产品,模塑树脂产品及其制备方法
    • US07935417B2
    • 2011-05-03
    • US12028213
    • 2008-02-08
    • Hiroshi ShimizuYongjin Li
    • Hiroshi ShimizuYongjin Li
    • B32B5/16B29B7/90
    • C08J3/201C08J3/005C08J2321/00C08J2327/16Y10S977/742Y10S977/773Y10T428/25
    • A melt-kneading method for filling material and elastomer or resin, characterized in that a filling material constituted by a filler, and an elastomer or resin (thermoplastic resin or thermosetting resin), are introduced from a material introduction part at the end of a melt-kneading part having a cylinder with a screw and a heater, and the molten elastomer or resin and filling material constituted by a filler are kneaded under the conditions of 1000 to 3000 rpm in the rotation speed of the screw and 1500 to 4500 sec−1 in shear speed to feed the mixture from the rear edge to tip of the screw to be trapped in a space provided at the tip of the screw, after which the mixture is moved from the space to the rear edge of the screw through a hole provided at the center of the screw, with the cycle process performed for a specified period based on recirculation using the screw.
    • 一种用于填充材料和弹性体或树脂的熔融捏合方法,其特征在于,由填料构成的填充材料和弹性体或树脂(热塑性树脂或热固性树脂)在熔体末端的材料导入部分引入 - 具有螺杆和加热器的圆筒的中空部件和由填料构成的熔融弹性体或树脂和填充材料在螺杆的旋转速度为1000〜3000rpm的条件下混炼,并且在1500〜4500秒-1 在剪切速度下将混合物从后边缘到螺杆的尖端进入,以将其捕获在设置在螺钉尖端处的空间中,之后混合物通过提供的孔从螺钉的空间移动到后边缘 在螺杆的中心处,循环过程基于使用螺杆的循环进行一段指定的时间段。
    • 6. 发明授权
    • High-shear melt-kneader and method of high shearing
    • 高剪切熔融捏合机和高剪切方法
    • US09199393B2
    • 2015-12-01
    • US13147925
    • 2010-02-02
    • Hiroshi ShimizuYongjin LiYukio YoshizawaTakayuki TakahashiKen-ichi Toyoshima
    • Hiroshi ShimizuYongjin LiYukio YoshizawaTakayuki TakahashiKen-ichi Toyoshima
    • B29B7/28B29B7/14B29B7/88
    • B29B7/28B29B7/14B29B7/88
    • A high-shear melt-kneader includes a high-shear unit (20) having an internal feedback-type screw (23) configured to apply high-shear stress to a melted resin, resin pressure sensors (33) for configured to detect a front portion resin pressure in the vicinity of an inlet of the internal feedback-type screw and a rear portion resin pressure in the vicinity of an outlet, and a control device configured to appropriately control a material supplying amount, a material temperature, a kneading time, and a screw rotation speed according to pressure values detected by the sensors. The control device controls the conditions such that waveforms with the lapse of time of the front and rear portion resin pressures are similar to each other and show variation to a steady state after formation of a predetermined peak value, and the front and rear portion resin pressures form a predetermined pressure difference with the lapse of time. According to the high-shear melt-kneader, it is possible to improve high-shear efficiency, increase precision of nano dispersion of a material, and stably and finely disperse/mix internal structures of immiscible polymer blend-based, polymer/filler-based and polymer blend/filler-based materials to a nano level.
    • 高剪切熔融捏合机包括具有内部反馈型螺杆(23)的高剪切单元(20),该内部反馈型螺杆(23)被配置为向熔融树脂施加高剪切应力;树脂压力传感器(33),用于检测前端 在内反馈型螺杆的入口附近的部分树脂压力和出口附近的后部树脂压力,以及控制装置,其被配置为适当地控制材料供给量,材料温度,混炼时间, 以及根据由传感器检测的压力值的螺杆转速。 控制装置控制使得前后树脂压力经过时间的波形彼此相似的条件,并且在形成预定峰值之后显示到稳定状态的变化,并且前部和后部树脂压力 随着时间的流逝形成预定的压力差。 根据高剪切熔融捏合机,可以提高高剪切效率,提高材料的纳米分散体的精度,并且可以稳定和细分散/混合不混溶聚合物共混物,基于聚合物/填料的内部结构 和聚合物共混物/填料基材料达到纳米级。