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    • 1. 发明授权
    • Reduction of acidic emissions from combustion of sulfur-laden fuels
    • 减少含硫燃料燃烧产生的酸性排放
    • US5024171A
    • 1991-06-18
    • US496872
    • 1990-03-19
    • Henry V. KrigmontEverett L. Coe, Jr.Barry J. Southam
    • Henry V. KrigmontEverett L. Coe, Jr.Barry J. Southam
    • B01D53/50F23J15/00
    • B01D53/50F23J15/006F23G2207/106F23G2207/60F23J2215/20F23J2217/102
    • The sulfur trioxide in the combustion gas stream of a power plant is reacted with injected ammonia to produce a solid ammonium sulfate that is captured, and not released to the atmosphere. A feedforward signal indicative of the total mass flow of sulfur trioxide is determined as the product of the measured boiler load and the sulfur trioxide content of the combustion gas, as measured prior to the addition of ammonia. The ammonia mass flow injection rate is preferably at a normal stoichiometric ratio of from about 1.0 to about 1.1 relative to the sulfur trioxide mass flow rate (that is, from about 2.0 to about 2.2 times the molar mass flow rate of the sulfur trioxide), avoiding the production of ammonia bisulfate. The ammonia content of the combustion gas stream is measured downstream of the location at which ammonia is added. Based upon this feedback measurement, the amount of ammonia added is adjusted to be just sufficient to react with all of the sulfur trioxide, but not in such excess as to be environmentally detrimental.
    • 发电厂燃烧气流中的三氧化硫与注入的氨反应生成固体硫酸铵,其被捕获而不被释放到大气中。 表示三氧化硫的总质量流量的前馈信号被确定为在加入氨之前测量的测量的锅炉负荷和燃烧气体的三氧化硫含量的乘积。 氨质量流量注入速率优选相对于三氧化硫质量流量(即,三氧化硫的摩尔质量流量的约2.0至约2.2倍)为约1.0至约1.1的正常化学计量比, 避免生产氨硫酸氢铵。 在添加氨的位置的下游测量燃烧气体流的氨含量。 基于这种反馈测量,加入的氨的量被调整为恰好足以与所有的三氧化硫反应,但不是过量的,因为对环境有害。