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1. 发明授权

US5994428A Storage-stable, silane-modified core-shell copolymers 有权
标题翻译：储存稳定的硅烷改性的核 - 壳共聚物
公开(公告)号：US5994428A
公开(公告)日：1999-11-30
申请号：US128921
申请日：1998-08-04
申请人： Hermann Lutz , Theo Mayer , Thomas Bastelberger
发明人： Hermann Lutz , Theo Mayer , Thomas Bastelberger
IPC分类号： C08F2/38 , C08F265/04 , C08F265/06 , C08F291/00 , C08F275/00
CPC分类号： C08F265/06 , C08F265/04 , C08F291/00
摘要： Storage-stable, silane-modified core-shell copolymers are provided comprising a shell-forming copolymer I ofa) from 70 to 95% by weight, based on the overall weight of the shell, of acrylic and/or methacrylic C.sub.1 - to C.sub.10 -alkyl esters of which from 20 to 80% by weight have a water solubility of not more than 2 g/l and from 80 to 20% by weight, based in each case on the comonomers a), have a water solubility of at least 10 g/l, andb) from 5 to 30% by weight, based on the overall weight of the shell, of one or more ethylenically unsaturated, functional and water-soluble monomers including a proportion of from 25 to 100% by weight, based on the comonomers b), of unsaturated carboxylic acids, and a core-forming copolymer II of one or more monomers c) from the group of the vinyl esters, monoolefinically unsaturated mono- or dicarboxylic esters, vinylaromatic compounds, olefins, 1,3-dienes and vinyl halides,wherein the shell contains no silane compounds and the core comprises one or more silane compounds d) from the group of the mercaptosilanes alone or in combination with olefinically unsaturated, hydrolyzable silicon compounds.
摘要翻译：提供了储存稳定的硅烷改性的核 - 壳共聚物，其包含a）70至95重量％的壳形共聚物I，基于壳的总重量，丙烯酸和/或甲基丙烯酸C 1 -C 10 - 烷基酯的20至80重量％水溶性不超过2克/升和80至20重量％，基于共聚单体a），其水溶性至少为 10g / l，和b）5至30重量％，基于壳的总重量，一种或多种烯键式不饱和官能和水溶性单体，其包含25至100重量％的比例，基于共聚单体b）的不饱和羧酸，以及一种或多种单体的成核共聚物II，c）来自乙烯基酯，单烯属不饱和单或二羧酸酯，乙烯基芳族化合物，烯烃，1,3 二烯和卤乙烯，其中所述壳不含硅烷化合物，并且所述核包含一个或多个Si 泳道化合物d）单独的巯基硅烷基团或与烯属不饱和的可水解的硅化合物组合。

2. 发明授权

US06590022B1 Process for preparing protective-colloid-stabilized vinylaromatic-1,3-diene copolymers 有权
标题翻译：制备保护胶体稳定的乙烯基芳族-1,3-二烯共聚物的方法
公开(公告)号：US06590022B1
公开(公告)日：2003-07-08
申请号：US09555591
申请日：2000-05-21
申请人： Thomas Bastelberger , Reinhard Haerzschel , Theo Mayer , Peter Weitzel , Peter Ball
发明人： Thomas Bastelberger , Reinhard Haerzschel , Theo Mayer , Peter Weitzel , Peter Ball
IPC分类号： C08F216
CPC分类号： C08F236/10 , C08F2/20
摘要： A method is provided for producing protective colloid-stabilized vinyl aromatic-1.3-diene-copolymers in the form of their aqueous polymer dispersions or in the form of a powder which can be re-dispersed in water, by emulsion-polymerizing a mixture containing at least one vinyl aromatic and at least one 1,3-diene in the presence of a protective colloid and optionally, drying the resulting polymer dispersions. In the method part of the protective colloid is provided straightaway and part is metered.
摘要翻译：提供了一种制备保护性胶体稳定的乙烯基芳族-1,3-二烯共聚物的形式，其聚合物水分散体形式或以可再分散在水中的粉末形式，通过将含有至少一种乙烯基芳族化合物和至少一种1,3-二烯在保护胶体存在下，任选地干燥所得聚合物分散体。在方法中，保护胶体的一部分直接提供，部分是计量的。

3. 发明授权

US06300403B1 Method for producing polymers stabilized with protective colloids 有权
标题翻译：制备保护胶体稳定聚合物的方法
公开(公告)号：US06300403B1
公开(公告)日：2001-10-09
申请号：US09424193
申请日：1999-11-19
申请人： Theo Mayer , Hans-Peter Weitzel , Reinhard Haerzschel , Thomas Bastelberger
发明人： Theo Mayer , Hans-Peter Weitzel , Reinhard Haerzschel , Thomas Bastelberger
IPC分类号： C08F220
CPC分类号： C08F2/24 , C08F6/24 , C08F236/10 , C08F2/20
摘要： A method for producing protective-colloid-stabilized polymers in the form of their aqueous polymer dispersions or in the form of powders which can be re-dispersed in water, wherein one or several monomers from the group made up of vinyl aromatics, 1.3 dienes, acrylic acid esters and methacrylic acid esters of alcohols with 1 to 15 C-atoms are polymerized in the presence of a combination of protective colloids consisting of one or several protective colloids from the group of hydrophobically modified, partly saponified polyvinyl esters which produce a surface tension of ≦40 mN/m as a 2% aqueous solution, and one or several protective colloids which produce a surface tension of >40 mN/m as a 2% aqueous solution.
摘要翻译：一种制备其聚合物水分散体形式的保护胶体稳定的聚合物的方法，或以可再分散在水中的粉末形式的方法，其中一种或多种由乙烯基芳族化合物，1,3-二烯，丙烯酸酯和具有1至15个C原子的醇的甲基丙烯酸酯在由一种或几种由疏水改性的部分皂化聚乙烯基酯组成的保护胶体组合的存在下聚合，产生表面张力作为2％水溶液<= 40mN / m，作为2％水溶液产生表面张力> 40mN / m的一种或几种保护胶体。

4. 发明授权

US5708093A Core/shell copolymer dispersion whose shell comprises hydrolyzable organosilicon comonomers 失效
标题翻译：壳/壳共聚物分散体，其壳包含可水解的有机硅共聚单体
公开(公告)号：US5708093A
公开(公告)日：1998-01-13
申请号：US505354
申请日：1995-10-02
申请人： Thomas Bastelberger , Hermann Lutz , Peter Heiling
发明人： Thomas Bastelberger , Hermann Lutz , Peter Heiling
IPC分类号： C08F230/08 , C04B26/32 , C08F2/24 , C08F30/08 , C08F291/00 , C09D151/00 , C09J151/00 , E04F13/02
CPC分类号： E04F13/02 , C04B26/32 , C08F291/00 , C09D151/003 , C09J151/003 , Y10S525/902
摘要： The invention relates to core/shell copolymer dispersions whose shell comprises hydrolyzable organosilicon comonomers, the shell consisting of a copolymer comprising, a) from 70 to 95% by weight of acrylic and/or methacrylic C.sub.1 to C.sub.10 alkyl esters of which from 20 to 80% by weight, based on the overall weight of a), have a water-solubility of not more than 2 g/l and from 80 to 20% by weight, based on the overall weight of a), have a water-solubility of at least 10 g/l, b) from 5 to 25% by weight of one or more ethylenically unsaturated, functional and water-soluble monomers including a proportion of from 25 to 100% by weight, based on the overall weight of b), of unsaturated carboxylic acids, and c) from 0.01 to 10% by weight of one or more olefinically unsaturated, hydrolyzable silicon compounds of the general formula R.sup.1 --Si(OR.sup.2).sub.3, and whose core, making up a proportion of from 75 to 98% by weight of the overall weight of the core/shell copolymer, consists of a polymer comprising d) one or more comonomers from the group consisting of vinyl esters, acrylic and/or methacrylic esters, vinyl chloride, vinylaromatic compounds and ethylene.
摘要翻译： PCT No.PCT / EP94 / 00624 Sec。 371 1995年10月2日日期 102（e）日期1995年10月2日PCT 1994年3月3日PCT公布。公开号WO94 / 20556 日期1994年9月15日本发明涉及其壳包含可水解有机硅共聚单体的壳/壳共聚物分散体，壳由共聚物组成，该共聚物包含：a）70至95重量％的丙烯酸和/或甲基丙烯酸C1至C10烷基酯其基于a）的总重量为20至80重量％，基于a）的总重量具有不超过2g / l和80至20重量％的水溶性，具有至少10g / l的水溶性，b）5至25重量％的一种或多种烯键式不饱和官能和水溶性单体，其包含基于总体的25至100重量％的比例 b）的不饱和羧酸的重量，和c）0.01至10重量％的一种或多种通式R 1 -Si（OR 2）3的烯属不饱和可水解的硅化合物，其核心占组成比例的核/壳共聚物的总重量的75-98重量％由聚醚组成 r包含d）一种或多种由乙烯基酯，丙烯酸和/或甲基丙烯酸酯组成的组的共聚单体，氯乙烯，乙烯基芳族化合物和乙烯。

5. 发明授权

US08795842B2 Fiber-containing pasty construction materials 有权
标题翻译：含纤维的糊状建筑材料
公开(公告)号：US08795842B2
公开(公告)日：2014-08-05
申请号：US13321430
申请日：2010-05-10
申请人： Stefan Ingrisch , Thomas Bastelberger , Jürgen Bezler , Jakob Mühlthaler
发明人： Stefan Ingrisch , Thomas Bastelberger , Jürgen Bezler , Jakob Mühlthaler
IPC分类号： C08L31/04 , C09D133/06 , C04B24/26
CPC分类号： C04B28/02 , C04B26/02 , C04B26/04 , C04B26/06 , C04B26/08 , C04B2103/0065 , C04B2111/00482 , C04B2111/00672 , C04B2111/1037 , C04B2111/60 , Y02W30/97 , Y10T428/31855 , C04B20/0048 , C04B14/042 , C04B14/06 , C04B14/28 , C04B14/303 , C04B16/0658 , C04B18/24 , C04B18/248 , C04B20/0076 , C04B24/383 , C04B2103/50 , C04B2103/67 , C04B24/2641
摘要： The invention relates to fiber-containing pasty construction materials, containing a) one or more fillers, b) optionally additives, characterized in that they contain c) fibers, d) one or more polymers based on one or more ethylenically unsaturated monomers, having a glass transition temperature Tg of ≧−15° C., e) ≦5% by weight hydraulically setting binders and f) water, wherein the information in % by weight relates to the dry weight of the fiber-containing pasty construction materials. The invention also relates to a process for producing a reinforcing composition free of woven reinforcing fabrics.
摘要翻译：本发明涉及含纤维的糊状结构材料，其包含a）一种或多种填料，b）任选的添加剂，其特征在于它们含有c）纤维，d）一种或多种基于一种或多种烯属不饱和单体的聚合物，其具有玻璃化转变温度Tg≥-15℃，e）和nlE; 5％（重量）水硬定型粘合剂和f）水，其中以重量％计的信息涉及含纤维的糊状结构材料的干重。本发明还涉及一种生产不含编织增强织物的增强组合物的方法。

6. 发明授权

US07972424B2 Hydrophobing additive 有权
标题翻译：疏水添加剂
公开(公告)号：US07972424B2
公开(公告)日：2011-07-05
申请号：US10557658
申请日：2004-05-13
申请人： Thomas Bastelberger , Reinhard Härzschel , Franz Jodlbauer
发明人： Thomas Bastelberger , Reinhard Härzschel , Franz Jodlbauer
IPC分类号： C08L23/00
CPC分类号： C04B40/0042 , C04B24/085 , C04B2103/0057 , C04B2103/65 , C04B14/26 , C04B24/2623 , C04B24/42
摘要： Hydrophobicizing agents which are easily admixed with construction chemical products are prepared by providing a solution of a protective colloid and adding thereto a fatty acid compound sensitive to high pH environments, optionally, a hydrophobicizing organosilicon compound, and drying the resulting aqueous mixture.
摘要翻译：通过提供保护胶体的溶液并向其中加入对高pH环境敏感的脂肪酸化合物，任选的疏水化有机硅化合物，并干燥所得的含水混合物，制备容易与构建化学产品混合的疏水剂。

7. 发明申请

US20070155862A1 Polyvinyl-Alcohol-Stabilized Redispersible Powders With Plasticized Properties 审中-公开
标题翻译：具有增塑性能的聚乙烯醇稳定的可再分散粉末
公开(公告)号：US20070155862A1
公开(公告)日：2007-07-05
申请号：US11686037
申请日：2007-03-14
申请人： Reinhard Haerzschel , Thomas Bastelberger , Ulf Dietrich , Armin Hoffmann
发明人： Reinhard Haerzschel , Thomas Bastelberger , Ulf Dietrich , Armin Hoffmann
IPC分类号： C04B24/26
CPC分类号： C08J3/122 , C04B24/163 , C04B24/2623 , C04B24/2641 , C04B24/2676 , C04B24/2688 , C04B2103/0057 , C04B2103/30 , C04B2111/62 , C04B2111/70 , C08L29/04
摘要： Polyvinyl-alcohol-stabilized redispersible powders which have plasticizing properties are obtained by drying polyvinyl-alcohol-stabilized aqueous dispersions of polymers of one or more monomers from the group of vinyl esters of optionally branched C1-18 alkylcarboxylic acids, (meth)acrylic esters of optionally branched C1-15 alcohols, dienes, olefins, vinylaromatics and vinylhalides, in the presence of a copolymer formed from a) one or more monomers from the group of ethylenically unsaturated monocarboxylic acids, ethylenically unsaturated dicarboxylic acids and their anhydrides, each having 4 to 8 carbon atoms, and salts thereof, b) one or more ethylenically unsaturated compounds containing sulfonic, sulfuric, and/or phosphonic acid groups, and salts thereof, and c) one or more monomers from the group consisting of vinyl esters of optionally branched C1-18 alkylcarboxylic acids and (meth)acrylic esters of optionally branched C1-15 alcohols.
摘要翻译：具有增塑性能的聚乙烯醇稳定的可再分散粉末通过干燥聚乙烯醇稳定的一种或多种单体的聚合物的水分散体获得，该水分散体由任选支链C 1-18烷基羧酸的乙烯基酯组酸，（甲基）丙烯酸酯，任选支链C 1-15醇，二烯，烯烃，乙烯基芳烃和卤代乙烯，在由以下组成的共聚物存在下形成：a）一种或多种烯属的单体不饱和一元羧酸，烯键式不饱和二羧酸及其酸酐，各自具有4至8个碳原子，及其盐，b）一种或多种含有磺酸，硫酸和/或膦酸基团的烯属不饱和化合物及其盐，以及c ）一种或多种由任选支链C 1-18烷基羧酸的乙烯基酯和任选支链C 1-15醇的（甲基）丙烯酸酯组成的组中的单体。

8. 发明授权

US09593046B2 Use of polypropylene oxide or ethylene oxide-propylene oxide copolymers in combination with starch ether derivatives as additive in dry mortar compositions 有权
标题翻译：聚丙烯氧化物或环氧乙烷 - 环氧丙烷共聚物与淀粉醚衍生物的组合用作干砂浆组合物中的添加剂
公开(公告)号：US09593046B2
公开(公告)日：2017-03-14
申请号：US14390595
申请日：2012-04-05
申请人： Thomas Bastelberger , Reinhard Härzschel , Xi Zhang
发明人： Thomas Bastelberger , Reinhard Härzschel , Xi Zhang
IPC分类号： C04B24/32 , C04B24/28 , C04B24/38 , C09D103/08 , C09J103/08 , C08L3/08 , C08L71/02 , C09J171/02 , C04B28/02 , C04B40/00 , C04B24/26 , C08L29/04 , C08L31/04 , C04B111/00 , C04B111/28 , C04B111/72 , C04B103/00
CPC分类号： C04B24/32 , C04B24/2623 , C04B24/28 , C04B24/38 , C04B28/02 , C04B40/0042 , C04B2103/0057 , C04B2111/00482 , C04B2111/00637 , C04B2111/28 , C04B2111/72 , C08L3/08 , C08L29/04 , C08L31/04 , C08L71/02 , C08L2205/035 , C09D103/08 , C09J103/08 , C09J171/02 , C04B24/2641 , C04B40/0608 , C04B24/2676 , C04B24/2682 , C04B24/2688
摘要： The use of an adhesion-promoting additive combination composed of one or more polyalkylenoxides out of the group comprising polypropylene oxides and ethylene oxide-propylene oxide copolymers, and of one or more starch ether derivatives out of the group comprising carboxyalkyl starch ethers and their alkali salts, and hydroxyalkyl starch ethers, in mortar compositions comprising mineral binders and water-redispersible polymer powders.
摘要翻译：由包含聚氧丙烯和环氧乙烷 - 环氧丙烷共聚物的组中的一种或多种聚亚烷基氧化物组成的粘合促进添加剂组合以及由羧基烷基淀粉醚及其碱金属盐组成的组中的一种或多种淀粉醚衍生物和羟烷基淀粉醚，其包含矿物粘合剂和水可再分散聚合物粉末的砂浆组合物。

9. 发明申请

US20120071588A1 Fiber-Containing Pasty Construction Materials 有权
标题翻译：含纤维包装的建筑材料
公开(公告)号：US20120071588A1
公开(公告)日：2012-03-22
申请号：US13321430
申请日：2010-05-10
申请人： Stefan Ingrisch , Thomas Bastelberger , Jürgen Bezler , Jakob Mühlthaler
发明人： Stefan Ingrisch , Thomas Bastelberger , Jürgen Bezler , Jakob Mühlthaler
IPC分类号： C08L31/04 , C09D133/06 , C04B24/26 , C09J133/06 , C09J131/04 , C08L33/06 , C09D131/04
CPC分类号： C04B28/02 , C04B26/02 , C04B26/04 , C04B26/06 , C04B26/08 , C04B2103/0065 , C04B2111/00482 , C04B2111/00672 , C04B2111/1037 , C04B2111/60 , Y02W30/97 , Y10T428/31855 , C04B20/0048 , C04B14/042 , C04B14/06 , C04B14/28 , C04B14/303 , C04B16/0658 , C04B18/24 , C04B18/248 , C04B20/0076 , C04B24/383 , C04B2103/50 , C04B2103/67 , C04B24/2641
摘要： The invention relates to fiber-containing pasty construction materials, containing a) one or more fillers, b) optionally additives, characterized in that they contain c) fibers, d) one or more polymers based on one or more ethylenically unsaturated monomers, having a glass transition temperature Tg of ≧−15° C., e) ≦5% by weight hydraulically setting binders and f) water, wherein the information in % by weight relates to the dry weight of the fiber-containing pasty construction materials.
摘要翻译：本发明涉及含纤维的糊状结构材料，其包含a）一种或多种填料，b）任选的添加剂，其特征在于它们含有c）纤维，d）一种或多种基于一种或多种烯属不饱和单体的聚合物，其具有玻璃化转变温度Tg≥-15℃，e）和nlE; 5％（重量）水硬定型粘合剂和f）水，其中以重量％计的信息涉及含纤维的糊状结构材料的干重。

10. 发明授权

US07250468B2 Polyvinyl-alcohol-stabilized redispersible powders with plasticizing properties 有权
标题翻译：具有增塑性能的聚乙烯醇稳定的可再分散粉末
公开(公告)号：US07250468B2
公开(公告)日：2007-07-31
申请号：US10819444
申请日：2004-04-07
申请人： Reinhard Harzschel , Thomas Bastelberger , Ulf Dietrich , Armin Hoffmann
发明人： Reinhard Harzschel , Thomas Bastelberger , Ulf Dietrich , Armin Hoffmann
IPC分类号： C08L29/04
CPC分类号： C08J3/122 , C04B24/163 , C04B24/2623 , C04B24/2641 , C04B24/2676 , C04B24/2688 , C04B2103/0057 , C04B2103/30 , C04B2111/62 , C04B2111/70 , C08L29/04
摘要： Polyvinyl-alcohol-stabilized redispersible powders which have plasticizing properties are obtained by drying polyvinyl-alcohol-stabilized aqueous dispersions of polymers of one or more monomers from the group of vinyl esters of optionally branched C1-18 alkylcarboxylic acids, (meth)acrylic esters of optionally branched C1-15 alcohols, dienes, olefins, vinylaromatics and vinylhalides, in the presence of a copolymer formed from a) one or more monomers from the group of ethylenically unsaturated monocarboxylic acids, ethylenically unsaturated dicarboxylic acids and their anhydrides, each having 4 to 8 carbon atoms, and salts thereof, b) one or more ethylenically unsaturated compounds containing sulfonic, sulfuric, and/or phosphonic acid groups, and salts thereof, and c) one or more monomers from the group consisting of vinyl esters of optionally branched C1-18 alkylcarboxylic acids and (meth)acrylic esters of optionally branched C1-15 alcohols.
摘要翻译：具有增塑性能的聚乙烯醇稳定的可再分散粉末通过干燥聚乙烯醇稳定的一种或多种单体的聚合物的水分散体获得，该水分散体由任选支链C 1-18烷基羧酸的乙烯基酯组酸，（甲基）丙烯酸酯，任选支链C 1-15醇，二烯，烯烃，乙烯基芳烃和卤代乙烯，在由以下组成的共聚物存在下形成：a）一种或多种烯属的单体不饱和一元羧酸，烯键式不饱和二羧酸及其酸酐，各自具有4至8个碳原子，及其盐，b）一种或多种含有磺酸，硫酸和/或膦酸基团的烯属不饱和化合物及其盐，以及c ）一种或多种由任选支链C 1-18烷基羧酸的乙烯基酯和任选支链C 1-15醇的（甲基）丙烯酸酯组成的组中的单体。

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